CN104039841B - 催化剂组分 - Google Patents

催化剂组分 Download PDF

Info

Publication number
CN104039841B
CN104039841B CN201280064680.2A CN201280064680A CN104039841B CN 104039841 B CN104039841 B CN 104039841B CN 201280064680 A CN201280064680 A CN 201280064680A CN 104039841 B CN104039841 B CN 104039841B
Authority
CN
China
Prior art keywords
group
formula
compound
alkyl
catalyst
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201280064680.2A
Other languages
English (en)
Chinese (zh)
Other versions
CN104039841A (zh
Inventor
乔基·基皮阿尼
蒂莫·莱诺宁
彼得·德尼弗
雷约·姆拉瑞
托米·克罗格罗斯
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Borealis AS
Original Assignee
Borealis AS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Borealis AS filed Critical Borealis AS
Publication of CN104039841A publication Critical patent/CN104039841A/zh
Application granted granted Critical
Publication of CN104039841B publication Critical patent/CN104039841B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/06—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen
    • C08F4/16—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen of silicon, germanium, tin, lead, titanium, zirconium or hafnium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/52—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from boron, aluminium, gallium, indium, thallium or rare earths

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
CN201280064680.2A 2011-12-30 2012-12-19 催化剂组分 Active CN104039841B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP11196166.0A EP2610273B1 (en) 2011-12-30 2011-12-30 Catalyst component
EP11196166.0 2011-12-30
PCT/EP2012/076053 WO2013098139A1 (en) 2011-12-30 2012-12-19 Catalyst component

Publications (2)

Publication Number Publication Date
CN104039841A CN104039841A (zh) 2014-09-10
CN104039841B true CN104039841B (zh) 2017-02-22

Family

ID=47522535

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201280064680.2A Active CN104039841B (zh) 2011-12-30 2012-12-19 催化剂组分

Country Status (8)

Country Link
US (2) US20140378298A1 (https=)
EP (1) EP2610273B1 (https=)
JP (1) JP5992534B2 (https=)
KR (1) KR101688709B1 (https=)
CN (1) CN104039841B (https=)
ES (1) ES2665889T3 (https=)
IN (1) IN2014DN05988A (https=)
WO (1) WO2013098139A1 (https=)

Families Citing this family (59)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2610274A1 (en) 2011-12-30 2013-07-03 Borealis AG Propylene random copolymer
US8575283B1 (en) * 2012-06-28 2013-11-05 Formosa Plastics Corporation, U.S.A. Heterocyclic organic compounds as electron donors for polyolefin catalysts
ES2653868T3 (es) * 2012-12-21 2018-02-09 Borealis Ag Procatalizador de Ziegler Natta soportado para la polimerización de etileno
ES2615499T3 (es) 2012-12-21 2017-06-07 Borealis Ag Procedimiento para la producción de un procatalizador de Ziegler-Natta para la polimerización de etileno
KR101787231B1 (ko) * 2013-06-03 2017-10-18 루머스 노보렌 테크놀로지 게엠베하 고성능 지글러-나타 촉매 시스템, 그 촉매 시스템의 제조 방법 및 용도
ES2651456T3 (es) 2013-08-14 2018-01-26 Borealis Ag Composición de propileno con mejor resistencia al impacto a baja temperatura
MX2016001930A (es) 2013-08-21 2016-05-26 Borealis Ag Composicion de poliolefina de alto flujo con alta rigidez y tenacidad.
MX2016001705A (es) 2013-08-21 2016-05-18 Borealis Ag Composicion de poliolefina de alto flujo con alta rigidez y tenacidad.
PT2853563T (pt) 2013-09-27 2016-07-14 Borealis Ag Filmes adequados para processamento de bopp a partir de polímeros com xs elevada e tm elevado
ES2568615T3 (es) 2013-10-11 2016-05-03 Borealis Ag Película para etiquetas orientada en la dirección de la máquina
EP2865713B1 (en) 2013-10-24 2016-04-20 Borealis AG Blow molded article based on bimodal random copolymer
ES2661108T3 (es) 2013-10-24 2018-03-27 Borealis Ag Homopolímero de polipropileno de bajo punto de fusión con alto contenido de regioerrores y alto peso molecular
EP3063185B9 (en) 2013-10-29 2017-11-15 Borealis AG Solid single site catalysts with high polymerisation activity
MX368147B (es) 2013-11-22 2019-09-20 Borealis Ag Homopolímero de propileno de baja emisión con alto flujo de masa fundida.
WO2015082379A1 (en) 2013-12-04 2015-06-11 Borealis Ag Phthalate-free pp homopolymers for meltblown fibers
CN105980457B (zh) 2013-12-18 2019-03-22 博里利斯股份公司 具有改善的刚性/韧性平衡的bopp膜
EP3094660B1 (en) 2014-01-17 2018-12-19 Borealis AG Process for preparing propylene/1-butene copolymers
US10100186B2 (en) 2014-02-06 2018-10-16 Borealis Ag Soft and transparent impact copolymers
WO2015117958A1 (en) 2014-02-06 2015-08-13 Borealis Ag Soft copolymers with high impact strength
EP2907841A1 (en) 2014-02-14 2015-08-19 Borealis AG Polypropylene composite
ES2659731T3 (es) 2014-05-20 2018-03-19 Borealis Ag Composición de polipropileno para aplicaciones en interiores de automóviles
EP3015503A1 (en) 2014-10-27 2016-05-04 Borealis AG Heterophasic polypropylene with improved stiffness/impact balance
CA2964654C (en) 2014-10-27 2019-03-12 Borealis Ag Heterophasic polypropylene with improved impact strength/stiffness balance, improved powder flowability, reduced emissions and low shrinkage
US9593184B2 (en) * 2014-10-28 2017-03-14 Formosa Plastics Corporation, Usa Oxalic acid diamides as modifiers for polyolefin catalysts
CN107108803B (zh) * 2014-12-18 2021-03-16 博里利斯股份公司 齐格勒-纳塔催化剂及其制备
CN107075020B (zh) 2014-12-22 2020-07-24 博里利斯股份公司 用于制备聚丙烯的方法
CN112979842B (zh) * 2015-02-05 2022-11-11 博里利斯股份公司 用于生产聚乙烯的方法
BR112017022651B1 (pt) 2015-06-12 2021-11-16 Borealis Ag Processo para a preparação de composições de polímero de propileno
EP3170864B1 (en) 2015-11-17 2018-10-17 Borealis AG High flow tpo composition with excellent balance in mechanical properties for automotive interior
US10633463B2 (en) 2015-12-31 2020-04-28 Braskem America, Inc. Non-phthalate catalyst system and its use in the polymerization of olefins
WO2017129721A1 (en) 2016-01-29 2017-08-03 Borealis Ag Heterophasic propylene copolymer with low shrinkage
KR102113467B1 (ko) 2016-03-04 2020-05-22 보레알리스 아게 개선된 강성/충격 균형을 갖는 고 유동 헤테로상 폴리올레핀 조성물
EP3255071B1 (en) 2016-06-06 2024-02-14 Borealis AG Polypropylene composition with improved heat resistance
ES2749861T3 (es) 2016-06-13 2020-03-24 Borealis Ag Bandas sopladas por fusión de alta calidad con propiedades de barrera mejoradas
EP3260489B1 (en) 2016-06-24 2019-12-25 Borealis AG Novel polypropylene compositions with low fogging
ES3046758T3 (en) 2016-06-28 2025-12-02 Borealis Gmbh Soft and transparent polypropylene composition
JP6742447B2 (ja) 2016-08-03 2020-08-19 ボレアリス エージー 繊維補強ポリプロピレン複合材料
US11427660B2 (en) 2016-08-17 2022-08-30 Formosa Plastics Corporation, Usa Organosilicon compounds as electron donors for olefin polymerization catalysts and methods of making and using same
ES2713267T3 (es) 2016-10-17 2019-05-20 Borealis Ag Compuesto de polipropileno reforzado con fibra
ES2952512T3 (es) 2016-12-15 2023-10-31 Borealis Ag Composición de polipropileno con excelente adhesión de la pintura
US11230637B2 (en) 2017-04-04 2022-01-25 Borealis Ag Soft polypropylene composition with improved properties
EP3421537B1 (en) 2017-06-29 2023-08-02 Borealis AG Polypropylene composition with outstanding impact performance
EP3421538B1 (en) 2017-06-30 2021-03-17 Borealis AG Polyolefin composition with improved surface appearance
PL3652247T5 (pl) 2017-07-14 2024-12-09 Borealis Ag Kompozycja polipropylenowa
ES2886432T3 (es) 2017-11-28 2021-12-20 Borealis Ag Composición de polímero con adherencia de la pintura mejorada
EP3489296B1 (en) 2017-11-28 2021-09-01 Borealis AG Polymer composition with improved paint adhesion
ES2837424T3 (es) 2017-12-05 2021-06-30 Borealis Ag Composición de polipropileno reforzada con fibra
EP3495423B1 (en) 2017-12-05 2021-03-03 Borealis AG Article comprising a fiber reinforced polypropylene composition
CA3106413A1 (en) 2018-07-19 2020-01-23 Borealis Ag Process for the preparation of an uhmwpe homopolymer
CN114585654B (zh) 2019-10-04 2023-11-07 北欧化工公司 用于烯烃聚合的齐格勒-纳塔催化剂
WO2021064083A1 (en) 2019-10-04 2021-04-08 Borealis Ag Ziegler-natta catalysts for olefin polymerization
CN114599687A (zh) * 2019-10-04 2022-06-07 北欧化工公司 用于烯烃聚合的齐格勒-纳塔催化剂
CN114466872B (zh) 2019-10-04 2024-01-30 北欧化工公司 用于烯烃聚合的齐格勒纳塔催化剂
EP3892653A1 (en) * 2020-04-09 2021-10-13 Borealis AG (co)polymerization of ethylene
WO2023180266A1 (en) 2022-03-23 2023-09-28 Borealis Ag Polypropylene composition for automotive applications
EP4375328A1 (en) 2022-11-23 2024-05-29 Borealis AG Polypropylene composition for automotive applications
US20250109218A1 (en) 2023-09-29 2025-04-03 Formosa Plastics Corporation, U.S.A. Method for preparing catalyst component for polymerization of polyolefin without the use of internal electron donors
EP4527884A1 (en) 2023-09-20 2025-03-26 Borealis AG Polypropylene composition for automotive applications
WO2025202314A1 (en) 2024-03-27 2025-10-02 Borealis Gmbh Polyolefin composition comprising polypropylene polymers and a blend of a plastic material comprising polypropylene and polyethylene

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1170003A (zh) * 1996-06-10 1998-01-14 三井石油化学工业株式会社 固体钛催化剂组分及制备,含该催化剂组分的催化剂及应用
CN1247625C (zh) * 2001-06-20 2006-03-29 玻利阿黎斯聚合物有限公司 烯烃聚合催化剂组分的制备方法
CN101080271A (zh) * 2004-12-17 2007-11-28 弗纳技术股份有限公司 可用于生产聚烯烃催化剂的可溶性镁络合物和由此生产的催化剂

Family Cites Families (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3471099B2 (ja) 1994-11-25 2003-11-25 昭和電工株式会社 オレフィン重合用触媒担体の製造方法
US5955396A (en) 1995-10-17 1999-09-21 Bp Amoco Corporation Morphology-controlled olefin polymerization catalyst formed from an emulsion
JP3824738B2 (ja) * 1996-06-10 2006-09-20 三井化学株式会社 オレフィン重合用固体状チタン触媒成分の製造方法
ATE234310T1 (de) 1997-12-23 2003-03-15 Borealis Tech Oy Magnesium-,halogen- und alkoxy-enthaldendes produkt
FI981718L (fi) 1998-08-07 2000-02-08 Borealis As Katalysaattorikomponentti, joka käsittää magnesiumia, titaania, halogeenia ja elektrodonorin, sen valmistus ja käyttö
FI981717A7 (fi) 1998-08-07 2000-02-08 Borealis As Katalysaattorikomponentti, joka käsittää magnesiumia, titaania, halogeenia ja elektronidonorin, sen valmistus ja käyttö
CN1137155C (zh) * 1999-12-06 2004-02-04 中国石油化工集团公司 用于烯烃聚合或共聚合的催化剂体系
GB0001914D0 (en) 2000-01-27 2000-03-22 Borealis Polymers Oy Catalyst
CN1169845C (zh) * 2002-02-07 2004-10-06 中国石油化工股份有限公司 用于烯烃聚合的固体催化剂组分和含该催化剂组分的催化剂及其应用
WO2003076480A1 (en) * 2002-03-08 2003-09-18 Basell Poliolefine Italia S.P.A. Process for preparing a diether-based catalyst component
WO2003095504A1 (en) * 2002-05-10 2003-11-20 Idemitsu Kosan Co., Ltd. Solid catalyst component for olefin polymerization, catalyst for olefin polymerization and method for producing olefin polymer
EP1403292B1 (en) 2002-09-30 2016-04-13 Borealis Polymers Oy Process for preparing an olefin polymerisation catalyst component with improved high temperature activity
CA2510254A1 (en) * 2002-12-18 2004-07-01 Basell Poliolefine Italia S.P.A. Magnesium dichloride-based adducts and catalyst components obtained therefrom
ES2420879T3 (es) * 2002-12-18 2013-08-27 Basell Poliolefine Italia S.R.L. Componentes catalizadores para la polimerización de olefinas
ES2377948T3 (es) 2003-06-20 2012-04-03 Borealis Polymers Oy Procedimiento para la preparación de una composición de un catalizador para la polimerización de olefinas
US7393806B2 (en) * 2003-09-23 2008-07-01 Dow Global Technologies Inc. Catalyst composition with monocarboxylic acid ester internal donor and propylene polymerization process
US7135531B2 (en) 2004-01-28 2006-11-14 Basf Catalysts Llc Spherical catalyst for olefin polymerization
US7351778B2 (en) * 2004-04-30 2008-04-01 China Petroleum & Chemical Corporation Catalyst component for olefin polymerization and catalyst comprising the same
CN1670043A (zh) * 2005-03-07 2005-09-21 营口市向阳催化剂有限责任公司 烯烃聚合用催化剂及其制备和聚合方法
EP1862481B1 (en) 2006-05-31 2016-08-31 Borealis Technology Oy Catalyst with al-alkoxy component
EP1862480B1 (en) 2006-05-31 2016-07-27 Borealis Technology Oy Process for preparing an olefin polymerisation catalyst component with improved high temperature activity
JP2009541545A (ja) * 2006-06-23 2009-11-26 バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ マグネシウムクロロアルコレートをベースとする触媒前駆体
JP5689232B2 (ja) * 2009-03-24 2015-03-25 三井化学株式会社 固体状チタン触媒成分、オレフィン重合用触媒およびオレフィンの重合方法
ES2541701T3 (es) * 2010-07-13 2015-07-23 Borealis Ag Componente de catalizador
KR101719981B1 (ko) * 2010-07-13 2017-03-27 엘지전자 주식회사 3차원 컨텐츠를 출력하는 디스플레이 기기의 사용자 인터페이스 출력 방법 및 그 방법을 채용한 디스플레이 기기
EP2610274A1 (en) * 2011-12-30 2013-07-03 Borealis AG Propylene random copolymer
US8575283B1 (en) * 2012-06-28 2013-11-05 Formosa Plastics Corporation, U.S.A. Heterocyclic organic compounds as electron donors for polyolefin catalysts

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1170003A (zh) * 1996-06-10 1998-01-14 三井石油化学工业株式会社 固体钛催化剂组分及制备,含该催化剂组分的催化剂及应用
CN1247625C (zh) * 2001-06-20 2006-03-29 玻利阿黎斯聚合物有限公司 烯烃聚合催化剂组分的制备方法
CN101080271A (zh) * 2004-12-17 2007-11-28 弗纳技术股份有限公司 可用于生产聚烯烃催化剂的可溶性镁络合物和由此生产的催化剂

Also Published As

Publication number Publication date
ES2665889T3 (es) 2018-04-30
US20140378298A1 (en) 2014-12-25
US20170066852A1 (en) 2017-03-09
JP5992534B2 (ja) 2016-09-14
JP2015503646A (ja) 2015-02-02
KR101688709B1 (ko) 2016-12-21
IN2014DN05988A (https=) 2015-06-26
EP2610273B1 (en) 2018-02-07
EP2610273A1 (en) 2013-07-03
KR20140107637A (ko) 2014-09-04
CN104039841A (zh) 2014-09-10
WO2013098139A1 (en) 2013-07-04

Similar Documents

Publication Publication Date Title
CN104039841B (zh) 催化剂组分
CN104039842B (zh) 无邻苯二甲酸酯的zn pp催化剂的制备
CN104039845B (zh) 丙烯无规共聚物
CN107810205B (zh) 催化剂组分
EP2610272B1 (en) Catalyst component
EP2610270B1 (en) Catalyst component
CN104854145B (zh) 制备用于乙烯聚合的齐格勒‑纳塔主催化剂的方法
EP2960257B1 (en) Improved process for preparing a particulate olefin polymerisation catalyst component
CN104903362A (zh) 用于烯烃聚合的催化剂组分以及由此获得的催化剂
WO2021175836A1 (en) Catalyst and preparation thereof
EP3898720A1 (en) Catalyst and preparation thereof

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant