CN104030364A - 一种用于催化重质油加氢裂化的铁硫化物的制备方法及使用该铁硫化物的工艺 - Google Patents
一种用于催化重质油加氢裂化的铁硫化物的制备方法及使用该铁硫化物的工艺 Download PDFInfo
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- CN104030364A CN104030364A CN201310071376.7A CN201310071376A CN104030364A CN 104030364 A CN104030364 A CN 104030364A CN 201310071376 A CN201310071376 A CN 201310071376A CN 104030364 A CN104030364 A CN 104030364A
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- Prior art keywords
- iron sulfide
- quality
- iron
- preparation
- hydrocracking
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- MBMLMWLHJBBADN-UHFFFAOYSA-N Ferrous sulfide Chemical compound [Fe]=S MBMLMWLHJBBADN-UHFFFAOYSA-N 0.000 title claims abstract description 97
- 238000004517 catalytic hydrocracking Methods 0.000 title claims abstract description 22
- 238000002360 preparation method Methods 0.000 title claims abstract description 20
- 239000000295 fuel oil Substances 0.000 title claims abstract description 14
- 238000005516 engineering process Methods 0.000 title description 5
- 238000006243 chemical reaction Methods 0.000 claims abstract description 41
- 239000000428 dust Substances 0.000 claims abstract description 27
- 238000000034 method Methods 0.000 claims abstract description 22
- 239000003245 coal Substances 0.000 claims abstract description 18
- 239000003054 catalyst Substances 0.000 claims abstract description 17
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 63
- 241000772415 Neovison vison Species 0.000 claims description 27
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 26
- 239000001257 hydrogen Substances 0.000 claims description 26
- 229910052739 hydrogen Inorganic materials 0.000 claims description 26
- 229910052742 iron Inorganic materials 0.000 claims description 21
- 238000003825 pressing Methods 0.000 claims description 13
- 238000005336 cracking Methods 0.000 claims description 11
- 238000006555 catalytic reaction Methods 0.000 claims description 10
- 238000005984 hydrogenation reaction Methods 0.000 claims description 10
- 238000007885 magnetic separation Methods 0.000 claims description 7
- 230000035484 reaction time Effects 0.000 claims description 2
- 239000002245 particle Substances 0.000 abstract description 10
- 239000012530 fluid Substances 0.000 abstract 1
- 238000003756 stirring Methods 0.000 description 32
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 20
- 229930195733 hydrocarbon Natural products 0.000 description 14
- 150000002430 hydrocarbons Chemical class 0.000 description 14
- 239000004215 Carbon black (E152) Substances 0.000 description 12
- 239000007795 chemical reaction product Substances 0.000 description 11
- 230000006698 induction Effects 0.000 description 11
- 239000002002 slurry Substances 0.000 description 11
- 229910001873 dinitrogen Inorganic materials 0.000 description 10
- 238000004523 catalytic cracking Methods 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 9
- 239000000126 substance Substances 0.000 description 8
- 239000002817 coal dust Substances 0.000 description 7
- 239000012535 impurity Substances 0.000 description 6
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 6
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 5
- 239000005864 Sulphur Substances 0.000 description 5
- 229910052757 nitrogen Inorganic materials 0.000 description 5
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 description 5
- VXWSFRMTBJZULV-UHFFFAOYSA-H iron(3+) sulfate hydrate Chemical compound O.[Fe+3].[Fe+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O VXWSFRMTBJZULV-UHFFFAOYSA-H 0.000 description 4
- 230000003197 catalytic effect Effects 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- GNVXPFBEZCSHQZ-UHFFFAOYSA-N iron(2+);sulfide Chemical compound [S-2].[Fe+2] GNVXPFBEZCSHQZ-UHFFFAOYSA-N 0.000 description 2
- HRZKFCSHISLTEI-UHFFFAOYSA-N iron;sulfuric acid;hydrate Chemical compound O.[Fe].OS(O)(=O)=O HRZKFCSHISLTEI-UHFFFAOYSA-N 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- NIPNSKYNPDTRPC-UHFFFAOYSA-N N-[2-oxo-2-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 NIPNSKYNPDTRPC-UHFFFAOYSA-N 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 239000010426 asphalt Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- VPOWUERJTYNPNF-UHFFFAOYSA-N cobalt iron manganese molybdenum nickel Chemical compound [Fe][Ni][Mn][Mo][Co] VPOWUERJTYNPNF-UHFFFAOYSA-N 0.000 description 1
- 238000004939 coking Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000012962 cracking technique Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000004452 microanalysis Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Landscapes
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Abstract
Description
重质油加氢催化裂化工艺 | 350℃以下馏分收率(wt%) |
实施例8 | 74.2 |
实施例9 | 75.8 |
实施例10 | 80.2 |
实施例11 | 78.6 |
实施例12 | 82.3 |
实施例13 | 79.3 |
实施例14 | 81.5 |
实施例15 | 74.7 |
对比例1 | 67.3 |
对比例2 | 71.2 |
对比例3 | 59.7 |
Claims (10)
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CN201310071376.7A CN104030364B (zh) | 2013-03-06 | 2013-03-06 | 一种用于催化重质油加氢裂化的铁硫化物的制备方法及使用该铁硫化物的工艺 |
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CN201310071376.7A CN104030364B (zh) | 2013-03-06 | 2013-03-06 | 一种用于催化重质油加氢裂化的铁硫化物的制备方法及使用该铁硫化物的工艺 |
Publications (2)
Publication Number | Publication Date |
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CN104030364A true CN104030364A (zh) | 2014-09-10 |
CN104030364B CN104030364B (zh) | 2015-11-25 |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105709781A (zh) * | 2016-01-24 | 2016-06-29 | 太原理工大学 | 一种煤直接液化催化剂、其制备方法和应用 |
CN110180558A (zh) * | 2018-05-17 | 2019-08-30 | 北京三聚环保新材料股份有限公司 | 一种生物质加氢液化催化剂和制备方法及生物质加氢的方法 |
CN110404563A (zh) * | 2018-04-28 | 2019-11-05 | 福建三聚福大化肥催化剂国家工程研究中心有限公司 | 一种铁基加氢催化剂及其制备方法 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6056935A (en) * | 1995-05-25 | 2000-05-02 | Asahi Kasei Kogyo Kabushiki Kaisha | Iron sulfide and process for producing the same |
CN102076611A (zh) * | 2008-06-30 | 2011-05-25 | 环球油品公司 | 用于淤浆氢化裂化的带有纳米微晶的催化剂组合物 |
CN102527432A (zh) * | 2011-01-04 | 2012-07-04 | 新疆大学 | 高活性铁基煤直接液化催化剂及其制备方法 |
-
2013
- 2013-03-06 CN CN201310071376.7A patent/CN104030364B/zh active Active
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6056935A (en) * | 1995-05-25 | 2000-05-02 | Asahi Kasei Kogyo Kabushiki Kaisha | Iron sulfide and process for producing the same |
CN102076611A (zh) * | 2008-06-30 | 2011-05-25 | 环球油品公司 | 用于淤浆氢化裂化的带有纳米微晶的催化剂组合物 |
CN102527432A (zh) * | 2011-01-04 | 2012-07-04 | 新疆大学 | 高活性铁基煤直接液化催化剂及其制备方法 |
Non-Patent Citations (1)
Title |
---|
盛昌栋等: "煤中含铁矿物在煤粉燃烧过程中行为的研究进展", 《煤炭转化》, vol. 21, no. 3, 31 July 1998 (1998-07-31), pages 14 - 18 * |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105709781A (zh) * | 2016-01-24 | 2016-06-29 | 太原理工大学 | 一种煤直接液化催化剂、其制备方法和应用 |
CN105709781B (zh) * | 2016-01-24 | 2018-06-22 | 太原理工大学 | 一种煤直接液化催化剂、其制备方法和应用 |
CN110404563A (zh) * | 2018-04-28 | 2019-11-05 | 福建三聚福大化肥催化剂国家工程研究中心有限公司 | 一种铁基加氢催化剂及其制备方法 |
CN110404563B (zh) * | 2018-04-28 | 2022-07-05 | 福建三聚福大化肥催化剂国家工程研究中心有限公司 | 一种铁基加氢催化剂及其制备方法 |
CN110180558A (zh) * | 2018-05-17 | 2019-08-30 | 北京三聚环保新材料股份有限公司 | 一种生物质加氢液化催化剂和制备方法及生物质加氢的方法 |
CN110180558B (zh) * | 2018-05-17 | 2022-05-10 | 北京三聚环保新材料股份有限公司 | 一种生物质加氢液化催化剂和制备方法及生物质加氢的方法 |
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CN104030364B (zh) | 2015-11-25 |
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Address after: 100029 Beijing City, Chaoyang District Hui New Street No. 11 Ziguang building A block 12 layer Patentee after: BEIJING BAOJU ENERGY SCIENCE AND TECHNOLOGY CO.,LTD. Address before: 100029 Beijing City, Chaoyang District Hui New Street No. 11 Ziguang building A block 12 layer Patentee before: BEIJING BAOTASANJU ENERGY TECHNOLOGY Co.,Ltd. |
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Effective date of registration: 20201019 Address after: 100080, Beijing, Haidian District North Road, No. 33, building 1, foundation building, 9 floor Patentee after: BEIJING SANJU ENVIRONMENTAL PROTECTION & NEW MATERIALS Co.,Ltd. Address before: 100029, Beijing, Chaoyang District Xin Tung Street, No. 11 violet development building, block A, 12 Patentee before: BEIJING BAOJU ENERGY SCIENCE AND TECHNOLOGY Co.,Ltd. |
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Address after: 100080 9th floor, Dahang Jiye building, No.1 building, 33 Renmin North Road, Haidian District, Beijing Patentee after: Beijing Haixin Energy Technology Co.,Ltd. Address before: 100080 9th floor, Dahang Jiye building, No.1 building, 33 Renmin North Road, Haidian District, Beijing Patentee before: BEIJING SANJU ENVIRONMENTAL PROTECTION & NEW MATERIALS Co.,Ltd. |
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