CN104024493B - 形成碳纳米管的方法和系统 - Google Patents

形成碳纳米管的方法和系统 Download PDF

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Publication number
CN104024493B
CN104024493B CN201280061389.XA CN201280061389A CN104024493B CN 104024493 B CN104024493 B CN 104024493B CN 201280061389 A CN201280061389 A CN 201280061389A CN 104024493 B CN104024493 B CN 104024493B
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CN
China
Prior art keywords
stream
reactor
gas
heat exchanger
feed
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
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CN201280061389.XA
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English (en)
Chinese (zh)
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CN104024493A (zh
Inventor
R·D·邓顿
D·B·诺伊斯
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Solid Carbon Goods Co
ExxonMobil Upstream Research Co
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Solid Carbon Goods Co
Exxon Production Research Co
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Publication of CN104024493A publication Critical patent/CN104024493A/zh
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    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C01B32/15—Nano-sized carbon materials
    • C01B32/158—Carbon nanotubes
    • C01B32/16—Preparation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/24—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F9/00—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments
    • D01F9/08—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments of inorganic material
    • D01F9/12—Carbon filaments; Apparatus specially adapted for the manufacture thereof
    • D01F9/127—Carbon filaments; Apparatus specially adapted for the manufacture thereof by thermal decomposition of hydrocarbon gases or vapours or other carbon-containing compounds in the form of gas or vapour, e.g. carbon monoxide, alcohols
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F9/00—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments
    • D01F9/08—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments of inorganic material
    • D01F9/12—Carbon filaments; Apparatus specially adapted for the manufacture thereof
    • D01F9/127—Carbon filaments; Apparatus specially adapted for the manufacture thereof by thermal decomposition of hydrocarbon gases or vapours or other carbon-containing compounds in the form of gas or vapour, e.g. carbon monoxide, alcohols
    • D01F9/1271—Alkanes or cycloalkanes
    • D01F9/1272—Methane
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F9/00—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments
    • D01F9/08—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments of inorganic material
    • D01F9/12—Carbon filaments; Apparatus specially adapted for the manufacture thereof
    • D01F9/127—Carbon filaments; Apparatus specially adapted for the manufacture thereof by thermal decomposition of hydrocarbon gases or vapours or other carbon-containing compounds in the form of gas or vapour, e.g. carbon monoxide, alcohols
    • D01F9/1278—Carbon monoxide
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/10—Process efficiency
    • Y02P20/129—Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
    • Y02P70/62—Manufacturing or production processes characterised by the final manufactured product related technologies for production or treatment of textile or flexible materials or products thereof, including footwear

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Nanotechnology (AREA)
  • Physics & Mathematics (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Textile Engineering (AREA)
  • Thermal Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Composite Materials (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Carbon And Carbon Compounds (AREA)
CN201280061389.XA 2011-12-12 2012-12-12 形成碳纳米管的方法和系统 Expired - Fee Related CN104024493B (zh)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US201161569494P 2011-12-12 2011-12-12
US61/569,494 2011-12-12
US201161582098P 2011-12-30 2011-12-30
US61/582,098 2011-12-30
PCT/US2012/069276 WO2013090444A1 (en) 2011-12-12 2012-12-12 Method and systems for forming carbon nanotubes

Publications (2)

Publication Number Publication Date
CN104024493A CN104024493A (zh) 2014-09-03
CN104024493B true CN104024493B (zh) 2016-08-24

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN201280061389.XA Expired - Fee Related CN104024493B (zh) 2011-12-12 2012-12-12 形成碳纳米管的方法和系统

Country Status (11)

Country Link
US (1) US9567219B2 (enExample)
EP (1) EP2800827A4 (enExample)
JP (1) JP6252911B2 (enExample)
KR (1) KR101821113B1 (enExample)
CN (1) CN104024493B (enExample)
AU (1) AU2012352339B2 (enExample)
CA (1) CA2858725C (enExample)
MX (1) MX360006B (enExample)
MY (1) MY165755A (enExample)
SG (1) SG11201402504PA (enExample)
WO (1) WO2013090444A1 (enExample)

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NZ595714A (en) 2009-04-17 2014-08-29 Seerstone Llc Method for producing solid carbon by reducing carbon oxides
US9475699B2 (en) 2012-04-16 2016-10-25 Seerstone Llc. Methods for treating an offgas containing carbon oxides
WO2013158160A1 (en) 2012-04-16 2013-10-24 Seerstone Llc Method for producing solid carbon by reducing carbon dioxide
US9796591B2 (en) 2012-04-16 2017-10-24 Seerstone Llc Methods for reducing carbon oxides with non ferrous catalysts and forming solid carbon products
EP2838838A4 (en) 2012-04-16 2015-10-21 Seerstone Llc METHOD AND SYSTEMS FOR DETECTING AND SEQUESTRATING CARBON AND REDUCING THE MASS OF CARBOX OXIDES IN A GAS FLOW
NO2749379T3 (enExample) 2012-04-16 2018-07-28
TW201408592A (zh) 2012-04-17 2014-03-01 艾克頌美孚上游研究公司 用於形成碳同素異形體之碳質進料
TWI627130B (zh) * 2012-04-18 2018-06-21 美商艾克頌美孚上游研究公司 由連續反應器流出物移出碳奈米管之方法
TWI570072B (zh) 2012-04-18 2017-02-11 艾克頌美孚上游研究公司 移除水流中奈米碳管之方法和系統
US9896341B2 (en) 2012-04-23 2018-02-20 Seerstone Llc Methods of forming carbon nanotubes having a bimodal size distribution
CN107651667A (zh) 2012-07-12 2018-02-02 赛尔斯通股份有限公司 包含碳纳米管的固体碳产物以及其形成方法
US10815124B2 (en) 2012-07-12 2020-10-27 Seerstone Llc Solid carbon products comprising carbon nanotubes and methods of forming same
MX2015000580A (es) 2012-07-13 2015-08-20 Seerstone Llc Metodos y sistemas para formar productos de carbono solido y amoniaco.
US9779845B2 (en) 2012-07-18 2017-10-03 Seerstone Llc Primary voltaic sources including nanofiber Schottky barrier arrays and methods of forming same
TWI638770B (zh) 2012-09-18 2018-10-21 美商艾克頌美孚上游研究公司 用於製造碳同素異形體之反應器系統
JP6389824B2 (ja) 2012-11-29 2018-09-12 シーアストーン リミテッド ライアビリティ カンパニー 固体炭素材料を製造するための反応器および方法
WO2014151144A1 (en) 2013-03-15 2014-09-25 Seerstone Llc Carbon oxide reduction with intermetallic and carbide catalysts
US10086349B2 (en) 2013-03-15 2018-10-02 Seerstone Llc Reactors, systems, and methods for forming solid products
EP3129133B1 (en) 2013-03-15 2024-10-09 Seerstone LLC Systems for producing solid carbon by reducing carbon oxides
US9783416B2 (en) 2013-03-15 2017-10-10 Seerstone Llc Methods of producing hydrogen and solid carbon
ES2900814T3 (es) 2013-03-15 2022-03-18 Seerstone Llc Electrodos que comprenden carbono nanoestructurado
WO2016097985A2 (en) * 2014-12-15 2016-06-23 Sodisetti Venkateswara Rao Production of carbon nanotubes in large scale continuously using industrial emission at industrial sites
US10000413B1 (en) 2015-12-16 2018-06-19 The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration Carbon-enhanced cement clinker
WO2018022999A1 (en) 2016-07-28 2018-02-01 Seerstone Llc. Solid carbon products comprising compressed carbon nanotubes in a container and methods of forming same
CA3133123A1 (en) * 2019-04-03 2020-10-08 Nanocomp Technologies, Inc. System and method of producing carbon nanotubes
US11685651B2 (en) 2019-10-25 2023-06-27 Mark Kevin Robertson Catalytic decomposition of hydrocarbons for the production of hydrogen and carbon
JP7779543B2 (ja) * 2020-05-19 2025-12-03 国立大学法人静岡大学 反応システム、固体炭素を捕集する方法、水素を含むガスを製造する方法、触媒セット、及び固体炭素捕集用触媒
CN112142038A (zh) * 2020-08-28 2020-12-29 西安交通大学 一种带有尾气余热回收再利用装置的碳纳米管批量制备系统
CN117285031B (zh) * 2023-11-24 2024-01-30 烁元新材料(东营)股份有限公司 一种利用炭黑尾气制造碳纳米材料的装置

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CN1495127A (zh) * 1999-06-02 2004-05-12 ����˹���ѧ���»� 用于生产碳纳米管的方法和催化剂
CN101707864A (zh) * 2007-06-06 2010-05-12 琳德有限公司 产生用于碳纳米材料生产的一氧化碳的联合方法
WO2010120581A1 (en) * 2009-04-17 2010-10-21 Noyes Dallas B Method for producing solid carbon by reducing carbon oxides

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JP4758130B2 (ja) * 2005-04-12 2011-08-24 国立大学法人北見工業大学 ナノ炭素の製造方法およびナノ炭素製造用触媒反応装置
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CN1495127A (zh) * 1999-06-02 2004-05-12 ����˹���ѧ���»� 用于生产碳纳米管的方法和催化剂
CN101707864A (zh) * 2007-06-06 2010-05-12 琳德有限公司 产生用于碳纳米材料生产的一氧化碳的联合方法
WO2010120581A1 (en) * 2009-04-17 2010-10-21 Noyes Dallas B Method for producing solid carbon by reducing carbon oxides

Also Published As

Publication number Publication date
US20140348739A1 (en) 2014-11-27
KR20140112504A (ko) 2014-09-23
AU2012352339A1 (en) 2014-07-03
SG11201402504PA (en) 2014-09-26
AU2012352339B2 (en) 2015-12-03
MX2014006550A (es) 2015-02-17
CA2858725C (en) 2018-09-18
CN104024493A (zh) 2014-09-03
JP6252911B2 (ja) 2017-12-27
MX360006B (es) 2018-10-18
CA2858725A1 (en) 2013-06-20
US9567219B2 (en) 2017-02-14
EP2800827A4 (en) 2015-08-05
KR101821113B1 (ko) 2018-01-23
JP2015500201A (ja) 2015-01-05
EP2800827A1 (en) 2014-11-12
WO2013090444A1 (en) 2013-06-20
MY165755A (en) 2018-04-23

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Granted publication date: 20160824

Termination date: 20211212