CA2858725C - Method and systems for forming carbon nanotubes - Google Patents
Method and systems for forming carbon nanotubes Download PDFInfo
- Publication number
- CA2858725C CA2858725C CA2858725A CA2858725A CA2858725C CA 2858725 C CA2858725 C CA 2858725C CA 2858725 A CA2858725 A CA 2858725A CA 2858725 A CA2858725 A CA 2858725A CA 2858725 C CA2858725 C CA 2858725C
- Authority
- CA
- Canada
- Prior art keywords
- stream
- reactor
- heat exchanger
- gas stream
- waste gas
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 161
- 238000000034 method Methods 0.000 title claims abstract description 117
- 239000002041 carbon nanotube Substances 0.000 title claims abstract description 105
- 229910021393 carbon nanotube Inorganic materials 0.000 title claims abstract description 102
- 239000007789 gas Substances 0.000 claims abstract description 266
- 239000002912 waste gas Substances 0.000 claims abstract description 116
- 238000006243 chemical reaction Methods 0.000 claims abstract description 85
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 85
- 239000002918 waste heat Substances 0.000 claims abstract description 16
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 200
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 186
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 99
- 239000001569 carbon dioxide Substances 0.000 claims description 97
- 229910001868 water Inorganic materials 0.000 claims description 78
- 230000008569 process Effects 0.000 claims description 70
- 239000003054 catalyst Substances 0.000 claims description 63
- 238000000926 separation method Methods 0.000 claims description 63
- 229910052751 metal Inorganic materials 0.000 claims description 32
- 239000002184 metal Substances 0.000 claims description 32
- 238000005194 fractionation Methods 0.000 claims description 29
- 239000011324 bead Substances 0.000 claims description 28
- 238000004519 manufacturing process Methods 0.000 claims description 23
- 239000000376 reactant Substances 0.000 claims description 17
- 239000002699 waste material Substances 0.000 claims description 17
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 10
- 230000003068 static effect Effects 0.000 claims description 7
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 6
- 230000015556 catabolic process Effects 0.000 claims description 6
- 238000006731 degradation reaction Methods 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 5
- 239000000463 material Substances 0.000 claims description 5
- 238000002156 mixing Methods 0.000 claims description 5
- 238000005422 blasting Methods 0.000 claims description 4
- 229910052742 iron Inorganic materials 0.000 claims description 4
- 229910052759 nickel Inorganic materials 0.000 claims description 3
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 2
- 229910052804 chromium Inorganic materials 0.000 claims description 2
- 239000011651 chromium Substances 0.000 claims description 2
- 239000011819 refractory material Substances 0.000 claims description 2
- 238000011144 upstream manufacturing Methods 0.000 claims 1
- 229910052799 carbon Inorganic materials 0.000 description 48
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 33
- 238000010586 diagram Methods 0.000 description 29
- 229910002091 carbon monoxide Inorganic materials 0.000 description 24
- 239000000047 product Substances 0.000 description 23
- 229930195733 hydrocarbon Natural products 0.000 description 20
- 239000007787 solid Substances 0.000 description 20
- 239000000919 ceramic Substances 0.000 description 19
- 150000002430 hydrocarbons Chemical class 0.000 description 19
- 238000010926 purge Methods 0.000 description 19
- 238000004806 packaging method and process Methods 0.000 description 17
- 239000003345 natural gas Substances 0.000 description 15
- 239000001257 hydrogen Substances 0.000 description 14
- 229910052739 hydrogen Inorganic materials 0.000 description 14
- 239000002245 particle Substances 0.000 description 14
- 230000015572 biosynthetic process Effects 0.000 description 13
- 239000000203 mixture Substances 0.000 description 13
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 11
- 229910002090 carbon oxide Inorganic materials 0.000 description 11
- 239000004215 Carbon black (E152) Substances 0.000 description 9
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 8
- 239000006229 carbon black Substances 0.000 description 8
- 238000001816 cooling Methods 0.000 description 8
- 238000010438 heat treatment Methods 0.000 description 8
- 229910052760 oxygen Inorganic materials 0.000 description 8
- 239000001301 oxygen Substances 0.000 description 8
- 239000002134 carbon nanofiber Substances 0.000 description 7
- 239000002737 fuel gas Substances 0.000 description 7
- XMWRBQBLMFGWIX-UHFFFAOYSA-N C60 fullerene Chemical class C12=C3C(C4=C56)=C7C8=C5C5=C9C%10=C6C6=C4C1=C1C4=C6C6=C%10C%10=C9C9=C%11C5=C8C5=C8C7=C3C3=C7C2=C1C1=C2C4=C6C4=C%10C6=C9C9=C%11C5=C5C8=C3C3=C7C1=C1C2=C4C6=C2C9=C5C3=C12 XMWRBQBLMFGWIX-UHFFFAOYSA-N 0.000 description 6
- 239000003153 chemical reaction reagent Substances 0.000 description 6
- 239000003638 chemical reducing agent Substances 0.000 description 6
- 229910003472 fullerene Inorganic materials 0.000 description 6
- -1 fullerenes Chemical compound 0.000 description 6
- 238000000197 pyrolysis Methods 0.000 description 6
- 229920000049 Carbon (fiber) Polymers 0.000 description 5
- 239000004917 carbon fiber Substances 0.000 description 5
- 238000011084 recovery Methods 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 239000006227 byproduct Substances 0.000 description 4
- 229910021389 graphene Inorganic materials 0.000 description 4
- 150000002431 hydrogen Chemical class 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 238000010248 power generation Methods 0.000 description 4
- 238000000746 purification Methods 0.000 description 4
- 238000005070 sampling Methods 0.000 description 4
- 230000009919 sequestration Effects 0.000 description 4
- 238000003786 synthesis reaction Methods 0.000 description 4
- 238000005229 chemical vapour deposition Methods 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 239000012467 final product Substances 0.000 description 3
- 229910002804 graphite Inorganic materials 0.000 description 3
- 239000010439 graphite Substances 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 239000002086 nanomaterial Substances 0.000 description 3
- 238000004088 simulation Methods 0.000 description 3
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 2
- 229910021387 carbon allotrope Inorganic materials 0.000 description 2
- 238000006555 catalytic reaction Methods 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- 239000000356 contaminant Substances 0.000 description 2
- 239000010779 crude oil Substances 0.000 description 2
- 238000010410 dusting Methods 0.000 description 2
- 230000005611 electricity Effects 0.000 description 2
- 238000003306 harvesting Methods 0.000 description 2
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 239000002071 nanotube Substances 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 239000002109 single walled nanotube Substances 0.000 description 2
- 241000894007 species Species 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000010744 Boudouard reaction Methods 0.000 description 1
- 102100028285 DNA repair protein REV1 Human genes 0.000 description 1
- 241000143432 Daldinia concentrica Species 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- MBMLMWLHJBBADN-UHFFFAOYSA-N Ferrous sulfide Chemical compound [Fe]=S MBMLMWLHJBBADN-UHFFFAOYSA-N 0.000 description 1
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 238000002679 ablation Methods 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000003463 adsorbent Substances 0.000 description 1
- 239000010692 aromatic oil Substances 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 239000011203 carbon fibre reinforced carbon Substances 0.000 description 1
- 239000002717 carbon nanostructure Substances 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 229910010293 ceramic material Inorganic materials 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000012993 chemical processing Methods 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 239000000571 coke Substances 0.000 description 1
- 239000000567 combustion gas Substances 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 239000002274 desiccant Substances 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 239000010432 diamond Substances 0.000 description 1
- 238000007323 disproportionation reaction Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000010891 electric arc Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 239000000295 fuel oil Substances 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 238000011031 large-scale manufacturing process Methods 0.000 description 1
- 238000000608 laser ablation Methods 0.000 description 1
- 239000012035 limiting reagent Substances 0.000 description 1
- 230000005486 microgravity Effects 0.000 description 1
- 239000002808 molecular sieve Substances 0.000 description 1
- 230000000877 morphologic effect Effects 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000006722 reduction reaction Methods 0.000 description 1
- 239000003507 refrigerant Substances 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/15—Nano-sized carbon materials
- C01B32/158—Carbon nanotubes
- C01B32/16—Preparation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
- B01J8/24—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F9/00—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments
- D01F9/08—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments of inorganic material
- D01F9/12—Carbon filaments; Apparatus specially adapted for the manufacture thereof
- D01F9/127—Carbon filaments; Apparatus specially adapted for the manufacture thereof by thermal decomposition of hydrocarbon gases or vapours or other carbon-containing compounds in the form of gas or vapour, e.g. carbon monoxide, alcohols
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F9/00—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments
- D01F9/08—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments of inorganic material
- D01F9/12—Carbon filaments; Apparatus specially adapted for the manufacture thereof
- D01F9/127—Carbon filaments; Apparatus specially adapted for the manufacture thereof by thermal decomposition of hydrocarbon gases or vapours or other carbon-containing compounds in the form of gas or vapour, e.g. carbon monoxide, alcohols
- D01F9/1271—Alkanes or cycloalkanes
- D01F9/1272—Methane
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F9/00—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments
- D01F9/08—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments of inorganic material
- D01F9/12—Carbon filaments; Apparatus specially adapted for the manufacture thereof
- D01F9/127—Carbon filaments; Apparatus specially adapted for the manufacture thereof by thermal decomposition of hydrocarbon gases or vapours or other carbon-containing compounds in the form of gas or vapour, e.g. carbon monoxide, alcohols
- D01F9/1278—Carbon monoxide
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
- Y02P20/129—Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
- Y02P70/62—Manufacturing or production processes characterised by the final manufactured product related technologies for production or treatment of textile or flexible materials or products thereof, including footwear
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Nanotechnology (AREA)
- Physics & Mathematics (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Textile Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Thermal Sciences (AREA)
- Inorganic Chemistry (AREA)
- Composite Materials (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Crystallography & Structural Chemistry (AREA)
- Combustion & Propulsion (AREA)
- Carbon And Carbon Compounds (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201161569494P | 2011-12-12 | 2011-12-12 | |
| US61/569,494 | 2011-12-12 | ||
| US201161582098P | 2011-12-30 | 2011-12-30 | |
| US61/582,098 | 2011-12-30 | ||
| PCT/US2012/069276 WO2013090444A1 (en) | 2011-12-12 | 2012-12-12 | Method and systems for forming carbon nanotubes |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2858725A1 CA2858725A1 (en) | 2013-06-20 |
| CA2858725C true CA2858725C (en) | 2018-09-18 |
Family
ID=48613147
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2858725A Expired - Fee Related CA2858725C (en) | 2011-12-12 | 2012-12-12 | Method and systems for forming carbon nanotubes |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US9567219B2 (enExample) |
| EP (1) | EP2800827A4 (enExample) |
| JP (1) | JP6252911B2 (enExample) |
| KR (1) | KR101821113B1 (enExample) |
| CN (1) | CN104024493B (enExample) |
| AU (1) | AU2012352339B2 (enExample) |
| CA (1) | CA2858725C (enExample) |
| MX (1) | MX360006B (enExample) |
| MY (1) | MY165755A (enExample) |
| SG (1) | SG11201402504PA (enExample) |
| WO (1) | WO2013090444A1 (enExample) |
Families Citing this family (29)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU2010236807B2 (en) | 2009-04-17 | 2014-09-25 | Seerstone Llc | Method for producing solid carbon by reducing carbon oxides |
| WO2013158156A1 (en) | 2012-04-16 | 2013-10-24 | Seerstone Llc | Methods and structures for reducing carbon oxides with non-ferrous catalysts |
| MX354526B (es) | 2012-04-16 | 2018-03-07 | Seerstone Llc | Metodos y sistemas para capturar y secuestrar carbono y para reducir la masa de oxidos de carbono en una corriente de gas de desechos. |
| MX354529B (es) | 2012-04-16 | 2018-03-07 | Seerstone Llc | Métodos para producir carbono sólido mediante la reducción de dióxido de carbono. |
| NO2749379T3 (enExample) | 2012-04-16 | 2018-07-28 | ||
| CN104284861A (zh) | 2012-04-16 | 2015-01-14 | 赛尔斯通股份有限公司 | 处理含有碳氧化物的废气的方法 |
| TW201410596A (zh) | 2012-04-17 | 2014-03-16 | 艾克頌美孚上游研究公司 | 用於形成碳的同素異形體的進料 |
| TWI627130B (zh) * | 2012-04-18 | 2018-06-21 | 美商艾克頌美孚上游研究公司 | 由連續反應器流出物移出碳奈米管之方法 |
| TWI570072B (zh) | 2012-04-18 | 2017-02-11 | 艾克頌美孚上游研究公司 | 移除水流中奈米碳管之方法和系統 |
| US9896341B2 (en) | 2012-04-23 | 2018-02-20 | Seerstone Llc | Methods of forming carbon nanotubes having a bimodal size distribution |
| WO2014011631A1 (en) | 2012-07-12 | 2014-01-16 | Seerstone Llc | Solid carbon products comprising carbon nanotubes and methods of forming same |
| US10815124B2 (en) | 2012-07-12 | 2020-10-27 | Seerstone Llc | Solid carbon products comprising carbon nanotubes and methods of forming same |
| WO2014011206A1 (en) | 2012-07-13 | 2014-01-16 | Seerstone Llc | Methods and systems for forming ammonia and solid carbon products |
| US9779845B2 (en) | 2012-07-18 | 2017-10-03 | Seerstone Llc | Primary voltaic sources including nanofiber Schottky barrier arrays and methods of forming same |
| TWI638770B (zh) | 2012-09-18 | 2018-10-21 | 美商艾克頌美孚上游研究公司 | 用於製造碳同素異形體之反應器系統 |
| JP6389824B2 (ja) | 2012-11-29 | 2018-09-12 | シーアストーン リミテッド ライアビリティ カンパニー | 固体炭素材料を製造するための反応器および方法 |
| WO2014151138A1 (en) | 2013-03-15 | 2014-09-25 | Seerstone Llc | Reactors, systems, and methods for forming solid products |
| EP3129321B1 (en) | 2013-03-15 | 2021-09-29 | Seerstone LLC | Electrodes comprising nanostructured carbon |
| WO2014151898A1 (en) | 2013-03-15 | 2014-09-25 | Seerstone Llc | Systems for producing solid carbon by reducing carbon oxides |
| US9783416B2 (en) | 2013-03-15 | 2017-10-10 | Seerstone Llc | Methods of producing hydrogen and solid carbon |
| WO2014151144A1 (en) | 2013-03-15 | 2014-09-25 | Seerstone Llc | Carbon oxide reduction with intermetallic and carbide catalysts |
| WO2016097985A2 (en) * | 2014-12-15 | 2016-06-23 | Sodisetti Venkateswara Rao | Production of carbon nanotubes in large scale continuously using industrial emission at industrial sites |
| US10000413B1 (en) | 2015-12-16 | 2018-06-19 | The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration | Carbon-enhanced cement clinker |
| US11752459B2 (en) | 2016-07-28 | 2023-09-12 | Seerstone Llc | Solid carbon products comprising compressed carbon nanotubes in a container and methods of forming same |
| EP3946725A4 (en) * | 2019-04-03 | 2023-09-20 | Nanocomp Technologies, Inc. | SYSTEM AND METHOD FOR PRODUCING CARBON NANOTUBE |
| US11685651B2 (en) | 2019-10-25 | 2023-06-27 | Mark Kevin Robertson | Catalytic decomposition of hydrocarbons for the production of hydrogen and carbon |
| CN115515895B (zh) * | 2020-05-19 | 2024-09-13 | 国立大学法人静冈大学 | 反应系统、捕集固体碳的方法、制造含氢气气体的方法、催化剂组及固体碳捕集用催化剂 |
| CN112142038A (zh) * | 2020-08-28 | 2020-12-29 | 西安交通大学 | 一种带有尾气余热回收再利用装置的碳纳米管批量制备系统 |
| CN117285031B (zh) * | 2023-11-24 | 2024-01-30 | 烁元新材料(东营)股份有限公司 | 一种利用炭黑尾气制造碳纳米材料的装置 |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4048352A (en) * | 1973-02-15 | 1977-09-13 | United States Steel Corporation | Method of producing a refractory lining in a cylinder or tube |
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| US6333016B1 (en) | 1999-06-02 | 2001-12-25 | The Board Of Regents Of The University Of Oklahoma | Method of producing carbon nanotubes |
| JP4082099B2 (ja) * | 2002-06-13 | 2008-04-30 | 三菱化学エンジニアリング株式会社 | 炭素質微細繊維状体の製造方法 |
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| TW200923121A (en) | 2007-11-30 | 2009-06-01 | Univ Yuan Ze | Fluidized-bed system and method for forming carbon nanotube |
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-
2012
- 2012-12-12 AU AU2012352339A patent/AU2012352339B2/en not_active Ceased
- 2012-12-12 JP JP2014547386A patent/JP6252911B2/ja not_active Expired - Fee Related
- 2012-12-12 MX MX2014006550A patent/MX360006B/es active IP Right Grant
- 2012-12-12 CA CA2858725A patent/CA2858725C/en not_active Expired - Fee Related
- 2012-12-12 EP EP12857836.6A patent/EP2800827A4/en not_active Withdrawn
- 2012-12-12 US US14/364,579 patent/US9567219B2/en active Active
- 2012-12-12 MY MYPI2014001545A patent/MY165755A/en unknown
- 2012-12-12 SG SG11201402504PA patent/SG11201402504PA/en unknown
- 2012-12-12 KR KR1020147019176A patent/KR101821113B1/ko not_active Expired - Fee Related
- 2012-12-12 WO PCT/US2012/069276 patent/WO2013090444A1/en not_active Ceased
- 2012-12-12 CN CN201280061389.XA patent/CN104024493B/zh not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| KR20140112504A (ko) | 2014-09-23 |
| EP2800827A4 (en) | 2015-08-05 |
| MY165755A (en) | 2018-04-23 |
| WO2013090444A1 (en) | 2013-06-20 |
| MX360006B (es) | 2018-10-18 |
| AU2012352339A1 (en) | 2014-07-03 |
| SG11201402504PA (en) | 2014-09-26 |
| JP6252911B2 (ja) | 2017-12-27 |
| MX2014006550A (es) | 2015-02-17 |
| AU2012352339B2 (en) | 2015-12-03 |
| US20140348739A1 (en) | 2014-11-27 |
| CN104024493A (zh) | 2014-09-03 |
| EP2800827A1 (en) | 2014-11-12 |
| CN104024493B (zh) | 2016-08-24 |
| JP2015500201A (ja) | 2015-01-05 |
| CA2858725A1 (en) | 2013-06-20 |
| KR101821113B1 (ko) | 2018-01-23 |
| US9567219B2 (en) | 2017-02-14 |
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