CN103981721B - A kind of natural fiber softener and preparation method thereof - Google Patents
A kind of natural fiber softener and preparation method thereof Download PDFInfo
- Publication number
- CN103981721B CN103981721B CN201410215833.XA CN201410215833A CN103981721B CN 103981721 B CN103981721 B CN 103981721B CN 201410215833 A CN201410215833 A CN 201410215833A CN 103981721 B CN103981721 B CN 103981721B
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- CN
- China
- Prior art keywords
- parts
- polyethylene glycol
- natural fiber
- fiber softener
- molecular weight
- Prior art date
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- 239000000835 fiber Substances 0.000 title claims abstract description 23
- 238000002360 preparation method Methods 0.000 title claims abstract description 7
- 239000002202 Polyethylene glycol Substances 0.000 claims abstract description 19
- 229920001223 polyethylene glycol Polymers 0.000 claims abstract description 19
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000008367 deionised water Substances 0.000 claims abstract description 10
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 10
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 claims abstract description 9
- 229920005610 lignin Polymers 0.000 claims abstract description 9
- 235000010413 sodium alginate Nutrition 0.000 claims abstract description 9
- 239000000661 sodium alginate Substances 0.000 claims abstract description 9
- 229940005550 sodium alginate Drugs 0.000 claims abstract description 9
- MTCFGRXMJLQNBG-UHFFFAOYSA-N Serine Natural products OCC(N)C(O)=O MTCFGRXMJLQNBG-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000004205 dimethyl polysiloxane Substances 0.000 claims abstract description 7
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims abstract description 7
- -1 polydimethylsiloxane Polymers 0.000 claims abstract description 7
- 239000011787 zinc oxide Substances 0.000 claims abstract description 7
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims abstract 3
- 239000004327 boric acid Substances 0.000 claims abstract 3
- 238000003756 stirring Methods 0.000 claims description 12
- 238000002156 mixing Methods 0.000 claims description 7
- 239000003643 water by type Substances 0.000 claims description 2
- 239000004744 fabric Substances 0.000 abstract description 6
- 238000012423 maintenance Methods 0.000 abstract description 4
- 238000005406 washing Methods 0.000 abstract description 4
- 230000000694 effects Effects 0.000 abstract description 3
- 238000006065 biodegradation reaction Methods 0.000 abstract description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract description 2
- 239000004615 ingredient Substances 0.000 abstract description 2
- 239000000463 material Substances 0.000 abstract 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 229910052796 boron Inorganic materials 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 3
- 238000011056 performance test Methods 0.000 description 3
- 238000000034 method Methods 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 206010070834 Sensitisation Diseases 0.000 description 1
- HDHICXMXQDZNGS-UHFFFAOYSA-N azanium dimethylazanium dichloride Chemical compound [Cl-].[NH4+].[Cl-].C[NH2+]C HDHICXMXQDZNGS-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- REZZEXDLIUJMMS-UHFFFAOYSA-M dimethyldioctadecylammonium chloride Chemical group [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCCCC REZZEXDLIUJMMS-UHFFFAOYSA-M 0.000 description 1
- 238000005367 electrostatic precipitation Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 230000008313 sensitization Effects 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
Landscapes
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention discloses a kind of natural fiber softener and preparation method thereof.This material is made up of the component comprising following weight portion: diquaternary polydimethylsiloxane 10 20 parts, sodium alginate 5 15 parts, Polyethylene Glycol 5 15 parts, serine 13 parts, zinc oxide 23 parts, lignin 25 parts, boric acid 0.5 2 parts, deionized water 100 parts.The present invention in terms of the selection of main component, have selected sodium alginate, Polyethylene Glycol, lignin etc., these components broadly fall into degradable, energy biodegradation, environmentally friendly component, owing to the various ingredients in the present invention has similar hydroxyl structure to natural fabric, can be fully contacted on the abundant surface with natural fiber, medicated clothing that can be hardening after Treatment of Washing so that it is submissive, has the effect on the damaged fibers surface of maintenance, maintenance clothes thing.
Description
Technical field
The invention belongs to softener field, particularly to a kind of natural fiber softener and preparation thereof
Method.
Background technology
Popularizing and closing fibre and the increase of blend fabric thereof, to fabric softening along with washing machine
The demand of agent is growing, and the fine fabric of major part synthesis and pure wool, nap silk fabric, through repeatedly
After washing the most hardening, feel is coarse, wearing feeling is uncomfortable, even produce electrostatic precipitation, emit
Pyrophoric behavio(u)r.
In existing softener, the most representational product is cationic surfactant, wherein makes
It is dioctadecyl dimethyl ammonium chloride with most or claim double hydrogenated-tallow group dimethylammonium chloride
Ammonium.Although its using effect is preferable, but there is also some problems, as biological degradability is poor,
It is likely to result in the impact on environment.Therefore, for the textile of contact skin and place
Reason agent must be safe, and to people's totally nontoxic, non-stimulated, softener must also be non-sensitization
Property.
Summary of the invention
For above-mentioned demand, it is an object of the invention to provide a kind of natural fiber softener
And preparation method thereof.
The purpose of the present invention can be achieved through the following technical solutions:
A kind of natural fiber softener, is made up of the component comprising following weight portion:
The relative molecular weight of described Polyethylene Glycol is the mixing of 400 and 800.
Described relative molecular weight is the Polyethylene Glycol of 400 and the poly-second two that relative molecular weight is 800
The mass ratio of alcohol is 1:1.
A kind of preparation method of natural fiber softener, the method comprises the following steps:
(1) in 30 parts of deionized waters, sodium alginate 5-15 part, Polyethylene Glycol 5-15 are added
Part, serine 1-3 part, zinc oxide 2-3 part, lignin 2-5 part and polydimethylsiloxane
Di-quaternary ammonium salt 10-20 part, at 40-50 DEG C, stirs；
(2) in the solution of step (1), add the deionized water of 70 parts, be slowly added to boron
Acid 0.5-2 part, stirs, obtains natural fiber softener.
In described step (1), stir speed (S.S.) is 1200 revs/min, and mixing time is that 1-3 is little
Time.
Beneficial effect:
Main component in the present invention has sodium alginate, Polyethylene Glycol, lignin etc., these groups
Dividing and broadly fall into degradable, energy biodegradation, environmentally friendly component, softener of the present invention is more
It is prone to dissolving be dispersed in water, owing to the various ingredients in the present invention has with natural fabric
Similar hydroxyl structure, can be fully contacted on the abundant surface with natural fiber, it is possible to after Treatment of Washing
Hardening medicated clothing so that it is submissive, has the work on the damaged fibers surface of maintenance, maintenance clothes thing
With.Additionally, present invention adds a small amount of serine, after addition, soft to whole natural fiber
The good facilitation of effect is had along agent.
Detailed description of the invention
Below in conjunction with embodiment, the present invention is further illustrated.
Embodiment 1
(1) add sodium alginate 5kg in 30kg deionized water, relative molecular weight is 400
Polyethylene Glycol 2.5kg, relative molecular weight is Polyethylene Glycol 2.5kg, the serine of 800
1kg, zinc oxide 2kg, lignin 3kg and diquaternary polydimethylsiloxane 10kg,
At 45 DEG C, stir speed (S.S.) is 1200 revs/min, and mixing time is 1 hour；
(2) in the solution of step (1), add the deionized water of 70kg, be slowly added to boron
Acid 2kg, stirs, obtains natural fiber softener.
The performance test results preparing natural fiber softener is as shown in table 1.
Embodiment 2
(1) add sodium alginate 15kg in 30kg deionized water, relative molecular weight is 400
Polyethylene Glycol 7.5kg, relative molecular weight is Polyethylene Glycol 7.5kg, the serine of 800
3kg, zinc oxide 3kg, lignin 2kg and diquaternary polydimethylsiloxane 20kg,
At 50 DEG C, stir speed (S.S.) is 1200 revs/min, and mixing time is 3 hours；
(2) in the solution of step (1), add the deionized water of 70kg, be slowly added to boron
Acid 0.5kg, stirs, obtains natural fiber softener.
The performance test results preparing natural fiber softener is as shown in table 1.
Embodiment 3
(1) add sodium alginate 10kg in 30kg deionized water, relative molecular weight is 400
Polyethylene Glycol 5kg, relative molecular weight be 800 Polyethylene Glycol 5kg, serine 2kg,
Zinc oxide 2kg, lignin 5kg and diquaternary polydimethylsiloxane 15kg, at 40 DEG C
Under, stir speed (S.S.) is 1200 revs/min, and mixing time is 2 hours；
(2) in the solution of step (1), add the deionized water of 70kg, be slowly added to boron
Acid 1kg, stirs, obtains natural fiber softener.
The performance test results preparing natural fiber softener is as shown in table 1.
Absorptive method of testing: 25 DEG C, under the conditions of humidity is 40%, by cotton towel
(2.5cm × 25cm) lower end is immersed in the water of 25 DEG C, the height that after measuring 15 minutes, water rises
Degree.
Table 1
The invention is not restricted to embodiment here, those skilled in the art are according to the announcement of the present invention, no
Depart from the improvement made of scope and amendment all should protection scope of the present invention it
In.
Claims (1)
1. a natural fiber softener, it is characterised in that be made up of the component comprising following weight portion:
Diquaternary polydimethylsiloxane: 10-20 part, sodium alginate: 5-15 part,
Polyethylene Glycol: 5-15 part, serine: 1-3 part, zinc oxide: 2-3 part,
Lignin: 2-5 part, boric acid: 0.5-2 part, deionized water: 100 parts；
Described Polyethylene Glycol be relative molecular weight be Polyethylene Glycol and the mixing of Polyethylene Glycol that relative molecular weight is 800 of 400；
Described relative molecular weight be Polyethylene Glycol and the relative molecular weight of 400 be the mass ratio of the Polyethylene Glycol of 800 be 1:1；
Described a kind of natural fiber softener is prepared by the preparation method comprised the following steps:
(1) in 30 parts of deionized waters, add sodium alginate 5-15 part, Polyethylene Glycol 5-15 part, serine 1-3 part, zinc oxide 2-3 part, lignin 2-5 part and diquaternary polydimethylsiloxane 10-20 part, at 40-50 DEG C, stir；
(2) in the solution of step (1), add the deionized water of 70 parts, be slowly added to boric acid 0.5-2 part, stir, obtain natural fiber softener；
In described step (1), stir speed (S.S.) is 1200 revs/min, and mixing time is 1-3 hour.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410215833.XA CN103981721B (en) | 2014-05-21 | 2014-05-21 | A kind of natural fiber softener and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410215833.XA CN103981721B (en) | 2014-05-21 | 2014-05-21 | A kind of natural fiber softener and preparation method thereof |
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| Publication Number | Publication Date |
|---|---|
| CN103981721A CN103981721A (en) | 2014-08-13 |
| CN103981721B true CN103981721B (en) | 2016-08-03 |
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| CN201410215833.XA Expired - Fee Related CN103981721B (en) | 2014-05-21 | 2014-05-21 | A kind of natural fiber softener and preparation method thereof |
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Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN104532572A (en) * | 2014-12-24 | 2015-04-22 | 湖州市菱湖重兆金辉丝织厂 | Novel electrostatic removal agent for textile materials and preparation method of novel electrostatic removal agent |
| CN105839393A (en) * | 2015-09-09 | 2016-08-10 | 杨恩弟 | Multifunctional multielement textile finishing agent |
| CN105064021A (en) * | 2015-09-11 | 2015-11-18 | 无锡市长安曙光手套厂 | Destaticizer, preparation method and textile materials containing destaticizer |
| CN105220497A (en) * | 2015-10-20 | 2016-01-06 | 湖州博润实业有限公司 | A kind of new type natural fiber softener and preparation method thereof |
| CN105220499A (en) * | 2015-11-13 | 2016-01-06 | 付淑珍 | A kind of novel electrostatic prevention, degerming fiber treatment materials and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| FR2831802B1 (en) * | 2001-11-08 | 2004-10-15 | Oreal | COSMETIC COMPOSITIONS CONTAINING AN AMINO SILICONE AND A THICKENING AGENT AND THEIR USES |
| JP2010090523A (en) * | 2008-10-11 | 2010-04-22 | Kanehisa:Kk | Antibacterial deodorization-bacteriostatic processing method for fibrous structure |
| CN103349622B (en) * | 2013-07-15 | 2015-10-21 | 澳宝化妆品（惠州）有限公司 | The shampoo that the maintenance of a kind of gentleness soft specially good effect is anti-dandruff |
| CN103437170B (en) * | 2013-09-14 | 2015-10-28 | 邢柯君 | Multiple-effect softening and lubricating agent of a kind of weaving face fabric and its production and use |
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Effective date of registration: 20230605 Address after: 528300 Jun'an Community Residents Committee, Jun'an Town, Shunde District, Foshan City, Guangdong Province Patentee after: Foshan Magic Crystal Technology Development Co.,Ltd. Address before: 215200 Gao Xin Village, Songling Town, Wujiang District, Suzhou, Jiangsu Patentee before: WUJIANG YINGLIDA PLASTIC PACKAGE Co.,Ltd. |
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Granted publication date: 20160803 |