CN103974942B - 在沸点高于60℃且低于200℃(在标准压力下，简称为低沸化合物)存在下由糖溶液制备5-羟甲基糠醛(hmf) - Google Patents

在沸点高于60℃且低于200℃(在标准压力下，简称为低沸化合物)存在下由糖溶液制备5-羟甲基糠醛(hmf) Download PDF

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Publication number
CN103974942B
CN103974942B CN201280059041.7A CN201280059041A CN103974942B CN 103974942 B CN103974942 B CN 103974942B CN 201280059041 A CN201280059041 A CN 201280059041A CN 103974942 B CN103974942 B CN 103974942B
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hmf
methods
boiler
fructose
low
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Chinese (zh)
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CN103974942A (zh
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R·贝克斯
B·布兰科
A·金德勒
C·菲尔内尔
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BASF SE
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BASF SE
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D307/38—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D307/40—Radicals substituted by oxygen atoms
    • C07D307/46—Doubly bound oxygen atoms, or two oxygen atoms singly bound to the same carbon atom

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Furan Compounds (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Saccharide Compounds (AREA)
CN201280059041.7A 2011-12-13 2012-12-11 在沸点高于60℃且低于200℃(在标准压力下，简称为低沸化合物)存在下由糖溶液制备5-羟甲基糠醛(hmf) Expired - Fee Related CN103974942B (zh)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
EP11193157 2011-12-13
EP11193157.2 2011-12-13
EP12180908.1 2012-08-17
EP12180908 2012-08-17
PCT/EP2012/075059 WO2013087614A1 (de) 2011-12-13 2012-12-11 HERSTELLUNG VON 5-HYDROXYMETHYLFURFURAL (HMF) AUS SACCHARIDLÖSUNGEN IN GEGENWART EINES LÖSEMITTELS MIT EINEM SIEDEPUNKT GRÖßER 60°C UND KLEINER 200°C (BEI NORMALDRUCK, KURZ LEICHTSIEDER GENANNT)

Publications (2)

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CN103974942A CN103974942A (zh) 2014-08-06
CN103974942B true CN103974942B (zh) 2016-08-24

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CN201280059041.7A Expired - Fee Related CN103974942B (zh) 2011-12-13 2012-12-11 在沸点高于60℃且低于200℃(在标准压力下，简称为低沸化合物)存在下由糖溶液制备5-羟甲基糠醛(hmf)

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EP (1) EP2791125B1 (enExample)
JP (1) JP6073364B2 (enExample)
KR (1) KR20140101850A (enExample)
CN (1) CN103974942B (enExample)
BR (1) BR112014014052B1 (enExample)
CA (1) CA2856466A1 (enExample)
ES (1) ES2648908T3 (enExample)
HU (1) HUE034627T2 (enExample)
IN (1) IN2014CN04393A (enExample)
RU (1) RU2014128459A (enExample)
WO (1) WO2013087614A1 (enExample)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9156802B2 (en) 2011-12-13 2015-10-13 Basf Se Separating off 5-hydroxymethylfurfural (HMF) from reaction solutions by steam distillation
US9611241B2 (en) * 2014-01-27 2017-04-04 Rennovia Inc. Conversion of fructose-containing feedstocks to HMF-containing product
WO2016207025A1 (de) 2015-06-24 2016-12-29 Basf Se Verfahren zum herstellen und abtrennen von hmf
CN108473455A (zh) * 2015-11-04 2018-08-31 巴斯夫欧洲公司 用于制备包含5-(羟基甲基)糠醛和特定的hmf酯的混合物的方法
RU187166U1 (ru) * 2018-11-15 2019-02-21 Нина Владимировна Смирнова Лабораторно-исследовательский стенд для изучения процессов дегидратации углеводов
CN113825745B (zh) * 2019-04-15 2025-04-04 斯道拉恩索公司 用于回收溶剂和分离腐殖质材料及其组合物的方法

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US4400468A (en) * 1981-10-05 1983-08-23 Hydrocarbon Research Inc. Process for producing adipic acid from biomass
CN101456850A (zh) * 2007-12-12 2009-06-17 中国科学院大连化学物理研究所 一种制备5-羟甲基糠醛的方法
CN101812039A (zh) * 2010-05-14 2010-08-25 天津大学 一种利用离子液体催化生成5-羟甲基糠醛的方法

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US2929823A (en) * 1956-11-26 1960-03-22 Merck & Co Inc Production of 5-hydroxymethylfurfural
US3201331A (en) * 1962-10-17 1965-08-17 Atlas Chem Ind Purification of hydroxymethyl furfural
DE3601281A1 (de) 1986-01-17 1987-07-23 Sueddeutsche Zucker Ag Verfahren zur herstellung von 5-hydroxymethylfurfural einschliesslich eines kristallinen produktes unter ausschliesslicher verwendung von wasser als loesungsmittel
FR2664273B1 (fr) 1990-06-27 1994-04-29 Beghin Say Sa Nouveau procede de preparation du 5-hydroxymethylfurfural a partir de saccharides.
FR2663933B1 (fr) 1990-06-27 1994-06-17 Beghin Say Sa Nouveau procede de preparation du 5-hydroxymethylfurfural a partir de saccharides.
DE10202838A1 (de) 2002-01-24 2003-08-07 Basf Ag Verfahren zur Abtrennung von Säuren aus chemischen Reaktionsgemischen mit Hilfe von ionischen Flüssigkeiten
EP1834951A1 (en) 2006-03-10 2007-09-19 Avantium International B.V. Method for the synthesis of organic acid esters of 5-hydroxymethylfurfural and their use
EP1834950A1 (en) 2006-03-10 2007-09-19 Avantium International B.V. Method for the synthesis of 5-alkoxymethylfurfural ethers and their use
BRPI0806908A2 (pt) 2007-01-23 2014-04-29 Basf Se Processos para a prepração de um produto de glicose a partir de um material lignocelulósico, e para a preparação de um produto de metabolismo microbiano, produto de glicose, e, produto de lignina
CN101617055A (zh) 2007-01-23 2009-12-30 巴斯夫欧洲公司 通过对使用含多原子阴离子的离子液体从含木素纤维素的材料得到的纤维素进行酶促水解来制备葡萄糖的方法
EP2033958A1 (en) * 2007-09-07 2009-03-11 Furanix Technologies B.V Hydroxymethylfurfural ethers from sugars and di- and triols
CN102399203B (zh) 2011-12-19 2014-05-07 浙江大学 一种离子液体降解碳水化合物制备5-羟甲基糠醛的方法

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4400468A (en) * 1981-10-05 1983-08-23 Hydrocarbon Research Inc. Process for producing adipic acid from biomass
CN101456850A (zh) * 2007-12-12 2009-06-17 中国科学院大连化学物理研究所 一种制备5-羟甲基糠醛的方法
CN101812039A (zh) * 2010-05-14 2010-08-25 天津大学 一种利用离子液体催化生成5-羟甲基糠醛的方法

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
离子液体中金属氯化物催化糖脱水制备5-羟甲基糠醛;代学民;《中国优秀硕士学位论文全文数据库工程科技Ⅰ辑》;20090915(第09 期);第32页 *

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RU2014128459A (ru) 2016-02-10
BR112014014052B1 (pt) 2019-03-26
JP6073364B2 (ja) 2017-02-01
ES2648908T3 (es) 2018-01-08
BR112014014052A2 (pt) 2017-06-13
EP2791125A1 (de) 2014-10-22
IN2014CN04393A (enExample) 2015-09-04
WO2013087614A1 (de) 2013-06-20
HUE034627T2 (en) 2018-02-28
CA2856466A1 (en) 2013-06-20
EP2791125B1 (de) 2017-08-23
CN103974942A (zh) 2014-08-06
KR20140101850A (ko) 2014-08-20
JP2015501821A (ja) 2015-01-19

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Granted publication date: 20160824