IN2014CN04393A - - Google Patents

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Publication number
IN2014CN04393A
IN2014CN04393A IN4393CHN2014A IN2014CN04393A IN 2014CN04393 A IN2014CN04393 A IN 2014CN04393A IN 4393CHN2014 A IN4393CHN2014 A IN 4393CHN2014A IN 2014CN04393 A IN2014CN04393 A IN 2014CN04393A
Authority
IN
India
Prior art keywords
hmf
called
short
reaction vessel
boiling point
Prior art date
Application number
Inventor
René Backes
Benoit Blank
Alois Kindler
Carmen Feldner
Original Assignee
Basf Se
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Se filed Critical Basf Se
Publication of IN2014CN04393A publication Critical patent/IN2014CN04393A/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D307/38—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D307/40—Radicals substituted by oxygen atoms
    • C07D307/46—Doubly bound oxygen atoms, or two oxygen atoms singly bound to the same carbon atom

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Saccharide Compounds (AREA)
  • Furan Compounds (AREA)

Abstract

A process for preparing 5 hydroxymethylfurfural (HMF) characterized in that a) solutions (called starting solution hereinafter) comprising one or more saccharides and an organic solvent having a boiling point greater than 200°C (at standard pressure) (called high boiler for short) and water and a solvent having a boiling point greater than 60°C and less than 200°C (at standard pressure called low boiler for short) are supplied to a reaction vessel b) a conversion of the hexose to HMF in the presence of steam with simultaneous distillative removal of the HMF is effected in the reaction vessel and c) the distillate obtained is an aqueous HMF containing solution (called distillate hereinafter).
IN4393CHN2014 2011-12-13 2012-12-11 IN2014CN04393A (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP11193157 2011-12-13
EP12180908 2012-08-17
PCT/EP2012/075059 WO2013087614A1 (en) 2011-12-13 2012-12-11 Preparation of 5-hydroxymethylfurfural (hmf) from saccharide solutions in the presence of a solvent having a boiling point greater than 60°c and less than 200°c (at standard pressure, called low boiler for short)

Publications (1)

Publication Number Publication Date
IN2014CN04393A true IN2014CN04393A (en) 2015-09-04

Family

ID=47351664

Family Applications (1)

Application Number Title Priority Date Filing Date
IN4393CHN2014 IN2014CN04393A (en) 2011-12-13 2012-12-11

Country Status (11)

Country Link
EP (1) EP2791125B1 (en)
JP (1) JP6073364B2 (en)
KR (1) KR20140101850A (en)
CN (1) CN103974942B (en)
BR (1) BR112014014052B1 (en)
CA (1) CA2856466A1 (en)
ES (1) ES2648908T3 (en)
HU (1) HUE034627T2 (en)
IN (1) IN2014CN04393A (en)
RU (1) RU2014128459A (en)
WO (1) WO2013087614A1 (en)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9156802B2 (en) 2011-12-13 2015-10-13 Basf Se Separating off 5-hydroxymethylfurfural (HMF) from reaction solutions by steam distillation
JP2017505310A (en) * 2014-01-27 2017-02-16 レノビア インコーポレイテッド Conversion of fructose-containing feedstock to HMF-containing product
WO2016207025A1 (en) 2015-06-24 2016-12-29 Basf Se Method for synthesizing and separating hmf
CN108473455A (en) * 2015-11-04 2018-08-31 巴斯夫欧洲公司 The method for being used to prepare the mixture comprising 5- (hydroxymethyl) furfurals and specific HMF esters
RU187166U1 (en) * 2018-11-15 2019-02-21 Нина Владимировна Смирнова LABORATORY RESEARCH STAND FOR STUDYING CARBOHYDRATE DEHYDRATION PROCESSES
CN113825745A (en) * 2019-04-15 2021-12-21 斯道拉恩索公司 Process for recovering solvents and separating humus materials and compositions thereof

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2929823A (en) * 1956-11-26 1960-03-22 Merck & Co Inc Production of 5-hydroxymethylfurfural
US3201331A (en) * 1962-10-17 1965-08-17 Atlas Chem Ind Purification of hydroxymethyl furfural
US4400468A (en) * 1981-10-05 1983-08-23 Hydrocarbon Research Inc. Process for producing adipic acid from biomass
DE3601281A1 (en) 1986-01-17 1987-07-23 Sueddeutsche Zucker Ag METHOD FOR PRODUCING 5-HYDROXYMETHYLFURFURAL, INCLUDING A CRYSTALINE PRODUCT, WITH THE EXCLUSIVE USE OF WATER AS A SOLVENT
FR2664273B1 (en) 1990-06-27 1994-04-29 Beghin Say Sa NEW PROCESS FOR THE PREPARATION OF 5-HYDROXYMETHYLFURFURAL FROM SACCHARIDES.
FR2663933B1 (en) 1990-06-27 1994-06-17 Beghin Say Sa NEW PROCESS FOR THE PREPARATION OF 5-HYDROXYMETHYLFURFURAL FROM SACCHARIDES.
DE10202838A1 (en) 2002-01-24 2003-08-07 Basf Ag Separation of acids from reaction mixtures by means of an auxiliary base that forms a liquid salt with the acid to result in two non-miscible phases with the product or solution of the product in a suitable solvent
EP1834950A1 (en) 2006-03-10 2007-09-19 Avantium International B.V. Method for the synthesis of 5-alkoxymethylfurfural ethers and their use
EP2053047A1 (en) 2006-03-10 2009-04-29 Furanix Technologies B.V Method for the synthesis of organic acid esters of 5-hydroxymethylfurfural and their use
CN101589153A (en) 2007-01-23 2009-11-25 巴斯夫欧洲公司 Method for producing glucose by enzymatic hydrolysis of cellulose that can be pretreated with an ionic liquid containing a polyatomic anion
US20100081798A1 (en) 2007-01-23 2010-04-01 Basf Se Method for producing glucose by enzymatic hydrolysis of cellulose that is obtained from material containing ligno-cellulose using an ionic liquid that comprises a polyatomic anion
EP2033958A1 (en) * 2007-09-07 2009-03-11 Furanix Technologies B.V Hydroxymethylfurfural ethers from sugars and di- and triols
CN101456850A (en) * 2007-12-12 2009-06-17 中国科学院大连化学物理研究所 Method for preparing 5-hydroxymethyl-furfural
CN101812039B (en) * 2010-05-14 2012-09-26 天津大学 Method for generating 5-hydroxymethylfurfural by using ionic liquid catalysis
CN102399203B (en) 2011-12-19 2014-05-07 浙江大学 Method for preparing 5-hydroxymethylfurfural by degrading carbonhydrate through ionic liquid

Also Published As

Publication number Publication date
KR20140101850A (en) 2014-08-20
ES2648908T3 (en) 2018-01-08
CA2856466A1 (en) 2013-06-20
JP6073364B2 (en) 2017-02-01
CN103974942B (en) 2016-08-24
RU2014128459A (en) 2016-02-10
HUE034627T2 (en) 2018-02-28
CN103974942A (en) 2014-08-06
JP2015501821A (en) 2015-01-19
EP2791125B1 (en) 2017-08-23
EP2791125A1 (en) 2014-10-22
BR112014014052A2 (en) 2017-06-13
WO2013087614A1 (en) 2013-06-20
BR112014014052B1 (en) 2019-03-26

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