BR112015016768A2 - process for producing ethanol and furfural from a mixture of pentoses and hexoses; process for producing furfural from a mixture of pentoses and hexoses; continuous process for producing furfural from a mixture of pentoses and hexoses; and continuous process to produce furan from a mixture of pentoses and hexoses - Google Patents

process for producing ethanol and furfural from a mixture of pentoses and hexoses; process for producing furfural from a mixture of pentoses and hexoses; continuous process for producing furfural from a mixture of pentoses and hexoses; and continuous process to produce furan from a mixture of pentoses and hexoses

Info

Publication number
BR112015016768A2
BR112015016768A2 BR112015016768A BR112015016768A BR112015016768A2 BR 112015016768 A2 BR112015016768 A2 BR 112015016768A2 BR 112015016768 A BR112015016768 A BR 112015016768A BR 112015016768 A BR112015016768 A BR 112015016768A BR 112015016768 A2 BR112015016768 A2 BR 112015016768A2
Authority
BR
Brazil
Prior art keywords
pentoses
hexoses
mixture
furfural
producing
Prior art date
Application number
BR112015016768A
Other languages
Portuguese (pt)
Inventor
Hilaly Ahmad
Sanborn Alexandra
Binder Tom
Christopher Hoffman William
Original Assignee
Archer Daniels Midland Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Archer Daniels Midland Co filed Critical Archer Daniels Midland Co
Publication of BR112015016768A2 publication Critical patent/BR112015016768A2/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P7/00—Preparation of oxygen-containing organic compounds
    • C12P7/02—Preparation of oxygen-containing organic compounds containing a hydroxy group
    • C12P7/04—Preparation of oxygen-containing organic compounds containing a hydroxy group acyclic
    • C12P7/06—Ethanol, i.e. non-beverage
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D11/00—Solvent extraction
    • B01D11/04—Solvent extraction of solutions which are liquid
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/04—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members
    • C07D307/06—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, directly attached to ring carbon atoms
    • C07D307/08—Preparation of tetrahydrofuran
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D307/36—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, directly attached to ring carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D307/38—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D307/40—Radicals substituted by oxygen atoms
    • C07D307/46—Doubly bound oxygen atoms, or two oxygen atoms singly bound to the same carbon atom
    • C07D307/48—Furfural
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D307/38—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D307/40—Radicals substituted by oxygen atoms
    • C07D307/46—Doubly bound oxygen atoms, or two oxygen atoms singly bound to the same carbon atom
    • C07D307/48—Furfural
    • C07D307/50—Preparation from natural products
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P17/00—Preparation of heterocyclic carbon compounds with only O, N, S, Se or Te as ring hetero atoms
    • C12P17/02—Oxygen as only ring hetero atoms
    • C12P17/04—Oxygen as only ring hetero atoms containing a five-membered hetero ring, e.g. griseofulvin, vitamin C
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P7/00—Preparation of oxygen-containing organic compounds
    • C12P7/02—Preparation of oxygen-containing organic compounds containing a hydroxy group
    • C12P7/04—Preparation of oxygen-containing organic compounds containing a hydroxy group acyclic
    • C12P7/06—Ethanol, i.e. non-beverage
    • C12P7/08—Ethanol, i.e. non-beverage produced as by-product or from waste or cellulosic material substrate
    • C12P7/10—Ethanol, i.e. non-beverage produced as by-product or from waste or cellulosic material substrate substrate containing cellulosic material
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/10—Biofuels, e.g. bio-diesel

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Zoology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Microbiology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Biotechnology (AREA)
  • Health & Medical Sciences (AREA)
  • Biochemistry (AREA)
  • Bioinformatics & Cheminformatics (AREA)
  • General Engineering & Computer Science (AREA)
  • General Health & Medical Sciences (AREA)
  • Genetics & Genomics (AREA)
  • Preparation Of Compounds By Using Micro-Organisms (AREA)
  • Furan Compounds (AREA)

Abstract

resumo processo para produzir etanol e furfural a partir de uma mistura de pentoses e hexoses; processo para produzir furfural a partir de uma mistura de pentoses e hexoses; processo contínuo para produzir furfural a partir de uma mistura de pentoses e hexoses; e processo contínuo para produzir furano a partir de uma mistura de pentoses e hexoses são descritos processos para produzir furfural a partir de uma mistura de pentoses e hexoses, por desidratação e ciclização de pentoses para produzir furfural usando um ácido hidrossolúvel em temperaturas elevadas na presença de um solvente orgânico imiscível em água, de baixo ponto de ebulição, como o tolueno, que é eficaz para extrair o furfural em uma porção de fase orgânica. em certas modalidades, uma etapa de fermentação ocorre antes da etapa de desidratação para converter as hexoses, na mistura de pentoses e hexoses, em etanol, preservando concomitantemente as pentoses para produzir o furfural. 32 1/1process for producing ethanol and furfural from a mixture of pentoses and hexoses; process for producing furfural from a mixture of pentoses and hexoses; continuous process for producing furfural from a mixture of pentoses and hexoses; and continuous process for producing furan from a mixture of pentoses and hexoses are described processes for producing furfural from a mixture of pentoses and hexoses, by dehydration and cyclization of pentoses to produce furfural using a water soluble acid at elevated temperatures in the presence of a low boiling, water-immiscible organic solvent, such as toluene, which is effective for extracting furfural in a portion of the organic phase. In certain embodiments, a fermentation step occurs prior to the dehydration step to convert the hexoses, in the mixture of pentoses and hexoses, to ethanol, while preserving the pentoses to produce furfural. 32 1/1

BR112015016768A 2014-02-20 2015-05-22 process for producing ethanol and furfural from a mixture of pentoses and hexoses; process for producing furfural from a mixture of pentoses and hexoses; continuous process for producing furfural from a mixture of pentoses and hexoses; and continuous process to produce furan from a mixture of pentoses and hexoses BR112015016768A2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201461942188P 2014-02-20 2014-02-20
PCT/US2015/013192 WO2015126581A1 (en) 2014-02-20 2015-01-28 Process for making furfural

Publications (1)

Publication Number Publication Date
BR112015016768A2 true BR112015016768A2 (en) 2017-07-11

Family

ID=53878807

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112015016768A BR112015016768A2 (en) 2014-02-20 2015-05-22 process for producing ethanol and furfural from a mixture of pentoses and hexoses; process for producing furfural from a mixture of pentoses and hexoses; continuous process for producing furfural from a mixture of pentoses and hexoses; and continuous process to produce furan from a mixture of pentoses and hexoses

Country Status (7)

Country Link
EP (1) EP2931906A4 (en)
JP (1) JP2017506083A (en)
KR (1) KR20160120196A (en)
CN (1) CN105378092A (en)
BR (1) BR112015016768A2 (en)
CA (1) CA2897613A1 (en)
WO (1) WO2015126581A1 (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6961963B2 (en) 2016-04-01 2021-11-05 三菱ケミカル株式会社 Furfural manufacturing method
EP3464256B1 (en) * 2016-06-03 2020-07-29 E. I. du Pont de Nemours and Company Process for the production of furfural using a water-immiscible organic solvent
WO2018085174A1 (en) * 2016-11-01 2018-05-11 Shell Oil Company Process for the recovery of furfural
TWI768017B (en) 2017-05-30 2022-06-21 日商保土谷化學工業股份有限公司 Process for producing bio-based polyether polyol, bio-based polyether polyol and bio-based polyurethane resin

Family Cites Families (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2846449A (en) 1956-08-15 1958-08-05 Du Pont Production of tetrahydrofuran
US5562777A (en) 1993-03-26 1996-10-08 Arkenol, Inc. Method of producing sugars using strong acid hydrolysis of cellulosic and hemicellulosic materials
EP1268460A2 (en) 2000-03-27 2003-01-02 E.I. Dupont De Nemours And Company Oxidaton of 5-(hydroxymethyl) furfural to 2,5-diformylfuran and subsequent decarbonylation to unsubstituted furan
US7572925B2 (en) * 2006-06-06 2009-08-11 Wisconsin Alumni Research Foundation Catalytic process for producing furan derivatives in a biphasic reactor
WO2011073253A1 (en) * 2009-12-16 2011-06-23 Shell Internationale Research Maatschappij B.V. Method for producing furfural from lignocellulosic biomass material
US8524924B2 (en) 2010-12-21 2013-09-03 E I Du Pont De Nemours And Company Process for furfural production from biomass
WO2012088208A2 (en) * 2010-12-21 2012-06-28 E. I. Du Pont De Nemours And Company Methods for furfural production from branched non-fermentable sugars in stillage or syrup
US10108783B2 (en) 2011-07-05 2018-10-23 Saudi Arabian Oil Company Systems, computer medium and computer-implemented methods for monitoring health of employees using mobile devices
US20140227742A1 (en) 2011-09-23 2014-08-14 Archer Daniels Midland Company C1-C2 Organic Acid Treatment of Lignocellulosic Biomass to Produce Acylated Cellulose Pulp, Hemicellulose, Lignin and Sugars and Fermentation of the Sugars
US8524925B2 (en) 2011-10-31 2013-09-03 E I Du Pont De Nemours And Company Production of furfural from biomass
US9181211B2 (en) 2011-12-28 2015-11-10 E I Du Pont De Nemours And Company Process for the production of furfural
CN104024238B (en) 2011-12-28 2016-07-06 纳幕尔杜邦公司 For the method preparing furfural
US20130172585A1 (en) 2011-12-28 2013-07-04 E I Du Pont De Nemours And Company Process for the production of furfural
WO2013102002A1 (en) 2011-12-28 2013-07-04 E. I. Du Pont De Nemours And Company Processes for making furfurals
EP2797905A4 (en) 2011-12-28 2015-07-08 Du Pont Process for the production of furfural
US20130168227A1 (en) 2011-12-28 2013-07-04 E I Du Pont De Nemours And Company Process for the production of furfural
DK2872495T3 (en) * 2012-07-13 2016-12-12 Dsm Ip Assets Bv METHOD OF PRODUCING furfural and levulinic OF lignocellulosic biomass
US9538658B2 (en) 2012-07-18 2017-01-03 Zte (Usa) Inc. Compact low loss transition with an integrated coupler

Also Published As

Publication number Publication date
CN105378092A (en) 2016-03-02
JP2017506083A (en) 2017-03-02
KR20160120196A (en) 2016-10-17
EP2931906A4 (en) 2016-07-13
WO2015126581A1 (en) 2015-08-27
EP2931906A1 (en) 2015-10-21
CA2897613A1 (en) 2015-08-20

Similar Documents

Publication Publication Date Title
ES2406189R1 (en) Procedure for lipid extraction from algae biomass
BR112012029213A2 (en) process for separating furfural from a liquid aqueous phase, and use of an aromatic hydrocarbon compound
BR112016011986A2 (en) LIGNIN DEPOLYMERIZATION METHOD
WO2012115706A3 (en) Process for furfural production from biomass
AR093155A1 (en) METHODS FOR THE PRODUCTION OF 5- (HALOMETIL) FURFURAL
BR112016030661B8 (en) Closed-loop process to convert biomass to furfuraldehyde
BR112015029141B8 (en) process for extracting ferulic acid, and process for producing natural vanillin
BR112015020685A2 (en) butanol recovery method, composition, alcohol extraction and drying methods
CU20140135A7 (en) PROCESS FOR THE PREPARATION OF TREPROSTINIL AND DERIVED FROM THEM
BR112012024133A2 (en) method for producing 5-hydroxymethylfurfural and for converting hmf, and use of 2,5-furanedicarboxylic acid
IN2014DN06715A (en)
BR112016029597A2 (en) process for selective oxidation of 5-hydroxymethylfurfural
BR112015016768A2 (en) process for producing ethanol and furfural from a mixture of pentoses and hexoses; process for producing furfural from a mixture of pentoses and hexoses; continuous process for producing furfural from a mixture of pentoses and hexoses; and continuous process to produce furan from a mixture of pentoses and hexoses
EA201390303A1 (en) REFINED PLANT OIL AND METHOD FOR ITS PREPARATION
ES2531212T3 (en) Procedure for removing siloxane-based derivatives from a liquid organic phase
BR112018011492A2 (en) process for the production of 2,5-furanedicarboxylic acid (fdca
WO2016106094A3 (en) Metal-organic frameworks for the conversion of lignocellulosic derivatives to renewable platform chemicals
WO2012031356A3 (en) Biomass extraction process
BR112017012473A2 (en) process for the production of solid saccharides from an aqueous saccharide solution.
BR112016013316A8 (en) method for the production of furfural and use of methanesulfonic acid
EA201491189A1 (en) METHOD OF OBTAINING LEVULINIC ACID
ES2571043T3 (en) Dihydropyridine Preparation
BR112013015693A2 (en) method for furfural production
BR112018007709A2 (en) A process for producing 5-hydroxymethylfurfural in the presence of a Lewis acid type catalyst and / or a heterogeneous base type catalyst and a homogeneous organic acid type catalyst in the presence of at least one polar aprotic solvent
BR112017010824A2 (en) process for preparing ethylene

Legal Events

Date Code Title Description
B08F Application fees: dismissal - article 86 of industrial property law
B08K Lapse as no evidence of payment of the annual fee has been furnished to inpi (acc. art. 87)