CN103946150B - 用于增加合成气的氢含量的方法 - Google Patents

用于增加合成气的氢含量的方法 Download PDF

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Publication number
CN103946150B
CN103946150B CN201280056318.0A CN201280056318A CN103946150B CN 103946150 B CN103946150 B CN 103946150B CN 201280056318 A CN201280056318 A CN 201280056318A CN 103946150 B CN103946150 B CN 103946150B
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Prior art keywords
gas
flow
shift
water
catalyst
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Expired - Fee Related
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CN201280056318.0A
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English (en)
Chinese (zh)
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CN103946150A (zh
Inventor
P·E·J·艾伯特
G·B·库姆斯
R·J·比维斯
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Johnson Matthey PLC
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Johnson Matthey PLC
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    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/06—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
    • C01B3/12—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide
    • C01B3/16—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide using catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K3/00—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide
    • C10K3/02—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide by catalytic treatment
    • C10K3/04—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide by catalytic treatment reducing the carbon monoxide content, e.g. water-gas shift [WGS]
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0283—Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step
    • C01B2203/0288—Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step containing two CO-shift steps
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0283—Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step
    • C01B2203/0294—Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step containing three or more CO-shift steps
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0415—Purification by absorption in liquids
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465—Composition of the impurity
    • C01B2203/0475—Composition of the impurity the impurity being carbon dioxide
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465—Composition of the impurity
    • C01B2203/0485—Composition of the impurity the impurity being a sulfur compound
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465—Composition of the impurity
    • C01B2203/0495—Composition of the impurity the impurity being water
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08—Methods of heating or cooling
    • C01B2203/0872—Methods of cooling
    • C01B2203/0883—Methods of cooling by indirect heat exchange
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1047—Group VIII metal catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1047—Group VIII metal catalysts
    • C01B2203/1052—Nickel or cobalt catalysts

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Industrial Gases (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN201280056318.0A 2011-11-18 2012-10-10 用于增加合成气的氢含量的方法 Expired - Fee Related CN103946150B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
GB1119960.1 2011-11-18
GBGB1119960.1A GB201119960D0 (en) 2011-11-18 2011-11-18 Process
PCT/GB2012/052506 WO2013072660A1 (en) 2011-11-18 2012-10-10 Process for increasing hydrogen content of synthesis gas

Publications (2)

Publication Number Publication Date
CN103946150A CN103946150A (zh) 2014-07-23
CN103946150B true CN103946150B (zh) 2015-11-25

Family

ID=45475394

Family Applications (1)

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CN201280056318.0A Expired - Fee Related CN103946150B (zh) 2011-11-18 2012-10-10 用于增加合成气的氢含量的方法

Country Status (8)

Country Link
US (1) US9206044B2 (enExample)
JP (1) JP2014533646A (enExample)
CN (1) CN103946150B (enExample)
AU (1) AU2012338628B2 (enExample)
CA (1) CA2853530A1 (enExample)
GB (2) GB201119960D0 (enExample)
IN (1) IN2014DN03289A (enExample)
WO (1) WO2013072660A1 (enExample)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9458014B2 (en) * 2012-12-28 2016-10-04 General Electronic Company Sytems and method for CO2 capture and H2 separation with three water-gas shift reactions and warm desulfurization
DE102013224037A1 (de) 2013-11-25 2015-05-28 Siemens Aktiengesellschaft Aufbereitung und Konditionierung von Syntheserohgasen
DE102013224039A1 (de) 2013-11-25 2015-05-28 Clariant International Ltd. Behandlung von Synthesegasen aus einer Vergasungseinrichtung
JP2016122346A (ja) * 2014-12-25 2016-07-07 株式会社東芝 空気供給システム
DE102018113743A1 (de) * 2018-06-08 2019-12-12 Thyssenkrupp Ag Verfahren und Vorrichtungen zur Durchführung einer Wassergas-Shift-Reaktion sowie die Verwendung mindestens zweier seriell oder parallel geschalteter Einheiten zur Niedertemperatur-CO-Konvertierung
CN109181782B (zh) * 2018-09-30 2020-07-24 中石化宁波工程有限公司 一种配套水煤浆气化的气冷并水冷等温变换工艺
DE102018007868A1 (de) * 2018-10-05 2020-04-09 Linde Aktiengesellschaft Verfahren und Vorrichtung zur Erzeugung von Gasprodukten unter Verwendung eines Shift-Konventers
GB2593939B (en) * 2020-04-09 2022-04-27 Velocys Tech Limited Manufacture of a synthetic fuel
GB202009970D0 (en) * 2020-06-30 2020-08-12 Johnson Matthey Plc Low-carbon hydrogen process
GB202009969D0 (en) * 2020-06-30 2020-08-12 Johnson Matthey Plc Low-carbon hydrogen process
FR3112537B1 (fr) 2020-07-14 2023-03-31 Engie Dispositif et procédé de production hybride de dihydrogène de synthèse et/ou de méthane de synthèse
CN112047299A (zh) * 2020-09-14 2020-12-08 湖南安淳高新技术有限公司 煤气的co变换工艺及变换装置
US11617984B2 (en) 2020-09-24 2023-04-04 Dastur Energy, Inc. System and method for conditioning syngas and capturing carbon dioxide from conditioned syngas for production of power, chemicals, and other value added products
CN113457444B (zh) * 2021-07-19 2023-02-28 重庆朗福环保科技有限公司 一种一氧化碳脱除系统

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3666682A (en) * 1969-11-26 1972-05-30 Texaco Inc Water-gas shift conversion process
US3825501A (en) * 1969-11-26 1974-07-23 Texaco Inc Exothermic reaction process
US5464606A (en) * 1994-05-27 1995-11-07 Ballard Power Systems Inc. Two-stage water gas shift conversion method
WO2010013026A1 (en) * 2008-08-01 2010-02-04 Johnson Matthey Plc Process for increasing hydrogen content of synthesis gas
CN101955153A (zh) * 2010-09-28 2011-01-26 山东齐鲁科力化工研究院有限公司 一种高浓度co耐硫变换工艺

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4721611A (en) * 1984-03-02 1988-01-26 Imperial Chemical Industries Plc Hydrogen production
GB9820608D0 (en) 1998-09-23 1998-11-11 Ici Plc Hydrogen
US20020061277A1 (en) * 2000-09-25 2002-05-23 Engelhard Corporation Non-pyrophoric water-gas shift reaction catalysts
US20040082669A1 (en) * 2002-10-28 2004-04-29 Ruettinger Wolfgang Friedrich Operating conditions for copper-based water-gas shift catalysts
US20050101740A1 (en) * 2003-09-01 2005-05-12 Nathalie Mougin Block ethylenic copolymers comprising a vinyllactam block, cosmetic compositions containing them and cosmetic use of these copolymers
US7503947B2 (en) * 2005-12-19 2009-03-17 Eastman Chemical Company Process for humidifying synthesis gas
CN102159500A (zh) 2008-08-18 2011-08-17 辛吉斯特公司 由生物质生产氨的方法
JP2012520819A (ja) 2009-03-19 2012-09-10 シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー 水素に富むガス混合物を調製する方法
GB0919385D0 (en) 2009-11-05 2009-12-23 Johnson Matthey Plc Process

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3666682A (en) * 1969-11-26 1972-05-30 Texaco Inc Water-gas shift conversion process
US3825501A (en) * 1969-11-26 1974-07-23 Texaco Inc Exothermic reaction process
US5464606A (en) * 1994-05-27 1995-11-07 Ballard Power Systems Inc. Two-stage water gas shift conversion method
WO2010013026A1 (en) * 2008-08-01 2010-02-04 Johnson Matthey Plc Process for increasing hydrogen content of synthesis gas
CN101955153A (zh) * 2010-09-28 2011-01-26 山东齐鲁科力化工研究院有限公司 一种高浓度co耐硫变换工艺

Also Published As

Publication number Publication date
AU2012338628A1 (en) 2014-05-15
JP2014533646A (ja) 2014-12-15
GB201119960D0 (en) 2012-01-04
CN103946150A (zh) 2014-07-23
US9206044B2 (en) 2015-12-08
WO2013072660A1 (en) 2013-05-23
GB201218123D0 (en) 2012-11-21
GB2496725A (en) 2013-05-22
CA2853530A1 (en) 2013-05-23
IN2014DN03289A (enExample) 2015-07-10
US20140264178A1 (en) 2014-09-18
GB2496725B (en) 2014-08-06
AU2012338628B2 (en) 2016-03-10

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