CN103935150A - Alcohol-free fountain solution with high viscosity and low surface tension - Google Patents

Alcohol-free fountain solution with high viscosity and low surface tension Download PDF

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Publication number
CN103935150A
CN103935150A CN201410198241.1A CN201410198241A CN103935150A CN 103935150 A CN103935150 A CN 103935150A CN 201410198241 A CN201410198241 A CN 201410198241A CN 103935150 A CN103935150 A CN 103935150A
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surface tension
high viscosity
low surface
alcohol
exempted
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CN201410198241.1A
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Inventor
景欣欣
王婷婷
陈珍珍
杜威劲
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SUZHOU HECHUAN CHEMICAL TECHNOLOGY SERVICE Co Ltd
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SUZHOU HECHUAN CHEMICAL TECHNOLOGY SERVICE Co Ltd
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Priority to CN201410198241.1A priority Critical patent/CN103935150A/en
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Abstract

The invention discloses alcohol-free fountain solution with high viscosity and low surface tension. The alcohol free fountain solution with high viscosity and low surface tension comprises the following components by weight, 30-55 parts of alcohol solvents, 2-6 parts of buffer agents, 3-8 parts of wetting agents, 1-4 parts of surface active agents, 0.3-2.2 parts of antifoaming agents, 0.5-3 parts of thickening agents, 0.5-1.2 parts of anticorrosion and bactericidal agents, 1-3 parts of penetrating agents, 0-2 parts of electrolyte and 20-45 parts of viscosity modifier water. The fountain solution is free of volatile solvents containing alcohol and isopropyl alcohol and pollution to the environment, the surface tension ranges from 4*10-2N/m to 7*10-2N/m, pH ranges from 4.8 to 5.5, the heat conduction rate ranges from 800mus/cm to 1200mus/cm, and therefore, quality requirements of the fountain solution can be met better.

Description

A kind of high viscosity low surface tension is exempted from alcohol edition-0 moistening liquid
Technical field
The present invention relates to field of fine chemical, be specifically related to a kind of high viscosity low surface tension and exempt from alcohol edition-0 moistening liquid.
Background technology
Fountain solution is indispensable a kind of auxiliary agent in offset printing process, in offset printing, first make its blank parts surface form moisture film with fountain solution forme, contact again ink, white space just can not contact ink like this, it forms uniform and stable moisture film in forme blank parts, infiltrates to blank parts to resist ink, prevents dirty version.Supplement on the other hand the hydrophilic layer of the space of a whole page can extend forme life-span, regulate control the space of a whole page temperature, prevent the emulsification of ink, can also remove ink and printing material shedding, fall other impurity such as hair, paper scrap, velveteen.The function of fountain solution is very comprehensive, and its effect is very important.
At present, what offset printing generally adopted is alcohol edition-0 moistening liquid, in use supplements and adds alcohol or isopropyl alcohol.Although such fountain solution is approved by most enterprises, itself exists some shortcomings.For example, alcohol or isopropyl alcohol easily volatilize, and the 30-40% of its consumption can evaporate in workshop, not only can cause raw-material waste, but also pollute the environment, harmful, and after mixing with air, easy combustion explosion, has certain danger simultaneously.Along with the further raising that people require printing quality, the enhancing gradually of health environment-friendly consciousness, the fountain solution of developing alcohol-free, high-performance, Environmental Safety has become a printing industry difficult problem urgently to be resolved hurrily.
In addition, high viscosity fountain solution is on the market relatively less, in offset printing process, can't well be met the demand of high viscosity fountain solution.
Summary of the invention
For overcoming the above problems, the invention provides a kind of high viscosity, low surface tension is exempted from alcohol edition-0 moistening liquid, this fountain solution does not contain the volatile material such as alcohol and isopropyl alcohol, and has higher viscosity, can meet the particular/special requirement in offset printing.
For achieving the above object, the technical solution used in the present invention is: a kind of high viscosity low surface tension is exempted from alcohol edition-0 moistening liquid, comprises by weight percentage following component: without alcoholic solvent 30-55 part, and buffer 2-6 part, wetting agent 3-8 part, surfactant 1-4 part, defoamer 0.3-2.2 part, thickener 0.5-3 part, anticorrosion and bactericidal agent 0.5-1.2 part, bleeding agent 1-3 part, electrolyte 0-2 part, viscosity modifier water 20-45 part.
Wherein, described is one or more the mixture in ethylene glycol monobutyl ether, propylene glycol monobutyl ether, ethylene glycol propyl ether, diethylene glycol ether, dipropylene glycol methyl ether, DPG propyl ether, Dipropylene glycol mono-n-butyl Ether, diethylene glycol monobutyl ether, triethanolamine without alcoholic solvent.
Wherein, described buffer is two or more the mixture in acetic acid, sodium acetate, citric acid, natrium citricum, tartaric acid, sodium tartrate, triethanolamine, phosphoric acid, sodium dihydrogen phosphate, ammonium dihydrogen phosphate (ADP), boric acid, butanedioic acid, malic acid, sodium succinate, natrium malicum.
Wherein, described wetting agent is one or more the mixture in glycerine, propane diols, NOP, low molecular poly; Wherein, the molecular weight of low molecular poly is between 200-400.
Wherein, described surfactant is isomery ten alcohol APEOs (E-1009), isomerous tridecanol polyoxyethylene ether (E-1310), AEO (AEO-9, paregal O-15), polyoxyethylene carboxylate (LAE-9), aliphatic amine polyoxyethylene ether (AC1210), isooctanol APEO (JFC), APES (NP-9, TX-10), fat alkynol APEO (Surfynol440), polysorbas20, Tween 80, cocoanut fatty acid diethanolamide (6501), polyethylene glycol (PEG), in APG (APG), any two kinds of surfactants is composite.
Wherein, described defoamer is silicone defoaming agent, AEO, 2,4,7,9-tetramethyl-5-decine-4, the mixture of one or more in 7-glycol, polyether antifoam agent, higher alcohols (C7-C9 alcohol), phosphoric acid ester material, Polyether Modified Polysiloxanes Defoaming Agent.
Wherein, phosphoric acid ester material refers to tributyl phosphate.
Wherein, described thickener is the one in xanthans, Arabic gum, sodium carboxymethylcellulose (CMC), hydroxypropyl cellulose (HPC), hydroxyethylcellulose (HEC), hydroxypropyl methylcellulose (HPMC), polyanion cellulose (PAC), soluble starch, gelatin, sodium alginate, agar, guar gum, casein.
Wherein, described anticorrosion and bactericidal agent is one or more the mixture in Sodium Benzoate, OIT, BIT, phenol, formaldehyde, potassium sorbate, parabens, benzalkonium chloride, calgon.
Wherein, described bleeding agent is the one in penetrating agent JFC, fast penetrant T.
Wherein, described electrolyte is one or more the mixture in magnesium nitrate, sodium nitrate, sodium chloride, potassium chloride, potassium nitrate, tertiary sodium phosphate.
The present invention also provides a kind of high viscosity low surface tension to exempt from the preparation method of alcohol edition-0 moistening liquid, comprises the following steps:
1) prepare the raw material (percentage by weight) of following proportioning: without alcoholic solvent 30-55 part, buffer 2-6 part, wetting agent 3-8 part, surfactant 1-4 part, defoamer 0.3-2.2 part, thickener 0.5-3 part, anticorrosion and bactericidal agent 0.5-1.2 part, bleeding agent 1-3 part, electrolyte 0-2 part, viscosity modifier water 20-45 part;
2) join in wetting agent and stir with thickener, then add while stirring water that thickener is disperseed completely;
3) solvent is joined in above-mentioned system and stirred, and then add surface-active, anticorrosion and bactericidal agent, bleeding agent, foam in hibitors, buffer, electrolyte mixing and stirring to obtain high viscosity low surface tension to exempt from alcohol edition-0 moistening liquid.
The present invention compared with prior art has following advantages:
1) do not contain alcohol, the volatile solvent of isopropyl alcohols, in improving sample effective content, reduced the environmental pollution bringing of volatilizing of alcohol, isopropyl alcohol.
2) viscosity is high, can effectively suppress on the one hand the volatilization of solvent, can also meet on the other hand the high viscosity requirement to fountain solution, and dampening roller also has the fountain solution of q.s to pass through dampening roller under low-speed conditions.
The present invention adopts environment-friendly type non-ionic surface active agent binary built technology, non-ionic surface active agent has nontoxicity, non-volatile, consumption is few, steady performance, and after surfactant compound, have than the better result of use of single surfactant, can produce additive synergism after composite.
The present invention relies on thickener to increase the viscosity of system, adopt environment-friendly type nonionic binary built surfactant to reduce surface tension, and replace the volatile materials such as alcohol and isopropyl alcohol with alcohol ether solvent, and being mixed with the liquid of homogeneous thickness, surface tension is 4 × 10 -2~7 × 10 -2n/m, pH is between 4.8-5.5, and electrical conductivity is 800-1200 μ s/cm, and viscosity is high, and surface tension is low, soft, has met preferably fountain solution quality requirement.
Detailed description of the invention
Below in conjunction with specific embodiment, further set forth the present invention.Should be understood that these embodiment are only not used in and limit the scope of the invention for the present invention is described.In addition should be understood that, after having read content of the present invention, those skilled in the art can make various changes or modifications the present invention, these equivalent form of values fall within limited range of the present invention equally.
Embodiment 1
A kind of high viscosity low surface tension is exempted from alcohol edition-0 moistening liquid, formulated by following raw material:
Without 44 parts of alcoholic solvents (ethylene glycol monobutyl ether 17g, dipropylene glycol methyl ether 28g), buffer 3 parts of (acetic acid 1g, sodium acetate 2g), wetting agent propane diols 5g, surfactant 3.5 parts of (E-13102g, AEO AEO-91.5g), silicone defoaming agent 0.3g, thickener sodium carboxymethylcellulose 1g, anticorrosion and bactericidal agent Sodium Benzoate 0.5g, bleeding agent fast penetrant T 2g, electrolyte magnesium nitrate 1.5g, excess water.
High viscosity, low surface tension are exempted from a compound method for alcohol edition-0 moistening liquid, comprise the following steps:
1) 1g sodium carboxymethylcellulose is joined in 5g propane diols and stir and soak, under the condition stirring, add water, be uniformly dispersed to clear;
2) in above-mentioned scattered solution, add 17g ethylene glycol monobutyl ether, 28g dipropylene glycol methyl ether, stir; Again 2gE-1310,1.5gAEO-9,0.5g Sodium Benzoate, 2g fast penetrant T, 1g acetic acid, 2g sodium acetate, 1.5g magnesium nitrate, 0.3g silicone defoaming agent are joined in solution, stir and obtain high viscosity, low surface tension is exempted from alcohol edition-0 moistening liquid.
The fountain solution of preparation as stated above, its pH value is 5.0-5.1, and electrical conductivity is 900-1000 μ s/cm, and surface tension is 4 × 10 -2n/m, meets the performance parameter of fountain solution.
Embodiment 2
A kind of high viscosity, low surface tension are exempted from alcohol edition-0 moistening liquid, formulated by following raw material:
Without alcoholic solvent 44g (propylene glycol monobutyl ether 17g, triethanolamine 7g, diethylene glycol ether 20g), buffer citric acid 4g, wetting agent glycerine 7g, surfactant 3g (Tween 80 2g, cocoanut fatty acid diethanolamide 65011g), silicone defoaming agent 0.3g, thickener sodium carboxymethylcellulose 0.5g, anticorrosion and bactericidal agent OIT 1g, penetrating agent JFC 2g, electrolyte tertiary sodium phosphate 1g, excess water.
1) 0.5g sodium carboxymethylcellulose is joined in 7g glycerine and stir and soak, under the condition stirring, add water, be uniformly dispersed to clear;
2) in above-mentioned scattered solution, add 17g propandiol butyl ether, 15g diethylene glycol ether, 7g triethanolamine to stir, again 1g OIT, 2g penetrating agent JFC, 2g Tween 80,1g6501,1g tertiary sodium phosphate, 0.3g silicone defoaming agent are joined in solution, stir and obtain high viscosity, low surface tension is exempted from alcohol edition-0 moistening liquid.
The fountain solution of preparation as stated above, its pH value is 5.1-5.2, and electrical conductivity is 800-900 μ s/cm, and surface tension is 5 × 10 -2n/m, meets the performance parameter of fountain solution.
Embodiment 3
A kind of high viscosity low surface tension is exempted from alcohol edition-0 moistening liquid, comprises that following raw material is formulated:
Without alcoholic solvent 51g (ethylene glycol propyl ether 15g, diethylene glycol ether 13g, dipropylene glycol methyl ether 23g), buffer 2.8g (malic acid 1.3g, natrium citricum 1.5g), wetting agent glycerine 6g, surfactant 2.3g (APES TX-100.8g, Surfynol440 surfactant 1.5g), defoamer 2.2g (2, 4, 7, 9-tetramethyl-5-decine-4, 7-glycol 2g, tributyl phosphate 0.2g), thickener hydroxypropyl methylcellulose 0.5g, anticorrosion and bactericidal agent calgon 1.2g, fast penetrant T 1.5g, electrolyte sodium chloride 1g, excess water.
1) 0.5g hydroxypropyl methylcellulose is joined in 6g glycerine and stir and soak, under the condition stirring, add water, be uniformly dispersed to clear;
2) in above-mentioned scattered solution, add 15g glycol propyl ether, 13g diethylene glycol ether, 23g dipropylene glycol methyl ether to stir, again by 1.5g fast penetrant T, 1.5g Surfynol440 surfactant, 0.8g TX-10,2g2,4,7,9-tetramethyl-5-decine-4, the calgon of 7-glycol, 1.3g malic acid, 1.5g natrium citricum, 1.2g, 1g sodium chloride, 0.2g tributyl phosphate join in solution, stir and obtain high viscosity, low surface tension is exempted from alcohol edition-0 moistening liquid;
The fountain solution of preparation as stated above, its pH value is 4.8-4.9, and electrical conductivity is 1000-1100 μ s/cm, and surface tension is 5 × 10 -2n/m, meets the performance parameter of fountain solution.
Embodiment tetra-
A kind of high viscosity, low surface tension are exempted from alcohol edition-0 moistening liquid, comprise that following raw material is formulated:
Without alcoholic solvent 45g (Dipropylene glycol mono-n-butyl Ether 15g, diethylene glycol ether 20g, ethylene glycol monobutyl ether 10g), buffer 3g (boric acid 1g, sodium tartrate 2g), wetting agent NOP 5g, surfactant 3g (polyoxyethylene carboxylate LAE-91g, polyethylene glycol PEG-4002g), polyether antifoam agent 0.3g, thickener Arabic gum 3g, anticorrosion and bactericidal agent Sodium Benzoate 1g, penetrating agent JFC 2g, electrolyte sodium nitrate 1.2g, excess water.
1) 7g Arabic gum is dispersed in water, stirs to disperseing completely;
2) in above-mentioned scattered solution, add 15g Dipropylene glycol mono-n-butyl Ether, 20g diethylene glycol ether, 10g butyl glycol ether to stir, again 1gLAE-9,2gPEG-400,5gN-octylpyrrolidone, 2g penetrating agent JFC, 1g Sodium Benzoate, 1.2g sodium nitrate, 1g boric acid, 2g sodium tartrate, 0.3g silicone defoaming agent are joined in solution, stir and obtain high viscosity, low surface tension is exempted from alcohol edition-0 moistening liquid.
The fountain solution of preparation as stated above, its pH value is 4.9-5.0, and electrical conductivity is 1000-1100 μ s/cm, and surface tension is 7 × 10 -2n/m, reaches the performance parameter of fountain solution.
Embodiment 5
A kind of high viscosity, low surface tension are exempted from alcohol edition-0 moistening liquid, comprise that following raw material is formulated:
Without alcoholic solvent 30g (diethylene glycol ether 20g, ethylene glycol monobutyl ether 10g), buffer 6g (boric acid 1g, sodium tartrate 2g, sodium dihydrogen phosphate 2g), wetting agent propane diols 8g, surfactant 4g (polyoxyethylene carboxylate LAE-92g, polyethylene glycol PEG-4002g), polyether antifoam agent 1g, thickener gelatin 3g, anticorrosion and bactericidal agent benzalkonium chloride 1g, penetrating agent JFC 3g, electrolyte sodium nitrate 2g, excess water.
The fountain solution of preparation as stated above, its pH value is 4.9-5.0, and electrical conductivity is 1100-1200 μ s/cm, and surface tension is 6 × 10 -2n/m, reaches the performance parameter of fountain solution.
Embodiment 6
Without alcoholic solvent 55g (propylene glycol monobutyl ether 15g, diethylene glycol ether 20g, dipropylene glycol methyl ether 20g), buffer sodium dihydrogen phosphate 2g, wetting agent glycerine 3g, surfactant polysorbas20 1g, polyether antifoam agent 1.5g, thickener xanthans 2g, anticorrosion and bactericidal agent potassium sorbate 1g, fast penetrant T 1g, electrolyte potassium chloride 0.5g, excess water.
The fountain solution of preparation as stated above, its pH value is 5.1-5.2, and electrical conductivity is 1100-1200 μ s/cm, and surface tension is 6 × 10 -2n/m, reaches the performance parameter of fountain solution.
It is high that high viscosity low surface tension prepared by the present invention is exempted from alcohol edition-0 moistening fluid viscosity, and or not containing volatile solvent, surface tension is 4 × 10 -2-7 × 10 -2n/m, pH is between 4.8-5.5, and electrical conductivity is 800-1200 μ s/cm, has met preferably fountain solution quality requirement.
Be more than the description to the embodiment of the present invention, by the above-mentioned explanation to the disclosed embodiments, make professional and technical personnel in the field can realize or use the present invention.To be apparent for those skilled in the art to the multiple amendment of these embodiment, General Principle as defined herein can, in the situation that not departing from the spirit or scope of the present invention, realize in other embodiments.Therefore, the present invention will can not be restricted to these embodiment shown in this article, but will meet the widest scope consistent with principle disclosed herein and features of novelty.

Claims (10)

1. a high viscosity low surface tension is exempted from alcohol edition-0 moistening liquid, it is characterized in that, described high viscosity low surface tension is exempted from alcohol edition-0 moistening liquid and is comprised by weight percentage following component: without alcoholic solvent 30-55 part, and buffer 2-6 part, wetting agent 3-8 part, surfactant 1-4 part, defoamer 0.3-2.2 part, thickener 0.5-3 part, anticorrosion and bactericidal agent 0.5-1.2 part, bleeding agent 1-3 part, electrolyte 0-2 part, viscosity modifier water 20-45 part.
2. high viscosity low surface tension according to claim 1 is exempted from alcohol edition-0 moistening liquid, it is characterized in that, described is one or more the mixture in ethylene glycol monobutyl ether, propylene glycol monobutyl ether, ethylene glycol propyl ether, diethylene glycol ether, dipropylene glycol methyl ether, DPG propyl ether, Dipropylene glycol mono-n-butyl Ether, diethylene glycol monobutyl ether, triethanolamine without alcoholic solvent.
3. high viscosity low surface tension according to claim 1 is exempted from alcohol edition-0 moistening liquid, it is characterized in that, described buffer is two or more the mixture in acetic acid, sodium acetate, citric acid, natrium citricum, tartaric acid, sodium tartrate, triethanolamine, phosphoric acid, sodium dihydrogen phosphate, ammonium dihydrogen phosphate (ADP), boric acid, butanedioic acid, malic acid, sodium succinate, natrium malicum.
4. high viscosity low surface tension according to claim 1 is exempted from alcohol edition-0 moistening liquid, it is characterized in that, described wetting agent is one or more the mixture in glycerine, propane diols, NOP, low molecular poly; Wherein, the molecular weight of low molecular poly is between 200-400.
5. high viscosity low surface tension according to claim 1 is exempted from alcohol edition-0 moistening liquid, it is characterized in that, described surfactant is the composite of any two kinds of surfactants in isomery ten alcohol APEOs, isomerous tridecanol polyoxyethylene ether, AEO, polyoxyethylene carboxylate, aliphatic amine polyoxyethylene ether, isooctanol APEO, APES, fatty alkynol APEO, polysorbas20, Tween 80, cocoanut fatty acid diethanolamide, polyethylene glycol, APG.
6. high viscosity low surface tension according to claim 1 is exempted from alcohol edition-0 moistening liquid, it is characterized in that, described defoamer is silicone defoaming agent, AEO, 2,4,7,9-tetramethyl-5-decine-4, the mixture of one or more in 7-glycol, polyether antifoam agent, higher alcohols, phosphoric acid ester material, Polyether Modified Polysiloxanes Defoaming Agent.
7. high viscosity low surface tension according to claim 1 is exempted from alcohol edition-0 moistening liquid, it is characterized in that, described thickener is the one in xanthans, Arabic gum, sodium carboxymethylcellulose, hydroxypropyl cellulose, hydroxyethylcellulose, hydroxypropyl methylcellulose, polyanion cellulose, soluble starch, gelatin, sodium alginate, agar, guar gum, casein.
8. high viscosity low surface tension according to claim 1 is exempted from alcohol edition-0 moistening liquid, it is characterized in that, described anticorrosion and bactericidal agent is one or more the mixture in Sodium Benzoate, OIT, BIT, phenol, formaldehyde, potassium sorbate, parabens, benzalkonium chloride, calgon.
9. high viscosity low surface tension according to claim 1 is exempted from alcohol edition-0 moistening liquid, it is characterized in that, described bleeding agent is the one in penetrating agent JFC, fast penetrant T.
10. high viscosity low surface tension according to claim 1 is exempted from alcohol edition-0 moistening liquid, it is characterized in that, described electrolyte is one or more the mixture in magnesium nitrate, sodium nitrate, sodium chloride, potassium chloride, potassium nitrate, tertiary sodium phosphate.
CN201410198241.1A 2014-05-12 2014-05-12 Alcohol-free fountain solution with high viscosity and low surface tension Pending CN103935150A (en)

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CN111055606A (en) * 2020-01-17 2020-04-24 上海世丰印刷有限公司 Alcohol-free fountain solution and preparation method thereof
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CN113400829A (en) * 2021-06-18 2021-09-17 红珊树(杭州)印刷科技有限公司 Alcohol-free fountain solution and preparation method thereof
CN113524938A (en) * 2021-08-10 2021-10-22 中山市富日印刷材料有限公司 Alcohol-free fountain solution special for metal printing and preparation method thereof
CN113524937A (en) * 2021-08-03 2021-10-22 上海洁意科技发展有限公司 zero-VOC offset alcohol-free fountain solution
CN113580799A (en) * 2021-08-13 2021-11-02 何国茂 Alcohol-free fountain solution
CN114369393A (en) * 2022-01-17 2022-04-19 杜广清 Printing roller cleaning protection liquid for multicolor printing machine and use method thereof
CN114590049A (en) * 2022-03-18 2022-06-07 安徽鑫州印刷科技有限公司 Fountain solution for offset printing and preparation method thereof

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Application publication date: 20140723