CN103978799A - Alcohol-free fountain solution and preparation method thereof - Google Patents
Alcohol-free fountain solution and preparation method thereof Download PDFInfo
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- CN103978799A CN103978799A CN201410235062.0A CN201410235062A CN103978799A CN 103978799 A CN103978799 A CN 103978799A CN 201410235062 A CN201410235062 A CN 201410235062A CN 103978799 A CN103978799 A CN 103978799A
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- polyethylene glycol
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- 238000002360 preparation method Methods 0.000 title claims abstract description 11
- 239000000203 mixture Substances 0.000 claims abstract description 73
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 70
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 41
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 41
- 239000002202 Polyethylene glycol Substances 0.000 claims abstract description 28
- 229920001223 polyethylene glycol Polymers 0.000 claims abstract description 28
- LPMBTLLQQJBUOO-KTKRTIGZSA-N (z)-n,n-bis(2-hydroxyethyl)octadec-9-enamide Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)N(CCO)CCO LPMBTLLQQJBUOO-KTKRTIGZSA-N 0.000 claims abstract description 21
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims abstract description 21
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 21
- 229930195729 fatty acid Natural products 0.000 claims abstract description 21
- 239000000194 fatty acid Substances 0.000 claims abstract description 21
- 150000004665 fatty acids Chemical class 0.000 claims abstract description 21
- 150000002191 fatty alcohols Chemical class 0.000 claims abstract description 21
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 claims abstract description 21
- 235000010234 sodium benzoate Nutrition 0.000 claims abstract description 21
- 239000004299 sodium benzoate Substances 0.000 claims abstract description 21
- 229910052938 sodium sulfate Inorganic materials 0.000 claims abstract description 21
- 235000011152 sodium sulphate Nutrition 0.000 claims abstract description 21
- ZNCPFRVNHGOPAG-UHFFFAOYSA-L sodium oxalate Chemical compound [Na+].[Na+].[O-]C(=O)C([O-])=O ZNCPFRVNHGOPAG-UHFFFAOYSA-L 0.000 claims abstract description 20
- 229940039790 sodium oxalate Drugs 0.000 claims abstract description 20
- IRXRGVFLQOSHOH-UHFFFAOYSA-L dipotassium;oxalate Chemical compound [K+].[K+].[O-]C(=O)C([O-])=O IRXRGVFLQOSHOH-UHFFFAOYSA-L 0.000 claims abstract description 18
- 229920000151 polyglycol Polymers 0.000 claims abstract description 15
- 239000010695 polyglycol Substances 0.000 claims abstract description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000007788 liquid Substances 0.000 claims description 33
- 235000013162 Cocos nucifera Nutrition 0.000 claims description 20
- 244000060011 Cocos nucifera Species 0.000 claims description 20
- 239000001828 Gelatine Substances 0.000 claims description 20
- 229920000159 gelatin Polymers 0.000 claims description 20
- 235000019322 gelatine Nutrition 0.000 claims description 20
- 235000011187 glycerol Nutrition 0.000 claims description 19
- 238000004945 emulsification Methods 0.000 claims description 9
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims description 6
- 235000006408 oxalic acid Nutrition 0.000 claims description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 abstract description 23
- 238000007639 printing Methods 0.000 abstract description 13
- 230000007613 environmental effect Effects 0.000 abstract description 5
- 239000002639 bone cement Substances 0.000 abstract 1
- 231100000739 chronic poisoning Toxicity 0.000 abstract 1
- 235000019864 coconut oil Nutrition 0.000 abstract 1
- 239000003240 coconut oil Substances 0.000 abstract 1
- 230000001804 emulsifying effect Effects 0.000 abstract 1
- 229940051841 polyoxyethylene ether Drugs 0.000 abstract 1
- 229920000056 polyoxyethylene ether Polymers 0.000 abstract 1
- 238000005516 engineering process Methods 0.000 description 3
- 230000008901 benefit Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 238000013016 damping Methods 0.000 description 1
- 239000013530 defoamer Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000007645 offset printing Methods 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
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- Detergent Compositions (AREA)
Abstract
The invention discloses an alcohol-free fountain solution and a preparation method thereof. The alcohol-free fountain solution is prepared by emulsifying a mixture formed by polyethylene glycol, glycerol, potassium oxalate, natural bone glue, oleic acid diethanolamide, coconut oil fatty acid diethanolamide, alkanolamide, sodium benzoate, fatty alcohol polyoxyethylene ether sodium sulfate, polyglycol ether, sodium oxalate and water at the temperature of 30-55 DEG C. By using the alcohol-free fountain solution, the aims of realizing safety and environmental friendliness, saving energy and reducing emission can be fulfilled, and a printing operator can be protected from chronic poisoning of alcohol or isopropanol; the original quality of the alcohol-free fountain solution is kept on the aspect of the quality of printed matters, and meanwhile the using amount can be controlled conveniently by operating personnel.
Description
Technical field
The invention belongs to offset printing fountain solution technical field, be specifically related to one and exempt from alcohol edition-0 moistening liquid and preparation method thereof.
Background technology
Lithographic printing is current mainstream technology, utilizes the principle of " profit is immiscible " to implement printing, and therefore fountain solution is its important printing material.Alcohol edition-0 moistening liquid is applied to lithographic printing history for many years, and alcohol (or isopropyl alcohol) is added in fountain solution and reduced surface tension, has not only improved damping speed, has also promoted print quality.But alcohol edition-0 moistening also exists a lot of problems, as because alcohol (or isopropyl alcohol) volatilizees, fast printing machine has increased cooling device, this raises machine construction complexity, manufacturing cost; In process, there is disaster hidden-trouble because alcohol (or isopropyl alcohol) flash-point is low to be deposited; Because alcohol (or isopropyl alcohol) has certain toxicity, harm operating personnel's health; Because the use of alcohol (or isopropyl alcohol) has increased the discharge of VOC, be unfavorable for environmental protection.To sum up, there is many drawbacks in the use of alcohol edition-0 moistening liquid, is not suitable with the trend of green printing.Therefore research can replace completely alcohol (or isopropyl alcohol) safety and environmental protection exempt from the important topic that alcohol edition-0 moistening liquid is printing industry, the exploitation of exempting from alcohol edition-0 moistening liquid has good economic benefit to printing enterprise, also adapts to the social demand of green printing.
On Vehicles Collected from Market, have some to exempt from alcohol edition-0 moistening liquid and bring into use, but technology is also immature, such as changing greatly with alcohol edition-0 moistening on consumption, operating personnel are difficult to control; Stability is not strong, changes fountain solution, to clean bucket frequency too high, increased non-cutting time etc.
Summary of the invention
The object of the present invention is to provide one to exempt from alcohol edition-0 moistening liquid and preparation method thereof, this exempts from alcohol edition-0 moistening liquid and can reach in use the object of safety and environmental protection, energy-saving and emission-reduction; Aspect print quality, also keep the original advantage of alcohol edition-0 moistening liquid, consumption control is convenient simultaneously.
In order to achieve the above object, the present invention exempts from that mixture that alcohol edition-0 moistening liquid forms by polyethylene glycol, glycerine, potassium oxalate, natural gelatine, oleic acid diethanol amine, cocoanut fatty acid diethanolamide, alkanolamide, Sodium Benzoate, sodium sulfate of polyethenoxy ether of fatty alcohol, polyglycol ether, sodium oxalate and water forms the emulsification of 30-55 DEG C, wherein, by mass percentage, polyethylene glycol accounts for the 10-15% of mixture quality, glycerine accounts for the 15-25% of mixture quality, oxalic acid accounts for the 0.2-0.8% of mixture quality, natural gelatine accounts for the 5-10% of mixture quality, oleic acid diethanol amine accounts for the 0.5-2.5% of mixture quality, cocoanut fatty acid diethanolamide accounts for the 1.2-2% of mixture quality, alkanolamide accounts for the 0.2-0.5% of mixture quality, Sodium Benzoate accounts for the 0.1-0.5% of mixture quality, sodium sulfate of polyethenoxy ether of fatty alcohol accounts for the 2-5% of mixture quality, polyglycol ether accounts for the 0.2-0.5% of mixture quality, sodium oxalate accounts for the 0.8-2.5% of mixture quality.
The molecular weight of described polyethylene glycol is 500-1000.
The described pH value of exempting from alcohol edition-0 moistening liquid is 4.5-5.5, and electrical conductivity is 800-1500 μ s/cm, and surface tension is 40-50mN/m.
A kind of preparation method who exempts from alcohol edition-0 moistening liquid, water is added in reactor, and be heated to 30-55 DEG C, then at 30-55 DEG C, add respectively polyethylene glycol, glycerine, potassium oxalate, natural gelatine, oleic acid diethanol amine, cocoanut fatty acid diethanolamide, alkanolamide, Sodium Benzoate, sodium sulfate of polyethenoxy ether of fatty alcohol, polyethylene glycol and sodium oxalate, insulated and stirred makes its emulsification, obtains exempting from alcohol edition-0 moistening liquid.
Compared with prior art, beneficial effect of the present invention is:
After the present invention is mixed by polyethylene glycol, glycerine, potassium oxalate, natural gelatine, oleic acid diethanol amine, cocoanut fatty acid diethanolamide, alkanolamide, Sodium Benzoate, sodium sulfate of polyethenoxy ether of fatty alcohol, polyglycol ether, sodium oxalate and water, heating emulsification forms; Wherein, oleic acid diethanol amine, the mixed liquor of the surfactants such as cocoanut fatty acid diethanolamide, alkanolamide and sodium sulfate of polyethenoxy ether of fatty alcohol is mainly used to reduce the surface tension of liquid, natural gelatine can be used for increasing the viscosity of fountain solution, Sodium Benzoate is mainly sterilizing, and polyglycol ether uses as defoamer; Owing to wherein not using these volatile and flash-point is low materials of alcohol or isopropyl alcohol, therefore, what the present invention made exempt from alcohol edition-0 moistening liquid can reduce the murder by poisoning to user, safety and environmental protection when use, and there is no the discharge of VOC, be therefore of value to energy-saving and emission-reduction.
In addition, what the present invention made exempt from alcohol edition-0 moistening liquid can replace current lithographic printing alcohol edition-0 moistening liquid used completely, respond well, can be applicable to use CTP version or PS version to complete the printing of plain paper or NCR on various offset presses, and improve printing product quality, reduced production costs.
Detailed description of the invention
Embodiment 1:
The mixture that the polyethylene glycol that is 500 by molecular weight, glycerine, potassium oxalate, natural gelatine, oleic acid diethanol amine, cocoanut fatty acid diethanolamide, alkanolamide, Sodium Benzoate, sodium sulfate of polyethenoxy ether of fatty alcohol, polyglycol ether, sodium oxalate and water form forms the emulsification of 30 DEG C, wherein, by mass percentage, polyethylene glycol accounts for 13% of mixture quality, glycerine accounts for 18% of mixture quality, potassium oxalate accounts for 0.5% of mixture quality, natural gelatine accounts for 9% of mixture quality, oleic acid diethanol amine accounts for 2.5% of mixture quality, cocoanut fatty acid diethanolamide accounts for 1.5% of mixture quality, alkanolamide accounts for 0.5% of mixture quality, Sodium Benzoate accounts for 0.2% of mixture quality, sodium sulfate of polyethenoxy ether of fatty alcohol accounts for 2.8% of mixture quality, polyglycol ether accounts for 0.3% of mixture quality, sodium oxalate accounts for 1.8% of mixture quality.
The preparation method that the present embodiment is exempted from alcohol edition-0 moistening liquid is:
Water is added in reactor and is heated to 30 DEG C, then add polyethylene glycol, glycerine, potassium oxalate, natural gelatine, oleic acid diethanol amine, cocoanut fatty acid diethanolamide, alkanolamide, Sodium Benzoate, sodium sulfate of polyethenoxy ether of fatty alcohol, polyethylene glycol and sodium oxalate at 30 DEG C, insulated and stirred 30min, obtains exempting from alcohol edition-0 moistening liquid.
After testing, the present embodiment system to exempt from alcohol edition-0 moistening liquid main performance as follows:
PH:4.5-5.5, electrical conductivity: 800-1500 μ s/cm, surface tension: 40-50mN/m
Embodiment 2:
The mixture that the polyethylene glycol that is 1000 by molecular weight, glycerine, potassium oxalate, natural gelatine, oleic acid diethanol amine, cocoanut fatty acid diethanolamide, alkanolamide, Sodium Benzoate, sodium sulfate of polyethenoxy ether of fatty alcohol, polyglycol ether, sodium oxalate and water form forms the emulsification of 40 DEG C, wherein, by mass percentage, polyethylene glycol accounts for 10% of mixture quality, glycerine accounts for 15% of mixture quality, potassium oxalate accounts for 0.7% of mixture quality, natural gelatine accounts for 5% of mixture quality, oleic acid diethanol amine accounts for 0.5% of mixture quality, cocoanut fatty acid diethanolamide accounts for 1.8% of mixture quality, alkanolamide accounts for 0.2% of mixture quality, Sodium Benzoate accounts for 0.5% of mixture quality, sodium sulfate of polyethenoxy ether of fatty alcohol accounts for 2.0% of mixture quality, polyglycol ether accounts for 0.2% of mixture quality, sodium oxalate accounts for 1.0% of mixture quality.
The preparation method that the present embodiment is exempted from alcohol edition-0 moistening liquid is:
Water is added in reactor and is heated to 40 DEG C, then add polyethylene glycol, glycerine, potassium oxalate, natural gelatine, oleic acid diethanol amine, cocoanut fatty acid diethanolamide, alkanolamide, Sodium Benzoate, sodium sulfate of polyethenoxy ether of fatty alcohol, polyethylene glycol and sodium oxalate at 40 DEG C, insulated and stirred 30min, obtains exempting from alcohol edition-0 moistening liquid.：
Embodiment 3:
The mixture that the polyethylene glycol that is 800 by molecular weight, glycerine, potassium oxalate, natural gelatine, oleic acid diethanol amine, cocoanut fatty acid diethanolamide, alkanolamide, Sodium Benzoate, sodium sulfate of polyethenoxy ether of fatty alcohol, polyglycol ether, sodium oxalate and water form forms the emulsification of 55 DEG C, wherein, by mass percentage, polyethylene glycol accounts for 15% of mixture quality, glycerine accounts for 25% of mixture quality, potassium oxalate accounts for 0.2% of mixture quality, natural gelatine accounts for 10% of mixture quality, oleic acid diethanol amine accounts for 1.4% of mixture quality, cocoanut fatty acid diethanolamide accounts for 1.2% of mixture quality, alkanolamide accounts for 0.4% of mixture quality, Sodium Benzoate accounts for 0.1% of mixture quality, sodium sulfate of polyethenoxy ether of fatty alcohol accounts for 5.0% of mixture quality, polyglycol ether accounts for 0.5% of mixture quality, sodium oxalate accounts for 0.8% of mixture quality.
The preparation method that the present embodiment is exempted from alcohol edition-0 moistening liquid is:
Water is added in reactor and is heated to 55 DEG C, then add polyethylene glycol, glycerine, potassium oxalate, natural gelatine, oleic acid diethanol amine, cocoanut fatty acid diethanolamide, alkanolamide, Sodium Benzoate, sodium sulfate of polyethenoxy ether of fatty alcohol, polyethylene glycol and sodium oxalate at 55 DEG C, insulated and stirred 30min, obtains exempting from alcohol edition-0 moistening liquid.
Embodiment 4:
The mixture that the polyethylene glycol that is 700 by molecular weight, glycerine, potassium oxalate, natural gelatine, oleic acid diethanol amine, cocoanut fatty acid diethanolamide, alkanolamide, Sodium Benzoate, sodium sulfate of polyethenoxy ether of fatty alcohol, polyglycol ether, sodium oxalate and water form forms the emulsification of 45 DEG C, wherein, by mass percentage, polyethylene glycol accounts for 12% of mixture quality, glycerine accounts for 20% of mixture quality, potassium oxalate accounts for 0.8% of mixture quality, natural gelatine accounts for 7% of mixture quality, oleic acid diethanol amine accounts for 2.0% of mixture quality, cocoanut fatty acid diethanolamide accounts for 2.0% of mixture quality, alkanolamide accounts for 0.3% of mixture quality, Sodium Benzoate accounts for 0.4% of mixture quality, sodium sulfate of polyethenoxy ether of fatty alcohol accounts for 3.6% of mixture quality, polyglycol ether accounts for 0.4% of mixture quality, sodium oxalate accounts for 2.5% of mixture quality.
The preparation method that the present embodiment is exempted from alcohol edition-0 moistening liquid is:
Water is added in reactor and is heated to 45 DEG C, then add polyethylene glycol, glycerine, potassium oxalate, natural gelatine, oleic acid diethanol amine, cocoanut fatty acid diethanolamide, alkanolamide, Sodium Benzoate, sodium sulfate of polyethenoxy ether of fatty alcohol, polyethylene glycol and sodium oxalate at 45 DEG C, insulated and stirred 30min, obtains exempting from alcohol edition-0 moistening liquid.
Claims (4)
1. exempt from an alcohol edition-0 moistening liquid, it is characterized in that: the mixture being formed by polyethylene glycol, glycerine, potassium oxalate, natural gelatine, oleic acid diethanol amine, cocoanut fatty acid diethanolamide, alkanolamide, Sodium Benzoate, sodium sulfate of polyethenoxy ether of fatty alcohol, polyglycol ether, sodium oxalate and water forms the emulsification of 30-55 DEG C, wherein, by mass percentage, polyethylene glycol accounts for the 10-15% of mixture quality, glycerine accounts for the 15-25% of mixture quality, oxalic acid accounts for the 0.2-0.8% of mixture quality, natural gelatine accounts for the 5-10% of mixture quality, oleic acid diethanol amine accounts for the 0.5-2.5% of mixture quality, cocoanut fatty acid diethanolamide accounts for the 1.2-2% of mixture quality, alkanolamide accounts for the 0.2-0.5% of mixture quality, Sodium Benzoate accounts for the 0.1-0.5% of mixture quality, sodium sulfate of polyethenoxy ether of fatty alcohol accounts for the 2-5% of mixture quality, polyglycol ether accounts for the 0.2-0.5% of mixture quality, sodium oxalate accounts for the 0.8-2.5% of mixture quality.
2. the alcohol edition-0 moistening liquid of exempting from according to claim 1, is characterized in that: the molecular weight of described polyethylene glycol is 500-1000.
3. the alcohol edition-0 moistening liquid of exempting from according to claim 1, is characterized in that: the described pH value of exempting from alcohol edition-0 moistening liquid is 4.5-5.5, and electrical conductivity is 800-1500 μ s/cm, and surface tension is 40-50mN/m.
4. the preparation method who exempts from alcohol edition-0 moistening liquid as described in any one claim in claim 1～3, is characterized in that:
Water is added in reactor, and be heated to 30-55 DEG C, then at 30-55 DEG C, add respectively polyethylene glycol, glycerine, potassium oxalate, natural gelatine, oleic acid diethanol amine, cocoanut fatty acid diethanolamide, alkanolamide, Sodium Benzoate, sodium sulfate of polyethenoxy ether of fatty alcohol, polyethylene glycol and sodium oxalate, insulated and stirred makes its emulsification, obtains exempting from alcohol edition-0 moistening liquid.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201410235062.0A CN103978799B (en) | 2014-05-29 | 2014-05-29 | One exempts from alcohol edition-0 moistening liquid and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410235062.0A CN103978799B (en) | 2014-05-29 | 2014-05-29 | One exempts from alcohol edition-0 moistening liquid and preparation method thereof |
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| Publication Number | Publication Date |
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| CN103978799A true CN103978799A (en) | 2014-08-13 |
| CN103978799B CN103978799B (en) | 2016-04-06 |
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| CN104228389A (en) * | 2014-09-15 | 2014-12-24 | 合肥环照高分子材料厂 | Peppermint oil-containing alcohol-free fountain solution and preparation method for same |
| CN104890393A (en) * | 2015-06-16 | 2015-09-09 | 合肥吉科新材料有限公司 | Moth-proof fountain solution and preparation method thereof |
| CN104943434A (en) * | 2015-07-11 | 2015-09-30 | 倪娉娉 | Non-ionic surfactant fountain solution |
| CN104960354A (en) * | 2015-06-29 | 2015-10-07 | 李子健 | Environment-friendly alcohol-free fountain solution for offset printing and preparing method thereof |
| CN105383202A (en) * | 2014-08-21 | 2016-03-09 | 上海申集印刷器材有限公司 | Alcohol-free offset-printing fountain solution |
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| CN104890393A (en) * | 2015-06-16 | 2015-09-09 | 合肥吉科新材料有限公司 | Moth-proof fountain solution and preparation method thereof |
| CN104960354A (en) * | 2015-06-29 | 2015-10-07 | 李子健 | Environment-friendly alcohol-free fountain solution for offset printing and preparing method thereof |
| CN104943434A (en) * | 2015-07-11 | 2015-09-30 | 倪娉娉 | Non-ionic surfactant fountain solution |
| CN105383203A (en) * | 2015-12-08 | 2016-03-09 | 上海杰易森股份有限公司 | Alcohol-free environment-friendly fountain solution and preparation method thereof |
| CN105383203B (en) * | 2015-12-08 | 2018-09-28 | 上海杰易森股份有限公司 | A kind of alcohol-free environment-friendly type fountain solution and preparation method thereof |
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| CN106183521A (en) * | 2016-07-11 | 2016-12-07 | 赵艳丽 | A kind of efficient fountain solution of low alcohol and preparation method thereof |
| CN106113967A (en) * | 2016-07-11 | 2016-11-16 | 赵艳丽 | Environmental protection high stability printing plate-moistening liquid and preparation technology thereof |
| CN106183521B (en) * | 2016-07-11 | 2018-12-28 | 深圳市东鹏科技发展有限公司 | A kind of efficient fountain solution of low alcohol and preparation method thereof |
| CN110065323A (en) * | 2019-06-03 | 2019-07-30 | 西安石油大学 | A kind of polyvinyl alcohol exempts from alcohol edition-0 moistening liquid and preparation method thereof |
| CN110065324A (en) * | 2019-06-03 | 2019-07-30 | 西安石油大学 | A kind of linalool exempts from alcohol edition-0 moistening liquid and preparation method thereof |
| CN110103604A (en) * | 2019-06-03 | 2019-08-09 | 西安石油大学 | A kind of citral exempts from alcohol edition-0 moistening liquid and preparation method thereof |
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