CN106042705A - High-viscosity low-surface-tension fountain solution containing k-carrageenan and preparation method of high-viscosity low-surface-tension fountain solution - Google Patents

High-viscosity low-surface-tension fountain solution containing k-carrageenan and preparation method of high-viscosity low-surface-tension fountain solution Download PDF

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Publication number
CN106042705A
CN106042705A CN201610500176.2A CN201610500176A CN106042705A CN 106042705 A CN106042705 A CN 106042705A CN 201610500176 A CN201610500176 A CN 201610500176A CN 106042705 A CN106042705 A CN 106042705A
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Prior art keywords
carrageenan
fountain solution
kappa
parts
viscosity low
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CN201610500176.2A
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Chinese (zh)
Inventor
王贵东
宋睿
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Hefei Ring Macromolecular Material Factory
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Hefei Ring Macromolecular Material Factory
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Priority to CN201610500176.2A priority Critical patent/CN106042705A/en
Publication of CN106042705A publication Critical patent/CN106042705A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41NPRINTING PLATES OR FOILS; MATERIALS FOR SURFACES USED IN PRINTING MACHINES FOR PRINTING, INKING, DAMPING, OR THE LIKE; PREPARING SUCH SURFACES FOR USE AND CONSERVING THEM
    • B41N3/00Preparing for use and conserving printing surfaces
    • B41N3/08Damping; Neutralising or similar differentiation treatments for lithographic printing formes; Gumming or finishing solutions, fountain solutions, correction or deletion fluids, or on-press development

Abstract

The invention discloses a high-viscosity low-surface-tension fountain solution containing k-carrageenan. The high-viscosity low-surface-tension fountain solution containing k-carrageenan consists of the following raw materials in parts by weight: 70-85 parts of deionized water, 10-15 parts of k-carrageenan, 6-10 parts of konjac gum, 3-6 parts of tea polyphenol, 2-5 parts of Turkey red oil, 1-3 parts of sorbitol, 3-6 parts of a pH regulator, 1-3 parts of cocoanut fatty acid diethanolamide, 1-3 parts of fatty alcohol-polyoxyethylene ether and 3-8 parts of glycerin. According to the fountain solution, k-carrageenan and konjac gum are compounded to serve as a hydrophilic film-forming agent to improve the durability of a water film, so that the fountain solution has favorable wettability and permeability.

Description

A kind of high viscosity low surface tension fountain solution containing kappa-carrageenan and preparation method thereof
Technical field
The present invention relates to offset printing fountain solution technical field, be specifically related to a kind of low surface of the high viscosity containing kappa-carrageenan Tension force fountain solution and preparation method thereof.
Background technology
Offset printing is to utilize the two natural law that profit is the most miscible, solid is to the selective absorption of liquid, The picture and text replicated and blank parts are set up jointly at the unified plate surface through technical finesse, makes blank parts have very Strong water absorbing properties, areas oleophylic water repellent.In printing process, first whole forme is supplied water, make the blank parts of the space of a whole page Adsorb water and form water membrane, subsequently, then give forme ink supply.Now, owing to forme blank parts has existed water membrane, Ink can not adsorb in blank parts, areas water repellent oleophylic and adsorb one layer of ink.Therefore, fountain solution work in offset printing With very important.
Non-ionic surface active fountain solution is the novel fountain solution grown up in recent years, is to use nonionic surfactant Replace the low surface tension fountain solution of ethanol, it is to avoid the alcohol steam produced after isopropanol volatilization in traditional water dampening system, by Low in nonionic surfactant surface tension, wettability good, can reduce the consumption of fountain solution, becomes high speed multicolour offset press In preferable fountain solution.Therefore, research new non-ionic fountain solution has great significance to improving printing quality.
Kappa-carrageenan (κ-carrageenan) is by the natural sea algin extracted in red algae, has heat-convertible gel, resists Albumen condenses and the hydrophilic characteristic such as nontoxic, also has formation hydrophilic colloid, gel, thickening, emulsifying, film forming, stable dispersion etc. excellent Optimum energy, is widely used in food industry, daily chemical industry and the field such as biochemistry, medical research, thus carrageenan industry is rapidly Development.The gel that kappa-carrageenan is formed has that desired concn is low, transparency advantages of higher, but exist gel fragility big, elastic little, The problems such as easy syneresis, can solve these problems by the synergistic function with other foodstuff glues.Research shows, After adding other polysaccharide in kappa-carrageenan, even non-gelled polysaccharide, its gelling properties also can be greatly improved.According to The reports such as Phillips etc. and Williams, after carrageenan mixes with locust bean gum, it is elastic, strength and stability has significantly Raising;Adding xanthan gum can make carrageenan more soft, more flexible and viscosity increase;Gelatin and the cogelled system of carrageenan In, storage modulus increases along with carrageenan concentrations and increases, and it is cogelled with carrageenan that low concentration sodium chloride is conducive to improving gelatin Matter structure.
Wei Yu, Wang Yuanlan, Hu Yunchu et al. report a kappa-carrageenan and Konjac glucomannan compound gel rheological property and Study on Microstructure, the impact on compound gel rheological behavior such as examination shear rate, frequency of vibration and temperature.In Kappa-Carraginan Add a certain amount of Konjac glucomannan (konjac gum), owing to Konjac glucomannan has higher retentiveness and stickiness, can be filled into smoothly In the ordered network structure that kappa-carrageenan is formed, defined by intermolecular hydrogen bonding based on kappa-carrageenan network structure, evil spirit Taro glue interts cross-linked network system therein, can form the resilient heat-convertible gel of tool, and the gel formed has required former Material less, the feature such as big, the good springiness of gel strength.Compound gel preparation fountain solution hence with kappa-carrageenan with Konjac glucomannan has very Big Research Prospects.
Summary of the invention
It is an object of the invention to for the deficiencies in the prior art, it is provided that a kind of high viscosity low surface tension containing kappa-carrageenan Fountain solution and preparation method thereof, in order to solve the ring that in now widely used alcohol edition-0 moistening liquid, ethanol and isopropanol volatilization cause Border problem.
The purpose of the present invention can be achieved through the following technical solutions:
A kind of high viscosity low surface tension fountain solution containing kappa-carrageenan, is made up of the raw material of following weight: deionization Water 70-85 part, kappa-carrageenan 10-15 part, Konjac glucomannan 6-10 part, tea polyphenols 3-6 part, turkey red oil 2-5 part, sorbitol 1-3 part, pH Regulator 3-6 part, cocoanut fatty acid diethanolamide 1-3 part, fatty alcohol-polyoxyethylene ether 1-3 part, glycerol 3-8 part.
Specifically comprise the following steps that
(1) preparation of kappa-carrageenan-Konjac glucomannan-Microspheres of Tea Polyphenols:
1., kappa-carrageenan, Konjac glucomannan and tea polyphenols are dissolved in deionized water standby as aqueous phase;
2., measuring turkey red oil, turkey red oil is 3-7:1 with the volume ratio of deionized water, is added thereto to sorbitol, fully dissolves also Stir, standby as oil phase;
3., aqueous phase is added in oil phase, homogenizing 4-8 minute under the conditions of 16000-24000rmp, the microemulsion that then will obtain Carry out oil-water separation with separatory funnel, take the aqueous solution after separation and carry out lyophilization, obtain kappa-carrageenan-Konjac glucomannan-tea many Phenol microsphere;
(2) being joined in glycerol by colloid micro ball prepared by step (1) and stir, adding deionized water the most while stirring will Colloid micro ball is completely dispersed;
(3) in the system of step (2), add cocoanut fatty acid diethanolamide, fatty alcohol-polyoxyethylene ether, be sufficiently stirred for Mixing, prepares mixed solution;
(4) during pH adjusting agent joins remaining deionized water, it is uniformly mixed, stirs 30-50 minute, be then added to step (3), in mixed solution, it is sufficiently stirred for dispersion, i.e. prepares the high viscosity low surface tension fountain solution containing kappa-carrageenan.
Deionized water resistance at 25 DEG C in described a kind of high viscosity low surface tension fountain solution containing kappa-carrageenan Rate is 1018mΩ•cm。
The described pH adjusting agent in a kind of high viscosity low surface tension fountain solution containing kappa-carrageenan is by phosphoric acid and phosphoric acid Ammonium dihydrogen mixes, and phosphoric acid is 1-3:1 with the mass ratio of ammonium dihydrogen phosphate.
A kind of high viscosity low surface tension fountain solution containing kappa-carrageenan of the present invention compared with prior art has as follows Advantage:
(1) compounding by kappa-carrageenan and Konjac glucomannan, both are defined by intermolecular hydrogen bonding with kappa-carrageenan network structure Being main, Konjac glucomannan interts cross-linked network system therein, can form the resilient heat-convertible gel of tool, and it is as hydrophilic film forming Agent, improves the persistency of moisture film so that fountain solution of the present invention has good moistening, permeability in use;
(2) kappa-carrageenan-Konjac glucomannan-Microspheres of Tea Polyphenols has the characteristic that mean diameter is thin and tea polyphenols slowly discharges, at damping The use of liquid delays the release of tea polyphenols, makes the non-oxidizability of tea polyphenols be greatly improved, it is ensured that the stability that fountain solution uses;
(3) present invention uses colloid micro ball to increase the viscosity of system, uses cocoanut fatty acid diethanolamide to assist with glycerol With reducing surface tension, being configured to the liquid of homogeneous thickness, surface tension, between 40-60mN/m, meets fountain solution quality Requirement.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is described in detail.
Embodiment 1
A kind of high viscosity low surface tension fountain solution containing kappa-carrageenan of the present embodiment, comprises following components and weight portion content: Deionized water 80 parts, kappa-carrageenan 12 parts, Konjac glucomannan 8 parts, tea polyphenols 4 parts, 3 parts of turkey red oil, sorbitol 2 parts, pH adjusting agent 4 Part, cocoanut fatty acid diethanolamide 2 parts, fatty alcohol-polyoxyethylene ether 2 parts, glycerol 6 parts.
Wherein deionized water resistivity at 25 DEG C is 1018m Ω cm;Described pH adjusting agent is by phosphoric acid and di(2-ethylhexyl)phosphate Hydrogen ammonium mixes, and phosphoric acid is 2:1 with the mass ratio of ammonium dihydrogen phosphate.
Specifically comprise the following steps that
(1) preparation of kappa-carrageenan-Konjac glucomannan-Microspheres of Tea Polyphenols:
1., kappa-carrageenan, Konjac glucomannan and tea polyphenols are dissolved in deionized water standby as aqueous phase;
2., measuring turkey red oil, turkey red oil is 5:1 with the volume ratio of deionized water, is added thereto to sorbitol, fully dissolves and stir Mix uniformly, standby as oil phase;
3., aqueous phase is added in oil phase, homogenizing 5 minutes under the conditions of 18000rmp, then the microemulsion separatory of acquisition is leaked Bucket carries out oil-water separation, takes the aqueous solution after separation and carries out lyophilization, obtains kappa-carrageenan-Konjac glucomannan-Microspheres of Tea Polyphenols;
(2) being joined in glycerol by colloid micro ball prepared by step (1) and stir, adding deionized water the most while stirring will Colloid micro ball is completely dispersed;
(3) in the system of step (2), add cocoanut fatty acid diethanolamide, fatty alcohol-polyoxyethylene ether, be sufficiently stirred for Mixing, prepares mixed solution;
(4) during pH adjusting agent joins remaining deionized water, it is uniformly mixed, stirs 30-50 minute, be then added to step (3), in mixed solution, it is sufficiently stirred for dispersion, i.e. prepares the high viscosity low surface tension fountain solution containing kappa-carrageenan.
Property indices data: pH value is 5.1, and conductivity is 1340 μ s/cm, and surface tension is 45mN/m, dynamically glues Degree is 1.34cPs, water-pickup of ink < 20% when being used for printing.

Claims (4)

1. the high viscosity low surface tension fountain solution containing kappa-carrageenan, it is characterised in that former by following weight Material composition: deionized water 70-85 part, kappa-carrageenan 10-15 part, Konjac glucomannan 6-10 part, tea polyphenols 3-6 part, turkey red oil 2-5 part, Sorbitol 1-3 part, pH adjusting agent 3-6 part, cocoanut fatty acid diethanolamide 1-3 part, fatty alcohol-polyoxyethylene ether 1-3 part, Glycerol 3-8 part.
2. according to the preparation method of a kind of high viscosity low surface tension fountain solution containing kappa-carrageenan described in claims 1, It is characterized in that, specifically comprise the following steps that
(1) preparation of kappa-carrageenan-Konjac glucomannan-Microspheres of Tea Polyphenols:
1., kappa-carrageenan, Konjac glucomannan and tea polyphenols are dissolved in deionized water standby as aqueous phase;
2., measuring turkey red oil, turkey red oil is 3-7:1 with the volume ratio of deionized water, is added thereto to sorbitol, fully dissolves also Stir, standby as oil phase;
3., aqueous phase is added in oil phase, homogenizing 4-8 minute under the conditions of 16000-24000rmp, the microemulsion that then will obtain Carry out oil-water separation with separatory funnel, take the aqueous solution after separation and carry out lyophilization, obtain kappa-carrageenan-Konjac glucomannan-tea many Phenol microsphere;
(2) being joined in glycerol by colloid micro ball prepared by step (1) and stir, adding deionized water the most while stirring will Colloid micro ball is completely dispersed;
(3) in the system of step (2), add cocoanut fatty acid diethanolamide, fatty alcohol-polyoxyethylene ether, be sufficiently stirred for Mixing, prepares mixed solution;
(4) during pH adjusting agent joins remaining deionized water, it is uniformly mixed, stirs 30-50 minute, be then added to step (3), in mixed solution, it is sufficiently stirred for dispersion, i.e. prepares the high viscosity low surface tension fountain solution containing kappa-carrageenan.
3. according to a kind of high viscosity low surface tension fountain solution containing kappa-carrageenan described in claims 1, it is characterised in that Described deionized water resistivity at 25 DEG C is 1018mΩ•cm。
4. according to a kind of high viscosity low surface tension fountain solution containing kappa-carrageenan described in claims 1, it is characterised in that Described pH adjusting agent is mixed with ammonium dihydrogen phosphate by phosphoric acid, and phosphoric acid is 1-3:1 with the mass ratio of ammonium dihydrogen phosphate.
CN201610500176.2A 2016-06-30 2016-06-30 High-viscosity low-surface-tension fountain solution containing k-carrageenan and preparation method of high-viscosity low-surface-tension fountain solution Pending CN106042705A (en)

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107160889A (en) * 2017-07-07 2017-09-15 合肥新意境材料有限责任公司 A kind of low irritant fountain solution of the konjac glucomannan of carragheen containing κ compounding and preparation method thereof
CN107160888A (en) * 2017-07-07 2017-09-15 合肥新意境材料有限责任公司 A kind of green alcohol-free fountain solution of the konjac glucomannan of carragheen containing κ compounding and preparation method thereof
CN107199795A (en) * 2017-07-07 2017-09-26 合肥新意境材料有限责任公司 A kind of delicate fragrance type fountain solution of the konjac glucomannan of carragheen containing κ compounding and preparation method thereof
CN107310290A (en) * 2017-07-07 2017-11-03 合肥新意境材料有限责任公司 A kind of environmentally friendly fountain solution of the konjac glucomannan of carragheen containing κ compounding and preparation method thereof
CN107336538A (en) * 2017-07-07 2017-11-10 合肥新意境材料有限责任公司 A kind of corrosion-mitigation scale-inhibition fountain solution of the konjac glucomannan of carragheen containing κ compounding and preparation method thereof
CN107379806A (en) * 2017-07-07 2017-11-24 合肥新意境材料有限责任公司 A kind of low foam fountain solution of the konjac glucomannan of carragheen containing κ compounding and preparation method thereof

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107160889A (en) * 2017-07-07 2017-09-15 合肥新意境材料有限责任公司 A kind of low irritant fountain solution of the konjac glucomannan of carragheen containing κ compounding and preparation method thereof
CN107160888A (en) * 2017-07-07 2017-09-15 合肥新意境材料有限责任公司 A kind of green alcohol-free fountain solution of the konjac glucomannan of carragheen containing κ compounding and preparation method thereof
CN107199795A (en) * 2017-07-07 2017-09-26 合肥新意境材料有限责任公司 A kind of delicate fragrance type fountain solution of the konjac glucomannan of carragheen containing κ compounding and preparation method thereof
CN107310290A (en) * 2017-07-07 2017-11-03 合肥新意境材料有限责任公司 A kind of environmentally friendly fountain solution of the konjac glucomannan of carragheen containing κ compounding and preparation method thereof
CN107336538A (en) * 2017-07-07 2017-11-10 合肥新意境材料有限责任公司 A kind of corrosion-mitigation scale-inhibition fountain solution of the konjac glucomannan of carragheen containing κ compounding and preparation method thereof
CN107379806A (en) * 2017-07-07 2017-11-24 合肥新意境材料有限责任公司 A kind of low foam fountain solution of the konjac glucomannan of carragheen containing κ compounding and preparation method thereof

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Application publication date: 20161026