CN104070871A - Non-phosphorus fountain solution and preparation method thereof - Google Patents

Non-phosphorus fountain solution and preparation method thereof Download PDF

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Publication number
CN104070871A
CN104070871A CN201410316446.5A CN201410316446A CN104070871A CN 104070871 A CN104070871 A CN 104070871A CN 201410316446 A CN201410316446 A CN 201410316446A CN 104070871 A CN104070871 A CN 104070871A
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water
parts
sodium
acid
phosphorus
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CN201410316446.5A
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CN104070871B (en
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李华令
肖昌明
向凯
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Anhui Suoya Decorative Materials Co Ltd
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Anhui Suoya Decorative Materials Co Ltd
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Abstract

The invention discloses a non-phosphorus fountain solution which is characterized by comprising, by weight, 2-6 parts of 2-hydroxyethyl-beta-cyclodextrin, 1-4 parts of cetearyl glucoside, 1-4 parts of glycerol trioleate, 1-2 parts of terpineol, 1-3 parts of menthone, 0.5-1 part of tartaric acid, 1-3 parts of imidazolidinyl urea, 1-3 parts of sodium lauroamphoacetate, 1-2 parts of sodium xylene sulfonate, 0.5-1 part of benzalkonium chloride, 0.2-1 part of span 60, 5-10 parts of addition agents and 30-50 parts of water. The fountain solution contains no phosphorus, can effectively avoid the adverse effect of phosphorus containing materials on a device, is favorable for device maintenance and reduces cost; deterioration of water quality caused by phosphorus containing emissions is avoided, and the environmental protection requirements are met.

Description

A kind of without phosphorus fountain solution and preparation method thereof
Technical field
The present invention relates to printing plate-moistening liquid, be specifically related to a kind of without phosphorus fountain solution and preparation method thereof.
Background technology
Fountain solution is indispensable a kind of chemical assistant in color press printing process, and it forms uniform moisture film in forme blank parts, to resist ink on picture and text to the infiltration of blank parts, prevents dirty version.Fountain solution is comprised of Multiple components, both inorganic salts had stably been generated, constantly supplement the hydrophilic layer that space of a whole page blank parts is worn, can play again the effect of clean space of a whole page greasy dirt and reduction space of a whole page temperature, make the China ink of picture and text part on forme and the water maintenance relative equilibrium of blank parts with stable, reach the printing effect of expection.Phosphorous in tradition fountain solution composition, can cause equipment key position metal deteriorated, phosphorus-containing wastewater is discharged in water body and can causes body eutrophication simultaneously, causes water quality deterioration, thereby threatens natural environment.
Summary of the invention
The object of this invention is to provide a kind of without phosphorus fountain solution.
The present invention is achieved by the following technical solutions:
A without phosphorus fountain solution, is characterized in that its raw material by following weight parts forms: hydroxyethyl-β-cyclodextrin 2-6, cetearyl glucoside 1-4, glycerol trioleate 1-4, terpinol 1-2, menthones 1-3, tartaric acid 0.5-1, imidazolidinyl urea 1-3, lauryl both sexes sodium acetate 1-3, sodium xylene sulfonate 1-2, benzalkonium chloride 0.5-1, sorbester p18 0.2-1, auxiliary agent 5-10, water 30-50.
Described auxiliary agent is made by the raw material of following weight portion: glycerine 5-10, polyethylene glycol 2-8, glycine 0.5-1.5, citric acid 1-3, oleic acid 2-3, caryophyllus oil 0.2-1, rhamnose 0.2-1, Tea Polyphenols 0.3-1, sodium acid carbonate 1-3, natrium citricum 10-30, Tween 80 1-5, water 30-50; First that citric acid, natrium citricum is water-soluble, be heated to 50-60 ℃, then add glycerine, polyethylene glycol, caryophyllus oil, oleic acid and sodium acid carbonate, stir 15min, add all the other raw materials after being cooled to room temperature, be stirred to completely and dissolve, after filtration and get final product.
Without phosphorus fountain solution according to claim 1, is characterized in that being comprised of the raw material of following weight parts: hydroxyethyl-β-cyclodextrin 4, cetearyl glucoside 3, glycerol trioleate 3, terpinol 1.5, menthones 2, tartaric acid 0.8, imidazolidinyl urea 2, lauryl both sexes sodium acetate 2, sodium xylene sulfonate 1.5, benzalkonium chloride 0.6, sorbester p18 0.8, auxiliary agent 8, water 40.
Described auxiliary agent is made by the raw material of following weight portion: glycerine 7, polyethylene glycol 6, glycine 1, citric acid 2, oleic acid 1.5, caryophyllus oil 0.5, rhamnose 0.5, Tea Polyphenols 0.5, sodium acid carbonate 2, natrium citricum 18, Tween 80 3, water 40; First that citric acid, natrium citricum is water-soluble, be heated to 50-60 ℃, then add glycerine, polyethylene glycol, caryophyllus oil, oleic acid and sodium acid carbonate, stir 15min, add all the other raw materials after being cooled to room temperature, be stirred to completely and dissolve, after filtration and get final product.
The preparation method of without phosphorus fountain solution according to claim 1, is characterized in that, comprises the following steps:
(1) by formula, take raw material, in reactor, add water, cetearyl glucoside, glycerol trioleate, terpinol, tartaric acid, sodium xylene sulfonate, benzalkonium chloride are dropped in reactor, be heated to 60-80 ℃, stir 10-15min;
(2) temperature is adjusted to 50-60 ℃, adds imidazolidinyl urea, hydroxyethyl-β-cyclodextrin, lauryl both sexes sodium acetate, sorbester p18 and auxiliary agent 600-800rpm to stir 15-30min;
(3) be cooled to room temperature, add rest materials, be stirred to and dissolve completely, filtering and impurity removing matter gets product.
Advantage of the present invention is:
1. not phosphorous in raw material, can effectively avoid rotary press contact site metal deteriorated, be conducive to plant maintenance, reduce costs; Reduce the pollution of emission to water body.
2. have good anti-hard water, be applicable to the running water in various sources, main component gentleness is non-stimulated, environmental friendliness.
3. picture and text printing is clear, and it is clean that the space of a whole page keeps, and printing effect is good.
The specific embodiment
Non-limiting examples of the present invention is as follows:
Embodiment 1: the preparation of fountain solution
A without phosphorus fountain solution, is prepared from by the component raw material of following weight (kg): hydroxyethyl-β-cyclodextrin 4, cetearyl glucoside 3, glycerol trioleate 3, terpinol 1.5, menthones 2, tartaric acid 0.8, imidazolidinyl urea 2, lauryl both sexes sodium acetate 2, sodium xylene sulfonate 1.5, benzalkonium chloride 0.6, sorbester p18 0.8, auxiliary agent 8, water 40;
Wherein, auxiliary agent is made by the raw material of following weight (kg): glycerine 7, polyethylene glycol 6, glycine 1, citric acid 2, oleic acid 1.5, caryophyllus oil 0.5, rhamnose 0.5, Tea Polyphenols 0.5, sodium acid carbonate 2, natrium citricum 18, Tween 80 3, water 40; First that citric acid, natrium citricum is water-soluble, be heated to 50-60 ℃, then add glycerine, polyethylene glycol, caryophyllus oil, oleic acid and sodium acid carbonate, stir 15min, add all the other raw materials after being cooled to room temperature, be stirred to completely and dissolve, after filtration and get final product.
Its preparation method comprises the following steps:
(1) by formula, take raw material, in reactor, add water, cetearyl glucoside, glycerol trioleate, terpinol, tartaric acid, sodium xylene sulfonate, benzalkonium chloride are dropped in reactor, be heated to 60-80 ℃, stir 10-15min;
(2) temperature is adjusted to 50-60 ℃, adds imidazolidinyl urea, hydroxyethyl-β-cyclodextrin, lauryl both sexes sodium acetate, sorbester p18 and auxiliary agent 600-800rpm to stir 15-30min;
(3) be cooled to room temperature, add rest materials, be stirred to and dissolve completely, filtering and impurity removing matter gets product.
Embodiment 2: water-pickup of ink is measured
Fountain solution is major effect ink-water balance performance in printing process, and wherein water-pickup of ink is an important parameter.To water-pickup of ink, there is material impact in the character of fountain solution.According to offset printing principle, in offset printing process, water-pickup of ink is feasible lower than 26%.
The mensuration of water-pickup of ink C: adopt gravimetric method.
By distilled water diluting to 3% for fountain solution described in embodiment 1, in container, once add the fountain solution after 50g black ink and 50g dilution, standing 10min after 100r/min stirring 1h, by unabsorbed fountain solution and ink multi_layer extraction, is calculated as follows water-pickup of ink:
Measurement result water-pickup of ink is 21.40%, far below 26% of limiting value, in normal range (NR), is conducive to print production.

Claims (3)

1. a without phosphorus fountain solution, is characterized in that its raw material by following weight parts forms: hydroxyethyl-β-cyclodextrin 2-6, cetearyl glucoside 1-4, glycerol trioleate 1-4, terpinol 1-2, menthones 1-3, tartaric acid 0.5-1, imidazolidinyl urea 1-3, lauryl both sexes sodium acetate 1-3, sodium xylene sulfonate 1-2, benzalkonium chloride 0.5-1, sorbester p18 0.2-1, auxiliary agent 5-10, water 30-50;
Described auxiliary agent is made by the raw material of following weight portion: glycerine 5-10, polyethylene glycol 2-8, glycine 0.5-1.5, citric acid 1-3, oleic acid 2-3, caryophyllus oil 0.2-1, rhamnose 0.2-1, Tea Polyphenols 0.3-1, sodium acid carbonate 1-3, natrium citricum 10-30, Tween 80 1-5, water 30-50; First that citric acid, natrium citricum is water-soluble, be heated to 50-60 ℃, then add glycerine, polyethylene glycol, caryophyllus oil, oleic acid and sodium acid carbonate, stir 15min, add all the other raw materials after being cooled to room temperature, be stirred to completely and dissolve, after filtration and get final product.
2. without phosphorus fountain solution according to claim 1, is characterized in that being comprised of the raw material of following weight parts: hydroxyethyl-β-cyclodextrin 4, cetearyl glucoside 3, glycerol trioleate 3, terpinol 1.5, menthones 2, tartaric acid 0.8, imidazolidinyl urea 2, lauryl both sexes sodium acetate 2, sodium xylene sulfonate 1.5, benzalkonium chloride 0.6, sorbester p18 0.8, auxiliary agent 8, water 40;
Described auxiliary agent is made by the raw material of following weight portion: glycerine 7, polyethylene glycol 6, glycine 1, citric acid 2, oleic acid 1.5, caryophyllus oil 0.5, rhamnose 0.5, Tea Polyphenols 0.5, sodium acid carbonate 2, natrium citricum 18, Tween 80 3, water 40; First that citric acid, natrium citricum is water-soluble, be heated to 50-60 ℃, then add glycerine, polyethylene glycol, caryophyllus oil, oleic acid and sodium acid carbonate, stir 15min, add all the other raw materials after being cooled to room temperature, be stirred to completely and dissolve, after filtration and get final product.
3. the preparation method of without phosphorus fountain solution according to claim 1, is characterized in that, comprises the following steps:
(1) by formula, take raw material, in reactor, add water, cetearyl glucoside, glycerol trioleate, terpinol, tartaric acid, sodium xylene sulfonate, benzalkonium chloride are dropped in reactor, be heated to 60-80 ℃, stir 10-15min;
(2) temperature is adjusted to 50-60 ℃, adds imidazolidinyl urea, hydroxyethyl-β-cyclodextrin, lauryl both sexes sodium acetate, sorbester p18 and auxiliary agent 600-800rpm to stir 15-30min;
(3) be cooled to room temperature, add rest materials, be stirred to and dissolve completely, filtering and impurity removing matter gets product.
CN201410316446.5A 2014-07-05 2014-07-05 A kind of without phosphorus fountain solution and preparation method thereof Active CN104070871B (en)

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Cited By (7)

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Publication number Priority date Publication date Assignee Title
CN104875519A (en) * 2015-06-16 2015-09-02 合肥吉科新材料有限公司 Novel environment-friendly fountain solution and preparation method thereof
CN105966103A (en) * 2016-06-30 2016-09-28 合肥环照高分子材料厂 Alcohol-free fountain solution containing k-carrageenan-konjac gum compound and preparation method of alcohol-free fountain solution
CN106042705A (en) * 2016-06-30 2016-10-26 合肥环照高分子材料厂 High-viscosity low-surface-tension fountain solution containing k-carrageenan and preparation method of high-viscosity low-surface-tension fountain solution
CN106183522A (en) * 2016-07-19 2016-12-07 合肥鼎亮光学科技有限公司 A kind of carbon sol modification fountain solution compounding containing κ carrageenan Konjac glucomannan and preparation method thereof
CN106739613A (en) * 2016-12-20 2017-05-31 当涂县金龙机械有限公司 A kind of alcohol of exempting from containing hydroxypropyl cyclodextrin prepared by magnetic activated water concentrates divergence type fountain solution high and preparation method thereof
CN109177566A (en) * 2018-09-17 2019-01-11 苏州市万丽珑新材料科技有限公司 One kind exempting from alcohol fountain solution and preparation method thereof
JP2021500585A (en) * 2017-10-19 2021-01-07 ストレック, インコーポレイテッド Compositions for hemolysis, coagulation regulation and extracellular vesicle stabilization

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CN101870213A (en) * 2009-04-27 2010-10-27 杜广清 Fountain solution and preparation method thereof
CN103189213A (en) * 2010-10-28 2013-07-03 巴斯夫欧洲公司 Fountain solution and fountain solution concentrates
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CN103640356A (en) * 2013-10-29 2014-03-19 安徽唯宝印刷科技有限公司 Alcohol-free printing fountain solution and preparation method thereof
CN103660668A (en) * 2013-11-18 2014-03-26 蚌埠天光传感器有限公司 Fountain solution with low-concentration ethyl alcohol and preparation method thereof
CN103660667A (en) * 2013-11-18 2014-03-26 蚌埠市英路光电有限公司 Business rotation fountain solution and preparing method of business rotation foundation solution
CN103786459A (en) * 2014-01-16 2014-05-14 合肥环照高分子材料厂 Environmentally-friendly fountain solution containing lotus leaf extract and preparation method thereof

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US20030032698A1 (en) * 2000-09-11 2003-02-13 Smith Carrington Duane Cationic-anionic blends for dynamic surface tension reduction
US20070137507A1 (en) * 2005-12-21 2007-06-21 Sun Chemical Corporation Novel means of delivery of fountain solutions for printing
CN101870213A (en) * 2009-04-27 2010-10-27 杜广清 Fountain solution and preparation method thereof
CN103189213A (en) * 2010-10-28 2013-07-03 巴斯夫欧洲公司 Fountain solution and fountain solution concentrates
CN103260890A (en) * 2010-11-01 2013-08-21 太阳化学公司 Fountain solutions for offset lithographic printing inks
CN103640356A (en) * 2013-10-29 2014-03-19 安徽唯宝印刷科技有限公司 Alcohol-free printing fountain solution and preparation method thereof
CN103660668A (en) * 2013-11-18 2014-03-26 蚌埠天光传感器有限公司 Fountain solution with low-concentration ethyl alcohol and preparation method thereof
CN103660667A (en) * 2013-11-18 2014-03-26 蚌埠市英路光电有限公司 Business rotation fountain solution and preparing method of business rotation foundation solution
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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104875519A (en) * 2015-06-16 2015-09-02 合肥吉科新材料有限公司 Novel environment-friendly fountain solution and preparation method thereof
CN105966103A (en) * 2016-06-30 2016-09-28 合肥环照高分子材料厂 Alcohol-free fountain solution containing k-carrageenan-konjac gum compound and preparation method of alcohol-free fountain solution
CN106042705A (en) * 2016-06-30 2016-10-26 合肥环照高分子材料厂 High-viscosity low-surface-tension fountain solution containing k-carrageenan and preparation method of high-viscosity low-surface-tension fountain solution
CN106183522A (en) * 2016-07-19 2016-12-07 合肥鼎亮光学科技有限公司 A kind of carbon sol modification fountain solution compounding containing κ carrageenan Konjac glucomannan and preparation method thereof
CN106739613A (en) * 2016-12-20 2017-05-31 当涂县金龙机械有限公司 A kind of alcohol of exempting from containing hydroxypropyl cyclodextrin prepared by magnetic activated water concentrates divergence type fountain solution high and preparation method thereof
JP2021500585A (en) * 2017-10-19 2021-01-07 ストレック, インコーポレイテッド Compositions for hemolysis, coagulation regulation and extracellular vesicle stabilization
JP7293244B2 (en) 2017-10-19 2023-06-19 ストレック, インコーポレイテッド Compositions for hemolysis, coagulation regulation and extracellular vesicle stabilization
CN109177566A (en) * 2018-09-17 2019-01-11 苏州市万丽珑新材料科技有限公司 One kind exempting from alcohol fountain solution and preparation method thereof

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Denomination of invention: Non-phosphorus fountain solution and preparation method thereof

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Pledgee: Quanjiao County Branch of China Postal Savings Bank Co.,Ltd.

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