CN103906566A - 用于从羟甲基糠醛制备2,5-呋喃二甲酸的喷雾氧化方法 - Google Patents

用于从羟甲基糠醛制备2,5-呋喃二甲酸的喷雾氧化方法 Download PDF

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Publication number
CN103906566A
CN103906566A CN201280049706.6A CN201280049706A CN103906566A CN 103906566 A CN103906566 A CN 103906566A CN 201280049706 A CN201280049706 A CN 201280049706A CN 103906566 A CN103906566 A CN 103906566A
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reactor
reaction vessel
oxidation
hmf
feed
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Chinese (zh)
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左晓斌
巴拉·萨布拉马尼亚姆
达里尔·布希
帕德麦什·温基塔苏布拉马尼安
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Archer Daniels Midland Co
University of Kansas
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Archer Daniels Midland Co
University of Kansas
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D307/56—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D307/68—Carbon atoms having three bonds to hetero atoms with at the most one bond to halogen
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    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24—Stationary reactors without moving elements inside
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2/00—Processes or devices for granulating materials, e.g. fertilisers in general; Rendering particulate materials free flowing in general, e.g. making them hydrophobic
    • B01J2/02—Processes or devices for granulating materials, e.g. fertilisers in general; Rendering particulate materials free flowing in general, e.g. making them hydrophobic by dividing the liquid material into drops, e.g. by spraying, and solidifying the drops
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B01J27/128—Halogens; Compounds thereof with iron group metals or platinum group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/04—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing carboxylic acids or their salts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J4/00—Feed or outlet devices; Feed or outlet control devices
    • B01J4/001—Feed or outlet devices as such, e.g. feeding tubes
    • B01J4/002—Nozzle-type elements
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D307/38—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D307/40—Radicals substituted by oxygen atoms
    • C07D307/46—Doubly bound oxygen atoms, or two oxygen atoms singly bound to the same carbon atom
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00002—Chemical plants
    • B01J2219/00004—Scale aspects
    • B01J2219/00006—Large-scale industrial plants
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00054—Controlling or regulating the heat exchange system
    • B01J2219/00056—Controlling or regulating the heat exchange system involving measured parameters
    • B01J2219/00058—Temperature measurement
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00054—Controlling or regulating the heat exchange system
    • B01J2219/00056—Controlling or regulating the heat exchange system involving measured parameters
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    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
    • B01J2219/00076—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements inside the reactor
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    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00164—Controlling or regulating processes controlling the flow
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/70—Oxidation reactions, e.g. epoxidation, (di)hydroxylation, dehydrogenation and analogues
    • B01J2231/76—Dehydrogenation
    • B01J2231/763—Dehydrogenation of -CH-XH (X= O, NH/N, S) to -C=X or -CX triple bond species

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  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Furan Compounds (AREA)
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CN201280049706.6A 2011-08-31 2012-08-28 用于从羟甲基糠醛制备2,5-呋喃二甲酸的喷雾氧化方法 Pending CN103906566A (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201161529425P 2011-08-31 2011-08-31
US61/529,425 2011-08-31
PCT/US2012/052600 WO2013033058A1 (en) 2011-08-31 2012-08-28 Spray oxidation process for producing 2,5-furandicarboxylic acid from hydroxymethylfurfural

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CN103906566A true CN103906566A (zh) 2014-07-02

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US (1) US9586923B2 (https=)
EP (1) EP2750789B1 (https=)
JP (2) JP6253581B2 (https=)
KR (1) KR101847683B1 (https=)
CN (1) CN103906566A (https=)
BR (1) BR112014004590B1 (https=)
ES (1) ES2689798T3 (https=)
PT (1) PT2750789T (https=)
WO (1) WO2013033058A1 (https=)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107848997A (zh) * 2015-07-24 2018-03-27 纳幕尔杜邦公司 制备2，5‑呋喃二甲酸及其酯的方法
CN108137523A (zh) * 2015-07-22 2018-06-08 巴斯夫欧洲公司 制备呋喃-2,5-二甲酸的方法
CN112898251A (zh) * 2019-11-19 2021-06-04 中国科学院宁波材料技术与工程研究所 一种制备2,5-呋喃二甲酸的方法

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US9586923B2 (en) * 2011-08-31 2017-03-07 University Of Kansas Spray oxidation process for producing 2,5-furandicarboxylic acid from hydroxymethylfurfural
AU2014241870B2 (en) * 2013-03-14 2017-06-08 Archer Daniels Midland Company Process for making 2,5-furandicarboxylic acid
BR112017003159B1 (pt) 2014-08-19 2021-10-05 Archer Daniels Midland Company Processo para converter hidroximetilfurfural em produtos furânicos
CN105688988B (zh) * 2014-12-16 2018-11-27 财团法人工业技术研究院 糠醛化合物的氧化反应催化剂及糠醛化合物的氧化方法
PL3283470T3 (pl) * 2015-04-14 2024-05-06 E I Du Pont De Nemours Sposoby wytwarzania kwasu 2,5-furanodikarboksylowego i jego pochodnych
EP3302423B1 (en) * 2015-06-04 2022-05-25 Crititech, Inc. Particle production system and particle collection device
US9321744B1 (en) 2015-06-26 2016-04-26 Industrial Technology Research Institute Method for preparing 2,5-furan dicarboxylic acid
CN108349920A (zh) 2015-09-17 2018-07-31 微麦德斯公司 呋喃醛上的氧化化学
EP3402787A4 (en) 2016-01-13 2019-11-27 Stora Enso Oyj PROCESS FOR THE PREPARATION OF 2,5-FURANDIC ACETIC ACID AND INTERMEDIATES AND DERIVATIVES THEREOF
EP3652161A1 (en) 2017-07-12 2020-05-20 Stora Enso Oyj Purified 2,5-furandicarboxylic acid pathway products
US11142833B2 (en) * 2017-10-09 2021-10-12 Wisconsin Alumni Research Foundation Electrochemical oxidation of aromatic aldehydes in acidic media
WO2020050215A1 (ja) * 2018-09-07 2020-03-12 国立大学法人東京工業大学 β－二酸化マンガンを用いた酸化物の製造方法
CN113117705B (zh) * 2019-12-31 2024-05-07 中国石油化工股份有限公司 一种改性钌基催化剂及由其催化制备2,5-呋喃二羧酸的方法
KR102347177B1 (ko) 2020-02-13 2022-01-04 한국화학연구원 5-알콕시메틸퍼퓨랄 제조방법
CN111606874B (zh) * 2020-05-28 2022-07-08 浙江恒逸石化研究院有限公司 一种微波诱导强化和恒沸精馏除水组合技术制备2,5-呋喃二甲酸的方法与装置
MX2023004204A (es) * 2020-10-13 2023-05-19 Archer Daniels Midland Co Pretratamiento oxidativo de productos de deshidratacion de carbohidratos que comprenden huminas.
CN113842851A (zh) * 2021-10-27 2021-12-28 南京延长反应技术研究院有限公司 一种2-甲基四氢呋喃的微界面制备系统及方法
CN115591481B (zh) * 2022-10-03 2026-04-14 湖南创大玉兔化工有限公司 一种催化反应向产物方向移动的可逆酯化反应控制器具

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JP2009001519A (ja) * 2007-06-21 2009-01-08 Canon Inc ２，５−フランジカルボン酸の製造方法
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WO2010111288A2 (en) * 2009-03-23 2010-09-30 University Of Kansas Spray process for selective oxidation
CN101896476A (zh) * 2007-12-12 2010-11-24 阿彻丹尼尔斯米德兰德公司 碳水化合物向羟甲基糠醛(hmf)及衍生物的转化
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WO2011043660A2 (en) * 2009-10-07 2011-04-14 Furanix Technologies B.V. Method for the preparation of 2,5-furandicarboxylic acid and esters thereof
CN102040571A (zh) * 2009-10-19 2011-05-04 佳能株式会社 2,5-呋喃二甲酸的制备方法

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JP4976732B2 (ja) * 2006-04-10 2012-07-18 トヨタ自動車株式会社 中間生成物の単離方法及び５−ヒドロキシメチルフルフラールの製造方法
JP2014531422A (ja) * 2011-08-31 2014-11-27 ザ・ユニヴァーシティ・オブ・カンザス バイオベースのコハク酸および２，５−フランジカルボン酸の両方を製造するための方法
US9586923B2 (en) * 2011-08-31 2017-03-07 University Of Kansas Spray oxidation process for producing 2,5-furandicarboxylic acid from hydroxymethylfurfural

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JP2009001519A (ja) * 2007-06-21 2009-01-08 Canon Inc ２，５−フランジカルボン酸の製造方法
CN101434589A (zh) * 2007-11-14 2009-05-20 中国科学院大连化学物理研究所 一种由果糖源生物质制备5-羟甲基糠醛的方法
CN101434588A (zh) * 2007-11-14 2009-05-20 中国科学院大连化学物理研究所 一种由5-羟甲基糠醛制备2.5-二甲基呋喃的方法
CN101896476A (zh) * 2007-12-12 2010-11-24 阿彻丹尼尔斯米德兰德公司 碳水化合物向羟甲基糠醛(hmf)及衍生物的转化
WO2010111288A2 (en) * 2009-03-23 2010-09-30 University Of Kansas Spray process for selective oxidation
WO2011043661A1 (en) * 2009-10-07 2011-04-14 Furanix Technologies B.V. Method for the preparation of 2,5-furandicarboxylic acid and for the preparation of the dialkyl ester of 2,5-furandicarboxylic acid
WO2011043660A2 (en) * 2009-10-07 2011-04-14 Furanix Technologies B.V. Method for the preparation of 2,5-furandicarboxylic acid and esters thereof
CN102040571A (zh) * 2009-10-19 2011-05-04 佳能株式会社 2,5-呋喃二甲酸的制备方法

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108137523A (zh) * 2015-07-22 2018-06-08 巴斯夫欧洲公司 制备呋喃-2,5-二甲酸的方法
CN108137523B (zh) * 2015-07-22 2022-07-26 巴斯夫欧洲公司 制备呋喃-2,5-二甲酸的方法
CN107848997A (zh) * 2015-07-24 2018-03-27 纳幕尔杜邦公司 制备2，5‑呋喃二甲酸及其酯的方法
CN107848997B (zh) * 2015-07-24 2022-11-29 纳幕尔杜邦公司 制备2，5-呋喃二甲酸及其酯的方法
CN115819383A (zh) * 2015-07-24 2023-03-21 纳幕尔杜邦公司 制备2，5-呋喃二甲酸及其酯的方法
CN112898251A (zh) * 2019-11-19 2021-06-04 中国科学院宁波材料技术与工程研究所 一种制备2,5-呋喃二甲酸的方法

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JP2018016632A (ja) 2018-02-01
JP6253581B2 (ja) 2017-12-27
JP2014528927A (ja) 2014-10-30
EP2750789A4 (en) 2015-05-13
BR112014004590A2 (pt) 2017-03-28
EP2750789B1 (en) 2018-07-11
KR20140088079A (ko) 2014-07-09
BR112014004590B1 (pt) 2019-11-19
EP2750789A1 (en) 2014-07-09
PT2750789T (pt) 2018-10-30
US9586923B2 (en) 2017-03-07
ES2689798T3 (es) 2018-11-15
KR101847683B1 (ko) 2018-05-24
JP6563992B2 (ja) 2019-08-21
WO2013033058A1 (en) 2013-03-07
US20150183755A1 (en) 2015-07-02

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