CN103889567B - 用于吸热催化脱氢工艺的催化剂床体系和吸热脱氢工艺 - Google Patents

用于吸热催化脱氢工艺的催化剂床体系和吸热脱氢工艺 Download PDF

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CN103889567B
CN103889567B CN201280051896.5A CN201280051896A CN103889567B CN 103889567 B CN103889567 B CN 103889567B CN 201280051896 A CN201280051896 A CN 201280051896A CN 103889567 B CN103889567 B CN 103889567B
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catalyst bed
inert material
temperature
catalyst
bed system
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CN103889567A (zh
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克里斯托弗·魏嫩
古汉·马蒂瓦南
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Borealis GmbH
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
    • C07C5/333—Catalytic processes
    • C07C5/3332—Catalytic processes with metal oxides or metal sulfides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/0242—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid flow within the bed being predominantly vertical
    • B01J8/025—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid flow within the bed being predominantly vertical in a cylindrical shaped bed
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/0285—Heating or cooling the reactor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/0292—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds with stationary packing material in the bed, e.g. bricks, wire rings, baffles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/04—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds
    • B01J8/0403—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the fluid flow within the beds being predominantly horizontal
    • B01J8/0407—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the fluid flow within the beds being predominantly horizontal through two or more cylindrical annular shaped beds
    • B01J8/0419—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the fluid flow within the beds being predominantly horizontal through two or more cylindrical annular shaped beds the beds being placed in separate reactors
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/04—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds
    • B01J8/0496—Heating or cooling the reactor
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
    • C07C5/333—Catalytic processes
    • C07C5/3335—Catalytic processes with metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00522—Controlling the temperature using inert heat absorbing solids outside the bed
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/26—Chromium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C07C2521/04—Alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/24—Chromium, molybdenum or tungsten
    • C07C2523/26—Chromium
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Fluid Mechanics (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
  • Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
CN201280051896.5A 2011-10-24 2012-10-22 用于吸热催化脱氢工艺的催化剂床体系和吸热脱氢工艺 Active CN103889567B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP11186322.1A EP2586524A1 (en) 2011-10-24 2011-10-24 A catalyst bed system for an endothermic catalytic dehydrogenation process and an endothermic dehydrogenation process
EP11186322.1 2011-10-24
PCT/EP2012/070860 WO2013060640A1 (en) 2011-10-24 2012-10-22 A catalyst bed system for an endothermic catalytic dehydrogenation process and an endothermic dehydrogenation process

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CN103889567A CN103889567A (zh) 2014-06-25
CN103889567B true CN103889567B (zh) 2017-02-22

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US (1) US9926241B2 (enExample)
EP (2) EP2586524A1 (enExample)
KR (1) KR101941616B1 (enExample)
CN (1) CN103889567B (enExample)
BR (1) BR112014009591B1 (enExample)
CA (1) CA2851427C (enExample)
EA (1) EA025815B1 (enExample)
IN (1) IN2014KN01094A (enExample)
MX (1) MX364478B (enExample)
MY (1) MY171930A (enExample)
UA (1) UA114610C2 (enExample)
WO (1) WO2013060640A1 (enExample)
ZA (1) ZA201402604B (enExample)

Families Citing this family (6)

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Publication number Priority date Publication date Assignee Title
US10155702B2 (en) 2015-11-04 2018-12-18 Exxonmobil Chemical Patents Inc. Processes and systems for converting hydrocarbons to cyclopentadiene
WO2017078891A1 (en) * 2015-11-04 2017-05-11 Exxonmoble Chemical Patents Inc. Integrated gas turbine and conversion system process
US20200239386A1 (en) * 2017-07-31 2020-07-30 Sabic Global Technologies B.V. System and method for dehydrogenating isobutane to isobutylene
US10836690B1 (en) * 2019-07-26 2020-11-17 Tpc Group Llc Dehydrogenation process and system with reactor re-sequencing
CN115608270B (zh) * 2021-07-14 2025-12-02 中国石油化工股份有限公司 内表面附着二氧化硅的反应器及其制备方法和甲烷氧化偶联制碳二烃的方法
CN115608271B (zh) * 2021-07-14 2025-12-02 中国石油化工股份有限公司 内表面附着氧化铝的反应器及其制备方法和甲烷氧化偶联制碳二烃的方法

Citations (4)

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WO1995023123A1 (en) * 1994-02-28 1995-08-31 Abb Lummus Crest Inc. Endothermic catalytic dehydrogenation process
CN1675146A (zh) * 2002-08-16 2005-09-28 巴斯福股份公司 烷烃脱氢的等温方法
US7566429B2 (en) * 2005-06-14 2009-07-28 Sandia Corporation Catalytic reactive separation system for energy-efficient production of cumene
CN101734987A (zh) * 2008-11-07 2010-06-16 中国石油化工股份有限公司 一种由c4烃制备乙烯、丙烯的方法

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US2419997A (en) 1943-03-05 1947-05-06 Houdry Process Corp Catalytic dehydrogenation of aliphatic hydrocarbons
NL301296A (enExample) * 1962-12-03 1900-01-01
US4560824A (en) 1985-05-07 1985-12-24 Air Products And Chemicals, Inc. Heat balance control in catalytic dehydrogenation of isobutane
NO316512B1 (no) * 2000-01-25 2004-02-02 Statoil Asa Fremgangsmate og reaktor for autoterm dehydrogenering av hydrokarboner
US6392113B1 (en) 2000-10-03 2002-05-21 Abb Lummus Global Inc. Catalytic hydrocarbon dehydrogenation system with prereaction
US8063261B2 (en) 2002-01-14 2011-11-22 Sud-Chemie Inc. Multi-layered dehydrogenation catalyst system and process of use
US7491860B2 (en) 2005-08-03 2009-02-17 Süd-Chemie Inc. Dehydrogenation process
US7973207B2 (en) 2005-09-02 2011-07-05 Sud-Chemie Inc. Endothermic hydrocarbon conversion process
US7622623B2 (en) 2005-09-02 2009-11-24 Sud-Chemie Inc. Catalytically inactive heat generator and improved dehydrogenation process
DE102006035718A1 (de) * 2006-07-28 2008-01-31 Basf Ag Verfahren zum Langzeitbetrieb einer kontinuierlich betriebenen heterogen katalysierten partiellen Dehydrierung eines zu dehydrierenden Kohlenwasserstoffs

Patent Citations (4)

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Publication number Priority date Publication date Assignee Title
WO1995023123A1 (en) * 1994-02-28 1995-08-31 Abb Lummus Crest Inc. Endothermic catalytic dehydrogenation process
CN1675146A (zh) * 2002-08-16 2005-09-28 巴斯福股份公司 烷烃脱氢的等温方法
US7566429B2 (en) * 2005-06-14 2009-07-28 Sandia Corporation Catalytic reactive separation system for energy-efficient production of cumene
CN101734987A (zh) * 2008-11-07 2010-06-16 中国石油化工股份有限公司 一种由c4烃制备乙烯、丙烯的方法

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Publication number Publication date
WO2013060640A1 (en) 2013-05-02
EP2586524A1 (en) 2013-05-01
US20140296606A1 (en) 2014-10-02
CN103889567A (zh) 2014-06-25
KR20140084129A (ko) 2014-07-04
BR112014009591A2 (pt) 2017-05-09
BR112014009591B1 (pt) 2019-11-12
US9926241B2 (en) 2018-03-27
CA2851427A1 (en) 2013-05-02
EP2771101A1 (en) 2014-09-03
EP2771101B1 (en) 2019-08-21
MX364478B (es) 2019-04-29
EA201400463A1 (ru) 2014-08-29
UA114610C2 (uk) 2017-07-10
KR101941616B1 (ko) 2019-01-23
EA025815B1 (ru) 2017-01-30
ZA201402604B (en) 2019-10-30
IN2014KN01094A (enExample) 2015-10-09
MX2014004909A (es) 2014-07-09
MY171930A (en) 2019-11-07
CA2851427C (en) 2021-04-27

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