CN103864303A - Glass lining ground coat - Google Patents
Glass lining ground coat Download PDFInfo
- Publication number
- CN103864303A CN103864303A CN201410087523.4A CN201410087523A CN103864303A CN 103864303 A CN103864303 A CN 103864303A CN 201410087523 A CN201410087523 A CN 201410087523A CN 103864303 A CN103864303 A CN 103864303A
- Authority
- CN
- China
- Prior art keywords
- parts
- adhesive agent
- oxide
- mixing adhesive
- enamel
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Glass Compositions (AREA)
Abstract
The invention provides a glass lining ground coat which comprises silicon dioxide, aluminum oxide, univalent alkaline oxide, boron oxide, calcium fluoride, sodium fluosilicate, a mixed adherence promoter and a coloring agent, wherein the mixed adherence promoter comprises fluorocarbon cerium ore, antimony oxide, nickel oxide, sodium sulfate and lithium carbonate. The invention further provides a preparation method of the mixed adherence promoter, and the ground coat containing the mixed adherence promoter can be firmly combined with a body, so that the scale burst porcelain is reduced, the product quality and the finished product rate are improved, and the cost is greatly lowered.
Description
Technical field
The present invention relates to a kind of glass lining bottom glaze and ground-coat enamel adhesive agent and preparation method, belong to lass lining and manufacture field.
Background technology
The glass-lined equipments such as glassed steel reaction vessels, with the distinctive corrosion resistance nature of its enamel, non-viscosity, insulativity, barrier property, fresh-keeping property with and high performance-price ratio, be widely used at present the industry such as chemical industry, oil, medicine, agricultural chemicals, food.
So-called enamel for glassed steel is exactly a kind of vitreous enamel of ability strong acid corrosion.Because its formula and melting technology and glass approach, so it is called to enamel for glassed steel.Enamel for glassed steel has lass lining cover-coat enamel and glass lining bottom glaze.
Ground-coat enamel can be divided into nickel enamel, cobalt enamel, cobalt nickel enamel, antimony molybdenum enamel and mixing ground-coat enamel etc. by adhesive agent kind.The function of glass lining bottom glaze: the one, as transition layer adhesive layer in other words, cover-coat enamel and steel are tied securely to stick together, the 2nd, play the effect of stored gas, because can produce CO in enamel firing process, CO2, the gases such as H2, it is just stable that these gases have part must stay in micro-pore of ground-coat enamel, due to factors such as furnace kiln structure, product structure, heating conditions, make ground-coat enamel will stand the temperature difference of 50-80 ℃ simultaneously.General requirement is about 840-860 ℃ of energy vitrifying, to 890-910 ℃ also in vitrifying and not burning.The viscosity of the glass lining bottom glaze within the scope of said temperature is greatly about 10
4.8pool is to 10
3.2between pool.
The burst porcelain of glass-lined equipment fish scale is a persistent ailment of lass lining industry.Fish scale burst porcelain is the burst porcelain phenomenon that enamel coating departs from the flakey differing in size, and also makes hydrogen quick-fried.The mechanism that forms fish scale burst porcelain is: in the steel plate of manufacture glass-lined equipment, have the hydrogen existing with various forms, in enameling glass product sintering process, it is saturated that hydrogen has reached in steel, and in the time that goods are cooled to enamel to solidify in air, hydrogen has little time to overflow, so that in steel, has reached hypersaturated state.After staying, to separate out locational this supersaturation hydrogen and produce certain pressure, its size during with high temperature in steel hydrogen content to separate out the degree of porosity of how many and enamel coating relevant.When this pressure increases to can make enamel coating come off time, just form fish scale burst porcelain.Because this fish scale burst porcelain has certain latent, can be under given conditions occur, thereby after glass-lined equipment manufacture completes, install in, all can occur while using, seriously perplexing the application of glass-lined equipment at chemical industry.
Summary of the invention
The present invention relates to a kind of glass lining bottom glaze, ground-coat enamel adhesive agent and its preparation method.
Glass lining bottom glaze provided by the invention, comprise silicon-dioxide, aluminium sesquioxide, monovalence basic oxide, boron oxide, Calcium Fluoride (Fluorspan), Sodium Silicofluoride, mix adhesive agent, staining agent, weight percent meter, it comprises following effect components: silicon-dioxide is 31.0-55.0%, aluminium sesquioxide is 4.0-9.0%, monovalence basic oxide are 8.0-19.0%, boron oxide is 15.5-29.0%, Calcium Fluoride (Fluorspan) is 3.3-6.9%, Sodium Silicofluoride is 2.1-2.9%, mixing adhesive agent are 0.5-2.5%, tinting material is 0.1-2.5%, wherein monovalence basic oxide are sodium oxide, potassium oxide, one or more in Lithium Oxide 98min.Contriver finds, weight percent meter, and in the time that the content of mixing adhesive agent is 1.0-2.0%, it is shock-resistant and anti-thermal shock effect is best, therefore preferred above-mentioned glass lining bottom glaze, by weight percentage, its content that mixes adhesive agent is 1.0-2.0%.
Mixing adhesive agent provided by the invention, by weight percentage: it comprises following effect components: hamartite stone is 45.0-56.0%, weisspiessglanz is 7-11%, nickel oxide is 21-39%, saltcake 8-11%, Quilonum Retard 3-7%, contriver, to above-mentioned mixing adhesive agent, has carried out preferably, preferably, above-mentioned mixing adhesive agent, by weight percentage: it comprises following effect components: hamartite stone 47.0%, weisspiessglanz 10%, nickel oxide 30.0%, saltcake 9.0%, Quilonum Retard 4.0%.
The preparation method of above-mentioned mixing adhesive agent provided by the invention, comprise take raw material, powder, mix, found, cooling, the process such as grind, sieve, the process of wherein founding is to mixing the influential effect maximum of adhesive agent.The process of founding that contriver provides comprises the following steps: (1) is first heated to 120-150 ℃ by mixture, and insulation reaction 10 minutes-1 hour, makes to hold volatile moisture and gas and be evaporated completely entirely, can stir if desired, to accelerate the speed of volatilization; (2) mixture is warming up to 450-600 ℃, is incubated 10 minutes-1 hour, this stage is that mineral substance decomposes, takes off in conjunction with material stages such as water, and (3) are finally warming up to 1300-1400 ℃, are filled with air, make each composition melting, sintering.Fully mix in order to make to mix adhesive agent, reach best technique effect, contriver is optimized the process of founding, and preferably, the above-mentioned process of founding is: (1) is first heated to mixture 130 ℃, insulation reaction 20 minutes, (2) mixture is warming up to 550 ℃, is incubated 30 minutes, (3) are finally warming up to 1350 ℃, be filled with air, sintering.After cooling, pulverize by ball mill, gained fine powder, crosses 80 mesh sieve, has obtained mixing adhesive agent.
These mixing adhesive agent are ground in ground-coat enamel formula as mill addition, in the sintering process of glass lining bottom glaze, there is complicated physical-chemical reaction with other components of ground-coat enamel, more microbubble and chemical bond are produced, these microbubbles in ground glaze layer, formed hold and effusion steel plate in nest and the hole of saturated supersaturation hydrogen, reduce the pressure of supersaturation hydrogen to enamel coating, be unlikely to make enamel coating to come off and form fish scale burst porcelain; The chemical bonds of iron in the more chemical bond generating and steel plate, brute force is typed in steel plate, makes ground-coat enamel and steel plate form powerful adherence.This friction pull has been much higher than to burn till after staying in rear steel will separate out the pressure that locational supersaturation hydrogen produces, and has stoped enamel coating to come off, and can not form fish scale burst porcelain.
Silicon-dioxide (the SiO that the present invention selects
2), aluminium sesquioxide (Al
2o
3), monovalence basic oxide (R
2o), boron oxide (B
2o
3), Calcium Fluoride (Fluorspan) (CaF
2), Sodium Silicofluoride (NaSiF
6) etc. body material are all conventional materials of this area, also be the common formula composition of glass lining bottom glaze, for example Jin nation is vast, " handbook-enamelled vessel is selected in petrochemical equipment design ", Chemical Industry Press, a kind of ground-coat enamel of mentioning for 2009, wherein silicon-dioxide 45-65%, aluminium sesquioxide 4-6%, monovalence basic oxide 12-18%, boron oxide 10-16%, Calcium Fluoride (Fluorspan) 4-8%, the adhesive agent 2-2.5% such as cobalt oxide, nickel oxide.
Those skilled in the art can use this mixing adhesive agent according to the using method of the conventional adhesive agent in this area, without special operational step.Meanwhile, ground-coat enamel provided by the present invention can use together with cover-coat enamel commercially available or known formulations.
Technical scheme of the present invention has following excellent effect:
1) enamel ground-coat enamel of the present invention is coated on idiosome and can makes idiosome have resistant to elevated temperatures characteristic,
2) mixing adhesive agent, that enamel glaze is combined with idiosome is more firm, has reduced fish scale burst porcelain,
3) improve the quality of products and finished product rate, reduced in a large number cost.
Embodiment
Below in conjunction with embodiment, the present invention is described in detail, embodiment is only the preferred embodiment of the present invention, is not limitation of the present invention.
, preparation mix adhesive agent
embodiment 1-1
By weight, taking hamartite stone is 47 parts, and weisspiessglanz is 10 parts, nickel oxide is 30 parts, 9 parts, saltcake, 4 parts of Quilonum Retards, pulverize, mix, first mixture is heated to 130 ℃, stir insulation reaction 20 minutes, be then warming up to 550 ℃, be incubated 30 minutes, be warming up to most 1350 ℃, be filled with air calcination.After cooling, pulverize by ball mill, gained fine powder, crosses 80 mesh sieve, has obtained mixing adhesive agent.
embodiment 1-2
By weight, taking hamartite stone is 45 parts, and weisspiessglanz is 7 parts, nickel oxide is 37 parts, 8 parts, saltcake, 3 parts of Quilonum Retards, pulverize, mix, first mixture is heated to 120 ℃, stir insulation reaction 30 minutes, be then warming up to 560 ℃, be incubated 30 minutes, be warming up to most 1300 ℃, be filled with air calcination.After cooling, pulverize by ball mill, gained fine powder, crosses 80 mesh sieve, has obtained mixing adhesive agent.
embodiment 1-3
By weight, taking hamartite stone is 50 parts, and weisspiessglanz is 8 parts, nickel oxide is 27 parts, 11 parts, saltcake, 4 parts of Quilonum Retards, pulverize, mix, first mixture is heated to 150 ℃, stir insulation reaction 30 minutes, be then warming up to 560 ℃, be incubated 30 minutes, be warming up to most 1370 ℃, be filled with air calcination.After cooling, pulverize by ball mill, gained fine powder, crosses 80 mesh sieve, has obtained mixing adhesive agent.
embodiment 1-4
By weight, taking hamartite stone is 56 parts, and weisspiessglanz is 9 parts, nickel oxide is 21 parts, 10 parts, saltcake, 4 parts of Quilonum Retards, pulverize, mix, first mixture is heated to 150 ℃, stir insulation reaction 30 minutes, be then warming up to 560 ℃, be incubated 30 minutes, be warming up to most 1350 ℃, be filled with air calcination.After cooling, pulverize by ball mill, gained fine powder, crosses 80 mesh sieve, has obtained mixing adhesive agent.
, prepare enamel ground-coat enamel
embodiment 2-1-1
By weight, get 40 parts of silicon-dioxide, 9 parts of aluminium sesquioxides, 16 parts of potassium oxides, 25 parts of boron oxides, 4.5 parts, Calcium Fluoride (Fluorspan), 2.5 parts of Sodium Silicofluorides, 2.0 parts of the mixing adhesive agent of embodiment 1-1,1.0 parts of ferric oxide, after batching, grind melting and make enamel ground-coat enamel, 850 ~ 890 ℃ of firing temperatures, 850 ℃ of minimum adherence temperature.
embodiment 2-1-2
By weight, get 44 parts of silicon-dioxide, 8 parts of aluminium sesquioxides, 16 parts, monovalence basic oxide, 23 parts of boron oxides, 3.5 parts, Calcium Fluoride (Fluorspan), 2.5 parts of Sodium Silicofluorides, 1.5 parts of the mixing adhesive agent of embodiment 1-1,1.5 parts of ferric oxide, after batching, grind melting and make enamel ground-coat enamel, 860 ~ 920 ℃ of firing temperatures, 860 ℃ of minimum adherence temperature.
embodiment 2-1-3
By weight, get 50 parts of silicon-dioxide, 6 parts of aluminium sesquioxides, 17 parts, monovalence basic oxide, 20 parts of boron oxides, 2.5 parts, Calcium Fluoride (Fluorspan), 2.5 parts of Sodium Silicofluorides, 1.0 parts of the mixing adhesive agent of embodiment 1-1,1.0 parts of ferric oxide, after batching, grind melting and make enamel ground-coat enamel, 870 ~ 950 ℃ of firing temperatures, 870 ℃ of minimum adherence temperature.
embodiment 2-2-1
By weight, get 40 parts of silicon-dioxide, 9 parts of aluminium sesquioxides, 16 parts of potassium oxides, 25 parts of boron oxides, 4.5 parts, Calcium Fluoride (Fluorspan), 2.5 parts of Sodium Silicofluorides, 2.0 parts of the mixing adhesive agent of embodiment 1-2,1.0 parts of ferric oxide, grind melting and make enamel ground-coat enamel after batching.
embodiment 2-2-2
By weight, get 44 parts of silicon-dioxide, 8 parts of aluminium sesquioxides, 16 parts, monovalence basic oxide, 23 parts of boron oxides, 3.5 parts, Calcium Fluoride (Fluorspan), 2.5 parts of Sodium Silicofluorides, 1.5 parts of the mixing adhesive agent of embodiment 1-2,1.5 parts of ferric oxide, grind melting and make enamel ground-coat enamel after batching.
embodiment 2-2-3
By weight, get 50 parts of silicon-dioxide, 6 parts of aluminium sesquioxides, 17 parts, monovalence basic oxide, 20 parts of boron oxides, 2.5 parts, Calcium Fluoride (Fluorspan), 2.5 parts of Sodium Silicofluorides, 1.0 parts of the mixing adhesive agent of embodiment 1-2,1.0 parts of ferric oxide, grind melting and make enamel ground-coat enamel after batching.
embodiment 2-3-1
By weight, get 40 parts of silicon-dioxide, 9 parts of aluminium sesquioxides, 16 parts of potassium oxides, 25 parts of boron oxides, 4.5 parts, Calcium Fluoride (Fluorspan), 2.5 parts of Sodium Silicofluorides, 2.0 parts of the mixing adhesive agent of embodiment 1-3,1.0 parts of ferric oxide, grind melting and make enamel ground-coat enamel after batching.
embodiment 2-3-2
By weight, get 44 parts of silicon-dioxide, 8 parts of aluminium sesquioxides, 16 parts, monovalence basic oxide, 23 parts of boron oxides, 3.5 parts, Calcium Fluoride (Fluorspan), 2.5 parts of Sodium Silicofluorides, 1.5 parts of the mixing adhesive agent of embodiment 1-3,1.5 parts of ferric oxide, grind melting and make enamel ground-coat enamel after batching.
embodiment 2-3-3
By weight, get 50 parts of silicon-dioxide, 6 parts of aluminium sesquioxides, 17 parts, monovalence basic oxide, 20 parts of boron oxides, 2.5 parts, Calcium Fluoride (Fluorspan), 2.5 parts of Sodium Silicofluorides, 1.0 parts of the mixing adhesive agent of embodiment 1-3,1.0 parts of ferric oxide, grind melting and make enamel ground-coat enamel after batching.
embodiment 2-4-1
By weight, get 40 parts of silicon-dioxide, 9 parts of aluminium sesquioxides, 16 parts of potassium oxides, 25 parts of boron oxides, 4.5 parts, Calcium Fluoride (Fluorspan), 2.5 parts of Sodium Silicofluorides, 2.0 parts of the mixing adhesive agent of embodiment 1-4,1.0 parts of ferric oxide, grind melting and make enamel ground-coat enamel after batching.
embodiment 2-4-2
By weight, get 44 parts of silicon-dioxide, 8 parts of aluminium sesquioxides, 16 parts, monovalence basic oxide, 23 parts of boron oxides, 3.5 parts, Calcium Fluoride (Fluorspan), 2.5 parts of Sodium Silicofluorides, 1.5 parts of the mixing adhesive agent of embodiment 1-4,1.5 parts of ferric oxide, grind melting and make enamel ground-coat enamel after batching.
embodiment 2-4-3
By weight, get 50 parts of silicon-dioxide, 6 parts of aluminium sesquioxides, 17 parts, monovalence basic oxide, 20 parts of boron oxides, 2.5 parts, Calcium Fluoride (Fluorspan), 2.5 parts of Sodium Silicofluorides, 1.0 parts of the mixing adhesive agent of embodiment 1-4,1.0 parts of ferric oxide, grind melting and make enamel ground-coat enamel after batching.
comparative example 1-1
By weight, get 40 parts of silicon-dioxide, 9 parts of aluminium sesquioxides, 16 parts of potassium oxides, 25 parts of boron oxides, 4.5 parts, Calcium Fluoride (Fluorspan), 2.5 parts of Sodium Silicofluorides, 2.0 parts of nickel oxide, 1.0 parts of ferric oxide, grind melting and make enamel ground-coat enamel after batching.
comparative example 1-2
By weight, get 44 parts of silicon-dioxide, 8 parts of aluminium sesquioxides, 16 parts, monovalence basic oxide, 23 parts of boron oxides, 3.5 parts, Calcium Fluoride (Fluorspan), 2.5 parts of Sodium Silicofluorides, 1.5 parts of nickel oxide, 1.5 parts of ferric oxide, grind melting and make enamel ground-coat enamel after batching.
comparative example 1-3
By weight, get 50 parts of silicon-dioxide, 6 parts of aluminium sesquioxides, 17 parts, monovalence basic oxide, 20 parts of boron oxides, 2.5 parts, Calcium Fluoride (Fluorspan), 2.5 parts of Sodium Silicofluorides, 1.0 parts of molybdenum oxides, 1.0 parts of ferric oxide, grind melting and make enamel ground-coat enamel after batching.
Contriver's enamel cover-coat enamel used is prepared by a common formula, and its formula is 40 parts of silicon-dioxide, 5.5 parts of aluminium sesquioxides, 18 parts of sodium oxides, 20.5 parts of boron oxides, 3 parts, Calcium Fluoride (Fluorspan), 7 parts of Sodium Silicofluorides, 0.01 part of cobalt oxide, 1.09 parts, zinc oxide, 4.9 parts of Vanadium Pentoxide in FLAKESs.
Steel test block used is Q 235 types, and specification is 60 mm*50 mm* 4 mm, wherein C, and Si, Mn, S, the content of P is respectively 0.17%, 0.024%, and 0.51%, 0.022%, 0.018%.
The enamel bed material application of slip prepared by above-described embodiment 2-1-1 to embodiment 2-4-3 and comparative example in steel test block, high-temperature firing.
Test to detect the adherence of porcelain sleeve coating and metallic matrix with impact and thermal shock.Shock test is carried out with reference to GB/T 7990-2002, evaluates the adhesion property of coating with the destroyed number of times being impacted of coating.
Thermal shock laboratory reference GB/T 4547-2007 carries out, and the Heating temperature of thermal fatigue test is 400 ℃.The test of heat-resisting acute degeneration is that test block is heated to chilling in the water of putting people's room temperature current downflow after 200 ℃, if enamel coating does not ftracture, increase progressively 50 ℃ reheat, chilling, continue to increase progressively temperature heating, chilling if do not ftracture, so circulation, until cracking.
The result of embodiment 2-1-1 to embodiment 2-4-3 and simultaneous test is as follows: (table 1)
| ? | Number of shocks | Thermal fatigue number of times | Resistance to sudden turn of events temperature head/℃ |
| Embodiment 2-1-1 | 55 | 14 | 480 |
| Embodiment 2-1-2 | 43 | 12 | 430 |
| Embodiment 2-1-3 | 31 | 8 | 380 |
| Embodiment 2-2-1 | 50 | 13 | 480 |
| Embodiment 2-2-2 | 44 | 12 | 430 |
| Embodiment 2-2-3 | 30 | 7 | 380 |
| Embodiment 2-3-1 | 49 | 13 | 430 |
| Embodiment 2-3-2 | 37 | 10 | 380 |
| Embodiment 2-3-3 | 28 | 6 | 380 |
| Embodiment 2-4-1 | 44 | 11 | 480 |
| Embodiment 2-4-2 | 37 | 9 | 380 |
| Embodiment 2-4-3 | 26 | 5 | 380 |
| Comparative example 1-1 | 24 | 5 | 380 |
| Comparative example 1-2 | 21 | 5 | 380 |
| Comparative example 1-3 | 17 | 6 | 380 |
By observation experiment, we find, after idiosome high-temperature firing, prefer to use the idiosome of ground-coat enamel of the present invention, on idiosome, ground-coat enamel all melts on the rough surface of embryo, does not form obvious ground glaze layer, the adherence of enamel bed material and idiosome is good.Having the above-mentioned cover-coat enamel of the application of slip on the idiosome of ground-coat enamel in the application of slip, there is stronger gloss in the enamel coating burning out surface.
Known by table 1, the use that mixes adhesive agent has improved impact resistance and the thermal shock resistance of test block, and with the increase that enters amount, its thermal shock resistance strengthens, and when content is 2%, thermal shock resistance is best.Impact test and thermal shock resistance test explanation add mixing adhesive agent to improve the bonding strength of enamel coating and matrix, and experimentation is not observed obvious fish scale burst porcelain phenomenon.
Claims (10)
1. a glass lining bottom glaze, comprise silicon-dioxide, aluminium sesquioxide, monovalence basic oxide, boron oxide, Calcium Fluoride (Fluorspan), Sodium Silicofluoride, mixing adhesive agent, staining agent, it is characterized in that these mixing adhesive agent comprise following effect components: hamartite stone, weisspiessglanz, nickel oxide, Quilonum Retard and saltcake.
2. a kind of glass lining bottom glaze as claimed in claim 1, is characterized in that, described monovalence basic oxide are one or more in sodium oxide, potassium oxide, Lithium Oxide 98min.
3. a kind of glass lining bottom glaze as claimed in claim 2, it is characterized in that, by weight percentage, described ground-coat enamel comprises following effect components: silicon-dioxide 40.0-55.0%, aluminium sesquioxide 4.0-9.0%, monovalence basic oxide 8.0-19.0%, boron oxide 15.5-29.0%, Calcium Fluoride (Fluorspan) 3.3-6.9%, Sodium Silicofluoride 2.1-2.9%, mixing adhesive agent 0.5-2.5% and tinting material 0.1-2.5%.
4. glass lining bottom glaze as claimed in claim 3, is characterized in that, by weight percentage, described mixing adhesive agent are 1.0-2.0%.
5. a kind of glass lining bottom glaze as claimed in claim 4, it is characterized in that, by weight percentage, described mixing adhesive agent comprise following effect components: hamartite stone 45.0-56.0%, weisspiessglanz 7-11%, nickel oxide 21-39%, saltcake 8-11% and Quilonum Retard 3-7%.
6. the mixing adhesive agent as described in as arbitrary in claim 1-5, it is characterized in that, by weight percentage, described mixing adhesive agent comprise following effect components: hamartite stone 47.0%, weisspiessglanz 10%, nickel oxide 30.0%, saltcake 9.0% and Quilonum Retard 4.0%.
7. a preparation method for the mixing adhesive agent as described in as arbitrary in claim 1-6, comprises weighing, powder, mixes, founds, cooling, the process of grinding, sieve, and it is characterized in that the process of founding comprises:
1) mixture is heated to 120-150 ℃, insulation reaction 10 minutes-1 hour;
2) be warming up to 450-600 ℃, be incubated 10 minutes-1 hour;
3) be warming up to 1300-1400 ℃, be filled with air, sintering.
8. the preparation method of mixing adhesive agent as claimed in claim 7, is characterized in that, the described process of founding comprises:
1) mixture is heated to 130 ℃, insulation reaction 20 minutes;
2) be warming up to 550 ℃, be incubated 30 minutes;
3) be warming up to 1350 ℃, be filled with air calcination.
9. the preparation method of mixing adhesive agent as claimed in claim 7, is characterized in that, described process of lapping is to adopt ball mill to carry out.
10. the preparation method of mixing adhesive agent as claimed in claim 7, is characterized in that, the described process of sieving referred to 80 object sieves.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410087523.4A CN103864303B (en) | 2014-03-12 | 2014-03-12 | A kind of glass lining bottom glaze |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410087523.4A CN103864303B (en) | 2014-03-12 | 2014-03-12 | A kind of glass lining bottom glaze |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103864303A true CN103864303A (en) | 2014-06-18 |
| CN103864303B CN103864303B (en) | 2015-12-09 |
Family
ID=50903388
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410087523.4A Active CN103864303B (en) | 2014-03-12 | 2014-03-12 | A kind of glass lining bottom glaze |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103864303B (en) |
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104383864A (en) * | 2014-12-13 | 2015-03-04 | 常熟市华懋化工设备有限公司 | Glass-lined reaction tank |
| CN104399419A (en) * | 2014-12-12 | 2015-03-11 | 常熟市永达化工设备厂 | Reaction still circularly heated by steam-heated heat transfer oil |
| CN104445950A (en) * | 2014-12-13 | 2015-03-25 | 常熟市华懋化工设备有限公司 | Glass lining stirrer |
| CN104445949A (en) * | 2014-12-12 | 2015-03-25 | 常熟市永达化工设备厂 | Open glass-lined storage tank |
| CN104455923A (en) * | 2014-12-13 | 2015-03-25 | 常熟市华懋化工设备有限公司 | Glassed steel pipe fitting |
| CN104529162A (en) * | 2014-12-12 | 2015-04-22 | 常熟市永达化工设备厂 | Efficient glass lining agitator |
| CN106242295A (en) * | 2016-07-15 | 2016-12-21 | 江西科盛环保股份有限公司 | Q345 hot rolled alloy steel counterenamel anti-squama burst porcelain glaze and function cover-coat enamel |
| CN106512907A (en) * | 2017-01-12 | 2017-03-22 | 临沂宏业化工设备有限公司 | High-strength corrosion-resistant glass-lined reactor |
| CN106957149A (en) * | 2017-05-04 | 2017-07-18 | 钦州学院 | Frit for porcelain enamel |
| CN106977100A (en) * | 2017-05-04 | 2017-07-25 | 钦州学院 | The good frit for porcelain enamel with steel plate adherence |
| CN109569472A (en) * | 2019-01-23 | 2019-04-05 | 临沂宏业化工设备有限公司 | A kind of high pressure corrosion resistant glassed steel reaction vessels |
| CN110698065A (en) * | 2019-09-05 | 2020-01-17 | 华庚新材料科技(嘉兴)有限公司 | Steel pipe with glass lining |
| CN112408788A (en) * | 2020-11-27 | 2021-02-26 | 淄博永正化工设备有限公司 | Formula of high-temperature-resistant strong-acid-resistant porcelain glaze |
| CN117510073A (en) * | 2024-01-05 | 2024-02-06 | 淄博中升机械有限公司 | Glass lining ground coat based on composite adhesive and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1772675A (en) * | 2005-09-20 | 2006-05-17 | 谢安建 | Low temperature electrostatic enamel powder for steel plate coating and its prepn |
| CN101139167A (en) * | 2007-08-06 | 2008-03-12 | 江阴硅普搪瓷有限公司 | Low-temperature adherence strength highly-firing amplitude broad glass lining bottom glaze |
| CN103058522A (en) * | 2012-12-27 | 2013-04-24 | 龙门协成新材料有限公司 | Metal enamel engobe |
| CN103145335A (en) * | 2012-12-27 | 2013-06-12 | 龙门协成新材料有限公司 | Metal porcelain glaze with high adherence |
-
2014
- 2014-03-12 CN CN201410087523.4A patent/CN103864303B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1772675A (en) * | 2005-09-20 | 2006-05-17 | 谢安建 | Low temperature electrostatic enamel powder for steel plate coating and its prepn |
| CN101139167A (en) * | 2007-08-06 | 2008-03-12 | 江阴硅普搪瓷有限公司 | Low-temperature adherence strength highly-firing amplitude broad glass lining bottom glaze |
| CN103058522A (en) * | 2012-12-27 | 2013-04-24 | 龙门协成新材料有限公司 | Metal enamel engobe |
| CN103145335A (en) * | 2012-12-27 | 2013-06-12 | 龙门协成新材料有限公司 | Metal porcelain glaze with high adherence |
Cited By (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104399419A (en) * | 2014-12-12 | 2015-03-11 | 常熟市永达化工设备厂 | Reaction still circularly heated by steam-heated heat transfer oil |
| CN104445949A (en) * | 2014-12-12 | 2015-03-25 | 常熟市永达化工设备厂 | Open glass-lined storage tank |
| CN104529162A (en) * | 2014-12-12 | 2015-04-22 | 常熟市永达化工设备厂 | Efficient glass lining agitator |
| CN104399419B (en) * | 2014-12-12 | 2016-06-22 | 常熟市永达化工设备厂 | Steam heating conduction oil circulating-heating reactor |
| CN104445950A (en) * | 2014-12-13 | 2015-03-25 | 常熟市华懋化工设备有限公司 | Glass lining stirrer |
| CN104455923A (en) * | 2014-12-13 | 2015-03-25 | 常熟市华懋化工设备有限公司 | Glassed steel pipe fitting |
| CN104383864B (en) * | 2014-12-13 | 2016-04-13 | 常熟市华懋化工设备有限公司 | Glass-lined reactor |
| CN104455923B (en) * | 2014-12-13 | 2016-10-05 | 常熟市华懋化工设备有限公司 | Enamel pipe fitting |
| CN104383864A (en) * | 2014-12-13 | 2015-03-04 | 常熟市华懋化工设备有限公司 | Glass-lined reaction tank |
| CN106242295B (en) * | 2016-07-15 | 2019-02-01 | 江西科盛环保股份有限公司 | The anti-squama burst porcelain glaze of Q345 hot rolled alloy steel counterenamel and function overglaze |
| CN106242295A (en) * | 2016-07-15 | 2016-12-21 | 江西科盛环保股份有限公司 | Q345 hot rolled alloy steel counterenamel anti-squama burst porcelain glaze and function cover-coat enamel |
| US11014846B2 (en) | 2016-07-15 | 2021-05-25 | Jiangxi Kosen EnTech Co., Ltd. | Scaling resistant ceramic glaze and functional overglaze for Q345 hot rolled alloy steel double sided enameling |
| CN106512907A (en) * | 2017-01-12 | 2017-03-22 | 临沂宏业化工设备有限公司 | High-strength corrosion-resistant glass-lined reactor |
| CN106977100A (en) * | 2017-05-04 | 2017-07-25 | 钦州学院 | The good frit for porcelain enamel with steel plate adherence |
| CN106957149A (en) * | 2017-05-04 | 2017-07-18 | 钦州学院 | Frit for porcelain enamel |
| CN109569472A (en) * | 2019-01-23 | 2019-04-05 | 临沂宏业化工设备有限公司 | A kind of high pressure corrosion resistant glassed steel reaction vessels |
| CN109569472B (en) * | 2019-01-23 | 2023-12-22 | 临沂宏业化工设备有限公司 | High-pressure anti-corrosion glass lining reaction kettle |
| CN110698065A (en) * | 2019-09-05 | 2020-01-17 | 华庚新材料科技(嘉兴)有限公司 | Steel pipe with glass lining |
| CN112408788A (en) * | 2020-11-27 | 2021-02-26 | 淄博永正化工设备有限公司 | Formula of high-temperature-resistant strong-acid-resistant porcelain glaze |
| CN117510073A (en) * | 2024-01-05 | 2024-02-06 | 淄博中升机械有限公司 | Glass lining ground coat based on composite adhesive and preparation method thereof |
| CN117510073B (en) * | 2024-01-05 | 2024-04-26 | 淄博中升机械有限公司 | Glass lining ground coat based on composite adhesive and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103864303B (en) | 2015-12-09 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103864303B (en) | A kind of glass lining bottom glaze | |
| CN105385934B (en) | Enamel pan and manufacturing process thereof | |
| CN102399090A (en) | Lightweight vitreous foamed ceramic | |
| CN107417289A (en) | A kind of continuous casting production prefabricated component castable and preparation method thereof | |
| CN107827433A (en) | A kind of middle low-temperature sintering ceramic product and its manufacturing process | |
| CN106673436A (en) | Travertine-like ceramic tile taking waste glaze as clinker raw material and preparation method of travertine-like ceramic tile | |
| CN108218398A (en) | A kind of ceramic exterior wall brick dry granular and the ceramic exterior wall brick containing the dry granular | |
| CN104446657A (en) | Dry granular additive for full polishing of ceramic tiles and preparation method of dry granular additive | |
| CN106698945A (en) | Glazed tile with waste glaze as glaze raw material and preparation method thereof | |
| CN106365691B (en) | Imitate old manufacturing method of ceramic | |
| CN111233435A (en) | Glazed ceramic product and preparation method thereof | |
| CN106316431A (en) | Corundum refractory coating mixture | |
| CN104193172A (en) | Titanium dioxide cover glaze used on gold smelting bucket and production method of titanium dioxide cover glaze | |
| CN107500535A (en) | A kind of high-strength abrasion-proof glaze and ceramic and preparation method with high-strength abrasion-proof glaze | |
| KR101978393B1 (en) | Glaze composition and cooking vessel producted using the same | |
| CN110668698A (en) | Titanium white overglaze for acid-resistant, alkali-resistant, heat-resistant and wear-resistant gold burning barrel and production method thereof | |
| CN104030565B (en) | A kind of thermos flask bottle base material of high heat stability | |
| CN114920541A (en) | High-wear-resistance ceramic material for ceramic tiles, preparation method of high-wear-resistance ceramic material and high-wear-resistance ceramic tiles | |
| EP2757082A1 (en) | Colored terracotta and method for obtaining it | |
| CN106698944A (en) | Glass ceramic brick using waste glaze material as frit raw material and preparation method thereof | |
| CN107698159A (en) | A kind of pottery hacking sky blue glaze and preparation method thereof | |
| CN113789514A (en) | Preparation method of high-temperature-resistant, wear-resistant and strong-impact-resistant anticorrosive microcrystalline glaze | |
| CN106588049A (en) | Silicon-free and carbon-free corundum water port stopper rod product for continuous casting and preparation process thereof | |
| CN106082967A (en) | A kind of ceramic tile utilizing blast furnace gas mud and desulfurization oil cinder to prepare and preparation method thereof | |
| CN104030569A (en) | Nickel base porcelain glaze for sintered metal drum and production method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant |