CN117510073A - Glass lining ground coat based on composite adhesive and preparation method thereof - Google Patents
Glass lining ground coat based on composite adhesive and preparation method thereof Download PDFInfo
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- CN117510073A CN117510073A CN202410015599.XA CN202410015599A CN117510073A CN 117510073 A CN117510073 A CN 117510073A CN 202410015599 A CN202410015599 A CN 202410015599A CN 117510073 A CN117510073 A CN 117510073A
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- composite adhesive
- glass lining
- oxide
- lining base
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Links
- 239000000853 adhesive Substances 0.000 title claims abstract description 79
- 239000002131 composite material Substances 0.000 title claims abstract description 77
- 230000001070 adhesive effect Effects 0.000 title claims abstract description 74
- 239000011521 glass Substances 0.000 title claims abstract description 63
- 238000002360 preparation method Methods 0.000 title abstract description 18
- 210000003298 dental enamel Anatomy 0.000 claims abstract description 75
- GNTDGMZSJNCJKK-UHFFFAOYSA-N divanadium pentaoxide Chemical compound O=[V](=O)O[V](=O)=O GNTDGMZSJNCJKK-UHFFFAOYSA-N 0.000 claims abstract description 58
- 239000000843 powder Substances 0.000 claims abstract description 51
- 229910045601 alloy Inorganic materials 0.000 claims abstract description 35
- 239000000956 alloy Substances 0.000 claims abstract description 35
- 229910000410 antimony oxide Inorganic materials 0.000 claims abstract description 30
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 claims abstract description 30
- 229910000943 NiAl Inorganic materials 0.000 claims abstract description 26
- NPXOKRUENSOPAO-UHFFFAOYSA-N Raney nickel Chemical compound [Al].[Ni] NPXOKRUENSOPAO-UHFFFAOYSA-N 0.000 claims abstract description 26
- 239000002994 raw material Substances 0.000 claims abstract description 24
- 239000000203 mixture Substances 0.000 claims abstract description 21
- 239000005995 Aluminium silicate Substances 0.000 claims abstract description 20
- 235000012211 aluminium silicate Nutrition 0.000 claims abstract description 20
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims abstract description 20
- 229910052664 nepheline Inorganic materials 0.000 claims abstract description 20
- 239000010434 nepheline Substances 0.000 claims abstract description 20
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 17
- PSHMSSXLYVAENJ-UHFFFAOYSA-N dilithium;[oxido(oxoboranyloxy)boranyl]oxy-oxoboranyloxyborinate Chemical compound [Li+].[Li+].O=BOB([O-])OB([O-])OB=O PSHMSSXLYVAENJ-UHFFFAOYSA-N 0.000 claims abstract description 17
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims abstract description 17
- FRWYFWZENXDZMU-UHFFFAOYSA-N 2-iodoquinoline Chemical compound C1=CC=CC2=NC(I)=CC=C21 FRWYFWZENXDZMU-UHFFFAOYSA-N 0.000 claims abstract description 15
- LTPBRCUWZOMYOC-UHFFFAOYSA-N beryllium oxide Inorganic materials O=[Be] LTPBRCUWZOMYOC-UHFFFAOYSA-N 0.000 claims abstract description 15
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000010937 tungsten Substances 0.000 claims abstract description 15
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 13
- 229910052814 silicon oxide Inorganic materials 0.000 claims abstract description 13
- JCCZVLHHCNQSNM-UHFFFAOYSA-N [Na][Si] Chemical compound [Na][Si] JCCZVLHHCNQSNM-UHFFFAOYSA-N 0.000 claims abstract description 12
- 229910052721 tungsten Inorganic materials 0.000 claims abstract description 9
- 239000000126 substance Substances 0.000 claims description 15
- 229910052742 iron Inorganic materials 0.000 claims description 12
- 238000007873 sieving Methods 0.000 claims description 12
- 238000002156 mixing Methods 0.000 claims description 11
- 229910018072 Al 2 O 3 Inorganic materials 0.000 claims description 10
- 238000003723 Smelting Methods 0.000 claims description 10
- 238000000498 ball milling Methods 0.000 claims description 10
- 229910052708 sodium Inorganic materials 0.000 claims description 10
- 239000011734 sodium Substances 0.000 claims description 10
- 238000000034 method Methods 0.000 claims description 7
- 239000000463 material Substances 0.000 claims description 6
- 229910001930 tungsten oxide Inorganic materials 0.000 claims description 6
- 239000004115 Sodium Silicate Substances 0.000 claims description 5
- 229910010413 TiO 2 Inorganic materials 0.000 claims description 5
- 239000012768 molten material Substances 0.000 claims description 5
- 238000010791 quenching Methods 0.000 claims description 5
- 230000000171 quenching effect Effects 0.000 claims description 5
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 5
- 229910052911 sodium silicate Inorganic materials 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- 229910000831 Steel Inorganic materials 0.000 abstract description 18
- 239000010959 steel Substances 0.000 abstract description 18
- 239000002585 base Substances 0.000 description 49
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 13
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 description 12
- 230000000052 comparative effect Effects 0.000 description 10
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 6
- 210000001787 dendrite Anatomy 0.000 description 4
- 239000011159 matrix material Substances 0.000 description 4
- 238000002844 melting Methods 0.000 description 4
- 230000008018 melting Effects 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 238000003466 welding Methods 0.000 description 4
- 229910000756 V alloy Inorganic materials 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000002320 enamel (paints) Substances 0.000 description 3
- 238000010304 firing Methods 0.000 description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 229910052787 antimony Inorganic materials 0.000 description 2
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 2
- 239000012298 atmosphere Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- ZGDWHDKHJKZZIQ-UHFFFAOYSA-N cobalt nickel Chemical compound [Co].[Ni].[Ni].[Ni] ZGDWHDKHJKZZIQ-UHFFFAOYSA-N 0.000 description 2
- 230000003628 erosive effect Effects 0.000 description 2
- 230000006911 nucleation Effects 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 238000011056 performance test Methods 0.000 description 2
- 229910052573 porcelain Inorganic materials 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 230000002195 synergetic effect Effects 0.000 description 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- WYWFMUBFNXLFJK-UHFFFAOYSA-N [Mo].[Sb] Chemical compound [Mo].[Sb] WYWFMUBFNXLFJK-UHFFFAOYSA-N 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910000272 alkali metal oxide Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000003487 electrochemical reaction Methods 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 238000010309 melting process Methods 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910000480 nickel oxide Inorganic materials 0.000 description 1
- 238000010899 nucleation Methods 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 238000006479 redox reaction Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
- C03C8/20—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions containing titanium compounds; containing zirconium compounds
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/02—Frit compositions, i.e. in a powdered or comminuted form
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
- C03C8/18—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions containing free metals
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2207/00—Compositions specially applicable for the manufacture of vitreous enamels
- C03C2207/04—Compositions specially applicable for the manufacture of vitreous enamels for steel
Abstract
The invention belongs to the technical field of glass lining glaze preparation, and particularly relates to a glass lining base glaze based on a composite adhesive and a preparation method thereof. The glass lining base enamel based on the composite adhesive comprises the following raw materials in parts by weight: 57-59 parts of silicon oxide, 3.3-4.2 parts of aluminum oxide, 5-7 parts of lithium tetraborate, 2-3 parts of sodium silicon titanate, 2.5-3.8 parts of composite adhesive, 3-5 parts of beryllium oxide, 2-2.5 parts of nepheline powder, 4-5.5 parts of calcined kaolin and 2.9-4.7 parts of nano tungsten; the composite adhesive is a mixture of NiAl alloy powder, antimony oxide and vanadium pentoxide. The adhesion strength between the glass lining base enamel and the base steel plate prepared by the preparation method disclosed by the invention is high, and the glass lining base enamel has excellent mechanical impact resistance.
Description
Technical Field
The invention belongs to the technical field of glass lining glaze preparation, and particularly relates to a glass lining base glaze based on a composite adhesive and a preparation method thereof.
Background
The enamel glass is a composite material formed by spraying enamel glass glaze (porcelain glaze) on the surface of metal and sintering at high temperature, has the advantages of corrosion resistance, oxidation resistance, easy cleaning and the like, and is widely applied to the aspects of pipeline transportation, industrial production and the like. The adhesion between metal and enamel is particularly important for the performance of the enamel product. The adhesion can be used for measuring the bonding strength between the enamel and the base steel plate, and the better the adhesion of the enamel layer is, the stronger the bonding between the primer and the steel plate is. The factors affecting the adhesion between the steel sheet and the enamel are complex, but in general, the adhesion between the enamel layer and the surface of the base steel sheet needs to satisfy 3 basic conditions: the surface of the base steel plate is completely infiltrated by enamel glaze; the base steel plate is saturated by metal oxide at the enamel interface; in enamel melts, the oxide is not reduced by the metal.
The ground glaze is enamel glaze directly coated on the blank body and mainly aims to firmly combine the blank body and the ground glaze. The base glaze can be divided into nickel base glaze, cobalt nickel base glaze, antimony molybdenum base glaze, mixed base glaze and the like according to the types of the adhesive. The cobalt-nickel primer has the widest application range. The antimonial molybdenum ground coat is milky white, also called white ground coat. It has the lowest cost and is commonly used as the ground enamel of daily-use enamel. The mixed base glaze is formed by mixing several base glazes according to a certain proportion, and can improve the firing process performance and the adhesion performance of the porcelain glaze and the green body.
The adhesion strength of enamel has a great relationship with the components and the introduced amount of the adhesive agent introduced into the enamel glaze, the adhesive agent can deepen the erosion of enamel frit to the metal surface, and the greater the erosion effect, the better the adhesion. In addition, in order to improve the adhesion strength of enamel, the adhesion strength is also very much related to the melting degree of the primer, and the adhesion is poor and the enamel product is possibly defective due to the excessive melting or incomplete melting. Therefore, it is necessary to explore a glass lining base enamel based on a composite adhesive and a preparation method of the glass lining base enamel.
Disclosure of Invention
The purpose of the invention is that: provides a glass lining base enamel based on a composite adhesive. The adhesion strength between the glass lining base enamel and the matrix steel plate is high, and the prepared glass lining base enamel has excellent mechanical impact resistance; in addition, the invention also provides a preparation method thereof.
The invention discloses a composite adhesive-based glass lining primer, which comprises the following raw materials in parts by weight: 57-59 parts of silicon oxide, 3.3-4.2 parts of aluminum oxide, 5-7 parts of lithium tetraborate, 2-3 parts of sodium silicon titanate, 2.5-3.8 parts of composite adhesive, 3-5 parts of beryllium oxide, 2-2.5 parts of nepheline powder, 4-5.5 parts of calcined kaolin and 2.9-4.7 parts of nano tungsten; the composite adhesive is a mixture of NiAl alloy powder, antimony oxide and vanadium pentoxide.
Wherein:
the mass ratio of the NiAl alloy powder to the antimony oxide to the vanadium pentoxide is 1:0.3-0.5:0.2-0.4.
The NiAl alloy powder comprises the following chemical components in percentage by mass: al 10%, ni the rest, manufacturer is Bozhi alloy welding material Co., ltd.
The nepheline powder comprises the following chemical components in percentage by mass: siO (SiO) 2 51.78%、Al 2 O 3 27.35%、Na 2 O 11.32%、K 2 O 6.30%、CaO 1.74%、MgO 0.06%、Fe 2 O 3 0.05% and loss on ignition of 1.40%.
The calcined kaolin comprises the following chemical components in percentage by mass: siO (SiO) 2 56.52%、Al 2 O 3 37.94%、Fe 2 O 3 1.37%、CaO 0.95%、TiO 2 0.45%、K 2 O 0.08%、Na 2 0.08% of O, 0.55% of MgO and 2.06% of loss on ignition.
Preferably, the glass lining base enamel based on the composite adhesive comprises the following raw materials in parts by weight: 58 parts of silicon oxide, 3.8 parts of aluminum oxide, 6 parts of lithium tetraborate, 2.5 parts of sodium silicate titanate, 3.2 parts of composite adhesive, 4 parts of beryllium oxide, 2.3 parts of nepheline powder, 4.8 parts of calcined kaolin and 3.0 parts of nano tungsten; the composite adhesive is a mixture of NiAl alloy powder, antimony oxide and vanadium pentoxide.
The composite adhesive-based glass lining primer disclosed by the invention takes lithium tetraborate and sodium silicon titanate as fluxing agents, wherein lithium tetraborate is taken as a main component, sodium silicon titanate is taken as an auxiliary component, and if the lithium tetraborate is singly used, defects such as cold explosion and overburning are easy to generate, so that the prepared glass lining primer is crisp, and therefore, the composite adhesive-based glass lining primer is compounded with sodium silicon titanate for use, the firing temperature of the glass lining primer is greatly reduced, and meanwhile, the low viscosity of the glass lining primer is ensured, so that the fired glass lining primer has good glossiness, hardness, tensile strength and compressive strength. In addition, nepheline powder, calcined kaolin, nano tungsten and beryllium oxide are additionally added into the glass lining base enamel raw material; the alkali metal oxide contained in the nepheline powder can further reduce the viscosity of the glaze in the firing process of the enamel coating, so that the porosity of the coating is reduced, the binding force between the enamel coating and a substrate steel plate is improved, and the mechanical impact resistance of the prepared enamel coating is further improved; the network structure of the enamel glaze can be firm and compact by introducing calcined kaolin, so that the alkali resistance of the enamel glaze is improved, nano tungsten is dispersed in the enamel glass ground glaze in an independent phase mode, the effect of preventing crack growth is achieved, and the enamel glass ground glaze has good toughness; the addition of beryllium oxide can reduce the stress of the glass lining base enamel and improve the interface bonding strength.
The glass lining base enamel based on the composite adhesive takes a mixture of NiAl alloy powder, antimony oxide and vanadium pentoxide as the composite adhesive, wherein the NiAl alloy powder, the antimony oxide and the vanadium pentoxide have a synergistic effect. In the preparation process of the enamel glaze, in order to enable the enamel glaze to form an iron oxide layer on the surface of a base steel plate, the enamel base glaze is favorable for good adhesion with a blank (steel plate), and the enamel base glaze is melted by adopting an oxidizing atmosphere. During the melting process, the NiAl alloy powder undergoes chemical reactions to form nickel monoxide and aluminum oxide. NiO-containing enamel can form more dendrites in the nucleation and growth stages of crystals to generate a transition layer, thereby improving the adhesion. The aluminum oxide has higher surface free energy, is easier to nucleate on the surface, and is used as nucleation center for dendrite growth, so that the number of dendrites and the bonding points of the matrix steel plate are obviously increased. The existence of the aluminum oxide has good promotion effect on the adhesion of the nickel oxide, the antimony oxide and the vanadium pentoxide on the base steel plate. Thereby ensuring the good adhesion between the enamel primer and the base steel plate fundamentally. The antimony oxide is added in the form of a ground material, the antimony oxide and iron undergo oxidation-reduction reaction to generate iron oxide and antimony, and the metallic antimony deposited on the surface of the iron plays an important role in the formation of a bonding layer. The vanadium element in the vanadium pentoxide generates an Fe-V alloy phase on the interface of the matrix and the glaze layer, so that the fusion and diffusion of Fe and FeO are promoted, the Fe-V alloy phase is more tightly combined, and the adhesion is enhanced.
The preparation method of the glass lining base enamel based on the composite adhesive comprises the following steps:
(1) Mechanically mixing silicon oxide, aluminum oxide, lithium tetraborate, sodium silicon titanate, beryllium oxide, nepheline powder, calcined kaolin, niAl alloy powder in a composite adhesive and vanadium pentoxide in the raw materials, smelting, finally, putting the molten materials into cold water for quenching to prepare a frit, crushing the frit, and sieving the frit with a 80-mesh sieve;
(2) Mixing nano tungsten and antimony oxide in the composite adhesive with the frit crushed material prepared in the step (1), and then ball milling and sieving to prepare the glass lining base enamel based on the composite adhesive.
Wherein:
the smelting temperature in the step (1) is 1270-1280 ℃.
And (3) ball milling for 5-6 hours in the step (2), and sieving the ball-milled mixture with a 200-mesh sieve.
Compared with the prior art, the invention has the following beneficial effects:
(1) According to the composite adhesive-based glass lining base glaze, the mixture of lithium tetraborate and sodium silicon titanate is used as a fluxing agent to ensure low viscosity of the glass lining base glaze, so that the sintered glass lining base glaze has excellent compressive strength; the composite adhesive is added, wherein NiAl alloy powder, antimony oxide and vanadium pentoxide have synergistic effect, compared with the direct addition of nickel monoxide, the nickel monoxide generated in situ can not be further oxidized even if a reducing agent is not added in an oxidizing atmosphere, and the generated aluminum oxide has good promoting effect on the adhesion of the nickel monoxide, antimony oxide and vanadium pentoxide to a base steel plate. The nickel monoxide plays a role in adhesion by forming dendrites, the antimony oxide plays a role in adhesion by electrochemical reaction, and the vanadium pentoxide plays a role in adhesion by forming an Fe-V alloy phase. Therefore, the action modes of the raw materials of the composite adhesive are completely different, so that the prepared glass lining base enamel and the substrate steel plate are ensured to have high adhesion strength.
(2) According to the preparation method of the glass lining base enamel based on the composite adhesive, disclosed by the invention, the adhesion strength of the prepared glass lining base enamel and a matrix steel plate is improved by strictly controlling the melting temperature of the glass lining base enamel and the feeding sequence of the composite adhesive, so that the prepared glass lining base enamel is ensured to have excellent mechanical impact resistance.
Detailed Description
The invention is further described below with reference to examples.
Example 1
The glass lining base enamel based on the composite adhesive in the embodiment 1 comprises the following raw materials in parts by weight: 58 parts of silicon oxide, 3.8 parts of aluminum oxide, 6 parts of lithium tetraborate, 2.5 parts of sodium silicate titanate, 3.2 parts of composite adhesive, 4 parts of beryllium oxide, 2.3 parts of nepheline powder, 4.8 parts of calcined kaolin and 3.0 parts of nano tungsten; the composite adhesive is a mixture of NiAl alloy powder, antimony oxide and vanadium pentoxide.
Wherein:
the mass ratio of the NiAl alloy powder to the antimony oxide to the vanadium pentoxide is 1:0.4:0.3.
The NiAl alloy powder comprises the following chemical components in percentage by mass: al 10%, ni the rest, manufacturer is Bozhi alloy welding material Co., ltd.
The nepheline powder comprises the following chemical components in percentage by mass: siO (SiO) 2 51.78%、Al 2 O 3 27.35%、Na 2 O 11.32%、K 2 O 6.30%、CaO 1.74%、MgO 0.06%、Fe 2 O 3 0.05% and loss on ignition of 1.40%.
The calcined kaolin comprises the following chemical components in percentage by mass: siO (SiO) 2 56.52%、Al 2 O 3 37.94%、Fe 2 O 3 1.37%、CaO 0.95%、TiO 2 0.45%、K 2 O 0.08%、Na 2 0.08% of O, 0.55% of MgO and 2.06% of loss on ignition.
The preparation method of the glass lining base enamel based on the composite adhesive agent in the embodiment 1 comprises the following steps:
(1) Mechanically mixing silicon oxide, aluminum oxide, lithium tetraborate, sodium silicon titanate, beryllium oxide, nepheline powder, calcined kaolin, niAl alloy powder in a composite adhesive and vanadium pentoxide in the raw materials, smelting, finally, putting the molten materials into cold water for quenching to prepare a frit, crushing the frit, and sieving the frit with a 80-mesh sieve;
(2) Mixing nano tungsten and antimony oxide in the composite adhesive with the frit crushed material prepared in the step (1), and then ball milling and sieving to prepare the glass lining base enamel based on the composite adhesive.
Wherein:
the smelting temperature in the step (1) is 1275 ℃.
The ball milling time in the step (2) is 5.5 hours, and the ball milled mixture is sieved by a 200-mesh sieve.
Example 2
The glass lining base enamel based on the composite adhesive in the embodiment 2 comprises the following raw materials in parts by weight: 57 parts of silicon oxide, 3.3 parts of aluminum oxide, 7 parts of lithium tetraborate, 2 parts of sodium silicate titanate, 2.5 parts of composite adhesive, 3 parts of beryllium oxide, 2.5 parts of nepheline powder, 4 parts of calcined kaolin and 3.2 parts of nano tungsten; the composite adhesive is a mixture of NiAl alloy powder, antimony oxide and vanadium pentoxide.
Wherein:
the mass ratio of the NiAl alloy powder to the antimony oxide to the vanadium pentoxide is 1:0.5:0.4.
The NiAl alloy powder comprises the following chemical components in percentage by mass: al 10%, ni the rest, manufacturer is Bozhi alloy welding material Co., ltd.
The nepheline powder comprises the following chemical components in percentage by mass: siO (SiO) 2 51.78%、Al 2 O 3 27.35%、Na 2 O 11.32%、K 2 O 6.30%、CaO 1.74%、MgO 0.06%、Fe 2 O 3 0.05% and loss on ignition of 1.40%.
The calcined kaolin comprises the following chemical components in percentage by mass: siO (SiO) 2 56.52%、Al 2 O 3 37.94%、Fe 2 O 3 1.37%、CaO 0.95%、TiO 2 0.45%、K 2 O 0.08%、Na 2 0.08% of O, 0.55% of MgO and 2.06% of loss on ignition.
The preparation method of the glass lining base enamel based on the composite adhesive in the embodiment 2 comprises the following steps:
(1) Mechanically mixing silicon oxide, aluminum oxide, lithium tetraborate, sodium silicon titanate, beryllium oxide, nepheline powder, calcined kaolin, niAl alloy powder in a composite adhesive and vanadium pentoxide in the raw materials, smelting, finally, putting the molten materials into cold water for quenching to prepare a frit, crushing the frit, and sieving the frit with a 80-mesh sieve;
(2) Mixing nano tungsten and antimony oxide in the composite adhesive with the frit crushed material prepared in the step (1), and then ball milling and sieving to prepare the glass lining base enamel based on the composite adhesive.
Wherein:
the smelting temperature in the step (1) is 1270 ℃.
In the step (2), the ball milling time is 5 hours, and the ball milled mixture is sieved by a 200-mesh sieve.
Example 3
The glass lining base enamel based on the composite adhesive agent in the embodiment 3 comprises the following raw materials in parts by weight: 59 parts of silicon oxide, 4.2 parts of aluminum oxide, 5 parts of lithium tetraborate, 3 parts of sodium silicate titanate, 3.8 parts of composite adhesive, 5 parts of beryllium oxide, 2 parts of nepheline powder, 5.5 parts of calcined kaolin and 2.9 parts of nano tungsten; the composite adhesive is a mixture of NiAl alloy powder, antimony oxide and vanadium pentoxide.
Wherein:
the mass ratio of the NiAl alloy powder to the antimony oxide to the vanadium pentoxide is 1:0.3:0.2.
The NiAl alloy powder comprises the following chemical components in percentage by mass: al 10%, ni the rest, manufacturer is Bozhi alloy welding material Co., ltd.
The nepheline powder comprises the following chemical components in percentage by mass: siO (SiO) 2 51.78%、Al 2 O 3 27.35%、Na 2 O 11.32%、K 2 O 6.30%、CaO 1.74%、MgO 0.06%、Fe 2 O 3 0.05% and loss on ignition of 1.40%.
The calcined kaolin comprises the following chemical components in percentage by mass: siO (SiO) 2 56.52%、Al 2 O 3 37.94%、Fe 2 O 3 1.37%、CaO 0.95%、TiO 2 0.45%、K 2 O 0.08%、Na 2 0.08% of O, 0.55% of MgO and 2.06% of loss on ignition.
The preparation method of the glass lining base enamel based on the composite adhesive agent in the embodiment 3 comprises the following steps:
(1) Mechanically mixing silicon oxide, aluminum oxide, lithium tetraborate, sodium silicon titanate, beryllium oxide, nepheline powder, calcined kaolin, niAl alloy powder in a composite adhesive and vanadium pentoxide in the raw materials, smelting, finally, putting the molten materials into cold water for quenching to prepare a frit, crushing the frit, and sieving the frit with a 80-mesh sieve;
(2) Mixing nano tungsten and antimony oxide in the composite adhesive with the frit crushed material prepared in the step (1), and then ball milling and sieving to prepare the glass lining base enamel based on the composite adhesive.
Wherein:
the smelting temperature in the step (1) is 1280 ℃.
And (3) ball milling time in the step (2) is 6 hours, and the ball milled mixture is sieved by a 200-mesh sieve.
Comparative example 1
The preparation method and the raw material composition of the composite adhesive-based glass lining base enamel described in this comparative example 1 are the same as those of example 1, except that the composite adhesive in the raw material is different from that of example 1. The composite adhesive in the raw material of the comparative example 1 is a mixture of antimony oxide and vanadium pentoxide, wherein: the mass ratio of the antimony oxide to the vanadium pentoxide is 0.4:0.3.
Comparative example 2
The preparation method and the raw material composition of the composite adhesive-based glass lining base enamel described in this comparative example 2 are the same as those of example 1, except that the composite adhesive in the raw material is different from that of example 1. The composite adhesive in the raw material of the comparative example 2 is a mixture of NiAl alloy powder and vanadium pentoxide, wherein: the mass ratio of the NiAl alloy powder to the vanadium pentoxide is 1:0.3.
Comparative example 3
The preparation method and the raw material composition of the composite adhesive-based glass lining base enamel described in this comparative example 3 are the same as those of example 1, except that the composite adhesive in the raw material is different from that of example 1. The composite adhesive in the raw material of the comparative example 3 is a mixture of NiAl alloy powder and antimony oxide, wherein: the mass ratio of the NiAl alloy powder to the antimony oxide is 1:0.4.
Performance tests were carried out on the glass lining base enamels based on the composite adhesive prepared in examples 1 to 3 and comparative examples 1 to 3, and the adhesion strength was measured on the adhesion grade of the enamel plate by a ball drop impact method (100 g steel ball impacts the enamel plate vertically from a height of 2 m, and the enamel layer is observed) specified in European standard BS EN 10209; the test method for the mechanical impact resistance is GB/T7990-2013; the test results are shown in table 1 below:
TABLE 1 enamel glass primer performance test results based on composite Adhesives
Claims (9)
1. A glass lining base enamel based on a composite adhesive is characterized in that: the raw materials comprise the following components in parts by weight: 57-59 parts of silicon oxide, 3.3-4.2 parts of aluminum oxide, 5-7 parts of lithium tetraborate, 2-3 parts of sodium silicon titanate, 2.5-3.8 parts of composite adhesive, 3-5 parts of beryllium oxide, 2-2.5 parts of nepheline powder, 4-5.5 parts of calcined kaolin and 2.9-4.7 parts of nano tungsten; the composite adhesive is a mixture of NiAl alloy powder, antimony oxide and vanadium pentoxide.
2. The composite adhesive-based glass lining base enamel according to claim 1, wherein: the mass ratio of the NiAl alloy powder to the antimony oxide to the vanadium pentoxide is 1:0.3-0.5:0.2-0.4.
3. The composite adhesive-based glass lining base enamel according to claim 1, wherein: the NiAl alloy powder comprises the following chemical components in percentage by mass: 10% of Al and the balance of Ni.
4. The composite adhesive-based glass lining base enamel according to claim 1, wherein: the nepheline powder comprises the following chemical components in percentage by mass: siO (SiO) 2 51.78%、Al 2 O 3 27.35%、Na 2 O 11.32%、K 2 O 6.30%、CaO 1.74%、MgO 0.06%、Fe 2 O 3 0.05% and loss on ignition of 1.40%.
5. The composite adhesive-based glass lining base enamel according to claim 1, wherein: the calcined kaolin comprises the following chemical components in percentage by mass: siO (SiO) 2 56.52%、Al 2 O 3 37.94%、Fe 2 O 3 1.37%、CaO 0.95%、TiO 2 0.45%、K 2 O 0.08%、Na 2 0.08% of O, 0.55% of MgO and 2.06% of loss on ignition.
6. The composite adhesive-based glass lining base enamel according to claim 1, wherein: the raw materials comprise the following components in parts by weight: 58 parts of silicon oxide, 3.8 parts of aluminum oxide, 6 parts of lithium tetraborate, 2.5 parts of sodium silicate titanate, 3.2 parts of composite adhesive, 4 parts of beryllium oxide, 2.3 parts of nepheline powder, 4.8 parts of calcined kaolin and 3.0 parts of nano tungsten; the composite adhesive is a mixture of NiAl alloy powder, antimony oxide and vanadium pentoxide.
7. A method for preparing a glass lining base enamel based on a composite adhesive according to claim 1, which is characterized in that: the method comprises the following steps:
(1) Mechanically mixing silicon oxide, aluminum oxide, lithium tetraborate, sodium silicon titanate, beryllium oxide, nepheline powder, calcined kaolin, niAl alloy powder in a composite adhesive and vanadium pentoxide in the raw materials, smelting, finally, putting the molten materials into cold water for quenching to prepare a frit, crushing the frit, and sieving the frit with a 80-mesh sieve;
(2) Mixing nano tungsten and antimony oxide in the composite adhesive with the frit crushed material prepared in the step (1), and then ball milling and sieving to prepare the glass lining base enamel based on the composite adhesive.
8. The method for preparing the composite adhesive-based glass lining base enamel, which is characterized by comprising the following steps of: the smelting temperature in the step (1) is 1270-1280 ℃.
9. The method for preparing the composite adhesive-based glass lining base enamel, which is characterized by comprising the following steps of: and (3) ball milling for 5-6 hours in the step (2), and sieving the ball-milled mixture with a 200-mesh sieve.
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Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101182119A (en) * | 2007-11-09 | 2008-05-21 | 东华大学 | Low-temperature leadless porcelain enamel composition and preparation method thereof |
| CN103863724A (en) * | 2014-03-12 | 2014-06-18 | 临沂宏业化工设备有限公司 | Enameled glass vessel and base coat formula thereof |
| CN103864303A (en) * | 2014-03-12 | 2014-06-18 | 临沂宏业化工设备有限公司 | Glass lining ground coat |
| CN108658462A (en) * | 2018-06-27 | 2018-10-16 | 沙冰娟 | A kind of high tenacity frit for porcelain enamel |
| CN112174527A (en) * | 2020-10-19 | 2021-01-05 | 青岛裕晋精搪涂层有限公司 | Low-temperature sintering process method for enamel |
| CN113832406A (en) * | 2021-10-27 | 2021-12-24 | 广东捷威家居发展有限公司 | Corrosion-resistant enamel material and preparation method thereof |
-
2024
- 2024-01-05 CN CN202410015599.XA patent/CN117510073B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101182119A (en) * | 2007-11-09 | 2008-05-21 | 东华大学 | Low-temperature leadless porcelain enamel composition and preparation method thereof |
| CN103863724A (en) * | 2014-03-12 | 2014-06-18 | 临沂宏业化工设备有限公司 | Enameled glass vessel and base coat formula thereof |
| CN103864303A (en) * | 2014-03-12 | 2014-06-18 | 临沂宏业化工设备有限公司 | Glass lining ground coat |
| CN108658462A (en) * | 2018-06-27 | 2018-10-16 | 沙冰娟 | A kind of high tenacity frit for porcelain enamel |
| CN112174527A (en) * | 2020-10-19 | 2021-01-05 | 青岛裕晋精搪涂层有限公司 | Low-temperature sintering process method for enamel |
| CN113832406A (en) * | 2021-10-27 | 2021-12-24 | 广东捷威家居发展有限公司 | Corrosion-resistant enamel material and preparation method thereof |
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