CN103803652B - 一种高含量钨掺杂的纳米vo2粉体材料及其制备方法 - Google Patents
一种高含量钨掺杂的纳米vo2粉体材料及其制备方法 Download PDFInfo
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- CN103803652B CN103803652B CN201210444845.0A CN201210444845A CN103803652B CN 103803652 B CN103803652 B CN 103803652B CN 201210444845 A CN201210444845 A CN 201210444845A CN 103803652 B CN103803652 B CN 103803652B
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- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 title claims abstract description 34
- 229910052721 tungsten Inorganic materials 0.000 title claims abstract description 34
- 238000002360 preparation method Methods 0.000 title claims abstract description 33
- 239000010937 tungsten Substances 0.000 title claims abstract description 33
- 239000000463 material Substances 0.000 title claims description 28
- 229910021542 Vanadium(IV) oxide Inorganic materials 0.000 claims abstract description 33
- GRUMUEUJTSXQOI-UHFFFAOYSA-N vanadium dioxide Chemical compound O=[V]=O GRUMUEUJTSXQOI-UHFFFAOYSA-N 0.000 claims abstract description 33
- CMPGARWFYBADJI-UHFFFAOYSA-L tungstic acid Chemical compound O[W](O)(=O)=O CMPGARWFYBADJI-UHFFFAOYSA-L 0.000 claims abstract description 32
- 239000000843 powder Substances 0.000 claims abstract description 28
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 53
- 239000000243 solution Substances 0.000 claims description 52
- 239000007864 aqueous solution Substances 0.000 claims description 40
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 36
- 239000008367 deionised water Substances 0.000 claims description 32
- 229910021641 deionized water Inorganic materials 0.000 claims description 32
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- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims description 30
- 239000012752 auxiliary agent Substances 0.000 claims description 29
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 22
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 20
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- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 14
- 229910020350 Na2WO4 Inorganic materials 0.000 claims description 14
- 239000000203 mixture Substances 0.000 claims description 14
- XMVONEAAOPAGAO-UHFFFAOYSA-N sodium tungstate Chemical compound [Na+].[Na+].[O-][W]([O-])(=O)=O XMVONEAAOPAGAO-UHFFFAOYSA-N 0.000 claims description 13
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 10
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- 229910021529 ammonia Inorganic materials 0.000 claims description 4
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- 235000011167 hydrochloric acid Nutrition 0.000 description 7
- 208000030208 low-grade fever Diseases 0.000 description 7
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical group OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
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- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
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- 229910000474 mercury oxide Inorganic materials 0.000 description 1
- UKWHYYKOEPRTIC-UHFFFAOYSA-N mercury(ii) oxide Chemical compound [Hg]=O UKWHYYKOEPRTIC-UHFFFAOYSA-N 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
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- 229910044991 metal oxide Inorganic materials 0.000 description 1
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- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 239000011573 trace mineral Substances 0.000 description 1
- 235000013619 trace mineral Nutrition 0.000 description 1
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CN104030357B (zh) * | 2014-06-27 | 2016-01-20 | 武汉工程大学 | 一种有机溶胶凝胶制备二氧化钒薄膜的方法 |
CN106957456B (zh) * | 2017-04-11 | 2019-08-30 | 武汉纺织大学 | 一种利用钨掺杂的二氧化钒合成的温敏材料及其合成方法 |
CN108659812B (zh) * | 2018-05-11 | 2020-07-03 | 中国科学院广州能源研究所 | 一种核壳结构的高效热致变色纳米复合粉体及其制备方法 |
CN109502643B (zh) * | 2018-11-26 | 2021-03-16 | 深圳大学 | 一种硼镁共掺杂vo2粉体及其制备方法和应用 |
CN109638257B (zh) * | 2018-12-18 | 2022-04-26 | 中科廊坊过程工程研究院 | 一种复合型五氧化二钒系材料及其制备方法和用途 |
CN110203972A (zh) * | 2019-06-13 | 2019-09-06 | 湖北大学 | M相二氧化钒纳米粉体的制备方法 |
CN112374854A (zh) * | 2020-11-12 | 2021-02-19 | 上海涂固安高科技有限公司 | 一种具备超强适应性的防碳化涂料及其制备方法 |
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CN102295312B (zh) * | 2010-06-22 | 2013-07-03 | 中国科学院合肥物质科学研究院 | 钨掺杂二氧化钒纳米粉体及其制备方法 |
CN101863511B (zh) * | 2010-07-05 | 2013-05-22 | 中国科学技术大学 | 制备单斜相二氧化钒及其掺杂纳米粉的方法 |
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