CN103787718A - Novel enhanced nutrient green 'LB' functional fertilizer - Google Patents

Novel enhanced nutrient green 'LB' functional fertilizer Download PDF

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CN103787718A
CN103787718A CN201310669361.0A CN201310669361A CN103787718A CN 103787718 A CN103787718 A CN 103787718A CN 201310669361 A CN201310669361 A CN 201310669361A CN 103787718 A CN103787718 A CN 103787718A
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fertilizer
nutrient
soil
crop
nutrition
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曹发魁
史振业
孙矿生
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LANZHOU WODEI DAMAGED LAND RESTORATION AND ENVIRONMENT ENGINEERING RESEARCH INSTITUTE
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GANSU JINYU ECOLOGICAL ENVIRONMENT ENGINEERING Co Ltd
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Abstract

The invention discloses a novel enhanced nutrient green 'LB' functional fertilizer which is rich in 'LB' materials containing 13 of 14 nutrient microelements which are essential for human bodies and animals and also discloses a composite mixed fertilizer prepared by taking 'LB' materials as base materials or auxiliary materials and compounding nutrient substances for crop growth such as N, P and K. A biologic nutrient element enhancing method is the process for enhancing nutrient and heath prompting factors in the plant growth process. The phenomenon of element shortage of human beings and animals is changed by improving the soil nutrient quality, prompting crop absorption level and improving the high nutrition effect of food, and the fertilizer is the first choice for agriculture and nutrition departments in handling the problem of unbalance nutrition. The most economic, simplest, most effective and long-lasting mode is to apply the biologic nutrient microelement enhanced functional fertilizer for improving the nutrient microelement supply capability of soil, the crop absorption level is prompted, and the requirements of human beings and animals on health are met.

Description

A kind of novel reinforced nutrient green " LB " fertilizers
Technical field
The present invention relates to modern agriculture advanced production data field, be specifically related to a kind of initiative of the nutrient green fertilizers that is rich in various trace elements.
Background technology
One or more essential trace elements absorptions of the puzzlement nearly half of world population (approximately 3,000,000,000 population) are at present unbalance, cause chronic disease (as heart trouble, cancer, apoplexy and diabetes etc.) to present trend occurred frequently.But people are difficult to find and be familiar with the problem of micro-insufficiency of intake conventionally.For tackling this global healthy crisis, some countries and regions have been taked to carry out trace element interpolation in diet and have been waited nutritional fortification measure, and more preferably mode is supplemented by meals.But due to the pollution of environment, the excessive use in the lavishment of chemical fertilizer and soil etc., cause Trace Elements in Soil disappearance, skewness and Crop low, thereby, to the strengthening means of farm crop employing nutrition and the health-promoting factor.Wherein, most economical, the most simply, the most effective and continuable mode is: the green functional fertilizer of using the effect of tool nutrient-reinforced.
In meals, the real source of nutrient imbalance is that agrosystem can not continuously, sufficiently provide essential nutrients and health factor-micro elements needed by human.And agricultural and nutrition department are also never using agricultural as the powerful that resists nutrient imbalance relative disease.But the harsh fact makes many developing countries, also comprise that development country recognizes that the caused health problem of the low inferior reason of Trace Elements in Soil skewness, disappearance and Crop has become main public health problem.Therefore, increasing the validity of the current essential trace element still lacking (as, iron, iodine, selenium, zinc etc.) and improve the nutrition of agricultural-food, crop, is first the trophic level of soil.Wherein, initiative nutrient-reinforced green functional fertilizer, being applied to soil is the most effective most economical and continuable effective measure, increases corps nutrient level not changing in farm crop genomic constitution situation.
The lifting of corps nutrient level, effectively solves Nourishment level, and then overcomes micronutrient element unbalance of human body.Therefore, increase the micro-element nutrition level of farm crop, primary is the micro-element nutrition level that promotes soil, under current Agricultural land envrionment conditions, only has the green functional fertilizer by be rich in various trace elements to soil application, with reinforced soil nutrition.
Although trace element only accounts for 9/10000ths in crop ash content, even 100,000/several, and constant, moderate-element nitrogen, phosphorus, potassium, calcium, magnesium etc. occupy 99%, and it is but vital to biological effect.These trace elements are to promote photosynthesis mostly, the enzyme of respiration and Substance Transformation effect etc. or the integral part of coenzyme, be the active centre of doing in object and animal body, have single-minded physiological function, in the growing process of crop and life, effect greatly.
In the time that some trace element in soil is not enough, crop just there will be deficiency disease shape, as apple tree iron deficiency, and young sprout yellow.Lack zinc, newly slightly leaf is little; The yellow of grape iron deficiency spire, it is light yellow that cob is.Grape calcium deficiency, blade is yellowish green, have macula lutea, lacks zinc and forms leaflet; Particularly food crop, wheat iron deficiency, blade takes off yellow death, lacks copper heading and is obstructed, and seed forms restricted; It is yellow that paddy rice boron deficiency blade tip is, and withered, lacks zinc, and tillering phase, new leaf base turned white, browning in Lao Ye edge.
Only, with regard to boron, crop is to boron sensitivity mostly, and boron deficiency is to plant growth, and especially on fruit impact greatly, but excessive boracic can be poisoning, affects equally the results of plant growth and fruit.Boron has special physiological function to crop, but different from other trace elements, is not the integral part of enzyme, but have special trophism, borate family is like phosphoric acid salt, and the OH reaction in energy and sugar, alcohol and organic acid forms boric acid ester, thereby, there is transportation and the metabolism of (1) participation carbohydrate; (2) promote building up and growing of reproductive organ; (3) oxidation system in control agent; (4) nitrogen fixing capacity of raising root nodule bacterium; (5) elongation and the division of promotion cell; (6) promote the running of nucleic acid and protein synthesis, growth hormone and improve crop drought resistance ability etc.Thereby the disappearance of boron is excessive almost to be had more deep associated with all compounds.
Soil is the main source ground of the required trace element of crop.In soil, always contain the trace element of different sorts and different quantities, some not necessarily crop need, also not necessarily Crop utilize form, therefore, must supplement by using trace element fertilizer.Nanjing Soil Inst., Chinese Academy of Sciences provides the result of study (as following table) that judges its deficiency according to the content of various trace elements in crop leaf
The rich scarce index of micro element content (unit: mg/kg) in crop leaf
Although the required trace element amount of crop seldom, in the ordinary course of things, in plant materials, only have ten thousand/several to 100,000/several (10-4-10-5), be equivalent to only contain in the plant stem body of 1 kilopond the trace element of 1-10 micrograms (1-10 μ g/kg), but crop still can produce micro-deficiency disease.Reason has three: the amount of application of (1) N, P, K chemical fertilizer is large, and crop yield significantly improves, and has taken away on the one hand more trace element from soil.Crop increases with the raising of N, P, K chemical fertilizer application level the ratio of absorption of trace elements on the other hand.Thereby, there will be trace element to supply with the phenomenon of relative deficiency; (2) impact of soil chemical properties on giving property of trace element, except molybdenum (Mo), most of trace elements are subject to the impact of soil pH value and have occurred to the different trend with changing of property, as just more active at acid soil in zinc (Zn), copper (Cu), boron (B), iron (Fe), generally exist with water-soluble state or replacement property, giving property is more intense, thereby, crop grows in the soil that contains these elements, can not produce deficiency disease.But, for the popularization of the agrotechnical measure to soil transformation, can have a significant impact (reduction) to property to soil trace element.As improve a large amount of limings of acid soil, and increase the alkaline matter in soil, make can obviously declining to property of most of trace element, occur that bringing out property of trace element lacks problem.So, in the time of liming improvement acid soil, suitably use trace element fertilizer; (3) mutual relationship between trace element, cause some trace element deficiency, as having antagonistic action between phosphorus (P) and zinc (Zn) or copper (Cu), at phosphorus (P) rich content or use in a large number in the soil that phosphorus (P) is fertile, will there is to lack zinc (Zn) or scarce copper (Cu) phenomenon.At this moment,, if be affixed by zinc (Zn) fertilizer or copper (Cu) fertilizer, just have obvious effect of increasing production.
Some main micronutrient elements, if iodine (I) is the anti-oxidant function of wisdom element, selenium (Se), the hematopoiesis physiology biological nature that zinc (Zn) tool helps the effect of growing, iron (Fe), significant equally to plant, most important to the mankind's health.
Therefore, in current agricultural planting activity in production: (1) excessive use chemical fertilizer; (2) N, P, K fertilizer proportional imbalance; (3) application process and fertilizer variety are selected improper technical matters, follow the basic theories of the rational application of fertilizer, use functional green fertilizer, simultaneously, adopt advanced fertilizer practice and technique, realize and improve crops quality and the target that promotes corps nutrient level.
Wherein, rational application of fertilizer basic theories and sophistication are most important.
1, the basic theories of the rational application of fertilizer
1) nutrient is given back and is learned opinion.The nutrient theory of returns that French scientist Li Bixi proposes, it is the basis of agricultural being regarded as to exchange of substance between the mankind and nature, the nutritive substance that namely absorbs and assimilate from soil and atmosphere by plant, absorbed as food by human and animal, through excremental corruption and the decomposition course of animals and plants self and animal, return to again in the earth and atmosphere and go, completed material and given back, shown agricultural biomass exchange basis.In addition, must give back the material that picked-up is walked to the earth, the mode of giving back is applied fertilizer exactly, otherwise, can affect soil fertility, impact is produced normally.
2) minimum nutrient rule
Due to nutrient situation difference in soil, fertilization effect is different.This is the height because of crop yield, and soil, for crop requirement, is restricted by the minimum nutrient of content (being minimum nutrient).This rule is also that French scientist Li Bixi proposes.Main points are: what (1) determined crop yield is the nutrient of relative content minimum in soil; (2) minimum Nutrient condition changes and changes, and minimum nutrient, owing to enriching specific aim fertilizer, makes crop yield, but now minimum nutrient is no longer minimum, and with condition, variation has occurred; (3) lack specific aim, do not contain minimum nutrient composition if enrich in fertilizer, not only do not increase production, run counter to desire on the contrary.
3) law of diminishing return
Law of diminishing return is that 18 th century later European economy scholar's Turgots and Anderson propose simultaneously, it is a ubiquitous rule of economics, prerequisite is under agriculture production steady state, and fertilising is controlled variable, has two main points: (1) increases ultimate production with rate of fertilizer application and increases; (2) units increased in production of fertilising increase, unit fertilizer, i.e. the remuneration of fertilizer is reducing gradually.What emphasize here is rational science consumption.
4) factor integration effect rule
Be subject to, under composite factor prerequisite, to emphasize active limiting factor.Its main points are that (1) crop high yield is the result of all factor integration effects; (2) utilize the interaction in comprehensive action between the factor to improve fertilizer efficiency.For example, apply fertilizer and irrigate each tool effect, if combination, effect of increasing production is greater than the two independent effect sum.
2, advanced technology and measure
1) determine rate of fertilizer application with method of fertilization for target yield.The method using the difference of required realize target output nutrient and soil supply amount of nutrients as determine rate of fertilizer application foundation, to reach nutrient budget balance, therefore, method of fertilization for target yield claims again nutrient balance method, calculating formula is as follows:
F = ( Y × C ) - S N × E
Wherein: F: amount of application (kg/ha);
Y: target output (kg/ha);
C: unit output nutrition absorption amount (kilogram);
S: soil supply amount of nutrients (kg/ha) [based on soil nutrien measuring value × 2.25(reduction factor) × soil nutrient utilization coefficient];
N: nutrient content (%) in institute's fertilise;
E: fertilizer this season utilization ratio (%).
2) the new measure of modern fertilising
(1) spray multielement micro-fertilizer (or use polynary base manure and topdress)
Multielement micro-fertilizer contains the required various weight element nutrients of various crop, not only comprehensive trace element supplement nutrient, but also the balance of embodiment nutrient is supplied with.
(2) fertigation
Because fertigation is that fertilizer enters soil with irrigation water, there is fertilizer efficiency fast, easily absorb, save water, fertile resource, save labour, the advantage of soil protection structure.
(3) carbonic acid gas (CO2)
In warm canopy, enrich CO2 fertilizer, improve photosynthesis effect, just can form the simplest carbohydrate---monose by chlorophyll.Under chemical equation is:
Figure DEST_PATH_GDA0000475956100000051
Under the effect of corresponding enzyme, plant can also utilize monose for raw material, synthetic more complicated disaccharide, and starch or conversion fat, also can participate in the metabolism of nitrogen, further synthesizing amino acid, protein.
In addition, fertilizer practice method mainly contains:
1, soil application.Make base manure, seed manure or topdress to be manured into soil, though utilization rate of fertilizer is low, aftereffect is better.For saving fertilizer, general employing spreaded manuer in holes and row replacement.
2, seed treatment.Comprise seed soaking and seed dressing.
3, foliage fertilization, sprays.
4, dip the seedling root in.Be used for transfer farm crop, as paddy rice etc.
Summary of the invention
In order to address the above problem, the object of the invention is to propose a kind of novel reinforced nutrient green " LB " fertilizers.
For achieving the above object, technical scheme that the present invention adopts is as follows:
A kind of novel reinforced nutrient green " LB " fertilizers, this fertilizer comprises 13 kinds " LB " material being rich in 14 kinds of essential nutritional trace elements of human body and animal, and take " LB " material as base-material or auxiliary material, the compound Bulk Blending Fertilizer of assembly plant growth nutritive substance N, P, K.
Further, described " LB " material is rich in 13 kinds of trace elements that iodine, selenium, zinc, iron are representative.
Further, also comprise " non-traditional mineral manure " and assembly N, P, the fertile manufacture of the compound blending of K (B, B) that " LB " material is raw material.
The present invention is directed to the great demand that this affects human health, formulated two kinds of two kinds of multi-Functional Fertilizers that are rich in trace nutrient (trace element).One is to adopt to be rich in 14 kinds of needed by human micronutrient elements " LB " material of 13 kinds and to be machined directly to " the micro-fertilizer of non-traditional mineral "; Another kind is material take " LB " material as base (auxiliary), the compound blending of assembly plant growth nutritive substance (N, P, K) processing (B, B) fertilizer.
The present invention utilizes 13 kinds of features that " LB " material contains in 14 kinds of needed by human nutritional trace elements take iodine, selenium, zinc, iron as representative (wherein also to contain the essential boron of crop, its important feature), for crop nutritional deficiency phenomenon, formulate nutritional fortification green functional fertilizer system.Be specially and produce two types of fertilizer:
1, the micro-fertilizer of non-traditional mineral.Because " LB " material itself is rich in 13 kinds in 14 kinds of crop and needed by human nutritional trace elements, and its material property is silicate, with soil be homogeneity, homology, as the supplier of various trace elements, itself be trace element fertilizer-" the micro-fertilizer of non-traditional mineral " of high-quality.Its application meets the rational application of fertilizer " factor integration effect rule ".
2, to utilize " LB " material be base (auxiliary) material and the crop desired nutritional material assembly such as N, P, K, can, according to the fertile feature of same-action need not, produce multiple specific aim fertilizers.
Use with apply fertilizer by science, reach rescuing crop nutritional deficiency disease.
To sum up, content of the present invention is two: one, " LB " material preparation technology technique, " the micro-fertilizer of non-traditional mineral " is manufactured, its two, blending (B, B) the fertilizer formula design of material take " LB " material as base (auxiliary).
Embodiment
Describe the present invention in detail below in conjunction with specific implementation method, be used for explaining the present invention in exemplary embodiment and description of the present invention, but not as a limitation of the invention.
Embodiment 1:
1, minimum plant element nutritional trouble and Diagnosis of Deficiency
1) minimum plant element nutritional trouble disease
Plant nutrition deficiency disorder comprises two kinds of nutritive deficiency and overnutrition (poisoning) diseases.In agriculture production, occurring maximum is plant nutrition deficiency disease, also claims plant nutrition nutritional deficiency disease.Wherein, it is increasing that in current agriculture production, micronutrient element lacks area, and this is because (1) crop yield is higher, and the micronutrient of taking away is just more; (2) N, P, K fertilizer amount increase, and the unbalancedness of having aggravated micro-supply becomes the important restriction factor that crop yield improves; (3) organic fertilizer consumption reduces, and micronutrient is difficult to be supplemented.Due to the expansion gradually of this plantation (work) thing trace element nutritional deficiency disease, the decline of crop failure and product quality will be affected.
For this phenomenon, from the angle of the fertilizer science of nutrient balance and balance fertilizing, in enriching N, P, K chemical fertilizer, science is used micro-fertilizer by an important Fertilization Decision that is 21 century.
2) Diagnosis of Deficiency
(1) planting (work) thing nutritional deficiency is physiological disturbance
Trace element disappearance is physiological disturbance for planting (work) thing.Cause poor growth, yellow leaf, deformity, even fallen flowers bud drop; Peanut iron deficiency causes chrysanthemum disease; Fruit tree lacks zinc and causes little leaf disease; Rape boron, blooms shaky; Tomato boron deficiency, except stem flavescence, also possibility blackening of centre portions; Cauliflower lacks molybdenum, and leaf is by macula lutea browning look, and tomato lacks molybdenum, and fallen flowers increase etc.
(2) diagnostic method
1. outward appearance diagnosis
Leaf look be the most obvious nutritional deficiency symptom of plant extremely.Generally be divided into first yellow (minus green) and on blade, produce the large class of various spots two.For example, the deficiency diseases such as iron, manganese, zinc, copper, because element is difficult for moving in plant materials, thereby, come across spire more; Molybdenum deficiency disease, due to the existence of molybdic acid negative ion, deficiency disease shows as first and occurs at the next Lao Ye and meta leaf.
2. diagnose according to edaphic condition
● pH value
Normally 5-8. is along with more than pH value exceedes neutrality to the pH value of ploughing, and the solubleness of essential element generally declines, and just there will be deficiency disease, and take iron, manganese, copper, zn deficiencie as main, iron deficiency occurs that yellows are the most outstanding; If pH value is down to below 5 in soil, wherein, manganese, aluminium are because solubleness increases, and element surplus, poisons and produce.
● redox state
The element that valency changes can occur, and when when carry out redox in soil, valency changes, solubleness also changes thereupon.Fe+3 and Mn+4 solubleness are low, if be reduced to Fe+2 and Mn+2, solubleness increases, so paddy field rice Fe+3 and Mn+4 are reduced to Fe+2 and Mn+2, and than dryland rice and wheat class, is not prone to iron deficiency, manganese deficiency disease.
● moisture state
Soil exchangeable manganese is significantly less than air dried condition under many wet conditions, and this is because soil water molecule is combined with manganese, improves degree of hydration, and manganese is become can not be to due to state.Facts have proved in some cases, soil water state is one of reason causing trace element deficiency.
● organism
The amount of soil organic matter and confrontation trace element can bring various impacts to degree.
Easily a large amount of existence of decomposing organic matter can promote soil reduction process, promote the dissolving of iron, manganese; Some small organic molecule has sequestering action, insoluble metal that can chelating stripping, and can form complex body with trace element, to insoluble conversion;
On the other hand, sometimes there is manganese in extreme organic soil or peat soil, copper lacks.For example, the northern area that oat graywall occurs of Holland, is that acid sandy peat and alkaline clayey soil join band mutually, and the dispersion of soil organic matter makes trace element dissolve the complicated result of generation.
● coexisting ion
Lack with element or superfluous relevant be " can to state " amount in soil, there is physiological working in coordination with and antagonistic action in interionic in addition, therefore, the essence of coexisting ion is its amount containing.There is selenium-rich soil in North America big area, suppresses by using vitriol.In addition, mantoquita can suppress the absorption of herbage to molybdenum, and these have all utilized antagonistic action between coexisting ion.
3. do object analysis
In the time can becoming component to increase to state in soil, Crop amount also increases certainly thereupon.In crop there are several stages in concentration of element: along with doing the rising of concentration of element in object, Development And Yield progressively increases, and this is the shortage stage that crop does not absorb normal fertility aequum.After this, maintain bulk concentration, and make Development And Yield increase (absorbed dose also increases), this is the suitable stage that keeps bulk concentration to grow.If along with soil concentration improves and absorbs surplus, finally there is obstacle, growth declines on the contrary, and this relation is all set up in principle on any element, any crop.
If the threshold concentration can regulate and control from the shortage stage to the suitable stage, from the suitable stage to superfluous phase transition time, facilitates to do and lacks, superfluous diagnosis.Formula fertilization by soil testing will address this problem.
2, fertilization compositions based on earth measurement
Be related to the well-being of the people, the rich and powerful and social stability of country for grain security, fertilising acts on up to 40%-50% in increases in grain production, and chemical fertilizer blindly and the serious negative effect brought of excessive use, No. 1 file of the Central Committee of the Communist Party of China in 2005 clearly proposes to promote Formula fertilization by soil testing, becomes one of the of paramount importance national science and technology action in recent years of China's agriculture field.
" the surveying native formula fertilizer technical specifications " of printing and distributing revised in March, 2007 by the Ministry of Agriculture, lasted so far 8 years.Current, the sport technique segment of the many keys in fertilization compositions based on earth measurement makes a breakthrough, and set up the region of " large formula, little adjustment " and joined fertilizer technology, and the native formula work of in-depth survey, form comparatively perfect basic fundamental route (key work) at present.
Formula fertilization by soil testing is mainly around " survey soil, fill a prescription, join fertilizer, fertilizer instruct " five links with carry out, 11 work such as " field study, sampling are surveyed and executed, field test, formulating of recipe, formula processing, Demonstration And Extension, advocacy and training, database establishment, natural Productivity Evaluation of Cultivated Land, effect assessment and technical research ".
Patent content of the present invention follows Ministry of Agriculture's " Formula fertilization by soil testing standard " and correlation technique route is implemented.
3, product manufacture
1) non-traditional mineral manure technology of preparing and technique
(1) ore dressing and purification
Because the raw material mineral (being called for short raw material mineral) of " LB " material are affected by build environment, and association has rhombspar, calcite, illite, quartz and a small amount of heavy mineral.In addition, high purity " LB " material feedstock mineral are less, and middle low grade ore is in the majority, thereby, need ore dressing, purification.Conventionally adopt dry technique technique and Wet technique technique.
Law technology technique
Raw ore, through pulverizing, classification, is processed as particulate material or powder.Particulate material granularity is 270 μ m(50-48, μ m-300 orders); Powder granularity is 45 μ m(325-200, μ m-75 orders).
Dry method ore dressing purification processing technical matters flow process is: raw ore → picking → dry → fragmentation → ore grinding → classification → packing.
The key operation of its processing is abrasive dust and classification.45-75 μ m products generally adopt rolling suspension disintegrating machine (Raymond mill), and tornado feeder set carries out classification." LB " material feedstock mineral contain hard ore particle (as quartz etc.), are difficult for grinding.Can remove by " size abandons " of selecting tornado feeder set.Because the sorting result of dry method ore dressing purification techniques technique is limited, so being only applicable to ore quality, the method better or to quality product requires very not high situation.
2. Wet technique technique
Wet technique technique is pulverizing mineral, on classification basis, by smashing the process flows such as slurry dispersion → processing → dehydrate, complete the processing of the product that " LB " material purity is had relatively high expectations, as the application in feed, fodder additives and part substitute antibiotics.
" LB " material feedstock mineral are crystallite mineral, need to be prepared as even ore pulp or finely disseminated suspension before purification, " LB " material mineral and impurity particle are fully disperseed, and impose the stirring of high shearing.Disperseing fully, is the basic of high efficiency separation impurity.
Conventional processing equipment is hydrocyclone, horizontal centrifuge, shaking table etc.
" LB " material feedstock mineral are silicate, and it is to be relatively easy to separating of non-silicate, but larger with the separating difficulty of similar mineral.For example montmorillonite and " LB " material mineral are that structure is close, be easily mutually and the mineral of symbiosis, and density and the disseminated grain size of two kinds of mineral are close, thereby separation must be taked unconventional method.
By purifying, soil, crop (comprising) needed by human nutritional trace element have also obtained enrichment, can be used as " non-traditional mineral manure " and directly use.
(2) acid treatment
Acid-treated object is to remove the impurity such as acid-soluble carbonate, promotes purity, increases its specific surface area, improves decoloring ability.Acid used is mainly the mineral acids such as hydrochloric acid, sulfuric acid and nitric acid or uses separately, or mixed.Aspect of performance hydrochloric acid is better than sulfuric acid, and cost aspect sulfuric acid is better than hydrochloric acid.
Acid treatment is acid activation, the concentration of purity that the principal element that affects its usefulness is mineral, granularity, chemical composition and acid, solid-to-liquid ratio, soak time etc.
(3) thermal treatment (calcining)
" LB " material feedstock mineral are heated to≤measure 200 ℃, lose planar water; At 200 ℃ of-400 ℃ of temperature lower calcinations, can greatly improve the absorption property of mineral, its mechanism is that the zeolite water in planar water and the structure pore between mineral fibre is removed, and inside and outside specific surface area significantly increases event.And along with temperature raises, specific surface area progressively increases, during to 252 ℃, be maximum, after this, along with temperature raises, specific surface area sharply declines on the contrary.The relation that " LB " material feedstock mineral specific surface area changes with Heating temperature is as following table:
Calcining temperature/℃ Do not burn 130 200 250 320 400
Dehydration % 0 8.5 10.0 12.5 16.7 18.9
Specific surface area (BED) m2g-1 71.1 2.7 268 320 282 241
2) production of the related bulk blended fertilizer of expecting take " LB " material as base (auxiliary) of patent of the present invention is according to the production technique processing and manufacturing of " blended fertilizer " of composite fertilizer (B, B fertilizer).
Effect
1, the ecological sustained slow-release fertilizer that " LB " material is base-material covers pair effect that ridges collection rain rill is broadcast complete sets of Techniques through evidence to the full film of corn, using " LB " material is that base (auxiliary) is expected " the ecological sustained slow-release fertilizer " manufactured and executes tradition fertilizer and compare, and can increase production more than 10%; The bald rate of corn ear declines 1-2.8 percentage points, and granule number increases by 25-26; The healthy trace elements with household such as iodine, selenium, zinc, iron in corn kernel, crude protein, fat, starch content are all significantly increased, reach respectively 0.401mg/kg, 0.015mg/kg, 22.87mg/kg, 9.92mg/kg, 12.3%, 3.9% and 61.3%(control group reach respectively 0.0231mg/kg, 0.0101mg/kg, 15.031mg/kg, 8.771mg/kg, 9.3%, 3.7% and 55.7%).Contents of heavy metal elements all reaches within the scope of national agricultural product quality standard-required." ecological sustained slow-release fertilizer " due to siliceous, boracic and speciality microtexture, also has to protect the growth of stem stalk, resistant to lodging, the ability that improves preserving soil moisture, water conservation, increase ventilation property.
2, food crop effect
Potato, wheat, increasing production of rice and quality improve
1) potato volume increase improves with quality
In Gansu, land for growing field crops multiple spot extend trial has carried out in totally 26 test points in 11 areas such as Qinghai, Inner Mongol, 407 mu of plantation demonstration areas, result shows: 1. " LB " material potato sustained-release synergistic special fertilizer is with to execute tradition fertile relatively, and stimulation ratio 11.2%~31.76%, becomes business to lead and improve 11%~33%; After testing, use after " LB " material potato sustained-release synergistic special fertilizer, in potato body, beneficial element content improves (as zinc improves 10%), and harmful element reduces (as lead reduces by 6.8%).2. relatively fertile with tradition, to use after " LB " material potato sustained-release synergistic special fertilizer, potato emerges neatly, grows fine, resistant to lodging, and potato shape is round and smooth, and eye is shallow, has effectively prevented the rotten worry of potato, and soil is had to obvious improving effect.
2) wheat increase yield and quality improve
While singly executing " LB " material, wheat is compared with control group volume increase 21.4%; Joining while executing with chemical fertilizer, agriculture fertilizer, wheat increase yield 5.9%.Wheat quality improves simultaneously, and wheat grain kind nutritional trace element promotes 10.3%-70.5%, and harmful element (lead, cadmium etc.) reduces, and does not all exceed country within the scope of the contamination index of grain regulation.
3) increasing production of rice and quality improve
Use the rice yield stimulation ratio 10.5%-29.9% of " LB " material silicon fertilizer, rice quality obviously improves after testing, wherein polished rice rate reach 75.2%(third-class be increased to second-class), the head rice rate 64.3%(fourth class is increased to first-class), the third-class first-class that is increased to of chalk white grain rate 10%(), the third-class first-class that is increased to of chalkiness degree 0.8%(), the second-class first-class that is increased to of amylose starch 17.1%(), the second-class first-class that is increased to of protein 9.2%(); Main nutrient elements selenium, zinc reach respectively 0.03mg/kg, 20.21mg/kg, and the plumbous cadmium of heavy metal element does not all detect.
3, vegetables and fruit effect
Singly execute " LB " material and can make circle eggplant volume increase 4.6%~16.3%, tomato production promoting 8.0%~15.3%, cucumber 2.2%~6.1%, seed melon 5.5%, celery 11.0%~14.8%.Joining while executing with chemical fertilizer, agriculture fertilizer, tomato production promoting 4.8%~7.9%, cucumber production promoting 3.5%, capsicum volume increase 4.1%, strawberry volume increase 10.3%~16.2%;
Circle eggplant is improved crude protein 4.2%, crude fat 12.5%~25.0%, VITAMIN 4.6%~2.3%, soluble sugar 3.9%~8.9%; Tomato is improved crude protein 10.8%~12.2%, crude fat 11.1%, soluble sugar 6.6%~9.2%; Cucumber is improved vitamins C 5.1%~12.7%, soluble sugar 1.3%; Strawberry is improved crude protein 10.6%, crude fat 5.4%, VITAMIN 3.8%~1.3%, soluble sugar 4.0%, and robust fibre declines 1.5%~2.9%.
The increase by 135.0%~183.3% of circle eggplant iodine, the content of selenium increases by 7.3%~182.9%, and the content of manganese, iron, calcium improves respectively 8.6%, 25.8%, 10.2%, and zinc and copper content decline 5.6% and 16.4%; The content of tomato iodine increases by 155.4%~179.0%, and selenium content increases by 17.6%~254.7%, and manganese content raising 8.3%, iron level improve 12.7%~38.7%, and zinc content declines 29.5%~46.57%, and copper content declines 10.3%, calcium content decreased 11.8%~23.5%; The content of cucumber iodine increases by 84.3%~251.0%, and the content of selenium increases by 14.1%~196.4%, and the content of zinc, manganese, copper improves respectively 26.0%, 18.4%, 25.8%; The content of strawberry iodine increases by 116.2%~239.5%, and selenium content increases by 16.3%~328.5%, and zinc, copper, iron level improve respectively 77.1%, 72.1%, 4.0%.
The content of circle eggplant arsenic contrasts and increases by 7.7%~23.1%, but lead contrasts reduction by 55.0%, and mercury contrasts clean reduction by 17.4%~87.2%; Tomato arsenic content increases by 46.7%, plumbous reduction by 21.0%, and mercury reduces by 33.3%; Cucumber arsenic increases by 17.1%, plumbous increase by 39.1%~56.5%, and mercury reduces by 33.3%; The content of strawberry arsenic, lead, mercury reduces respectively 53.1%~65.6%, 35.9%~44.9% and 81.8%~89.8%.
The technical scheme above embodiment of the present invention being provided is described in detail, applied principle and the embodiment of specific case to the embodiment of the present invention herein and set forth, the explanation of above embodiment is only applicable to help to understand the principle of the embodiment of the present invention; , for one of ordinary skill in the art, according to the embodiment of the present invention, in embodiment and range of application, all will change, in sum, this description should not be construed as limitation of the present invention meanwhile.

Claims (3)

1. a novel reinforced nutrient green " LB " fertilizers, it is characterized in that: this fertilizer comprises 13 kinds " LB " material being rich in 14 kinds of essential nutritional trace elements of human body and animal, and take " LB " material as base-material or auxiliary material, the compound Bulk Blending Fertilizer of assembly plant growth nutritive substance N, P, K.
2. fertilizers according to claim 1, is characterized in that: described " LB " material is rich in 13 kinds of trace elements that iodine, selenium, zinc, iron are representative.
3. fertilizers according to claim 1, is characterized in that: also comprise " non-traditional mineral manure " and assembly N, P, the fertile manufacture of the compound blending of K (B, B) that " LB " material is raw material.
CN201310669361.0A 2013-12-11 2013-12-11 Novel enhanced nutrient green 'LB' functional fertilizer Pending CN103787718A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109287417A (en) * 2018-07-27 2019-02-01 广东省农业科学院作物研究所 A kind of method for potted of potato zinc-deficiency

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JPH0859379A (en) * 1994-08-12 1996-03-05 Bio Baransu:Kk Septic treatment of animal excreta and its treated matter
CN1203210A (en) * 1998-03-05 1998-12-30 户振卿 Plant mineral element composite ore dressing extraction and use thereof
CN101353285A (en) * 2008-08-29 2009-01-28 薛立成 Natural multifunctional mineral compound fertilizer
CN101709007A (en) * 2009-11-12 2010-05-19 谢浩 Medical stone mineral compound fertilizer
CN102503726A (en) * 2011-11-16 2012-06-20 元向尧 Efficient nutrient increasing and controlling water retention and aeration agent and preparation method

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Publication number Priority date Publication date Assignee Title
JPH0859379A (en) * 1994-08-12 1996-03-05 Bio Baransu:Kk Septic treatment of animal excreta and its treated matter
CN1203210A (en) * 1998-03-05 1998-12-30 户振卿 Plant mineral element composite ore dressing extraction and use thereof
CN101353285A (en) * 2008-08-29 2009-01-28 薛立成 Natural multifunctional mineral compound fertilizer
CN101709007A (en) * 2009-11-12 2010-05-19 谢浩 Medical stone mineral compound fertilizer
CN102503726A (en) * 2011-11-16 2012-06-20 元向尧 Efficient nutrient increasing and controlling water retention and aeration agent and preparation method

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109287417A (en) * 2018-07-27 2019-02-01 广东省农业科学院作物研究所 A kind of method for potted of potato zinc-deficiency

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