CN106008018A - Novel graphene fertilizer and preparation method thereof - Google Patents
Novel graphene fertilizer and preparation method thereof Download PDFInfo
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- CN106008018A CN106008018A CN201610474138.4A CN201610474138A CN106008018A CN 106008018 A CN106008018 A CN 106008018A CN 201610474138 A CN201610474138 A CN 201610474138A CN 106008018 A CN106008018 A CN 106008018A
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05D—INORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
- C05D9/00—Other inorganic fertilisers
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/80—Soil conditioners
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G5/00—Fertilisers characterised by their form
- C05G5/10—Solid or semi-solid fertilisers, e.g. powders
- C05G5/12—Granules or flakes
Abstract
The invention discloses a novel graphene fertilizer and a preparation method thereof. The fertilizer is mainly prepared from graphene, expanded vermiculite powder, soybean cake, distillers' grains, barnyard manure, straw, rapeseed oil, rice bran and water. The dispersion effect of graphene is improved by conducting ball-milling on the expanded vermiculite powder and graphene; meanwhile, due to the fact that the raw materials containing plant fiber are used in the fertilizer, the loss of effective ingredients in the fertilizer is greatly reduced, and the use effect of the fertilizer is improved; in the actual usage process, the use amount of the fertilizer can reduced by 50% or above, and the yield is increased by 15%-20%.
Description
Technical field
The present invention relates to technical field of fertilizers, it particularly relates to a kind of Graphene new-type fertilizer and preparation method thereof.
Background technology
The two dimensional crystal of only one layer of atomic thickness that Graphene (Graphene) is made up of carbon atom.2004, English
University of Manchester of state physicist An Deliegaimu and Constantine's Nuo Woxiao love, stone is isolated in success from graphite
Ink alkene, it was demonstrated that it can be with individualism, and two people obtain Nobel Prize in physics in 2010 the most jointly.
Before at the end of 2015, boron alkene finds, Graphene is the thinnest material, is also the most tough material, fracture strength
More taller than best steel 200 times.It has again good elasticity simultaneously, and stretch range can reach the 20% of own dimensions.It
It is the material that current nature is the thinnest, intensity is the highest, if making hammock, this heavy sensation of the body with the Graphene of one piece of area 1 square metre
Amount just can bear the cat of a kilogram less than 1 milligram.
The current most potential application of Graphene is the succedaneum becoming silicon, manufactures superminiature transistor, is used for producing not
The supercomputer come.Replacing silicon with Graphene, the speed of service of computer processor will hundreds times soon.
It addition, Graphene is almost fully transparent, only absorb the light of 2.3%.On the other hand, it is the finest and close, even if
The gas atom (helium atom) being minimum also cannot penetrate.These features make it be highly suitable as the former of transparent electron product
Material, such as transparent touch display screen, luminous plaque and solar panel.
As the thinnest, a kind of novel nano-material that maximum intensity, electrical and thermal conductivity performance are the strongest that have now been found that, Graphene
Being referred to as " dark fund ", be " king of new material ", scientist even foretells that Graphene " will thoroughly change 21 century ".Very likely lift
Play a subversiveness new technique new industrial revolution have swept the globe.
Chinese invention patent CN1105585380A discloses a kind of compound fertilizer synergist modified by graphene oxide, should
Fertilizer synergist is by being coated with the nanogel microgranule that fertilizer is formed by graphene oxide and cyclodextrin, thus improves
The fertilizer efficiency of compound fertilizer.
Chinese invention patent CN105110849A discloses fertilizer of a kind of xylose residue and preparation method thereof, and this fertilizer will
Graphene joins in strain, then sprays, it is possible to reduce strain consumption, promotes the obscure of xylose residue, makes strain play
Maximum effect.
When but above Graphene uses in fertilizer, Graphene is only simply added；Owing to Graphene is monolayer
Structure, the most farthest plays its effect, thus the usage amount reducing fertilizer still requires study.
Summary of the invention
In view of this, it is an object of the invention to provide a kind of Graphene new-type fertilizer and preparation method thereof, the method is significantly
Improve the using effect of Graphene, reduce the usage amount of fertilizer.
A kind of Graphene new-type fertilizer, by weight, including following Main Ingredients and Appearance:
Soybean cake 15-25%
Testa oryzae 12-28%
Distiller grains 18-25%
Barnyard manure 25-40%
Expanded vermiculite powder 2-5%
Oleum Brassicae campestris 0.5-0.8%
Graphene 0.01-0.05%
Straw surplus.
Soybean cake also known as " lucky cake " is gained oil cake after soybean extract oil, can do feedstuff, fertilizer.Semen sojae atricolor (mainly Semen Glycines
And Semen sojae atricolor) oil expression after side-product, various plant Middle nutrition be worth the highest.In general, in the dry of every kilogram of soybean cake
Digestible energy is all more than 3000 kilocalories, and gross protein value is more than 40%, and the biological value of protein is higher than any one
Oilseed meal.Wherein lysine content necessary to poultry reaches 2.5%～3%, higher 10 times than Semen Maydis.
Oryza glutinosa is China the 1st generalized grain kind. produces about 2.06 hundred million tons per year at present, accounts for the 42% of whole nation total output of grain.
Rice yield accounts for the 37% of total output of grain in the world.Oryza glutinosa shell to be removed and account for gross weight during being processed into polished rice
Peel, seed coat, perisperm, mush layer and the embryo of about 10%, traditional Testa oryzae i.e. existing national standards Testa oryzae are mainly
It is processed into by peel, seed coat, perisperm, aleurone and embryo, therefore can infiltrate a small amount of rice husk and in the course of processing
Quantitative dust and microorganism, so being only used for feedstuff, be the principal by product of paddy processing.Result of study both domestic and external and
Data shows, rich in various nutrients and biological active substances in Testa oryzae.Raw material and the processing used due to processing Testa oryzae
Technology is different. and the constituent of Testa oryzae is the most just the same.In general, average containing protein 15%, fat 16%-in Testa oryzae
22%, sugar 3%-8%, moisture 10%, heat is about 125.1KJ/g.Fatty acid main in fat is mostly oleic acid, sub-oil
The unsaturated fatty acids such as acid, and containing a large amount vitamin, pohytol, dietary fiber, aminoacid and mineral etc..
Distiller grains, another name red wine dregs, fermented grain grain, dregs of rice etc., be remaining residue after the wine brewing such as rice, wheat, Sorghum vulgare Pers..Distiller grains are wine brewing
During direct leftover bits and pieces, it does not contain only a certain proportion of grain can save feed cattle concentrate, it is possibly together with abundant
Crude protein, about exceeds 2-3 times of Semen Maydis content, simultaneously possibly together with various trace elements, vitamin, yeast etc., lysine, egg
The content of propylhomoserin and tryptophan is the highest, and this is that agricultural crop straw is not provided that.Distiller grains are all fermented rear high temperature steamings
Rear formation, so its crude fiber content is relatively low.
Barnyard manure is livestock waste and gasket materials, feedstuff stubble mixed-stacking the fertilizer through microbial action.Rich
Containing organic and various nutrients.In various domestic animals manures, high with the nitrogen of sheep stool, phosphorus, potassium content, pig, horsehit take second place, and cattle manure is
Low；Excretion then cattle manure is most, and pig, horse class are taken second place, and sheep stool is minimum.Gasket materials has straw, weeds, fallen leaves, peat and dry ground
Deng.Barnyard manure divides circle inner product system (absorbing fecaluria in gasket materials is directly sprinkled into colony house) and circle apposition system (to be cleared out by domestic animal fecaluria
Colony house is outer and gasket materials is successively piled up).Through disliking edema caused by disorder of QI solution to become thoroughly decomposed.During long-pending system, its chemical constituent is acted on by microorganism
And change.
The effect of barnyard manure:
1. plant nutrient is provided.Including required a great number of elements nitrogen, phosphorus, potassium, calcium, magnesium, sulfur and trace elements iron, manganese, boron,
The inorganic nutrients such as zinc, molybdenum, copper；Organic nutrient and active substance such as vitamin B1, the B6 etc. such as aminoacid, amide, nucleic acid.Keep supporting
The relative equilibrium divided.
2. the effectiveness of soil nutrient is improved.Containing a large amount of microorganisms and various enzyme (protease, urase, phosphorylation in barnyard manure
Enzyme), promote organic nitrogen, phosphorus to become inorganic states, for Crop.And the formation such as calcium in soil, magnesium, ferrum, aluminum can be made to stablize network
Compound, reduces phosphorus fixation, improves available phosphorus content.
3. Soil structure is improved.Humus colloid promotes that soil aggregate is formed, and reduces unit weight, improves the penetrating of soil
Property, coordinate water, gas contradiction.Resiliency and the improvement poison field, ore deposit of soil can also be improved.
4. culture fertility, improves the fertilizer conservation of soil, moisture holding capacity.Barnyard manure is mainly used as base manure after becoming thoroughly decomposed.Supporting of fresh manure
Dividing and mostly be organic, carbon-nitrogen ratio (C/N) value is big, should not directly use, especially can not directly apply rice terrace.
Vermiculitum is the secondary metamorphic mineral of water aluminosilicate containing magnesium of a kind of layer structure, like Muscovitum outside raw ore, generally by
Black (golden) Muscovitum forms through hydrothermal alteration effect or air slaking, because of its be heated dehydration expand time in flexure shape, form exactly likes Hirudo, therefore
Claim Vermiculitum.Fabric and raw-vermiculite sheet is after high-temperature roasting, and its volume energy expands rapidly several times to tens times, and the Vermiculitum after volumetric expansion is just
It is expanded vermiculite.Vermiculitum can be used as soil conditioner, owing to it has good cation commutativity and adsorptivity, can improve soil
The structure of earth, water storage preserves soil moisture, and improves breathability and the property of water-bearing of soil, makes acid ground become neutral soil；Vermiculitum also can rise
To cushioning effect, hinder the rapid change of pH value, make fertilizer slowly discharge in plant growth medium, and allow the most excessively to make
With fertilizer, plant is safe from harm；Vermiculitum also can to crop provide K, Mg, Ca, the Fe that self contain and the Mn of trace, Cu,
The elements such as Zn.The water absorption of Vermiculitum, cation commutativity and properties of chemical composition so that it is play fertilizer conservation, water conservation, water storage, breathe freely
With multiple actions such as mineral fertilizers.Test shows: is mixed in compound fertilizer by the expanded vermiculite of 0.5-1%, can make crop yield
Improve 15-20%.
Straw is the general name of ripe crops stem and leaf (fringe) part.It is often referred to Semen Tritici aestivi, Oryza sativa L., Semen Maydis, potato class, Brassica campestris L, cotton
Flower, Caulis Sacchari sinensis and other crops (usually coarse grain) remainder after results seed.The photosynthetic product of crops has
More than half is present in straw, straw rich in nitrogen, phosphorus, potassium, calcium, magnesium and organic matter etc., be one have multiduty can be again
Raw living resources, straw is also a kind of roughage.Feature is that crude fiber content is high (30%-40%), and containing lignin etc..
Though lignocellulose can not be utilized by pig, chicken, but can be absorbed by domestic animals such as ruminant cattle, sheep and utilize.
The preparation method of a kind of Graphene new-type fertilizer, comprises the following steps:
A, expanded vermiculite is put in pulverizer, be crushed to powdery, cross 250 mesh sieves, siftage is put into wet ball mill
In, and add water, Graphene and Oleum Brassicae campestris, use ball-milling method to be ground, obtain compound；
B, soybean cake is put in blender, mixing speed is adjusted to 150-200rpm, stir 10-15min, will stirring speed
Degree is adjusted to 250-300rpm, adds Testa oryzae and straw, stirs 20-25min；
C, mixing speed is adjusted to 380-400rpm, adds barnyard manure, distiller grains and the compound of step A, stir 25-
30min；
D, dry, pelletize, obtain Graphene new-type fertilizer.
Preferably, in described step A, the addition sum of each raw material and the mass ratio of water are 1: (10-15).
Preferably, the particle diameter of the described compound in step A is 10-30 μm.
Preferably, owing to distiller grains and barnyard manure containing substantial amounts of microorganism and various enzyme, therefore the novel fertilizer of described Graphene
Expect be dried, carrying out ferment effect more preferably before pelletize.
The preparation method of Graphene new-type fertilizer provided by the present invention, one is by expanded vermiculite powder and the common ball of Graphene
Mill, owing to expanded vermiculite powder has layer structure, after ball milling common with Graphene, beneficially Graphene is fitted in expanded vermiculite powder
Superficies, thus the dispersion of beneficially Graphene, without flocking together；Two is to add a small amount of Oleum Brassicae campestris when grinding
Being conducive to increasing lubricant effect, grinding effect is more preferably；Three is the proportioning of the various raw materials by the present invention, makes the use of fertilizer imitate
Fruit is more preferably；Four is to employ the various raw materials containing Plant fiber such as distiller grains, barnyard manure, Testa oryzae, straw in fertilizer, these raw materials with
Expanded vermiculite powder matches with Graphene and can further enhance Graphene to the protective effect of effective ingredient in fertilizer, minimizing battalion
The loss formed point, and the thickness of the Plant fiber in distiller grains, barnyard manure, Testa oryzae, straw, decomposition rate in soil differ
Sample, therefore can match with Graphene with expanded vermiculite powder for a long time, strengthen the fertilizer protected effect to effective ingredient.To sum up
Described, the fertilizer of the present invention and the preparation method of fertilizer can greatly reduce the effective ingredient in fertilizer and run off, and improves former fertilizer
The using effect of material, actually used during, the consumption of fertilizer can reduce more than 50%, increases production 15-20%.
Detailed description of the invention
Below embodiment, labor further to the present invention:
Embodiment 1
The preparation method of a kind of Graphene new-type fertilizer, is carried out as steps described below:
A, expanded vermiculite is put in pulverizer, be crushed to powdery, cross 250 mesh sieves, siftage is put into wet ball mill
In, and add water, Graphene and Oleum Brassicae campestris, use ball-milling method to be ground, obtain compound；
B, soybean cake is put in blender, mixing speed is adjusted to 180rpm, stir 12min, mixing speed is regulated
To 275rpm, add Testa oryzae and straw, stir 20min；
C, mixing speed is adjusted to 390rpm, adds barnyard manure, distiller grains and the compound of step A, stir 28min；
D, fertilizer is taken out and sealing and fermenting 10 days；
E, dry, pelletize, obtain Graphene new-type fertilizer.
In described step A, the addition sum of each raw material and the mass ratio of water are 1: 12.
The particle diameter of the described compound in step A is 10-30 μm.
Described Graphene new-type fertilizer, by weight, including following Main Ingredients and Appearance:
Soybean cake 20%
Testa oryzae 15%
Distiller grains 25%
Barnyard manure 30%
Expanded vermiculite powder 4%
Oleum Brassicae campestris 0.8%
Graphene 0.03%
Straw surplus.
Embodiment 2
The preparation method of a kind of Graphene new-type fertilizer, is carried out as steps described below:
A, expanded vermiculite is put in pulverizer, be crushed to powdery, cross 250 mesh sieves, siftage is put into wet ball mill
In, and add water, Graphene and Oleum Brassicae campestris, use ball-milling method to be ground, obtain compound；
B, soybean cake is put in blender, mixing speed is adjusted to 200rpm, stir 10min, mixing speed is regulated
To 300rpm, add Testa oryzae and straw, stir 25min；
C, mixing speed is adjusted to 380rpm, adds barnyard manure, distiller grains and the compound of step A, stir 30min；
D, fertilizer is taken out and sealing and fermenting 12 days；
E, dry, pelletize, obtain Graphene new-type fertilizer.
In described step A, the addition sum of each raw material and the mass ratio of water are 1: 15.
The particle diameter of the described compound in step A is 10-30 μm.
Described Graphene new-type fertilizer, by weight, including following Main Ingredients and Appearance:
Soybean cake 20%
Testa oryzae 12%
Distiller grains 18%
Barnyard manure 40%
Expanded vermiculite powder 5%
Oleum Brassicae campestris 0.5%
Graphene 0.01%
Straw surplus.
Embodiment 3
The preparation method of a kind of Graphene new-type fertilizer, is carried out as steps described below:
A, expanded vermiculite is put in pulverizer, be crushed to powdery, cross 250 mesh sieves, siftage is put into wet ball mill
In, and add water, Graphene and Oleum Brassicae campestris, use ball-milling method to be ground, obtain compound；
B, soybean cake is put in blender, mixing speed is adjusted to 200rpm, stir 10min, mixing speed is regulated
To 300rpm, add Testa oryzae and straw, stir 25min；
C, mixing speed is adjusted to 400rpm, adds barnyard manure, distiller grains and the compound of step A, stir 25min；
D, fertilizer is taken out and sealing and fermenting 8 days；
E, dry, pelletize, obtain Graphene new-type fertilizer.
In described step A, the addition sum of each raw material and the mass ratio of water are 1: 10.
The particle diameter of the described compound in step A is 10-30 μm.
Described Graphene new-type fertilizer, by weight, including following Main Ingredients and Appearance:
Soybean cake 15%
Testa oryzae 28%
Distiller grains 18%
Barnyard manure 25%
Expanded vermiculite powder 2%
Oleum Brassicae campestris 0.8%
Graphene 0.05%
Straw surplus.
Embodiment 4
The preparation method of a kind of Graphene new-type fertilizer, is carried out as steps described below:
A, expanded vermiculite is put in pulverizer, be crushed to powdery, cross 250 mesh sieves, siftage is put into wet ball mill
In, and add water, Graphene and Oleum Brassicae campestris, use ball-milling method to be ground, obtain compound；
B, soybean cake is put in blender, mixing speed is adjusted to 180rpm, stir 12min, mixing speed is regulated
To 275rpm, add Testa oryzae and straw, stir 20min；
C, mixing speed is adjusted to 390rpm, adds barnyard manure, distiller grains and the compound of step A, stir 28min；
D, dry, pelletize, obtain Graphene new-type fertilizer.
In described step A, the addition sum of each raw material and the mass ratio of water are 1: 12.
The particle diameter of the described compound in step A is 10-30 μm.
Described Graphene new-type fertilizer, by weight, including following Main Ingredients and Appearance:
Soybean cake 18%
Testa oryzae 28%
Distiller grains 20%
Barnyard manure 30%
Expanded vermiculite powder 3%
Oleum Brassicae campestris 0.7%
Graphene 0.03%
Straw surplus.
Embodiment 5
The preparation method of a kind of Graphene new-type fertilizer, is carried out as steps described below:
A, expanded vermiculite is put in pulverizer, be crushed to powdery, cross 250 mesh sieves, siftage is put into wet ball mill
In, and add water, Graphene and Oleum Brassicae campestris, use ball-milling method to be ground, obtain compound；
B, soybean cake is put in blender, mixing speed is adjusted to 180rpm, stir 12min, mixing speed is regulated
To 250rpm, add Testa oryzae and straw, stir 20min；
C, mixing speed is adjusted to 400rpm, adds barnyard manure, distiller grains and the compound of step A, stir 28min；
D, dry, pelletize, obtain Graphene new-type fertilizer.
In described step A, the addition sum of each raw material and the mass ratio of water are 1: 10.
The particle diameter of the described compound in step A is 10-30 μm.
Described Graphene new-type fertilizer, by weight, including following Main Ingredients and Appearance:
Soybean cake 15%
Testa oryzae 22%
Distiller grains 22%
Barnyard manure 28%
Expanded vermiculite powder 4%
Oleum Brassicae campestris 0.5%
Graphene 0.02%
Straw surplus.
By the fertilizer application of embodiment 1-5 in wheat growth is tested, and mixing prepared by step A in embodiment 1
Material is removed, and as a control group 1, the usage amount of the fertilizer in matched group 1 is doubled as a control group 2 (this consumption is general Semen Tritici aestivi
The fertilizer amount in field), the wheat breed of follow-up sowing and field management, 7 pieces of ground keep consistent, during results, calculate per mu yield.
| Group | Per mu yield (kg) |
| Embodiment 1 | 575 |
| Embodiment 2 | 565 |
| Embodiment 3 | 560 |
| Embodiment 4 | 540 |
| Embodiment 5 | 545 |
| Matched group 1 | 405 |
| Matched group 2 | 480 |
Comparative example 1
Being removed by expanded vermiculite powder in embodiment 1, remaining preparation condition is different, obtains Graphene new-type fertilizer, and will
It is used in wheat planting, and planting conditions is same as in Example 1, obtains following per mu yield data:
By comparative example 1 it is recognised that under conditions of being added without expanded vermiculite powder, add Graphene only can ratio with
Per mu yield increase about 10% etc. the fertilizer of addition；Compare, under conditions of being added without expanded vermiculite powder, the mu adding expanded vermiculite powder
Product decreases about 30%.
The above, the only present invention preferably detailed description of the invention, but protection scope of the present invention is not limited thereto,
Any those familiar with the art in the technical scope that the invention discloses, according to technical scheme and
Inventive concept equivalent or change in addition, all should contain within protection scope of the present invention.
Claims (6)
1. a Graphene new-type fertilizer, it is characterised in that include the composition of following percentage by weight:
Soybean cake 15-25%
Testa oryzae 12-28%
Distiller grains 18-25%
Barnyard manure 25-40%
Expanded vermiculite powder 2-5%
Oleum Brassicae campestris 0.5-0.8%
Graphene 0.01-0.05%
Straw surplus.
2. the preparation method of a Graphene new-type fertilizer, it is characterised in that carry out as steps described below:
A, expanded vermiculite is put in pulverizer, be crushed to powdery, cross 250 mesh sieves, siftage is put in wet ball mill, and
Add water, Graphene and Oleum Brassicae campestris, use ball-milling method to be ground, obtain compound；
B, soybean cake is put in blender, mixing speed is adjusted to 150-200rpm, stir 10-15min, mixing speed is adjusted
Joint, to 250-300rpm, adds Testa oryzae and straw, stirs 20-25min；
C, mixing speed is adjusted to 380-400rpm, adds barnyard manure, distiller grains and the compound of step A, stir 25-30min；
D, dry, pelletize, obtain Graphene new-type fertilizer.
The preparation method of Graphene new-type fertilizer the most according to claim 2, it is characterised in that in described step A, respectively
The addition sum of raw material and the mass ratio of water are 1: (10-15).
The preparation method of Graphene new-type fertilizer the most according to claim 2, it is characterised in that in described step A
The particle diameter of compound is 10-30 μm.
The preparation method of Graphene new-type fertilizer the most according to claim 2, it is characterised in that described Graphene is novel
Fertilizer is being dried, is fermenting before pelletize.
The preparation method of Graphene new-type fertilizer the most according to claim 2, it is characterised in that enter as steps described below
OK:
A, expanded vermiculite is put in pulverizer, be crushed to powdery, cross 250 mesh sieves, siftage is put in wet ball mill, and
Add water, Graphene and Oleum Brassicae campestris, use ball-milling method to be ground, obtain compound；
B, soybean cake is put in blender, mixing speed is adjusted to 180rpm, stir 12min, mixing speed is adjusted to
275rpm, adds Testa oryzae and straw, stirs 20min；
C, mixing speed is adjusted to 390rpm, adds barnyard manure, distiller grains and the compound of step A, stir 28min；
D, fertilizer is taken out and sealing and fermenting 10 days；
E, dry, pelletize, obtain Graphene new-type fertilizer；
In described step A, the addition sum of each raw material and the mass ratio of water are 1: 12；
The particle diameter of the described compound in step A is 10-30 μm；
Described Graphene new-type fertilizer, by weight, including following Main Ingredients and Appearance:
Soybean cake 20%
Testa oryzae 15%
Distiller grains 25%
Barnyard manure 30%
Expanded vermiculite powder 4%
Oleum Brassicae campestris 0.8%
Graphene 0.03%
Straw surplus.
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| CN106966797A (en) * | 2017-04-06 | 2017-07-21 | 浙江伟豪能源科技有限公司 | A kind of fertilizer specially for wheat for adding graphene and preparation method thereof |
| CN107010999A (en) * | 2017-04-06 | 2017-08-04 | 浙江伟豪能源科技有限公司 | A kind of preparation method for the modified graphene that can be applied to fertilizer |
| CN107089868A (en) * | 2017-06-01 | 2017-08-25 | 广东绿亨生物科技有限公司 | A kind of preparation method for being conducive to preventing and treating the microbial manure of sugar orange anthracnose |
| CN107235783A (en) * | 2017-07-28 | 2017-10-10 | 秦皇岛出入境检验检疫局煤炭检测技术中心 | A kind of grape special fertilizer and preparation method for adding flyash, rare earth and graphene |
| CN107667816A (en) * | 2017-09-26 | 2018-02-09 | 界首市四季旺家庭农场 | A kind of implantation methods of high-quality chrysanthemum |
| CN108129195A (en) * | 2017-12-29 | 2018-06-08 | 郴州市通源生物科技有限公司 | A kind of disease-resistant fertilizer of graphene |
| WO2018107212A1 (en) * | 2016-12-12 | 2018-06-21 | The University Of Adelaide | Graphene for fertilizer applications |
| CN109734529A (en) * | 2019-03-25 | 2019-05-10 | 河北森然生物科技有限公司 | A kind of biological organic fertilizer that utilization rate is high |
| WO2019127124A1 (en) * | 2017-12-27 | 2019-07-04 | 深圳市大富科技股份有限公司 | Method for preparing graphite-based organic fertilizer dry powder |
| CN110698285A (en) * | 2019-10-22 | 2020-01-17 | 秾源科技(北京)有限公司 | Organic fertilizer prepared from pulping solid waste and preparation method thereof |
| CN111285729A (en) * | 2020-04-04 | 2020-06-16 | 江苏碳谷二维世界科技有限公司 | Carbon-based mica fertilizer, preparation method and application thereof |
| CN112079672A (en) * | 2020-08-24 | 2020-12-15 | 广西清鹿新材料科技有限责任公司 | Application of graphene aqueous dispersion in farmland water retention, fertilizer retention and bacteriostasis |
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| CN106577644A (en) * | 2016-11-25 | 2017-04-26 | 广西田园生化股份有限公司 | Medical fertilizer containing graphene nano material and preparation method of medical fertilizer |
| AU2017376826B2 (en) * | 2016-12-12 | 2022-07-07 | The University Of Adelaide | Graphene for fertilizer applications |
| US11040918B2 (en) | 2016-12-12 | 2021-06-22 | The University Of Adelaide | Graphene for fertilizer applications |
| WO2018107212A1 (en) * | 2016-12-12 | 2018-06-21 | The University Of Adelaide | Graphene for fertilizer applications |
| US11731915B2 (en) | 2016-12-12 | 2023-08-22 | The University Of Adelaide | Graphene for fertilizer applications |
| CN110248914A (en) * | 2016-12-12 | 2019-09-17 | 阿德莱德大学 | Graphene for fertilizer application |
| IL267266B2 (en) * | 2016-12-12 | 2024-03-01 | Univ Adelaide | Graphene for fertilizer applications |
| IL267266B1 (en) * | 2016-12-12 | 2023-11-01 | Univ Adelaide | Graphene for fertilizer applications |
| CN107010999A (en) * | 2017-04-06 | 2017-08-04 | 浙江伟豪能源科技有限公司 | A kind of preparation method for the modified graphene that can be applied to fertilizer |
| CN106966797A (en) * | 2017-04-06 | 2017-07-21 | 浙江伟豪能源科技有限公司 | A kind of fertilizer specially for wheat for adding graphene and preparation method thereof |
| CN107089868A (en) * | 2017-06-01 | 2017-08-25 | 广东绿亨生物科技有限公司 | A kind of preparation method for being conducive to preventing and treating the microbial manure of sugar orange anthracnose |
| CN107235783A (en) * | 2017-07-28 | 2017-10-10 | 秦皇岛出入境检验检疫局煤炭检测技术中心 | A kind of grape special fertilizer and preparation method for adding flyash, rare earth and graphene |
| CN107667816A (en) * | 2017-09-26 | 2018-02-09 | 界首市四季旺家庭农场 | A kind of implantation methods of high-quality chrysanthemum |
| WO2019127124A1 (en) * | 2017-12-27 | 2019-07-04 | 深圳市大富科技股份有限公司 | Method for preparing graphite-based organic fertilizer dry powder |
| CN108129195A (en) * | 2017-12-29 | 2018-06-08 | 郴州市通源生物科技有限公司 | A kind of disease-resistant fertilizer of graphene |
| CN109734529A (en) * | 2019-03-25 | 2019-05-10 | 河北森然生物科技有限公司 | A kind of biological organic fertilizer that utilization rate is high |
| CN110698285A (en) * | 2019-10-22 | 2020-01-17 | 秾源科技(北京)有限公司 | Organic fertilizer prepared from pulping solid waste and preparation method thereof |
| CN111285729A (en) * | 2020-04-04 | 2020-06-16 | 江苏碳谷二维世界科技有限公司 | Carbon-based mica fertilizer, preparation method and application thereof |
| CN112079672A (en) * | 2020-08-24 | 2020-12-15 | 广西清鹿新材料科技有限责任公司 | Application of graphene aqueous dispersion in farmland water retention, fertilizer retention and bacteriostasis |
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