CN103755481A - Nanocarbon organic fertilizer - Google Patents
Nanocarbon organic fertilizer Download PDFInfo
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- CN103755481A CN103755481A CN201410032850.XA CN201410032850A CN103755481A CN 103755481 A CN103755481 A CN 103755481A CN 201410032850 A CN201410032850 A CN 201410032850A CN 103755481 A CN103755481 A CN 103755481A
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- 239000003895 organic fertilizer Substances 0.000 title claims abstract description 33
- 229910021392 nanocarbon Inorganic materials 0.000 title abstract description 10
- 239000003337 fertilizer Substances 0.000 claims abstract description 40
- 239000000203 mixture Substances 0.000 claims abstract description 23
- 241000196324 Embryophyta Species 0.000 claims abstract description 12
- 229910052761 rare earth metal Inorganic materials 0.000 claims abstract description 12
- 150000001413 amino acids Chemical class 0.000 claims abstract description 9
- 241000589152 Azotobacter chroococcum Species 0.000 claims abstract description 8
- -1 rare earth compound Chemical class 0.000 claims abstract description 8
- 102000016938 Catalase Human genes 0.000 claims abstract description 7
- 108010053835 Catalase Proteins 0.000 claims abstract description 7
- 241000218682 Pseudolarix amabilis Species 0.000 claims abstract description 7
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000004202 carbamide Substances 0.000 claims abstract description 7
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims abstract description 6
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229910052796 boron Inorganic materials 0.000 claims abstract description 6
- 239000011790 ferrous sulphate Substances 0.000 claims abstract description 6
- 235000003891 ferrous sulphate Nutrition 0.000 claims abstract description 6
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 claims abstract description 6
- 229910000359 iron(II) sulfate Inorganic materials 0.000 claims abstract description 6
- 239000011701 zinc Substances 0.000 claims abstract description 6
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 6
- 229910052799 carbon Inorganic materials 0.000 claims description 40
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 37
- 239000002105 nanoparticle Substances 0.000 claims description 36
- 238000002156 mixing Methods 0.000 claims description 21
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 20
- 238000000855 fermentation Methods 0.000 claims description 20
- 230000004151 fermentation Effects 0.000 claims description 20
- 238000003756 stirring Methods 0.000 claims description 17
- 229930006000 Sucrose Natural products 0.000 claims description 11
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 claims description 11
- 239000000463 material Substances 0.000 claims description 11
- 239000000843 powder Substances 0.000 claims description 11
- 239000005720 sucrose Substances 0.000 claims description 11
- UNIYDALVXFPINL-UHFFFAOYSA-N 3-(2-methylprop-2-enoyloxy)propylsilicon Chemical compound CC(=C)C(=O)OCCC[Si] UNIYDALVXFPINL-UHFFFAOYSA-N 0.000 claims description 10
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 10
- MCEBKLYUUDGVMD-UHFFFAOYSA-N [SiH3]S(=O)=O Chemical compound [SiH3]S(=O)=O MCEBKLYUUDGVMD-UHFFFAOYSA-N 0.000 claims description 10
- 230000001580 bacterial effect Effects 0.000 claims description 10
- 239000007788 liquid Substances 0.000 claims description 10
- 239000011780 sodium chloride Substances 0.000 claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- 235000011073 invertase Nutrition 0.000 claims description 8
- 241000894006 Bacteria Species 0.000 claims description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 7
- 101710184309 Probable sucrose-6-phosphate hydrolase Proteins 0.000 claims description 6
- 102400000472 Sucrase Human genes 0.000 claims description 6
- 101710112652 Sucrose-6-phosphate hydrolase Proteins 0.000 claims description 6
- 241000411851 herbal medicine Species 0.000 claims description 6
- 230000007062 hydrolysis Effects 0.000 claims description 6
- 238000006460 hydrolysis reaction Methods 0.000 claims description 6
- 239000002994 raw material Substances 0.000 claims description 6
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims description 5
- 235000008733 Citrus aurantifolia Nutrition 0.000 claims description 5
- 235000011941 Tilia x europaea Nutrition 0.000 claims description 5
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 claims description 5
- 229910052921 ammonium sulfate Inorganic materials 0.000 claims description 5
- 235000011130 ammonium sulphate Nutrition 0.000 claims description 5
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims description 5
- 230000008014 freezing Effects 0.000 claims description 5
- 238000007710 freezing Methods 0.000 claims description 5
- 238000005469 granulation Methods 0.000 claims description 5
- 230000003179 granulation Effects 0.000 claims description 5
- 238000009775 high-speed stirring Methods 0.000 claims description 5
- 239000004571 lime Substances 0.000 claims description 5
- 238000006386 neutralization reaction Methods 0.000 claims description 5
- 239000002245 particle Substances 0.000 claims description 5
- 238000002360 preparation method Methods 0.000 claims description 5
- 238000003809 water extraction Methods 0.000 claims description 5
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 2
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims description 2
- BXJPTTGFESFXJU-UHFFFAOYSA-N yttrium(3+);trinitrate Chemical compound [Y+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O BXJPTTGFESFXJU-UHFFFAOYSA-N 0.000 claims description 2
- 239000011573 trace mineral Substances 0.000 abstract description 6
- 235000013619 trace mineral Nutrition 0.000 abstract description 6
- 235000007164 Oryza sativa Nutrition 0.000 abstract description 5
- 241000209140 Triticum Species 0.000 abstract description 5
- 235000021307 Triticum Nutrition 0.000 abstract description 5
- 230000009286 beneficial effect Effects 0.000 abstract description 5
- 201000010099 disease Diseases 0.000 abstract description 5
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 abstract description 5
- 235000009566 rice Nutrition 0.000 abstract description 5
- 240000008042 Zea mays Species 0.000 abstract description 4
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 abstract description 4
- 235000002017 Zea mays subsp mays Nutrition 0.000 abstract description 4
- 235000005822 corn Nutrition 0.000 abstract description 4
- 239000011259 mixed solution Substances 0.000 abstract description 4
- 229920000742 Cotton Polymers 0.000 abstract description 3
- 244000068988 Glycine max Species 0.000 abstract description 3
- 235000010469 Glycine max Nutrition 0.000 abstract description 3
- 241000238631 Hexapoda Species 0.000 abstract description 3
- 238000005903 acid hydrolysis reaction Methods 0.000 abstract description 3
- 239000000835 fiber Substances 0.000 abstract description 3
- 229910052625 palygorskite Inorganic materials 0.000 abstract description 2
- PXQVXFBEYAYXHI-UHFFFAOYSA-N silyl but-2-enoate Chemical compound CC=CC(=O)O[SiH3] PXQVXFBEYAYXHI-UHFFFAOYSA-N 0.000 abstract 3
- TXDNPSYEJHXKMK-UHFFFAOYSA-N sulfanylsilane Chemical compound S[SiH3] TXDNPSYEJHXKMK-UHFFFAOYSA-N 0.000 abstract 3
- 240000007594 Oryza sativa Species 0.000 abstract 1
- 241000589180 Rhizobium Species 0.000 abstract 1
- 241000607479 Yersinia pestis Species 0.000 abstract 1
- BIGPRXCJEDHCLP-UHFFFAOYSA-N ammonium bisulfate Chemical compound [NH4+].OS([O-])(=O)=O BIGPRXCJEDHCLP-UHFFFAOYSA-N 0.000 abstract 1
- 108010062085 ligninase Proteins 0.000 abstract 1
- 239000002689 soil Substances 0.000 description 27
- 239000000243 solution Substances 0.000 description 26
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 9
- 230000000694 effects Effects 0.000 description 7
- 102000004190 Enzymes Human genes 0.000 description 6
- 108090000790 Enzymes Proteins 0.000 description 6
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 4
- 241000209094 Oryza Species 0.000 description 4
- 238000010521 absorption reaction Methods 0.000 description 4
- 230000035558 fertility Effects 0.000 description 4
- 235000013305 food Nutrition 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 239000002086 nanomaterial Substances 0.000 description 4
- 235000015097 nutrients Nutrition 0.000 description 4
- 150000002910 rare earth metals Chemical class 0.000 description 4
- 229910021529 ammonia Inorganic materials 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 230000008635 plant growth Effects 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 235000013311 vegetables Nutrition 0.000 description 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 230000003213 activating effect Effects 0.000 description 2
- 238000012271 agricultural production Methods 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 108010051210 beta-Fructofuranosidase Proteins 0.000 description 2
- BDIZXIOWAPGQTJ-UHFFFAOYSA-N bis(2-ethylhexyl) phosphono phosphate Chemical compound CCCCC(CC)COP(=O)(OP(O)(O)=O)OCC(CC)CCCC BDIZXIOWAPGQTJ-UHFFFAOYSA-N 0.000 description 2
- 239000007822 coupling agent Substances 0.000 description 2
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- 235000016709 nutrition Nutrition 0.000 description 2
- 230000035764 nutrition Effects 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- 230000002195 synergetic effect Effects 0.000 description 2
- RFSUNEUAIZKAJO-VRPWFDPXSA-N D-Fructose Natural products OC[C@H]1OC(O)(CO)[C@@H](O)[C@@H]1O RFSUNEUAIZKAJO-VRPWFDPXSA-N 0.000 description 1
- 102100031780 Endonuclease Human genes 0.000 description 1
- 108010042407 Endonucleases Proteins 0.000 description 1
- RFSUNEUAIZKAJO-ARQDHWQXSA-N Fructose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O RFSUNEUAIZKAJO-ARQDHWQXSA-N 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- 229960000892 attapulgite Drugs 0.000 description 1
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 1
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Abstract
The invention provides a nanocarbon organic fertilizer. The nanocarbon organic fertilizer comprises the following components in proper parts by weight: urea, ammonia sulfate, hair, palygorskite, a mercaptosilane and methylacryloyloxysilane mixed solution, a mixture of boron fertilizers and zinc fertilizers in a weight ratio of 1:0.5, ferrous sulfate, rhizobium, azotobacter chroococcum, nanocarbon, rhizoma curculiginis, golden larch bark, radix sophorae flavescentis, ligninase, plant ash, catalase and a rare earth compound, wherein the Si mole ratio of mercaptosilane to methylacryloyloxysilane in the mercaptosilane and methylacryloyloxysilane mixed solution is 1:1, and the concentration of the mixed solution is 1.5-1.8%. The nanocarbon organic fertilizer has the beneficial effects that amino acid is generated by carrying out acid hydrolysis on the hair, and then medium and trace elements are chelated, thus being beneficial for effective utilization of the medium and trace elements; the nanocarbon organic fertilizer is suitable for crops such as wheat, rice, corn, soybeans, rapes and the like, can enhance the capabilities of resisting cold, resisting drought and resisting plant diseases and insect pests, can enhance the tensile force and strength of fibers when used on cotton and linen crops, and obviously increases the yield and the quality.
Description
Technical field
The present invention relates to the organic fertilizer in agricultural, be specifically related to a kind of nano-sized carbon organic fertilizer.
Background technology
Since reform and opening-up, China's agriculture production has obtained significant progress, yet long-term application chemical fertilizer has brought the serious negative issues such as Soil structure destruction, water pollution, utilization rate of fertilizer decline and quality of agricultural product reduction.Current, China's food safety situation is still severe, and the pollution of agricultural-food source ranks first.Soil is the supplier of nutrient, and soil is again that the guarantor of nutrient holds agent, is that other material is irreplaceable, regulate soil, improvement soil, bring up soil, recover soil vitality, demonstrate the natural true qualities of soil, food safety, the only way of human civilization and scientific development.And in agricultural production process, the use of fertilizer is absolutely necessary again, so all the time, people are carrying out the research improvement of fertilizer, and expectation can obtain soil and crop harm very little even harmless, but the fertilizer that can play a significant role in agriculture production.If using of a kind of fertilizer can also improve soil assurance provides nutrition source and guarantees plant growth for crop when, it will be with a wide range of applications.
The fertilizer of the suitability for industrialized production that can accept extensively for vast farmers, makes peasant gladly accept use, to Modern Agricultural is ecological, improves, and promote pollution-less agriculture and produce, be the direction of following fertilizer industry development.
Domestic fertilizer of a great variety, but its utilization ratio is generally lower, is only 30%-40%, this has caused the massive losses of fertilizer, and therefore, how improving utilization rate of fertilizer is problem demanding prompt solution in China's agricultural production process.
Summary of the invention
For overcoming above problem, extend the fertilizer efficiency of fertilizer, increase operation rate, the object of this invention is to provide a kind of nano-sized carbon organic fertilizer.
The present invention solves the problems of the technologies described above adopted technical scheme to be: a kind of nano-sized carbon organic fertilizer, and the weight part of its constitutive material is:
In above-mentioned hydrosulphonyl silane and methacryloxypropyl silane mixing solutions, the Si mol ratio of the two is 1: 1, and the concentration of this mixing solutions is 1.5%-1.8%;
This nano-sized carbon organic fertilizer is by following step preparation method:
(1) by the constitutive material weight part of afore mentioned rules, take each raw material; Cultivate azotobacter chroococcum, in substratum, adding mass percent is the NaCl solution that the sucrose of 95-98% and the concentration of 2-5% are 0.5-2.5g/L, ferments and within 30-40 hour, produces bacterial classification, and the temperature of fermentation is 20-28 ℃, and pH value is 5.0-5.5; Cultivate root nodule bacterium simultaneously, in another substratum, adding mass percent is the NaCl solution that the sucrose of 95-97% and the concentration of 2-4% are 0.5-2.5g/L, and adds 1% sucrase, ferments and within 30-40 hour, produces bacterial classification, the temperature of fermentation is 30-40 ℃, and pH value is 5.5-6.0;
(2) hair is added the 25-35% sulfuric acid that 3-5 doubly measures adjust pH value to 5.5-7.0, and be hydrolyzed 12-18 hour at 40-50 ℃, generate amino acid, then add lime neutralization, every 10 weight part hydrolysis liquid add 2-3 weight part carboxymethyl cellulose in proportion, add again urea, ammonium sulfate, boron fertilizer and zinc fertilizer mixture and ferrous sulfate to dissolve, generate fertilizer liquid;
3) thizoma curculiginis taking, Golden Larch Bark and kuh-seng are pulverized rear mixing, carried out water extraction or alcohol extracting, obtain extract, adopt low-temperature freezing dry extract, dried Chinese medical extract was pulverized to 130-140 mesh sieve, obtain Chinese herbal medicine extract powder; ;
(4) in nano-sized carbon, add hydrosulphonyl silane and methacryloxypropyl silane mixing solutions, with the rotating speed high-speed stirring 1-2 hour of 900-1100r/m;
(5) the rotating speed stirring 1-1.5 hour with 800-850r/m by the product obtaining in plant ash, lignoenzyme, catalase and step (4), fully mixes, and then adding appropriate water mix to become water content is the mixture of 40-45%; Again described mixture is piled up in and in fermentation vat, carries out sealed fermenting 15-20 days; Treat that leavening temperature rises to 40-45 ℃, fall pond once, after having fermented, pour out fermentation vat, at 100-110 ℃, dry, pulverize, cross 85-95 mesh sieve;
(6) product obtaining in above-mentioned steps (1)-(3) and (5) is mixed, rotating speed with 300-600r/m stirs 1.5-2.5 hour, during this period at interval of the polygorskite and the rare earth compound that within 10 minutes, add successively grind into powder, stir rear granulation and obtain finished product, and be dried 1.5-2.5 hour at 55-60 ℃.
Preferably, described rare earth compound is Yttrium trinitrate.
In above-mentioned arbitrary scheme preferably, in above-mentioned steps (1) with, (NH4)
2sO4 solution replaces NaCl solution, and its concentration is 0.05-0.50g/L.
In above-mentioned arbitrary scheme, preferably, the leavening temperature while cultivating azotobacter chroococcum is 25 ℃, and the leavening temperature while cultivating root nodule bacterium is 35 ℃.
In above-mentioned arbitrary scheme, preferably, the diameter of described nano-sized carbon is 1-80nm, and the nano-sized carbon organic fertilizer particle diameter of last gained is 3-5mm.
The major ingredient of hair is keratoprotein, accounts for 97%.And keratoprotein is comprised of amino acid.
Sucrase can become sucrose hydrolysis D-Fructose and D-Glucose, claims again saccharase.Generally, in soil, invertase activity is higher, and fertility is higher, and its activity can characterize the conversion situation of organic carbon in soil indirectly.
Hydrogen peroxide endonuclease capable reduces hydrogen peroxide to soil and biological toxic action, and its activity has substantial connection with aerobic microbiological quantity, soil fertility, and it can represent the intensity of soil oxidising process.
Plant ash can sweetening of the soil acidity, the ground temperature that increases soil, control vegetable sprout term disease and strengthen crop disease-resistant and ability resistant to lodging.Plant ash, because containing 5%～15% potassium element, can provide potassium element.
The nano-sized carbon mixed solution of plant ash, lignoenzyme, catalase and acquisition carries out sealed fermenting after mixing, and has improved raw-material nutrition.
These herbal medicine of thizoma curculiginis, Golden Larch Bark and kuh-seng can effectively strengthen insecticidal effect.
Add polygorskite can improve the utilization ratio of fertilizer, further promote the effect of increasing crop yield.
Nano-carbon rare-earth is desirable ammonia stablizer, and the urea that adds nano-carbon rare-earth can reduce ammonia volatilization amount, and basic controlling is lived the volatilization loss of ammonia.
Beneficial effect of the present invention:
1. the present invention adopts acid hydrolysis hair to generate amino acid, and then centering, trace element carry out chelating, in being conducive to, effective utilization of trace element; Be applicable to the crops such as wheat, paddy rice, corn, soybean, rape, can impel wheat, rice striking root fast, tiller many, resistant to lodgingly, strengthen the ability of cold-resistant, drought resisting and disease and insect resistance; On cotton crudefiber crop, use pulling force and the intensity of energy fortifying fibre, significantly improve output and quality.
2. the nano-sized carbon of small scale, high surface energy activity can strengthen the absorption of plant to fertilizer, improves utilization rate of fertilizer, reduces organic fertilizer loss; Meanwhile, utilize biological enzyme combining nano material, both can guarantee the absorption of enzyme molecule and nano material, increased again the action time of biological enzyme in soil, also improved the utilization ratio of organic fertilizer.
3. nano-carbon rare-earth synergistic fertilizer has good environmental benefit, raising that can be in various degree and the quality of improving food crop, vegetable crop and fruit.
4. the fertilizer of gained had both contained and had enriched active organic composition, can activating soil, and beneficial microorganism quantity is multiplied, vigor strengthens, and after being manured into soil, both can provide immediately plant-growth required available nutrient, can make again that soil improves, soil fertility strengthens.
Embodiment
Below in conjunction with embodiment, the invention will be further described.
Embodiment 1
A nano-sized carbon organic fertilizer, the weight part of its constitutive material is:
In above-mentioned hydrosulphonyl silane and methacryloxypropyl silane mixing solutions, the Si mol ratio of the two is 1: 1, and the concentration of this mixing solutions is 1.8%; The diameter of nano-sized carbon is 1nm;
This nano-sized carbon organic fertilizer is by following step preparation method:
(1) by the constitutive material weight part of afore mentioned rules, take each raw material; Cultivate azotobacter chroococcum, in substratum, adding mass percent is the NaCl solution that the concentration of 98% sucrose and 2% is 2.5g/L, ferments and within 30 hours, produces bacterial classification, and the temperature of fermentation is 28 ℃, and pH value is 5.0; Cultivate root nodule bacterium, in another substratum, adding mass percent is the NaCl solution that the concentration of 97% sucrose and 2% is 2.5g/L, and adds 1% sucrase, ferments and within 30 hours, produces bacterial classification simultaneously, and the temperature of fermentation is 40 ℃, and pH value is 5.5;
(2) hair is added 25% sulfuric acid of 5 times of amounts adjust pH value to 7.0, and at 40 ℃, be hydrolyzed 12 hours, generate amino acid, then add lime neutralization, every 10 weight part hydrolysis liquid add 3 weight part carboxymethyl celluloses in proportion, add again urea, ammonium sulfate, boron fertilizer and zinc fertilizer mixture and ferrous sulfate to dissolve, generate fertilizer liquid;
(3) thizoma curculiginis taking, Golden Larch Bark and kuh-seng are pulverized rear mixing, carried out water extraction or alcohol extracting, obtain extract, adopt low-temperature freezing dry extract, dried Chinese medical extract was pulverized to 130 mesh sieves, obtain Chinese herbal medicine extract powder; ;
(4) in nano-sized carbon, add hydrosulphonyl silane and methacryloxypropyl silane mixing solutions, with the rotating speed high-speed stirring of 1100r/m 2 hours;
(5) by the product obtaining in plant ash, lignoenzyme, catalase and step (4), the rotating speed with 800r/m stirs 1.5 hours, fully mixes, and then adding appropriate water mix to become water content is 40% mixture; Again described mixture is piled up in fermentation vat and carries out sealed fermenting 20 days; Treat that leavening temperature rises to 40 ℃, fall pond once, after having fermented, pour out fermentation vat, at 110 ℃, dry, pulverize, cross 85 mesh sieves;
(6) product obtaining in above-mentioned steps (1)-(3) and (5) is mixed, rotating speed with 600r/m stirs 1.5 hours, during this period at interval of the polygorskite and the rare earth compound that within 10 minutes, add successively grind into powder, stir rear granulation and obtain finished product, and being dried 1.5 hours at 60 ℃, the nano-sized carbon organic fertilizer particle diameter of last gained is 3mm.
Embodiment 2
A nano-sized carbon organic fertilizer, the weight part of its constitutive material is:
In above-mentioned hydrosulphonyl silane and methacryloxypropyl silane mixing solutions, the Si mol ratio of the two is 1: 1, and the concentration of this mixing solutions is 1.5%; The diameter of nano-sized carbon is 80nm;
This nano-sized carbon organic fertilizer is by following step preparation method:
(1) by the constitutive material weight part of afore mentioned rules, take each raw material; Cultivate azotobacter chroococcum, in substratum, adding mass percent is (NH4) that the concentration of 95% sucrose and 5% is 0.05-0.50g/L
2sO4 solution, ferments and within 40 hours, produces bacterial classification, and the temperature of fermentation is 20 ℃, and pH value is 5.5; Cultivate root nodule bacterium, in another substratum, adding mass percent is (NH4) that the concentration of 95% sucrose and 4% is 0.05-O.50g/L simultaneously
2sO4 solution, and add 1% sucrase, to ferment and within 40 hours, produce bacterial classification, the temperature of fermentation is 30 ℃, pH value is 6.O;
(2) hair is added 35% sulfuric acid of 3 times of amounts adjust pH value to 5.5, and at 50 ℃, be hydrolyzed 18 hours, generate amino acid, then add lime neutralization, every 10 weight part hydrolysis liquid add 2 weight part carboxymethyl celluloses in proportion, add again urea, ammonium sulfate, boron fertilizer and zinc fertilizer mixture and ferrous sulfate to dissolve, generate fertilizer liquid;
(3) thizoma curculiginis taking, Golden Larch Bark and kuh-seng are pulverized rear mixing, carried out water extraction or alcohol extracting, obtain extract, adopt low-temperature freezing dry extract, dried Chinese medical extract was pulverized to 140 mesh sieves, obtain Chinese herbal medicine extract powder; ;
(4) in nano-sized carbon, add hydrosulphonyl silane and methacryloxypropyl silane mixing solutions, with the rotating speed high-speed stirring of 900r/m 2 hours;
(5) by the product obtaining in plant ash, lignoenzyme, catalase and step (4), the rotating speed with 850r/m stirs 1 hour, fully mixes, and then adding appropriate water mix to become water content is 45% mixture; Again described mixture is piled up in fermentation vat and carries out sealed fermenting 15 days; Treat that leavening temperature rises to 45 ℃, fall pond once, after having fermented, pour out fermentation vat, at 1OO ℃, dry, pulverize, cross 95 mesh sieves;
(6) product obtaining in above-mentioned steps (1)-(3) and (5) is mixed, rotating speed with 300r/m stirs 2.5 hours, during this period at interval of the polygorskite and the rare earth compound that within 10 minutes, add successively grind into powder, stir rear granulation and obtain finished product, and being dried 2.5 hours at 55 ℃, the nano-sized carbon organic fertilizer particle diameter of last gained is 5mm.
Embodiment 3
A nano-sized carbon organic fertilizer, the weight part of its constitutive material is:
In above-mentioned hydrosulphonyl silane and methacryloxypropyl silane mixing solutions, the Si mol ratio of the two is 1: 1, and the concentration of this mixing solutions is 1.6%; The diameter of nano-sized carbon is 40nm;
This nano-sized carbon organic fertilizer is by following step preparation method:
(1) by the constitutive material weight part of afore mentioned rules, take each raw material; Cultivate azotobacter chroococcum, in substratum, adding mass percent is the NaCl solution that the concentration of 96% sucrose and 4% is 1.0g/L, ferments and within 35 hours, produces bacterial classification, and the temperature of fermentation is 205 ℃, and pH value is 5.3; Cultivate root nodule bacterium, in another substratum, adding mass percent is the NaCl solution that the concentration of 96% sucrose and 3% is 1.5g/L, and adds 1% sucrase, ferments and within 35 hours, produces bacterial classification simultaneously, and the temperature of fermentation is 35 ℃, and pH value is 5.8;
(2) hair is added 30% sulfuric acid of 4 times of amounts adjust pH value to 6.0, and at 45 ℃, be hydrolyzed 15 hours, generate amino acid, then add lime neutralization, every 10 weight part hydrolysis liquid add 3 weight part carboxymethyl celluloses in proportion, add again urea, ammonium sulfate, boron fertilizer and zinc fertilizer mixture and ferrous sulfate to dissolve, generate fertilizer liquid;
(3) thizoma curculiginis taking, Golden Larch Bark and kuh-seng are pulverized rear mixing, carried out water extraction or alcohol extracting, obtain extract, adopt low-temperature freezing dry extract, dried Chinese medical extract was pulverized to 135 mesh sieves, obtain Chinese herbal medicine extract powder; ;
(4) in nano-sized carbon, add hydrosulphonyl silane and methacryloxypropyl silane mixing solutions, with the rotating speed high-speed stirring of 1000r/m 1 hour;
(5) by the product obtaining in plant ash, lignoenzyme, catalase and step (4), the rotating speed with 800r/m stirs 1.5 hours, fully mixes, and then adding appropriate water mix to become water content is 403% mixture; Again described mixture is piled up in fermentation vat and carries out sealed fermenting 18 days; Treat that leavening temperature rises to 43 ℃, fall pond once, after having fermented, pour out fermentation vat, at 100 ℃, dry, pulverize, cross 90 mesh sieves;
(6) product obtaining in above-mentioned steps (1)-(3) and (5) is mixed, rotating speed with 500r/m stirs 2.0 hours, during this period at interval of the polygorskite and the rare earth compound that within 10 minutes, add successively grind into powder, stir rear granulation and obtain finished product, and being dried 2.0 hours at 60 ℃, the nano-sized carbon organic fertilizer particle diameter of last gained is 4mm.
Take corn crop as example, and the contrast of the result of use of nano-sized carbon organic fertilizer result of use of the present invention and existing fertilizer is as shown in the table.
Table 1
The above results represents, the various consumptions in the present invention and concentration and diameter range are all most preferred embodiments, can obtain best effect.
Polygorskite in above-mentioned embodiment can be made by following method: polygorskite is put into high speed mixer with the rotating speed stirring 8-10min of 600-800r/m, the dissolve with ethanol solution dilution NDZ-311 titanate coupling agent that is 40-45% by the concentration of the 1-2% of polygorskite quality, the consumption of NDZ-311 titanate coupling agent is the 5-6% of attapulgite weight, with Sprayable, add in high speed mixer, with discharging after the rotating speed stirring 15-20min of 800-1000r/m, at 120 ℃, dry 15-20min, be ground into powder.
The present invention adopts acid hydrolysis hair to generate amino acid, and then centering, trace element carry out chelating, in being conducive to, effective utilization of trace element; Be applicable to the crops such as wheat, paddy rice, corn, soybean, rape, can impel wheat, rice striking root fast, tiller many, resistant to lodgingly, strengthen the ability of cold-resistant, drought resisting and disease and insect resistance; On cotton crudefiber crop, use pulling force and the intensity of energy fortifying fibre, significantly improve output and quality.
The nano-sized carbon of small scale, high surface energy activity can strengthen the absorption of plant to fertilizer, improves utilization rate of fertilizer, reduces organic fertilizer loss; Meanwhile, utilize biological enzyme combining nano material, both can guarantee the absorption of enzyme molecule and nano material, increased again the action time of biological enzyme in soil, also improved the utilization ratio of organic fertilizer.
Nano-carbon rare-earth synergistic fertilizer has good environmental benefit, raising that can be in various degree and the quality of improving food crop, vegetable crop and fruit.
The fertilizer of gained had both contained and had enriched active organic composition, can activating soil, and beneficial microorganism quantity is multiplied, vigor strengthens, and after being manured into soil, both can provide immediately plant-growth required available nutrient, can make again that soil improves, soil fertility strengthens.
The above, be only preferred embodiment of the present invention, is not the present invention to be done to the restriction of other form, and any those skilled in the art may utilize the technology contents of above-mentioned announcement to be changed or be modified as the equivalent embodiment of equivalent variations.But every technical solution of the present invention content that do not depart from, any simple modification, equivalent variations and the remodeling above embodiment done according to technical spirit of the present invention, still belong to the protection domain of technical solution of the present invention.
Claims (5)
1. a nano-sized carbon organic fertilizer, is characterized in that the weight part of its constitutive material is:
In above-mentioned hydrosulphonyl silane and methacryloxypropyl silane mixing solutions, the Si mol ratio of the two is 1: 1, and the concentration of this mixing solutions is 1.5%-1.8%;
This nano-sized carbon organic fertilizer is by following step preparation method:
(1) by the constitutive material weight part of afore mentioned rules, take each raw material; Cultivate azotobacter chroococcum, in substratum, adding mass percent is the NaCl solution that the sucrose of 95-98% and the concentration of 2-5% are 0.5-2.5g/L, ferments and within 30-40 hour, produces bacterial classification, and the temperature of fermentation is 20-28 ℃, and pH value is 5.0-5.5; Cultivate root nodule bacterium simultaneously, in another substratum, adding mass percent is the NaCl solution that the sucrose of 95-97% and the concentration of 2-4% are 0.5-2.5g/L, and adds 1% sucrase, ferments and within 30-40 hour, produces bacterial classification, the temperature of fermentation is 30-40 ℃, and pH value is 5.5-6.0;
(2) hair is added the 25-35% sulfuric acid that 3-5 doubly measures adjust pH value to 5.5-7.0, and be hydrolyzed 12-18 hour at 40-50 ℃, generate amino acid, then add lime neutralization, every 10 weight part hydrolysis liquid add 2-3 weight part carboxymethyl cellulose in proportion, add again urea, ammonium sulfate, boron fertilizer and zinc fertilizer mixture and ferrous sulfate to dissolve, generate fertilizer liquid;
(3) thizoma curculiginis taking, Golden Larch Bark and kuh-seng are pulverized rear mixing, carried out water extraction or alcohol extracting, obtain extract, adopt low-temperature freezing dry extract, dried Chinese medical extract was pulverized to 130-140 mesh sieve, obtain Chinese herbal medicine extract powder;
(4) in nano-sized carbon, add hydrosulphonyl silane and methacryloxypropyl silane mixing solutions, with the rotating speed high-speed stirring 1-2 hour of 900-1100r/m;
(5) the rotating speed stirring 1-1.5 hour with 800-850r/m by the product obtaining in plant ash, lignoenzyme, catalase and step (4), fully mixes, and then adding appropriate water mix to become water content is the mixture of 40-45%; Again described mixture is piled up in and in fermentation vat, carries out sealed fermenting 15-20 days; Treat that leavening temperature rises to 40-45 ℃, fall pond once, after having fermented, pour out fermentation vat, at 100-110 ℃, dry, pulverize, cross 85-95 mesh sieve;
(6) product obtaining in above-mentioned steps (1)-(3) and (5) is mixed, rotating speed with 300-600r/m stirs 1.5-2.5 hour, during this period at interval of the polygorskite and the rare earth compound that within 10 minutes, add successively grind into powder, stir rear granulation and obtain finished product, and be dried 1.5-2.5 hour at 55-60 ℃.
2. nano-sized carbon organic fertilizer according to claim 1, is characterized in that described rare earth compound is Yttrium trinitrate.
3. nano-sized carbon organic fertilizer according to claim 1 and 2, is characterized in that use, (NH4) 2S04 solution replace NaCl solution in above-mentioned steps (1), and its concentration is 0.05-0.50g/L.
4. nano-sized carbon organic fertilizer according to claim 3, the leavening temperature while it is characterized in that cultivating azotobacter chroococcum is 25 ℃, the leavening temperature while cultivating root nodule bacterium is 35 ℃.
5. nano-sized carbon organic fertilizer according to claim 4, the diameter that it is characterized in that described nano-sized carbon is 1-80nm, the nano-sized carbon organic fertilizer particle diameter of last gained is 3-5mm.
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