CN103721285B - A kind of anion hydrogel air purifies freshener and preparation method thereof - Google Patents
A kind of anion hydrogel air purifies freshener and preparation method thereof Download PDFInfo
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- CN103721285B CN103721285B CN201410016656.2A CN201410016656A CN103721285B CN 103721285 B CN103721285 B CN 103721285B CN 201410016656 A CN201410016656 A CN 201410016656A CN 103721285 B CN103721285 B CN 103721285B
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Abstract
A kind of anion hydrogel air of offer is provided and purifies freshener and preparation method thereof, including following component, with listed as parts by weight for gel: 0.5～1 part, calcium ion aqueous solution: 2～5 parts, anion powder: 2～10 parts, non-volatile antifreezing agent: 2～10 parts, preservative: 0～0.1 part, deionized water: add to 100 parts.The anion hydrogel air of the present invention purifies freshener and does not need to add essence and volatile organic solvent, will not manufacture secondary pollution；By interpolation natural negative ion powder anion releasing, anion and the odor molecules in air and particulate matter effect, remove the abnormal flavour in air, reach to purify the effect of air.
Description
Technical field
The present invention relates to chemical material field, particularly relate to a kind of anion hydrogel air and purify freshener and preparation method thereof.
Background technology
No matter traditional air freshener is aerosol-type, solid gel type or evaporates type, is substantially all containing the composition such as volatile solvent and essence.During use, volatile solvent helps essence to distribute together to air, and with fragrance covering smell, resolving harmful gas, does not reach the purpose of fresh air.But these volatile solvents and essence, or some composition inherently air pollutants produced after chemolysis in atmosphere, be substantially the pollution level of aggravation air, and people is known from experience generation pessimal stimulation by life-time service.The nervous system of people, respiratory system even can be produced harm by the aromatic contained in some air freshener, such as, can stimulate the respiratory mucosa etc. of child.Traditional air freshener is in order to ensure stablizing of air freshener, it is necessary to adding preservative, preservative also can in use be discharged in the middle of air, manufactures second time and pollutes, and harmful.
In sum, in existing air purification agent field, lack a kind of without perfume, safety non-toxic, the air purification agent product of air odor molecules can be removed.
Summary of the invention
In order to solve problem above, a kind of anion hydrogel air of offer is provided and purifies freshener and preparation method thereof.The anion hydrogel air of the present invention purifies freshener and does not need to add essence and volatile organic solvent, will not manufacture secondary pollution；By interpolation natural negative ion powder anion releasing, anion and the odor molecules in air and particulate matter effect, remove the abnormal flavour in air, reach to purify the effect of air；The product of interpolation anion can add less and even not add preservative, utilizes the bactericidal property of anion, carries out self-preserving.
A kind of anion hydrogel air purifies freshener, with listed as parts by weight, including following components: gel: 0.5～1 part, calcium ion aqueous solution: 2～5 parts, anion powder: 2～10 parts, non-volatile antifreezing agent: 2～10 parts, preservative: 0～0.1 part, deionized water: add to 100 parts.
Preferably, preservative selected from be in Methylisothiazolinone, chlormethylisothiazo,ine ketone, benzene isothiazolone, benzyl alcohol, phenoxyethanol, poly hexamethylene biguanide one or more mixing.
Preferably, described non-volatile antifreezing agent one or more mixing in ethylene glycol, propylene glycol, glycerol.
Preferably, anion hydrogel air purifies freshener formula, with listed as parts by weight, including: gel: 0.8 part, anion powder: 5 parts, calcium ion aqueous solution: 2～3.5 parts, non-volatile antifreezing agent: 2～10 parts, preservative: 0.1 part, deionized water: add to 100 parts.
Preferably, anion hydrogel air purifies freshener formula, with listed as parts by weight, including: gel: 0.8 part, anion powder: 2 parts, calcium ion aqueous solution: 3.5 parts, propylene glycol: 5 parts, deionized water: 88.7 parts.
Preferably, anion hydrogel air purifies freshener formula, with listed as parts by weight, including: gel: 0.8 part, anion powder: 10 parts, calcium ion aqueous solution: 3.5 parts, propylene glycol: 5 parts, deionized water: 80.7 parts.
Preferably, described calcium ion aqueous solution is mass concentration is the calcium chloride water of 1%.
Preferably, the described gel one or more mixing in gellan gum, carrageenan, locust bean gum, sodium alginate.
The present invention also provides for the preparation method that a kind of anion hydrogel air purifies freshener, and it comprises the following steps:
1) after weighing material by proportioning, gel mixes with deionized water, is heated with stirring to 85～95 DEG C, continues heating to gel and is completely dissolved；
2) calcium ion aqueous solution is added in mixed liquor, be incubated after being cooled to 55～65 DEG C after stirring；
3) add non-volatile antifreezing agent, anion powder to mixed liquor, stir successively；
4) it is cooled to room temperature.
Preferably, the anion hydrogel air that the present invention contains preservative purifies freshener, synchronizes to add in the 3rd step and non-volatile antifreezing agent, anion powder, stirs.
The anion hydrogel air of the present invention purifies freshener and has following notable beneficial effect:
Natural mineral matter anion powder energy anion releasing, anion is mobile in atmosphere presents " Z " font, and carry negative charge to antibacterial, dust, smoke particles and water droplet etc., this microgranule of electric charge and this combines and is polymerized to ball and sinks, thus reaching to purify the purpose of air.The energy and anion has microbe killing properties, can carry out self-preserving.By adjusting the concentration of anion powder, to reach good to press down bactericidal effect, thus product also can add preservative less, even do not add preservative.Gel be heated swelling after, under the effect of calcium ion, after cooling, form gel carrier with hydrone, anion is played the effect of slow release by this gel, not only protects the service life of product of the present invention, and air purification effect is extended.Adjust the consumption of calcium ion aqueous solution, to adjust the concentration of calcium ion to obtain the gel of required intensity.Adjusting the consumption of non-volatile antifreezing agent, change the freeze proof temperature of described gel to reach the freeze proof demand of different demand, gel all can keep colloidal state, will not freeze because the too low colloid of temperature precipitates out substantial amounts of water, affect result of use.
The anion hydrogel air of the present invention purifies freshener and becomes to be grouped into without adding volatile solvent, essence etc., does not result in secondary pollution, lowers the stimulation to user and harm.
Detailed description of the invention
The present invention will be further described by the examples below, and it limits the scope of the invention only for purpose of being best understood from present disclosure.
Specific embodiment 1
Weigh llowing group of materials in proportion: gellan gum: 0.5 part, anion powder: 5 parts, 1% calcium chloride water: 2 parts, propylene glycol: 2 parts, Methylisothiazolinone: 0.1 part, deionized water: 90.4 parts.First gellan gum is mixed with deionized water, it is heated with stirring to 90 DEG C, continue heating to gellan gum to be completely dissolved, again 1% calcium chloride water is added in mixed liquor, it is incubated after being cooled to 60 DEG C after stirring, then add propylene glycol, anion powder, Methylisothiazolinone to mixed liquor successively, stir, be finally cooled to room temperature.
Specific embodiment 2
Weigh llowing group of materials in proportion: gellan gum: 0.4 part, carrageenan: 0.4 part, anion powder: 2 parts, 0.75% calcium chloride water: 5 parts, propylene glycol: 5 parts, Methylisothiazolinone: 0.03 part, benzene isothiazolone: 0.02 part, deionized water: 87.15 parts.First gellan gum and carrageenan are mixed with deionized water, it is heated with stirring to 85 DEG C, continue heating to gellan gum and carrageenan to be completely dissolved, again 0.75% calcium chloride water is added in mixed liquor, it is incubated after being cooled to 65 DEG C after stirring, then adds propylene glycol, anion powder, Methylisothiazolinone, benzene isothiazolone to mixed liquor successively, stir, be finally cooled to room temperature.
Specific embodiment 3
Weigh llowing group of materials in proportion: carrageenan: 0.8 part, gellan gum: 0.2 part, anion powder: 7.5 parts, 1% calcium lactate aqueous solution: 3.5 parts, propylene glycol: 5 parts, glycerol: 5 parts, deionized water: 78 parts.First carrageenan and gellan gum are mixed with deionized water, it is heated with stirring to 95 DEG C, continue heating to carrageenan and gellan gum to be completely dissolved, again 1% calcium lactate aqueous solution is added in mixed liquor, it is incubated after being cooled to 55 DEG C after stirring, then add propylene glycol, glycerol, anion powder to mixed liquor successively, stir, be finally cooled to room temperature.
Specific embodiment 4
Weigh llowing group of materials in proportion: gellan gum: 0.8 part, anion powder: 5 parts, 0.5% calcium chloride water: 7 parts, propylene glycol: 10 parts, benzyl alcohol: 0.03 part, phenoxyethanol: 0.03 part, poly hexamethylene biguanide: 0.04 part, deionized water: 77.1 parts.First gellan gum is mixed with deionized water, it is heated with stirring to 90 DEG C, continue heating to gellan gum to be completely dissolved, again 0.5% calcium chloride water is added in mixed liquor, it is incubated after being cooled to 65 DEG C after stirring, then add propylene glycol, anion powder, benzyl alcohol, phenoxyethanol, poly hexamethylene biguanide to mixed liquor successively, stir, be finally cooled to room temperature.
Specific embodiment 5
Weigh llowing group of materials in proportion: locust bean gum: 0.8 part, anion powder: 5 parts, 0.65% calcium chloride water: 3.5 parts, ethylene glycol: 10 parts, benzyl alcohol: 0.09 part, phenoxyethanol: 0.01 part, deionized water: 80.6 parts.First locust bean gum is mixed with deionized water, it is heated with stirring to 88 DEG C, continue heating to locust bean gum to be completely dissolved, again 0.65% calcium chloride water is added in mixed liquor, it is incubated after being cooled to 63 DEG C after stirring, then add ethylene glycol, anion powder, benzyl alcohol, phenoxyethanol to mixed liquor successively, stir, be finally cooled to room temperature.
Specific embodiment 6
Weigh llowing group of materials in proportion: locust bean gum: 0.6, sodium alginate: 0.4 part, anion powder: 5 parts, 0.85% calcium chloride water: 3.5 parts, ethylene glycol: 7 parts, phenoxyethanol: 0.1 part, deionized water: 83.4 parts.First locust bean gum and sodium alginate are mixed with deionized water, it is heated with stirring to 93 DEG C, continue heating to locust bean gum and sodium alginate to be completely dissolved, again 0.85% calcium chloride water is added in mixed liquor, it is incubated after being cooled to 58 DEG C after stirring, then add ethylene glycol, anion powder, phenoxyethanol to mixed liquor successively, stir, be finally cooled to room temperature.
Specific embodiment 7
Weigh llowing group of materials in proportion: carrageenan: 0.8 part, anion powder: 2 parts, 1% calcium lactate aqueous solution: 3.5 parts, propylene glycol: 5 parts, deionized water: 88.7 parts.First carrageenan is mixed with deionized water, it is heated with stirring to 95 DEG C, continue heating to carrageenan to be completely dissolved, again 1% calcium lactate aqueous solution is added in mixed liquor, it is incubated after being cooled to 55 DEG C after stirring, then add propylene glycol, anion powder to mixed liquor, stir successively, be finally cooled to room temperature.
Specific embodiment 8
Weigh llowing group of materials in proportion: gellan gum: 0.8 part, anion powder: 10 parts, 1% calcium chloride water: 3.5 parts, propylene glycol: 5 parts, deionized water: 80.7 parts.First gellan gum is mixed with deionized water, it is heated with stirring to about 85 DEG C, continue heating to gellan gum to be completely dissolved, again 1% calcium chloride water is added in mixed liquor, it is incubated after being cooled to 60 DEG C after stirring, then add propylene glycol, anion powder to mixed liquor, stir successively, be finally cooled to room temperature.
Specific embodiment 9
Following test is using ammonia as air pollution source, carry out 4 tests, comparison does not use the anion hydrogel air of the present invention to purify freshener, the anion hydrogel air using embodiments of the invention 1 purified freshener after 2 hours, except ammonia rate reaches 98.59%, minimum also reach 97.91%, effectively remove the pollutant in air.
Table 1., using ammonia as air pollution source, removes ammonia experimental result in 2 hours
Specific embodiment 10
The anion hydrogel air illustrating specific embodiment 7 and specific embodiment 8 in table 2 purifies the respective fungistatic effect of freshener.After 14 days, use the mycete of specific embodiment 7 to begin with and be remarkably decreased, after 14 days, add an order of magnitude than the concentration of initial mycete, effectively control the breeding of mycete；The mycete using specific embodiment 8 controls more significantly, and when anion powder concentration is added into 10%, the concentration of mycete is after 14 days, and still little 2 orders of magnitude than initial concentration, press down bactericidal property very superior.The increase of anion weight portion can increase the effect of antiseptic and inhibiting bacteria function, thus according to needing without preservative or adding preservative less.
The anion hydrogel air of table 2. specific embodiment 7 and specific embodiment 8 purifies the fungistatic effect of freshener
The announcement of book and instruction according to the above description, above-mentioned embodiment can also be modified and revise by those skilled in the art in the invention.Therefore, the invention is not limited in detailed description of the invention disclosed and described above, should also be as some modifications and changes of the present invention falling in the scope of the claims of the present invention.Although additionally, employ some specific terms in this specification, but these terms are intended merely to convenient explanation, and the present invention does not constitute any restriction.
Claims (9)
1. an anion hydrogel air purifies freshener, it is characterized in that, with listed as parts by weight, including following components: gel: 0.5～1 part, calcium ion aqueous solution: 2～5 parts, anion powder: 2～10 parts, non-volatile antifreezing agent: 2～10 parts, preservative: 0～0.1 part, deionized water: add to 100 parts, the gel one or more mixing in gellan gum, carrageenan, locust bean gum, sodium alginate.
2. anion hydrogel air according to claim 1 purifies freshener, it is characterised in that one or more mixing in Methylisothiazolinone, chlormethylisothiazo,ine ketone, benzene isothiazolone, benzyl alcohol, phenoxyethanol, poly hexamethylene biguanide of described preservative.
3. anion hydrogel air according to claim 1 purifies freshener, it is characterised in that one or more mixing in ethylene glycol, propylene glycol, glycerol of described non-volatile antifreezing agent.
4. anion hydrogel air according to claim 1 purifies freshener, it is characterized in that, described anion hydrogel air purifies freshener formula, with listed as parts by weight, including: gel: 0.8 part, anion powder: 5 parts, calcium ion aqueous solution: 2～3.5 parts, non-volatile antifreezing agent: 2～10 parts, preservative: 0.1 part, deionized water: add to 100 parts.
5. anion hydrogel air according to claim 1 purifies freshener, it is characterized in that, described anion hydrogel air purifies freshener formula, with listed as parts by weight, including: gel: 0.8 part, anion powder: 2 parts, calcium ion aqueous solution: 3.5 parts, propylene glycol: 5 parts, deionized water: 88.7 parts.
6. anion hydrogel air according to claim 1 purifies freshener, it is characterized in that, described anion hydrogel air purifies freshener formula, with listed as parts by weight, including: gel: 0.8 part, anion powder: 10 parts, calcium ion aqueous solution: 3.5 parts, propylene glycol: 5 parts, deionized water: 80.7 parts.
7. the anion hydrogel air according to any one of claim 1-6 purifies freshener, it is characterised in that described calcium ion aqueous solution is mass concentration is the calcium chloride water of 1%.
8. the preparation method that an anion hydrogel air as claimed in claim 1 purifies freshener, it is characterised in that comprise the following steps:
A, weigh material by proportioning after, gel mixes with deionized water, is heated with stirring to 85～95 DEG C, continues heating and is completely dissolved to gel；
B, calcium ion aqueous solution is added in mixed liquor, be incubated after being cooled to 55～65 DEG C after stirring；
C, successively to mixed liquor add non-volatile antifreezing agent, anion powder, stir；
D, it is cooled to room temperature.
9. the preparation method that an anion hydrogel air as claimed in claim 8 purifies freshener, it is characterised in that add preservative in step c.
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| CN201410016656.2A CN103721285B (en) | 2014-01-14 | 2014-01-14 | A kind of anion hydrogel air purifies freshener and preparation method thereof |
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| CN108159465A (en) * | 2018-01-24 | 2018-06-15 | 合肥华盖生物科技有限公司 | One kind de-tastes antibacterial air freshener of flavouring and preparation method thereof |
| CN110585467A (en) * | 2019-09-25 | 2019-12-20 | 深圳市绿安居科技有限公司 | Air purification gel composition and preparation method thereof |
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| CN102091337A (en) * | 2010-09-08 | 2011-06-15 | 成进学 | Nano tourmaline and fragrant flower essential oil air freshening aromatizer |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN102091337A (en) * | 2010-09-08 | 2011-06-15 | 成进学 | Nano tourmaline and fragrant flower essential oil air freshening aromatizer |
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