CN103651414A - Fungicidal composition containing fluoro-azole acibenzolar and methoxyl acrylate - Google Patents
Fungicidal composition containing fluoro-azole acibenzolar and methoxyl acrylate Download PDFInfo
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- CN103651414A CN103651414A CN201210355378.4A CN201210355378A CN103651414A CN 103651414 A CN103651414 A CN 103651414A CN 201210355378 A CN201210355378 A CN 201210355378A CN 103651414 A CN103651414 A CN 103651414A
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- Prior art keywords
- fluorine
- azoles acibenzolar
- acibenzolar
- active component
- fluorine azoles
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- CGIHPACLZJDCBQ-UHFFFAOYSA-N acibenzolar Chemical compound SC(=O)C1=CC=CC2=C1SN=N2 CGIHPACLZJDCBQ-UHFFFAOYSA-N 0.000 title claims abstract description 98
- 239000000203 mixture Substances 0.000 title claims abstract description 43
- CVCDRFTUJQLDOH-UHFFFAOYSA-N 2-fluoro-1h-pyrrole Chemical compound FC1=CC=CN1 CVCDRFTUJQLDOH-UHFFFAOYSA-N 0.000 title abstract 3
- 230000000855 fungicidal effect Effects 0.000 title abstract 3
- BSDQITJYKQHXQR-UHFFFAOYSA-N methyl prop-2-eneperoxoate Chemical compound COOC(=O)C=C BSDQITJYKQHXQR-UHFFFAOYSA-N 0.000 title abstract 2
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 claims abstract description 47
- 201000010099 disease Diseases 0.000 claims abstract description 45
- 239000005762 Dimoxystrobin Substances 0.000 claims abstract description 20
- 239000005800 Kresoxim-methyl Substances 0.000 claims abstract description 20
- WXUZAHCNPWONDH-DYTRJAOYSA-N dimoxystrobin Chemical compound CNC(=O)C(=N\OC)\C1=CC=CC=C1COC1=CC(C)=CC=C1C WXUZAHCNPWONDH-DYTRJAOYSA-N 0.000 claims abstract description 20
- ZOTBXTZVPHCKPN-HTXNQAPBSA-N kresoxim-methyl Chemical compound CO\N=C(\C(=O)OC)C1=CC=CC=C1COC1=CC=CC=C1C ZOTBXTZVPHCKPN-HTXNQAPBSA-N 0.000 claims abstract description 20
- JHIPUJPTQJYEQK-ZLHHXESBSA-N orysastrobin Chemical compound CNC(=O)C(=N\OC)\C1=CC=CC=C1CO\N=C(/C)\C(=N\OC)\C(\C)=N\OC JHIPUJPTQJYEQK-ZLHHXESBSA-N 0.000 claims abstract description 20
- WHDHEVMINMZADQ-UHFFFAOYSA-N [F].N1C=CC=C1 Chemical class [F].N1C=CC=C1 WHDHEVMINMZADQ-UHFFFAOYSA-N 0.000 claims description 87
- 150000003851 azoles Chemical class 0.000 claims description 30
- 239000000375 suspending agent Substances 0.000 claims description 25
- 241000894006 Bacteria Species 0.000 claims description 19
- 150000002148 esters Chemical class 0.000 claims description 19
- 239000005784 Fluoxastrobin Substances 0.000 claims description 18
- UFEODZBUAFNAEU-NLRVBDNBSA-N fluoxastrobin Chemical compound C=1C=CC=C(OC=2C(=C(OC=3C(=CC=CC=3)Cl)N=CN=2)F)C=1C(=N/OC)\C1=NOCCO1 UFEODZBUAFNAEU-NLRVBDNBSA-N 0.000 claims description 18
- 230000000844 anti-bacterial effect Effects 0.000 claims description 16
- 235000007164 Oryza sativa Nutrition 0.000 claims description 15
- 241000233679 Peronosporaceae Species 0.000 claims description 15
- 235000009566 rice Nutrition 0.000 claims description 15
- 239000003094 microcapsule Substances 0.000 claims description 14
- 239000000839 emulsion Substances 0.000 claims description 13
- 241000221785 Erysiphales Species 0.000 claims description 11
- 229910052731 fluorine Inorganic materials 0.000 claims description 10
- 239000011737 fluorine Substances 0.000 claims description 10
- 239000000843 powder Substances 0.000 claims description 10
- 238000009736 wetting Methods 0.000 claims description 10
- 206010039509 Scab Diseases 0.000 claims description 9
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 7
- 239000000725 suspension Substances 0.000 claims description 7
- 239000004530 micro-emulsion Substances 0.000 claims description 6
- 239000004562 water dispersible granule Substances 0.000 claims description 6
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 5
- 241001530056 Athelia rolfsii Species 0.000 claims description 4
- 241000582441 Peronospora tabacina Species 0.000 claims description 4
- 230000035613 defoliation Effects 0.000 claims description 4
- 125000001153 fluoro group Chemical group F* 0.000 claims 3
- 240000007594 Oryza sativa Species 0.000 claims 1
- 230000002195 synergetic effect Effects 0.000 abstract description 27
- 239000000575 pesticide Substances 0.000 abstract description 15
- 239000005730 Azoxystrobin Substances 0.000 abstract description 2
- 206010059866 Drug resistance Diseases 0.000 abstract description 2
- 238000012271 agricultural production Methods 0.000 abstract description 2
- 150000001875 compounds Chemical class 0.000 abstract description 2
- 230000007613 environmental effect Effects 0.000 abstract description 2
- 238000003912 environmental pollution Methods 0.000 abstract description 2
- 239000004480 active ingredient Substances 0.000 abstract 6
- WFDXOXNFNRHQEC-GHRIWEEISA-N azoxystrobin Chemical compound CO\C=C(\C(=O)OC)C1=CC=CC=C1OC1=CC(OC=2C(=CC=CC=2)C#N)=NC=N1 WFDXOXNFNRHQEC-GHRIWEEISA-N 0.000 abstract 1
- 244000144972 livestock Species 0.000 abstract 1
- HIIRDDUVRXCDBN-OBGWFSINSA-N metominostrobin Chemical compound CNC(=O)C(=N\OC)\C1=CC=CC=C1OC1=CC=CC=C1 HIIRDDUVRXCDBN-OBGWFSINSA-N 0.000 abstract 1
- URXNNPCNKVAQRA-XMHGGMMESA-N pyraoxystrobin Chemical compound CO\C=C(\C(=O)OC)C1=CC=CC=C1COC1=CC(C=2C=CC(Cl)=CC=2)=NN1C URXNNPCNKVAQRA-XMHGGMMESA-N 0.000 abstract 1
- 238000012360 testing method Methods 0.000 description 52
- 239000002131 composite material Substances 0.000 description 41
- 239000003814 drug Substances 0.000 description 32
- 230000003449 preventive effect Effects 0.000 description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 20
- 241000209094 Oryza Species 0.000 description 14
- 239000008367 deionised water Substances 0.000 description 14
- 229910021641 deionized water Inorganic materials 0.000 description 14
- 239000012071 phase Substances 0.000 description 14
- 239000002270 dispersing agent Substances 0.000 description 13
- 239000013530 defoamer Substances 0.000 description 12
- 240000008067 Cucumis sativus Species 0.000 description 11
- 235000010799 Cucumis sativus var sativus Nutrition 0.000 description 11
- 239000003995 emulsifying agent Substances 0.000 description 10
- 230000002528 anti-freeze Effects 0.000 description 9
- 239000000470 constituent Substances 0.000 description 9
- 239000000080 wetting agent Substances 0.000 description 9
- 238000000034 method Methods 0.000 description 8
- 239000002904 solvent Substances 0.000 description 8
- 239000002562 thickening agent Substances 0.000 description 8
- 238000002474 experimental method Methods 0.000 description 7
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- 231100000820 toxicity test Toxicity 0.000 description 7
- 206010067482 No adverse event Diseases 0.000 description 6
- 238000004458 analytical method Methods 0.000 description 6
- 229940079593 drug Drugs 0.000 description 6
- 238000011835 investigation Methods 0.000 description 6
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- 241000227653 Lycopersicon Species 0.000 description 5
- 235000007688 Lycopersicon esculentum Nutrition 0.000 description 5
- 230000010165 autogamy Effects 0.000 description 5
- 235000020971 citrus fruits Nutrition 0.000 description 5
- 208000031513 cyst Diseases 0.000 description 5
- 235000013399 edible fruits Nutrition 0.000 description 5
- 229920002521 macromolecule Polymers 0.000 description 5
- 241000223600 Alternaria Species 0.000 description 4
- 241000510928 Erysiphe necator Species 0.000 description 4
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- 238000009472 formulation Methods 0.000 description 4
- 239000003002 pH adjusting agent Substances 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 241000196324 Embryophyta Species 0.000 description 3
- 239000013543 active substance Substances 0.000 description 3
- 230000008485 antagonism Effects 0.000 description 3
- 239000008346 aqueous phase Substances 0.000 description 3
- 238000000498 ball milling Methods 0.000 description 3
- 239000011230 binding agent Substances 0.000 description 3
- 239000007884 disintegrant Substances 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 241000219112 Cucumis Species 0.000 description 2
- 235000015510 Cucumis melo subsp melo Nutrition 0.000 description 2
- FJJCIZWZNKZHII-UHFFFAOYSA-N [4,6-bis(cyanoamino)-1,3,5-triazin-2-yl]cyanamide Chemical compound N#CNC1=NC(NC#N)=NC(NC#N)=N1 FJJCIZWZNKZHII-UHFFFAOYSA-N 0.000 description 2
- 239000003905 agrochemical Substances 0.000 description 2
- 239000012752 auxiliary agent Substances 0.000 description 2
- 239000003899 bactericide agent Substances 0.000 description 2
- 235000013339 cereals Nutrition 0.000 description 2
- 210000003608 fece Anatomy 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 238000005469 granulation Methods 0.000 description 2
- 230000003179 granulation Effects 0.000 description 2
- 230000009036 growth inhibition Effects 0.000 description 2
- 230000001939 inductive effect Effects 0.000 description 2
- 235000021374 legumes Nutrition 0.000 description 2
- 239000010871 livestock manure Substances 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 238000010008 shearing Methods 0.000 description 2
- 230000001954 sterilising effect Effects 0.000 description 2
- 238000004659 sterilization and disinfection Methods 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 230000001988 toxicity Effects 0.000 description 2
- 231100000419 toxicity Toxicity 0.000 description 2
- 230000001018 virulence Effects 0.000 description 2
- YBNQFFSHDBUNAA-UHFFFAOYSA-N 2,3,4-trifluoro-1h-pyrrole Chemical class FC1=CNC(F)=C1F YBNQFFSHDBUNAA-UHFFFAOYSA-N 0.000 description 1
- UXPRZZZNGFVXRR-UHFFFAOYSA-N 2,3-difluoro-1h-pyrrole Chemical class FC=1C=CNC=1F UXPRZZZNGFVXRR-UHFFFAOYSA-N 0.000 description 1
- 208000031968 Cadaver Diseases 0.000 description 1
- 241000222290 Cladosporium Species 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- -1 azoxystrobin compound Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000000825 pharmaceutical preparation Substances 0.000 description 1
- 244000144977 poultry Species 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a fungicidal composition containing fluoro-azole acibenzolar and methoxyl acrylate. The fungicidal composition contains an active ingredient A and an active ingredient B, wherein the active ingredient A is selected from fluoro-azole acibenzolar, the active ingredient B is any compound selected from azoxystrobin, kresoxim-methyl, dimoxystrobin, orysastrobin, metominostrobin and pyraoxystrobin, and the weight ratio of the active ingredient A to the active ingredient B is (1: 80) to (60: 1). The composition disclosed by the invention has a synergistic effect on a variety of diseases which endanger agricultural production, so that the pesticide dosage is reduced, the residual quantity of the pesticide on crops is reduced, the environmental pollution is alleviated, the composition is safe to human and livestock, the environmental compatibility is good, and the drug resistance for the diseases is difficult to generate.
Description
Technical field
The invention belongs to technical field of pesticide, the application of the bactericidal composition that relates to a kind of fluorine-containing azoles Acibenzolar and methoxy acrylic on corps diseases.
Background technology
Fluorine azoles Acibenzolar is a class novel plant inducing anti-disease activator, and this compounds itself does not have bactericidal activity, and can produce infecting the resistance of germ by inducing plant on live plant.
Fluoxastrobin, kresoxim-methyl, dimoxystrobin, orysastrobin, SSF 126, azoles bacterium ester all belong to methoxy acrylic bactericide, are widely used in the disease of crops.
Yet in the real process of agricultural production, preventing and treating the problem that disease the most easily produces is the generation of disease drug resistance.Different cultivars composition carries out composite, is to prevent and treat the very common method of resistance disease.Heterogeneity is carried out composite, according to practical application effect, judge certain composite be synergy, add and or antagonism.In most cases, the composite effect of sterilization is all additive effect, really has the seldom composite of synergistic effect, especially synergistic effect very obviously, synergy ratio very high composite just still less.Through inventor's research, after discovery is composite by fluorine azoles Acibenzolar and Fluoxastrobin, kresoxim-methyl, dimoxystrobin, orysastrobin, SSF 126, azoles bacterium ester, can produce good synergistic effect, and not yet open about the composite relevant report of fluorine azoles Acibenzolar and Fluoxastrobin, kresoxim-methyl, dimoxystrobin, orysastrobin, SSF 126, azoles bacterium ester.
Summary of the invention
The object of the invention is to propose a kind of have synergistic function, use cost is low, preventive effect is good fluorine-containing azoles Acibenzolar and the bactericidal composition of methoxy acrylic.
The fluorine-containing azoles Acibenzolar that the present invention proposes and the bactericidal composition of methoxy acrylic contain active components A and active component B, active components A and active component B weight ratio are 1 ︰ 80 ~ 60 ︰ 1, described active components A is selected from fluorine azoles Acibenzolar, active component B is selected from a kind of in Fluoxastrobin, kresoxim-methyl, dimoxystrobin, orysastrobin, SSF 126, azoles bacterium ester, and active components A and the preferred weight ratio of active component B are 1 ︰ 60 ~ 40 ︰ 1; More preferably the weight ratio of fluorine azoles Acibenzolar and Fluoxastrobin or kresoxim-methyl is 1 ︰ 30 ~ 10 ︰ 1, the weight ratio of fluorine azoles Acibenzolar and dimoxystrobin or orysastrobin is 1 ︰ 30 ~ 20 ︰ 1, the weight ratio of fluorine azoles Acibenzolar and SSF 126 is 1 ︰ 35 ~ 10 ︰ 1, and the weight ratio of fluorine azoles Acibenzolar and azoles bacterium ester is 1 ︰ 25 ~ 20 ︰ 1; The weight ratio that most preferably is fluorine azoles Acibenzolar and Fluoxastrobin or kresoxim-methyl is 1 ︰ 15 ~ 1 ︰ 4, the weight ratio of fluorine azoles Acibenzolar and dimoxystrobin or orysastrobin is 1 ︰ 12 ~ 1 ︰ 1, the weight ratio of fluorine azoles Acibenzolar and SSF 126 is 1 ︰ 19 ~ 1 ︰ 9, and the weight ratio of fluorine azoles Acibenzolar and azoles bacterium ester is 1 ︰ 9 ~ 1 ︰ 1
The fluorine-containing azoles Acibenzolar that the present invention proposes and the bactericidal composition of methoxy acrylic are for preventing and treating the purposes of disease on crops, and described crops comprise cereal crops, legume crop, fiber crop, sugar [yielding, melon crop, fruits crop, dry fruit crop, hobby crop, root crop, oil crop, flowers crop, medicinal crop, raw material crop, green manure pasture crop; Described disease comprises powdery mildew, downy mildew, epidemic disease, leaf mold, shot hole, scab, peronospora tabacina, anthracnose, spot defoliation, rust, rice blast, banded sclerotial blight, brown spot.
The weight ratio of active components A, active component B is 1 ︰ 80 ~ 60 ︰ 1.Conventionally in composition, the weight percentage of active component is gross weight 0.5%～90%, is preferably 5%～80%.According to different preparation types, active component content scope is different.Conventionally, liquid preparation contains 1%～70% active substance by weight, is preferably 5%～50%; Solid pharmaceutical preparation contains 5%～80% active substance by weight, is preferably 10%～80%.
In bactericidal composition of the present invention, at least contain a kind of surfactant, the dispersion of active component in water while being beneficial to use.Surface-active contents is 5%～30% of total formulation weight amount, and surplus is solid or liquid diluent.
Bactericidal composition of the present invention can be by user before use through dilution or directly use.Its preparation can be prepared by common processing method known in those skilled in the art, after being about to active substance and mixing with liquid flux or solid carrier, then add surfactant as one or more in dispersant, stabilizing agent, wetting agent, binding agent, defoamer, disintegrant, antifreeze etc.
Bactericidal composition of the present invention, can be processed on demand acceptable formulation in any sterilization, wherein more preferably formulation is wetting powder, water dispersible granules, suspending agent, suspension emulsion, aqueous emulsion, microemulsion, microcapsule suspending agent, microcapsule suspension-suspending agent.
When making wetting powder, composition comprises following constituent content: active components A 1% ~ 60%, active component B1% ~ 80%, dispersant 2% ~ 10%, wetting agent 2% ~ 10%, filler surplus.
When making water dispersible granules, composition comprises following constituent content: active components A 1% ~ 60%, active component B1% ~ 80%, dispersant 3% ~ 12%, wetting agent 1% ~ 8%, disintegrant 1% ~ 10%, binding agent 0 ~ 8%, filler surplus.
When making suspending agent, composition comprises following constituent content: active components A 0.5% ~ 50%, active component B0.5% ~ 50%, dispersant 2% ~ 10%, wetting agent 2% ~ 10%, defoamer 0.01% ~ 2%, thickener 0 ~ 2%, antifreeze 0 ~ 8%, deionized water add to 100%.
When making suspension emulsion, composition comprises following constituent content: active components A 0.5% ~ 50%, active component B0.5% ~ 50%, dispersant 2% ~ 10%, defoamer 0.01% ~ 2%, solvent 1% ~ 15%, thickener 0 ~ 2%, emulsifier 2% ~ 12%, antifreeze 0 ~ 8%, deionized water add to 100%.
When making aqueous emulsion, composition comprises following constituent content: active components A 0.5% ~ 50%, active component B0.5% ~ 50%, solvent 1% ~ 30%, emulsifier 1% ~ 15%, antifreeze 0 ~ 8%, thickener 0 ~ 2%, defoamer 0.01% ~ 2%, deionized water are supplied surplus.
When making microemulsion, composition comprises following constituent content: active components A 0.5% ~ 50%, active component B0.5% ~ 50%, solvent 1% ~ 30%, emulsifier 3% ~ 25%, antifreeze 0 ~ 8%, defoamer 0.01% ~ 2%, deionized water are supplied surplus.
When making microcapsule suspending agent, composition comprises following constituent content: active components A 0.5% ~ 50%, active component B0.5% ~ 50%, macromolecule cyst material 2% ~ 10%, dispersant 1% ~ 10%, organic solvent 1% ~ 10%, emulsifier 1% ~ 7%, defoamer 0.01% ~ 2%, pH adjusting agent 0.01% ~ 5%, deionized water add to 100%.
When making microcapsule suspension-suspending agent, composition comprises following constituent content: active components A 0.5% ~ 50%, active component B0.5% ~ 50%, macromolecule cyst material 2% ~ 10%, dispersant 1% ~ 12%, wetting agent 1% ~ 8%, organic solvent 1% ~ 15%, emulsifier 1% ~ 6%, defoamer 0.01% ~ 2%, thickener 0 ~ 2%, pH adjusting agent 0.01% ~ 5%, deionized water add to 100%;
Wetting powder the key technical indexes of the present invention:
Water dispersible granules the key technical indexes of the present invention:
Suspending agent the key technical indexes of the present invention:
Suspension emulsion the key technical indexes of the present invention:
Aqueous emulsion the key technical indexes of the present invention:
Microemulsion the key technical indexes of the present invention:
Microcapsule suspending agent the key technical indexes of the present invention:
Microcapsule suspension-suspending agent the key technical indexes of the present invention:
The invention has the advantages that:
(1) fluorine azoles Acibenzolar and Fluoxastrobin, kresoxim-methyl, dimoxystrobin, orysastrobin, SSF 126, azoles bacterium ester composite after, there is obvious synergy and lasting effect; (2) disease on cereal crops, legume crop, fiber crop, sugar [yielding, melon crop, fruits crop, dry fruit crop, hobby crop, root crop, oil crop, flowers crop, medicinal crop, raw material crop, green manure pasture crop is all had to greater activity; (3) reduce agricultural chemicals dosage, reduced the residual quantity of agricultural chemicals on crop, alleviated environmental pollution; (4), to person poultry safety, Environmental compatibility is good; And preparation adhesion strength strengthens, resistance of rainwater washing against.
Embodiment
Below in conjunction with embodiment, to further instruction of the present invention, the percentage in embodiment is all weight percentage, but the present invention is not limited thereto.
Application Example one
Embodiment 1～16 wetting powder
Fluorine azoles Acibenzolar, active component B, dispersant, wetting agent, filler are mixed in mixed cylinder, after airslide disintegrating mill is pulverized, mix again, can make wetting powder product of the present invention, specifically in Table 1.
Table 1 embodiment 1～16 each component and weight portion
Embodiment 17～32 water dispersible granules
Fluorine azoles Acibenzolar, active component B, dispersant, wetting agent, disintegrant, filler etc. are obtained to the particle diameter needing through air-flow crushing together, then add other auxiliary agents such as binding agent (can add and can not add), obtain the materials of granulating.By item quantitatively send in fluidized bed granulation dryer through granulation and dry after, can make water dispersible granules product of the present invention, specifically in Table 2.
Table 2 embodiment 17～32 each component and weight portions
Embodiment 33～48 suspending agents
By dispersant, wetting agent, defoamer, thickener (can add and can not add), antifreeze (can add and can not add), through high speed shear, mix, add fluorine azoles Acibenzolar, active component B, in ball mill, ball milling is 2 ~ 3 hours, make diameter of particle all below 5 μ m, surplus is supplied by deionized water, can make suspending agent product of the present invention, specifically in Table 3.
Table 3 embodiment 33～48 each component and weight portions
Embodiment 49～56 suspension emulsions
Dispersant, defoamer, thickener (can add and can not add), antifreeze (can add and can not add) are mixed through high speed shear, add active component B, in ball mill, ball milling is 2 ~ 3 hours, make diameter of particle all below 5 μ m, make active component B suspending agent, then by fluorine azoles Acibenzolar, solvent, emulsifier and various auxiliary agent with the direct emulsification of high speed agitator in suspending agent, surplus is supplied by deionized water, make suspension emulsion product of the present invention, specifically in Table 4,5.
Table 4 embodiment 49～52 each component and weight portions
Table 5 embodiment 53～56 each component and weight portions
Embodiment 57～66 aqueous emulsions
Fluorine azoles Acibenzolar, active component B, solvent, emulsifier are added together, make to be dissolved into even oil phase; Deionized water, antifreeze (can add and can not add), thickener (can add and can not add), defoamer are mixed, become homogeneous water.Under high-speed stirred, water is added to oil phase, surplus is supplied by deionized water; Can make aqueous emulsion product of the present invention, specifically in Table 6.
Table 6 embodiment 57～66 each component and weight portions
By Fluoxastrobin, kresoxim-methyl, dimoxystrobin, orysastrobin, SSF 126, azoles bacterium ester interchange in table 1 ~ 6, can make novel formulation.
Embodiment 67～69 microemulsions
Fluorine azoles Acibenzolar, active component B, solvent, emulsifier, antifreeze (can add and can not add), defoamer are fully mixed into the oil phase of homogeneous transparent, under agitation slowly add deionized water, form WO emulsion, again through agitating heating, make it rapid phase inversion and become oil-in-water type, be chilled to room temperature and make it to reach balance, after filtration, surplus is supplied by deionized water; Can make microemulsion product of the present invention, specifically in Table 7.
Table 7 embodiment 67～69 each component and weight portions
Embodiment 70,71 microcapsule suspending agents
By fluorine azoles Acibenzolar, active component B, macromolecule cyst material, solvent, make to be dissolved into even oil phase, under shearing condition, oil phase is joined in the aqueous phase solution that contains emulsifier, pH adjusting agent, dispersant, surplus is supplied by deionized water, bi-material reacts at oil-water interfaces, forms macromolecule cyst wall, makes the finely disseminated microcapsule suspending agent product of the present composition.Specifically in Table 8.
Table 8 embodiment 70,71 each component and weight portions
Embodiment 72,73 microcapsule suspensions-suspending agent
By fluorine azoles Acibenzolar, macromolecule cyst material, solvent, make to be dissolved into even oil phase, oil phase is joined in the aqueous phase solution that contains emulsifier, pH adjusting agent under shearing condition, make finely disseminated microcapsule suspending agent.Dispersant, wetting agent, defoamer, thickener (can add and can not add) are mixed through high speed shear, add active component B, in ball mill, ball milling is 2 ~ 3 hours, make diameter of particle all below 5 μ m, make suspending agent, then suspending agent is joined in the aqueous phase solution of micro-capsule suspension, deionized water is supplied surplus, make the finely disseminated microcapsule suspension-suspending agent of present composition product, specifically in Table 9.
Table 9 embodiment 72,73 each component and weight portions
The embodiment of the present invention is the method that adopts Toxicity Determination and field trial to combine.First by Toxicity Determination, the synergy ratio (SR) after clear and definite two kinds of medicaments are composite by a certain percentage, SR < 0.5 is antagonism, 0.5≤SR≤1.5 are summation action, SR > 1.5 is synergistic effect, on this basis, then carries out field trial.
Test method: after the effective inhibition concentration scope of each medicament is determined in prerun, medicament is established respectively 5 dosage by active constituent content and processed, and establishes clear water contrast.With reference to < < farm-chemical indoor determination test rule bactericide > >, carry out, adopt mycelial growth rate method to measure the virulence of medicament to crop germ.After 72h, by right-angled intersection method, measure colony diameter, calculate and respectively process net growth, mycelial growth inhibition rate.
Net growth (mm)=measurement colony diameter-5
Mycelial growth inhibition rate is converted into probit value (y), and liquor strength (μ g/mL) converts logarithm value to (x), with method of least squares, tries to achieve virulence regression equation (y=a+bx), and calculates thus the EC of every kind of medicament
50value.According to Wadley method, calculate the different proportioning synergy ratio (SR) of two medicaments, SR < 0.5 is antagonism simultaneously, and 0.5≤SR≤1.5 are summation action, and SR > 1.5 is synergistic effect.Computing formula is as follows:
Wherein: a, b are respectively active components A and active component B shared ratio in combination;
A is fluorine azoles Acibenzolar;
B is selected from a kind of in Fluoxastrobin, kresoxim-methyl, dimoxystrobin, orysastrobin, SSF 126, azoles bacterium ester.
Application Example two:
For trying disease: powdery mildew of cucumber
Test medicine provides by Shaanxi Mei Bang agricultural chemicals Co., Ltd.
Experimental scheme: effective inhibition concentration scope of determining fluorine azoles Acibenzolar and the former medicine of Fluoxastrobin and the two different proportioning mixture through preliminary experiment.
Toxicity test result
Table 10 fluorine azoles Acibenzolar and the azoxystrobin compound toxicity test analysis of results table to powdery mildew of cucumber
As shown in Table 10, fluorine azoles Acibenzolar and the Fluoxastrobin proportioning synergy ratio SR to powdery mildew of cucumber when 1 ︰ 80 ~ 60 ︰ 1 is all greater than 1.5, illustrate that both are mixed and all show synergistic effect in 1 ︰ 80 ~ 60 ︰ 1 scopes, when the proportioning of fluorine azoles Acibenzolar and Fluoxastrobin is during at 1 ︰ 30 ~ 10 ︰ 1, synergistic effect is more outstanding, and synergy ratio is all more than 2.25.Through applicant, test and find that the optimum ratio of fluorine azoles Acibenzolar and Fluoxastrobin is 10:1,5:1,2:1,1:1,1:2,1:3,1:4,1:5,1:6,1:7,1:8,1:9,1:10,1:11,1:12,1:13,1:14,1:15,1:18,1:20,1:25,1:30, especially when fluorine azoles Acibenzolar and Fluoxastrobin weight ratio are 1:9, synergy ratio is maximum, and synergistic effect is the most obvious.
Application Example three
For trying disease: grape powdery mildew
Test medicine provides by Shaanxi Mei Bang agricultural chemicals Co., Ltd.
Experimental scheme: effective inhibition concentration scope of determining fluorine azoles Acibenzolar and the former medicine of kresoxim-methyl and the two different proportioning mixture through preliminary experiment.
The composite toxicity test analysis of results table to grape powdery mildew of table 11 fluorine azoles Acibenzolar and kresoxim-methyl
As shown in Table 11, fluorine azoles Acibenzolar and the kresoxim-methyl proportioning synergy ratio SR to grape powdery mildew when 1 ︰ 80 ~ 60 ︰ 1 is all greater than 1.5, illustrate that both are mixed and all show synergistic effect in 1 ︰ 80 ~ 60 ︰ 1 scopes, when the proportioning of fluorine azoles Acibenzolar and kresoxim-methyl is during at 1 ︰ 30 ~ 10 ︰ 1, synergistic effect is more outstanding, and synergy ratio is all more than 2.25.Through applicant, test and find that the optimum ratio of fluorine azoles Acibenzolar and kresoxim-methyl is 10:1,5:1,2:1,1:1,1:2,1:3,1:4,1:5,1:6,1:7,1:8,1:9,1:10,1:11,1:12,1:13,1:14,1:15,1:18,1:20,1:25,1:30, especially when fluorine azoles Acibenzolar and kresoxim-methyl weight ratio are 1:9, synergy ratio is maximum, and synergistic effect is the most obvious.
Application Example four
For trying disease: downy mildew of garpe
Test medicine provides by Shaanxi Mei Bang agricultural chemicals Co., Ltd.
Experimental scheme: effective inhibition concentration scope of determining fluorine azoles Acibenzolar and the former medicine of dimoxystrobin and the two different proportioning mixture through preliminary experiment.
The composite toxicity test analysis of results table to downy mildew of garpe of table 12 fluorine azoles Acibenzolar and dimoxystrobin
As shown in Table 12, fluorine azoles Acibenzolar and the dimoxystrobin proportioning synergy ratio SR to downy mildew of garpe when 1 ︰ 80 ~ 60 ︰ 1 is all greater than 1.5, illustrate that both are mixed and all show synergistic effect in 1 ︰ 80 ~ 60 ︰ 1 scopes, when the proportioning of fluorine azoles Acibenzolar and dimoxystrobin is during at 1 ︰ 30 ~ 20 ︰ 1, synergistic effect is more outstanding, and synergy ratio is all more than 2.25.Through applicant, test and find that the optimum ratio of fluorine azoles Acibenzolar and dimoxystrobin is 20:1,15:1,10:1,5:1,1:1,1:2,1:3,1:4,1:5,1:6,1:7,1:8,1:9,1:10,1:11,1:12,1:13,1:15,1:20,1:25,1:30, especially when fluorine azoles Acibenzolar and dimoxystrobin weight ratio are 1:6, synergy ratio is maximum, and synergistic effect is the most obvious.
Application Example five
For trying disease: rice sheath blight disease
Test medicine provides by Shaanxi Mei Bang agricultural chemicals Co., Ltd.
Experimental scheme: effective inhibition concentration scope of determining fluorine azoles Acibenzolar and the former medicine of orysastrobin and the two different proportioning mixture through preliminary experiment.
The composite toxicity test analysis of results table to rice sheath blight disease of table 13 fluorine azoles Acibenzolar and orysastrobin
As shown in Table 13, fluorine azoles Acibenzolar and the orysastrobin proportioning synergy ratio SR to rice sheath blight disease when 1 ︰ 80 ~ 60 ︰ 1 is all greater than 1.5, illustrate that both are mixed and all show synergistic effect in 1 ︰ 80 ~ 60 ︰ 1 scopes, when the proportioning of fluorine azoles Acibenzolar and orysastrobin is during at 1 ︰ 30 ~ 20 ︰ 1, synergistic effect is more outstanding, and synergy ratio is all more than 2.20.Through applicant, test and find that the optimum ratio of fluorine azoles Acibenzolar and orysastrobin is 20:1,15:1,10:1,6:1,5:1,4:1,3:1,2:1,3:2,1:1,1:2,1:3,1:4,1:5,1:6,1:7,1:8,1:9,1:10,1:11,1:12,1:13,1:14,1:15,1:20,1:30, especially when fluorine azoles Acibenzolar and orysastrobin weight ratio are 1:6, synergy ratio is maximum, and synergistic effect is the most obvious.
Application Example six
For trying disease: rice blast
Test medicine provides by Shaanxi Mei Bang agricultural chemicals Co., Ltd.
Experimental scheme: effective inhibition concentration scope of determining fluorine azoles Acibenzolar and the former medicine of SSF 126 and the two different proportioning mixture through preliminary experiment.
The composite toxicity test analysis of results table to rice blast of table 14 fluorine azoles Acibenzolar and SSF 126
As shown in Table 14, fluorine azoles Acibenzolar and the SSF 126 proportioning synergy ratio SR to rice blast when 1 ︰ 80 ~ 60 ︰ 1 is all greater than 1.5, illustrate that both are mixed and all show synergistic effect in 1 ︰ 80 ~ 60 ︰ 1 scopes, when the proportioning of fluorine azoles Acibenzolar and SSF 126 is during at 1 ︰ 35 ~ 10 ︰ 1, synergistic effect is more outstanding, and synergy ratio is all more than 2.25.Through applicant, test and find that the optimum ratio of fluorine azoles Acibenzolar and SSF 126 is 10:1,5:1,1:1,1:5,1:9,1:10,1:11,1:12,1:13,1:14,1:15,1:16,1:17,1:18,1:19,1:20,1:30,1:35, especially when fluorine azoles Acibenzolar and SSF 126 weight ratio are 1:14, synergy ratio is maximum, and synergistic effect is the most obvious.
Application Example seven
For trying disease: cucumber downy mildew
Test medicine provides by Shaanxi Mei Bang agricultural chemicals Co., Ltd.
Experimental scheme: effective inhibition concentration scope of determining fluorine azoles Acibenzolar and the former medicine of azoles bacterium ester and the two different proportioning mixture through preliminary experiment.
The composite toxicity test analysis of results table to cucumber downy mildew of table 15 fluorine azoles Acibenzolar and azoles bacterium ester
As shown in Table 15, fluorine azoles Acibenzolar and the azoles bacterium ester proportioning synergy ratio SR to cucumber downy mildew when 1 ︰ 80 ~ 60 ︰ 1 is all greater than 1.5, illustrate that both are mixed and all show synergistic effect in 1 ︰ 80 ~ 60 ︰ 1 scopes, when the proportioning of fluorine azoles Acibenzolar and azoles bacterium ester is during at 1 ︰ 25 ~ 20 ︰ 1, synergistic effect is more outstanding, and synergy ratio is all more than 2.20.Through applicant, test and find that the optimum ratio of fluorine azoles Acibenzolar and azoles bacterium ester is 20:1,10:1,5:1,3:1,2:1,1:1,1:2,1:3,1:4,1:5,1:6,1:7,1:8,1:9,1:10,1:15,1:20,1:25, especially when fluorine azoles Acibenzolar and azoles bacterium ester weight ratio are 1:4, synergy ratio is maximum, and synergistic effect is the most obvious.
Through test, find: after fluorine azoles Acibenzolar and active component B are composite, the control of the powdery mildew in various crop, downy mildew, epidemic disease, leaf mold, shot hole, scab, peronospora tabacina, anthracnose, spot defoliation, rust, rice blast, banded sclerotial blight, brown spot is had to obvious synergistic effect, synergy ratio SR is all greater than 1.5.
Effect experiment part: test medicine is researched and developed, provided by Shaanxi Mei Bang agricultural chemicals Co., Ltd, contrast medicament 20% fluorine azoles Acibenzolar missible oil (autogamy), 250 grams per liter Fluoxastrobin suspending agents (commercial), 30% kresoxim-methyl wetting powder (commercial), 20% dimoxystrobin wetting powder (autogamy), 20% orysastrobin wetting powder (autogamy), 20% SSF 126 wetting powder (autogamy), 20% azoles bacterium ester suspending agent (autogamy).
Application Example octafluoro azoles Acibenzolar and active component B and the composite powdery mildew of cucumber test of pesticide effectiveness of preventing and treating thereof
This test arrangement is at Xian District, Shanxi Province suburban area, and investigation powdery mildew of cucumber disease index before medicine, in the dispenser of disease initial stage of origination, investigates disease indexes and calculate preventive effect for after dispenser 5 days, 15 days, 30 days.Result of the test is as follows:
Table 16 fluorine azoles Acibenzolar and active component B and the composite powdery mildew of cucumber test of pesticide effectiveness of preventing and treating thereof
As can be seen from Table 16, after fluorine azoles Acibenzolar and active component B are composite, can effectively prevent and treat powdery mildew of cucumber, through applicant, test and find that fluorine azoles Acibenzolar and active component B also can effectively prevent and treat cucumber downy mildew, epidemic disease after composite, control efficiency is all higher than 96%, the preventive effect that is better than single dose, and the preventive effect phase is long.In test scope of medication, target crop is had no adverse effects.
Application Example nine fluorine azoles Acibenzolars and active component B and the composite control tomato blight test of pesticide effectiveness thereof
This test arrangement is at Xian District, Shanxi Province suburban area, and investigation tomato blight disease index before medicine, in the dispenser of disease initial stage of origination, investigates disease indexes and calculate preventive effect for after dispenser 3 days, 10 days, 20 days.Result of the test is as follows:
Table 17 fluorine azoles Acibenzolar and active component B and the composite control tomato blight test of pesticide effectiveness thereof
As can be seen from Table 17, after fluorine azoles Acibenzolar and active component B are composite, can effectively prevent and treat tomato blight, through applicant, test and find that fluorine azoles Acibenzolar and active component B also can effectively prevent and treat cladosporium leaf and fruit mould of tomato after composite, control efficiency is all higher than 96%, the preventive effect that is better than single dose, and the preventive effect phase is long.In test scope of medication, target crop is had no adverse effects.
Application Example ten fluorine azoles Acibenzolars and active component B and the composite control rice blast test of pesticide effectiveness thereof
This test arrangement is in Hanzhong City suburb, Shaanxi Province, and investigation rice blast disease index before medicine, in the dispenser of disease initial stage of origination, investigates disease indexes and calculate preventive effect for after dispenser 5 days, 15 days, 30 days.Result of the test is as follows:
Table 18 fluorine azoles Acibenzolar and active component B and the composite control rice blast test of pesticide effectiveness thereof
As can be seen from Table 18, fluorine azoles Acibenzolar and active component B and composite control rice blast thereof, test and find that fluorine azoles Acibenzolar and active component B also can effectively prevent and treat rice sheath blight disease after composite through applicant, and control efficiency is all higher than 95%, the preventive effect that is better than single dose, and the preventive effect phase is long.In test scope of medication, target crop is had no adverse effects.
Application Example 11 fluorine azoles Acibenzolars and active component B and the composite control alternaria leaf spot of apple test of pesticide effectiveness thereof
This test arrangement is at Shaanxi Province's Weinan City Baishui County, and investigation alternaria leaf spot of apple disease index before medicine, in the dispenser of disease initial stage of origination, investigates disease indexes and calculate preventive effect for after dispenser 3 days, 10 days, 20 days.Result of the test is as follows:
Table 19 fluorine azoles Acibenzolar and active component B and the composite control alternaria leaf spot of apple test of pesticide effectiveness thereof
As can be seen from Table 19, after fluorine azoles Acibenzolar and active component B are composite, can effectively prevent and treat alternaria leaf spot of apple, through applicant, test and find that fluorine azoles Acibenzolar and active component B also can effectively prevent and treat apple scab, rust, brown spot after composite, control efficiency is all higher than 95%, the preventive effect that is better than single dose, and the preventive effect phase is long.In test scope of medication, target crop is had no adverse effects.
Application Example ten difluoro azoles Acibenzolars and active component B and the composite citrus scab test of pesticide effectiveness of preventing and treating thereof
This test arrangement is in Hanzhong City suburb, Shaanxi Province, and investigation citrus scab disease index before medicine, in the dispenser of disease initial stage of origination, investigates disease indexes and calculate preventive effect for after dispenser 10 days, 20 days, 30 days.Result of the test is as follows:
Table 20 fluorine azoles Acibenzolar and active component B and the composite citrus scab test of pesticide effectiveness of preventing and treating thereof
As can be seen from Table 20, after fluorine azoles Acibenzolar and active component B are composite, can effectively prevent and treat citrus scab, through applicant, test and find that fluorine azoles Acibenzolar and active component B also can effectively prevent and treat citrus anthracnose after composite, control efficiency is all higher than 95%, the preventive effect that is better than single dose, and the preventive effect phase is long.In test scope of medication, target crop is had no adverse effects.
Application Example ten trifluoro azoles Acibenzolars and active component B and the composite downy mildew of garpe test of pesticide effectiveness of preventing and treating thereof
This test arrangement is in Weinan City Dali County, Shaanxi Province, and investigation downy mildew of garpe disease index before medicine, in the dispenser of disease initial stage of origination, investigates disease indexes and calculate preventive effect for after dispenser 7 days, 14 days, 25 days.Result of the test is as follows:
Table 21 fluorine azoles Acibenzolar and active component B and the composite downy mildew of garpe test of pesticide effectiveness of preventing and treating thereof
As can be seen from Table 21, after fluorine azoles Acibenzolar and active component B are composite, can effectively prevent and treat downy mildew of garpe, through applicant, test and find that fluorine azoles Acibenzolar and active component B also can effectively prevent and treat grape powdery mildew after composite, control efficiency is all higher than 96%, the preventive effect that is better than single dose, and the preventive effect phase is long.In test scope of medication, target crop is had no adverse effects.
After through different local throughout the country tests, draw, fluorine azoles Acibenzolar and Fluoxastrobin, kresoxim-methyl, dimoxystrobin, orysastrobin, SSF 126, azoles bacterium ester composite rear to the preventive effect of the Common Diseases such as the powdery mildew in various crop, downy mildew, epidemic disease, leaf mold, shot hole, scab, peronospora tabacina, anthracnose, spot defoliation, rust, rice blast, banded sclerotial blight, brown spot all more than 95%, be better than single dose preventive effect, synergistic effect is obvious.
Claims (6)
1. the bactericidal composition of a fluorine-containing azoles Acibenzolar and methoxy acrylic, contain active components A and active component B, it is characterized in that: active components A and active component B weight ratio are 1 ︰ 80 ~ 60 ︰ 1, described active components A is selected from fluorine azoles Acibenzolar, and active component B is selected from a kind of in Fluoxastrobin, kresoxim-methyl, dimoxystrobin, orysastrobin, SSF 126, azoles bacterium ester.
2. the bactericidal composition of fluorine-containing azoles Acibenzolar according to claim 1 and methoxy acrylic, is characterized in that: the weight ratio of active components A and active component B is 1 ︰ 60 ~ 40 ︰ 1.
3. the bactericidal composition of fluorine-containing azoles Acibenzolar according to claim 2 and methoxy acrylic, is characterized in that:
The weight ratio of fluorine azoles Acibenzolar and Fluoxastrobin or kresoxim-methyl is 1 ︰ 30 ~ 10 ︰ 1;
The weight ratio of fluorine azoles Acibenzolar and dimoxystrobin or orysastrobin is 1 ︰ 30 ~ 20 ︰ 1;
The weight ratio of fluorine azoles Acibenzolar and SSF 126 is 1 ︰ 35 ~ 10 ︰ 1;
The weight ratio of fluorine azoles Acibenzolar and azoles bacterium ester is 1 ︰ 25 ~ 20 ︰ 1.
4. according to the fluorine-containing azoles Acibenzolar described in any one in claims 1 to 3 and the bactericidal composition of methoxy acrylic, it is characterized in that: composition is made wetting powder, water dispersible granules, suspending agent, suspension emulsion, aqueous emulsion, microemulsion, microcapsule suspending agent, microcapsule suspension-suspending agent.
5. the bactericidal composition of fluorine-containing azoles Acibenzolar according to claim 4 and methoxy acrylic is for preventing and treating the purposes of disease on crops.
6. purposes according to claim 5, is characterized in that, described disease comprises: powdery mildew, downy mildew, epidemic disease, leaf mold, shot hole, scab, peronospora tabacina, anthracnose, spot defoliation, rust, rice blast, banded sclerotial blight, brown spot.
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| CN201510197172.7A CN104886077A (en) | 2012-09-21 | 2012-09-21 | Sterilization composition containing fluoro-substituted benzothiadiazole derivatives and methoxy acrylic ester |
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| CN106212483A (en) * | 2016-08-16 | 2016-12-14 | 田文华 | A kind of containing fluoxastrobin with the bactericidal composition of fluorine azoles Acibenzolar |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4931581A (en) * | 1987-08-21 | 1990-06-05 | Ciba-Geigy Corporation | Process and a composition for immunizing plants against diseases |
| CN1450057A (en) * | 2003-05-16 | 2003-10-22 | 华东理工大学 | Diazosulfide compound and application in plant cell thereof |
| CN1868277A (en) * | 2006-06-20 | 2006-11-29 | 华东理工大学 | Application of benzothidiazole derivatives as activator for plant disease-resistant agent |
| CN101708001A (en) * | 2009-12-15 | 2010-05-19 | 深圳诺普信农化股份有限公司 | Sterilizing composition containing active ester |
| CN101836640A (en) * | 2010-03-04 | 2010-09-22 | 中国农业科学院蔬菜花卉研究所 | Application of elicitor in controlling soil-borne diseases of garden crops |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2157863A2 (en) * | 2007-06-14 | 2010-03-03 | Syngeta Participations AG | Pesticidal combinations |
| CN101731237B (en) * | 2009-12-15 | 2013-03-13 | 深圳诺普信农化股份有限公司 | Acibenzolar-containing sterilizing composition |
| CN101708003B (en) * | 2009-12-23 | 2013-02-27 | 深圳诺普信农化股份有限公司 | Sterilizing composition containing active ester |
-
2012
- 2012-09-21 CN CN201510197172.7A patent/CN104886077A/en active Pending
- 2012-09-21 CN CN201210355378.4A patent/CN103651414B/en not_active Expired - Fee Related
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4931581A (en) * | 1987-08-21 | 1990-06-05 | Ciba-Geigy Corporation | Process and a composition for immunizing plants against diseases |
| CN1450057A (en) * | 2003-05-16 | 2003-10-22 | 华东理工大学 | Diazosulfide compound and application in plant cell thereof |
| CN1868277A (en) * | 2006-06-20 | 2006-11-29 | 华东理工大学 | Application of benzothidiazole derivatives as activator for plant disease-resistant agent |
| CN101708001A (en) * | 2009-12-15 | 2010-05-19 | 深圳诺普信农化股份有限公司 | Sterilizing composition containing active ester |
| CN101836640A (en) * | 2010-03-04 | 2010-09-22 | 中国农业科学院蔬菜花卉研究所 | Application of elicitor in controlling soil-borne diseases of garden crops |
Non-Patent Citations (1)
| Title |
|---|
| WEIPING ZHU ET AL: "Derivatives of benzothiadiazole-7-carboxylates:synthesis and biological activity", 《MONATSHEFTE FUR CHEMIE》, 18 February 2008 (2008-02-18), pages 1067 - 1071, XP019634274 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106212483A (en) * | 2016-08-16 | 2016-12-14 | 田文华 | A kind of containing fluoxastrobin with the bactericidal composition of fluorine azoles Acibenzolar |
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Address after: 715500 Pucheng high tech Industrial Development Zone, Weinan, Shaanxi Patentee after: SHAANXI MEIBANG PHARMACEUTICAL GROUP Co.,Ltd. Address before: 715500 Shaanxi Pucheng Weinan County agricultural base industrial park Patentee before: Shaanxi Meibang pesticide Co.,Ltd. |
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