CN103648627A - Carbonated spring generating device - Google Patents

Carbonated spring generating device Download PDF

Info

Publication number
CN103648627A
CN103648627A CN201280033880.1A CN201280033880A CN103648627A CN 103648627 A CN103648627 A CN 103648627A CN 201280033880 A CN201280033880 A CN 201280033880A CN 103648627 A CN103648627 A CN 103648627A
Authority
CN
China
Prior art keywords
bubble
carbon dioxide
water
carbonate spring
generating apparatus
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201280033880.1A
Other languages
Chinese (zh)
Other versions
CN103648627B (en
Inventor
宫崎秀树
前川和信
清水泰贵
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Design Science And Technology Ltd Of Fuji
Fujidenolo Co Ltd
Original Assignee
Design Science And Technology Ltd Of Fuji
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Design Science And Technology Ltd Of Fuji filed Critical Design Science And Technology Ltd Of Fuji
Publication of CN103648627A publication Critical patent/CN103648627A/en
Application granted granted Critical
Publication of CN103648627B publication Critical patent/CN103648627B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61HPHYSICAL THERAPY APPARATUS, e.g. DEVICES FOR LOCATING OR STIMULATING REFLEX POINTS IN THE BODY; ARTIFICIAL RESPIRATION; MASSAGE; BATHING DEVICES FOR SPECIAL THERAPEUTIC OR HYGIENIC PURPOSES OR SPECIFIC PARTS OF THE BODY
    • A61H33/00Bathing devices for special therapeutic or hygienic purposes
    • A61H33/02Bathing devices for use with gas-containing liquid, or liquid in which gas is led or generated, e.g. carbon dioxide baths
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F23/00Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
    • B01F23/20Mixing gases with liquids
    • B01F23/23Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids
    • B01F23/232Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids using flow-mixing means for introducing the gases, e.g. baffles
    • B01F23/2323Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids using flow-mixing means for introducing the gases, e.g. baffles by circulating the flow in guiding constructions or conduits
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F23/00Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
    • B01F23/20Mixing gases with liquids
    • B01F23/23Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids
    • B01F23/237Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids characterised by the physical or chemical properties of gases or vapours introduced in the liquid media
    • B01F23/2376Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids characterised by the physical or chemical properties of gases or vapours introduced in the liquid media characterised by the gas being introduced
    • B01F23/23762Carbon dioxide
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F23/00Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
    • B01F23/40Mixing liquids with liquids; Emulsifying
    • B01F23/45Mixing liquids with liquids; Emulsifying using flow mixing
    • B01F23/454Mixing liquids with liquids; Emulsifying using flow mixing by injecting a mixture of liquid and gas
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F25/00Flow mixers; Mixers for falling materials, e.g. solid particles
    • B01F25/40Static mixers
    • B01F25/45Mixers in which the materials to be mixed are pressed together through orifices or interstitial spaces, e.g. between beads
    • B01F25/452Mixers in which the materials to be mixed are pressed together through orifices or interstitial spaces, e.g. between beads characterised by elements provided with orifices or interstitial spaces
    • B01F25/4521Mixers in which the materials to be mixed are pressed together through orifices or interstitial spaces, e.g. between beads characterised by elements provided with orifices or interstitial spaces the components being pressed through orifices in elements, e.g. flat plates or cylinders, which obstruct the whole diameter of the tube
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/68Treatment of water, waste water, or sewage by addition of specified substances, e.g. trace elements, for ameliorating potable water

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Rehabilitation Therapy (AREA)
  • Physical Education & Sports Medicine (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Veterinary Medicine (AREA)
  • Pain & Pain Management (AREA)
  • Epidemiology (AREA)
  • Dispersion Chemistry (AREA)
  • Devices For Medical Bathing And Washing (AREA)
  • Accessories For Mixers (AREA)

Abstract

Provided is a carbonated spring generating device capable of efficiently generating a carbonated spring without increasing the water pressure. The carbonated spring generating device has an air-bubble dissolving path (12) through which water having carbon dioxide bubbles mixed therein flows; the air-bubble dissolving path (12) has at least one constricted section (14) that divides the carbon dioxide bubbles, and a pressure holding section (16) that maintains the water pressure in the output side end of the air-bubble dissolving path (12), at the water pressure of inside the air-bubble dissolving path (12); the effective diameter of the air-bubble dissolving path (12) is stipulated such that the viscous resistance (R) of the air bubbles at the flow speed of the water flowing through the air-bubble dissolving path (12) is at least the buoyancy (F) of the carbon dioxide bubbles when the carbon dioxide bubbles have a maximum diameter (D) as the effective diameter thereof; and the constricted section (14) has a smaller effective diameter than the air-bubble dissolving path (12).

Description

Carbonate spring generating apparatus
Technical field
The present invention relates to carbonate spring generating apparatus.
Background technology
Carrying out the water and/or the hot water that are dissolved with carbon dioxide is that carbonate spring is for bathing use always.Accompany with it, generate efficiently the exploitation of the carbonate spring generating apparatus of carbonate spring.
For example, the technology of recording in patent documentation 1 is exactly one example, discloses a kind of carbonic acid hot water generating device, it is characterized in that having and dwindle the restriction of cross-sectional flow area and the extension that cross-sectional flow area increases on the flow direction of carbonic acid hot water.Like this, in the generation of carbonate spring, expectation is dissolved in carbon dioxide efficiency the technology of water well.
Patent documentation 1: TOHKEMY 2006-212098 communique
For example disclosed in patent documentation 1, can make carbon dioxide efficiency be dissolved in well water as object, in carbonate spring generating apparatus, mostly use and possess for improving the device of the pump of hydraulic pressure.On the other hand, due to by carbonate spring as bathing use, so expect to try one's best small-sized and do not need the such carbonate spring generating apparatus of power supply.
Summary of the invention
The present invention completes above situation as a setting, its objective is that providing a kind of can improve hydraulic pressure and efficiently generate the carbonate spring generating apparatus of carbonate spring.
In order to reach this object, feature as the 1st invention, (a) be a kind of carbonate spring generating apparatus, the gas bubble stream with the water flow that is mixed with carbon dioxide bubble, by this carbon dioxide bubble, be dissolved in this water and generate carbonate spring, (b) this gas bubble stream has at least one restriction, and pressure retaining parts, described restriction is cut apart above-mentioned carbon dioxide bubble, described pressure retaining parts remains on the hydraulic pressure in above-mentioned stream in outlet side one end of this gas bubble stream, (c) effective diameter of this gas bubble stream is determined, so that the viscous drag of the bubble under the flow velocity of the above-mentioned water of this gas bubble flow path, more than the buoyancy of the above-mentioned carbon dioxide bubble in the situation that to become above-mentioned carbon dioxide bubble be the maximum diameter of this effective diameter, (d) length of this gas bubble stream is determined, so that in the above-mentioned water that is mixed with carbon dioxide bubble that circulates in this gas bubble stream, guarantee for making the concentration of carbon dioxide arrive the dissolution time of normal concentration, (e) effective diameter of above-mentioned restriction is less than above-mentioned gas bubble stream, (f) above-mentioned pressure retaining parts, have for the hydraulic pressure of this carbonate spring generating apparatus inside is maintained the dissolving that can promote above-mentioned carbon dioxide bubble pressure pass through area.
Like this, because the carbon dioxide bubble in water is cut apart by above-mentioned restriction, so the contact area of carbon dioxide bubble and water increases, and does not flow bubble because of the effective diameter by above-mentioned gas bubble stream with being detained, so can increase the time of contact of carbon dioxide bubble and water.In addition, because the hydraulic pressure of carbonate spring generating apparatus inside maintains the pressure of the dissolving that can promote carbon dioxide bubble by pressure retaining parts, need not can promote carbon dioxide to the dissolving of water by raising hydraulic pressure such as pumps.And because make to be mixed with the water of carbon dioxide bubble by gas bubble stream, in this gas bubble stream, circulation is for making more than the concentration of carbon dioxide arrives the dissolution time of normal concentration, so can obtain the carbonate spring of normal concentration.
In addition, feature as the 2nd invention, in the 1st invention, being set by area of above-mentioned pressure retaining parts, so that in the situation that the flow of the water of supplying with to above-mentioned carbonate spring generating apparatus is the scope of 5L/ minute~30L/ minute, the hydraulic pressure of this carbonate spring generating apparatus inside is maintained to the pressure of the dissolving that can promote above-mentioned carbon dioxide bubble.Like this, in the situation that the water yield of generally supplying with by water channel or hot water supply apparatus be the scope of 5L/ minute~30L/ minute for feedwater, can by raising hydraulic pressure such as pumps, not generate carbonate spring.
In addition as the 3rd feature of inventing, it is characterized in that, in the 1st or the 2nd invention, the distance of the portion that spues of above-mentioned restriction and above-mentioned carbonate spring determined, so that the carbon dioxide bubble of having been cut apart by above-mentioned restriction can be in conjunction with becoming large so that hindering carbonate spring to flow to the portion that spues of carbonate spring.Like this, even in the situation that by restriction grain refined carbon dioxide bubble dissolve residually, the stream of the carbonate spring from restriction to the portion of spuing, dissolve residual bubble divided and keep grain refined state to be spued from the portion of spuing.Therefore can prevent from dissolving residual bubble and be detained formation air pocket the stream of the carbonate spring from restriction to the portion of spuing, this air pocket is sent bubble bubble sound by plug-flow once by the portion of spuing, or water mobile gets clogged and such give user the not situation of sensation soon.
In addition as the 4th feature of inventing, in the 1st~3rd invention, the length of this gas bubble stream determined, so that in the above-mentioned water that is mixed with carbon dioxide bubble that circulates in this gas bubble stream, guarantee for making the concentration of carbon dioxide arrive the roughly dissolution time of saturated concentration.Like this, can be not by raising hydraulic pressure such as pumps, do not generate gas concentration lwevel for the carbonate spring of saturated concentration roughly.
In addition, as the feature of the 5th invention, in arbitrary invention of the 1st~4th, the passing through area and can change of above-mentioned pressure retaining parts.Like this, even in the situation that the water yield of the water of supplying with to carbonate spring generating apparatus is different, also can by area, set the suitable area that passes through by what change above-mentioned pressure retaining parts, can by raising hydraulic pressure such as pumps, not generate carbonate spring.
In addition, as the feature of the 6th invention, in arbitrary invention of the 1st~5th, above-mentioned pressure retaining parts, has the effective diameter less than the effective diameter of above-mentioned gas bubble stream, can from the different a plurality of pressure retaining parts of effective diameter, optionally install.Like this, even in the situation that hydraulic pressure and/or the water yield of the water of the above-mentioned carbonate spring generating apparatus of inflow are different, also can prevent that the hydraulic pressure in above-mentioned gas bubble stream from dropping to atmospheric pressure.In addition, in the situation that the above-mentioned the 7th and the 8th invention is used in combination, can prevent that the hydraulic pressure in above-mentioned gas bubble stream from dropping to atmospheric pressure, guarantee for making bubble supply valve, bubble supply with the hydraulic pressure of stop valve work simultaneously.
In addition, as the feature of the 7th invention, in arbitrary invention of the 1st~6th, above-mentioned gas bubble stream is flexual pipe.Like this, such as the flexual pipe that can gas bubble stream be set to flexible pipe etc.Therefore than beyond gas bubble stream, the situation of flexible pipe being only set for water distribution, can shorten as a whole the length of pipe arrangement.
In addition, the feature as the 8th invention, in arbitrary invention of the 1st~7th, has (a) carbon dioxide generating unit, and it makes the raw material and the water that by reacting with water, produce carbon dioxide react to produce carbon dioxide; (b) bubble injection unit, it is by the carbon dioxide having generated in advance with in bubble form injected water, and (c) above-mentioned carbon dioxide bubble is to generate by optionally carrying out the either party of this carbon dioxide generating unit and this bubble injection unit.Like this, can select from the either party of carbon dioxide generating unit and bubble injection unit the generation source of carbon dioxide bubble.
In addition, feature as the 9th invention, in the 8th invention, (a) above-mentioned raw materials material is the solid matter of regulation shape, (b) above-mentioned carbon dioxide generating unit comprises with respect to atmosphere reative cell airtight, that make above-mentioned raw materials material and water reaction, (c) by regulating the water yield of supplying with to above-mentioned reative cell, and the dipping water level of the above-mentioned raw materials material in this reative cell can be regulated, the reaction time of above-mentioned raw materials material can be controlled thus.Like this, can control well the growing amount of the carbon dioxide in carbon dioxide generating unit.
In addition, feature as the 10th invention, in the 8th or the 9th invention, (a) comprise optionally to carry out whether to above-mentioned gas bubble stream, for the carbonate spring feeding water, generate switching part, (b) above-mentioned bubble injection unit, has and can only by this carbonate spring generation switching part, inject the bubble supply valve of above-mentioned carbon dioxide in the situation that above-mentioned gas bubble stream supplies feedwater.Like this, in the situation that not generating carbonate spring, can easily stop the injection from the carbon dioxide of bubble injection unit.
In addition, feature as the 11st invention, in the 8th~10th any of inventing, (a) comprise to above-mentioned carbon dioxide generating unit supply with above-mentioned water the 1st supply unit, to above-mentioned bubble injection unit, supply with the 2nd supply unit of above-mentioned water and optionally to the either party of the 1st supply unit and the 2nd supply unit, supply with the selection portion of above-mentioned water, (b) above-mentioned bubble injection unit, has at the bubble that stops the injection of above-mentioned carbon dioxide by this selection portion in the situation that above-mentioned the 1st supply unit supplies feedwater and supplies with stop valve.Like this, control and only make to become easy being chosen as the injection of carrying out use bubble injection unit in the situation that from the carbon dioxide of bubble injection unit by above-mentioned selection portion.
The specific embodiment
Below, for one embodiment of the invention, Yi Bian with reference to accompanying drawing, explain on one side.
Embodiment 1
Fig. 1 is the figure of summary of the structure of the carbonate spring generating apparatus 10 of explanation in one embodiment of the invention.As shown in Figure 1, the carbonate spring generating apparatus 10 of the present embodiment has: for gas bubble stream 12 that carbon dioxide bubble is dissolved in the water with for by the carbon dioxide generating unit 20 of carbon dioxide bubble injected water and bubble injection unit 30.
Particularly, the water for example injecting from the water injection pipe portion 40 being connected with water channel, the selection portion 48 as triple valve by following, optionally circulate in the either party of the 1st supply unit 42 and the 2nd supply unit 44 or be truncated.In the situation of water flowing in the 1st supply unit 42, and as the tablet (tablet) 24 of raw material, react and produce carbon dioxide in following carbon dioxide generating unit 20.The carbon dioxide having produced former state with bubble form, sneaked under the state in water, by the generation switching part 46 as triple valve, circulate in gas bubble stream 12.
Switch generating unit 46 and be set up, with by the 2nd supply unit 44 be arranged on that the 1st of gas bubble stream 12 terminals spue portion 18 or the 2nd either party who spues portion 50 that do not spue by gas bubble stream 12 is optionally communicated with or blocks.By selection portion 48, make water circulate in the 2nd supply unit 44, and by generating switching part 46, water is being spued in the mobile situation of portion 18 to the 1st, bubble is by following bubble injection unit 30 injected waters.In addition, by selection portion 48, make water circulate in the 2nd supply unit 44, and by generating switching part 46, water is being spued in the mobile situation of portion 50 to the 2nd, can not generate carbonate spring, from the 2nd portion 50 that spues, be discharged to the water former state being injected into from water injection pipe portion 40.Moreover, for preventing owing to entering carbon dioxide generating unit 20 in the mobile water generation adverse current of the 2nd supply unit 44, the pipe arrangement of the water being discharged from from carbon dioxide supply unit 20, with the 2nd supply unit 44 interflow near be provided with check (non-return) valve 54.
Wherein, gas bubble stream 12 is for by following carbon dioxide generating unit 20 or bubble injection unit 30 and the current of injecting carbon dioxide bubble are logical, the stream that this carbon dioxide bubble is dissolved in the water thus.That is, carbon dioxide bubble is by Plug Flow(plug flow) mode (cast reactive mode) dissolving.In gas bubble stream 12, the effective diameter of gas bubble stream 12 is determined, so that the viscous drag of the carbon dioxide bubble in this water under the flow velocity of the mobile water of this gas bubble stream 12, become the situation that the carbon dioxide bubble in this gas bubble stream 12 is maximum diameter, more than being the buoyancy of this carbon dioxide bubble in the situation of effective diameter of this gas bubble stream 12.Like this, can prevent the flowing instability at the interior carbon dioxide bubble delay of gas bubble stream 12 and carbon dioxide bubble.This result, carbon dioxide can be dissolved in water well, obtains needing the carbonate spring of concentration.Moreover, below show as in the situation of water, except as otherwise noted, comprise the water that is injected with carbon dioxide bubble.
Particularly, according to Archimedes principle, buoyancy F draws according to following formula (1).
[several 1]
F = π D B 3 ρg 6 - - - ( 1 )
At this, D bfor the maximum [m] of bubble diameter, the density [kg/m that ρ is water 3], g is acceleration of gravity [ms -2].
On the other hand, if consider at the flow of the mobile water of gas bubble stream 12 etc., the water that circulates in gas bubble stream 12 is turbulent flow, its viscous drag R draws as shown in the formula (2) like that as the approximate expression obtaining according to experiment value.
[several 2]
R = π 8 D B 2 ρ C D v 2 - - - ( 2 )
At this C dthe resistance coefficient bearing for bubble, for
[several 3]
C D = ( 0.55 + 4.8 Re ) 2
Re is dimensionless number Reynolds number, Re=Dv ρ/μ,
D is the effective diameter [m] of gas bubble stream 12, the flow velocity that v is water [m/s], the viscosity that μ is water [Pas].
At this, the diameter of carbon dioxide bubble is maximum, is buoyancy F and viscous drag R balance in the situation of effective diameter of gas bubble stream 12, for
[several 4]
π 5 D B 2 ρ C D v 2 = π D B 3 ρg 6 - - - ( 3 )
By its arrangement, for
[several 5]
3 4 ( 0.55 + 4.8 Dvρ μ ) 2 v 2 = D B g - - - ( 4 )
Flow velocity v be flow H divided by the value of cross section (the passing through area) gained of gas bubble stream 12, for
[several 6]
v = 4 H π D 2
Therefore using above-mentioned (4) formula as flow H and bubble diameter D brelation decomposing solve and can draw relation as shown in Figure 2.From the relation obtaining in this wise, the flow H[m based on carbonate spring generating apparatus 10 needed water 3/ s], the effective diameter D[m of gas bubble stream 12] diameter D based on carbon dioxide bubble bmaximum set.Particularly, to become the mode in the region more than curve in Fig. 2, set the effective diameter of gas bubble stream 12.In the example of Fig. 2, known water for example in the mode of flow H=10L/ minute 12 circulation of gas bubble stream in the situation that, the effective diameter D of gas bubble stream 12 is about below 16.5mm.
Moreover, in the present embodiment, the effective diameter of pipe, the cross section that refers to pipe is corresponding to this diameter of a circle, in the situation that the shape beyond this, corresponding to the concept of the equal circular diameter of sectional area in circular situation.
On the other hand, in the present embodiment, carbon dioxide bubble in injected water dissolves by Plug Flow mode, therefore the length of gas bubble stream 12 is determined, so that the water that is injected with carbon dioxide bubble in the time (passing through the time) of gas bubble stream 12 circulations, becomes the concentration of ordinary dissolution of (desired) carbon dioxide in order to obtain stipulating more than the required time.At this, above-mentioned by time T [s] as the length L [m] of gas bubble stream 12 and the relation of the flow velocity v of mobile water therein, for
[several 7]
T = L v = πL D 2 4 H - - - ( 4 )
It is solved for L, for
[several 8]
L = 4 HT π D 2 - - - ( 5 )
Therefore, exist gas bubble stream 12 thinner, i.e. the length L of the less gas bubble of the effective diameter D stream 12 of gas bubble stream 12 relation of more growing of just having to.Particularly, according to the present application person's experiment, at flow H=8L/ minute, in the situation that the effective diameter D of gas bubble stream 12 is 12mm, for example for obtain as the carbonate spring of the 1000ppm of the gas concentration lwevel of expectation by time T, be about 4 seconds, so the length L of gas bubble stream 12 need to be more than about 5m.Moreover water is used as the concept that comprises water and hot water in this description.In addition, carbonate spring is used as the concept that extensively comprises the water that is dissolved with carbon dioxide, is not limited to for example to require the carbonate spring of the spa code regulation of gas concentration lwevel more than 250ppm.Moreover, in the situation that flowing of the water in gas bubble stream 12 can be seen complete turbulent flow as, the resistance coefficient C of bubble dalso can replace using above-mentioned (3) formula and be approximately C d=0.44.
In gas bubble stream 12, be provided with at least one restriction 14, the effective diameter of restriction 14 is less than the effective diameter of gas bubble stream 12 that restriction 14 is not set.Fig. 3 is the length direction of the gas bubble stream 12 that contains a restriction 14, i.e. axial sectional view.
When water passes through restriction 14 as shown in Figure 3, the carbon dioxide bubble injecting in this water is by grain refined.Therefore,, due to the contact area increase of carbon dioxide bubble and water, can expect that dissolution time shortens.According to inventor's experiment, learn at the effective diameter d that there is no the part of restriction 14 12in gas bubble stream 12 for 12mm, 5 effective diameter d have been configured 14after restriction 14 for 8mm, be the gas bubble stream 12 below 1.5m, just can realize with there is no the situation of restriction 14 under need the concentration of ordinary dissolution of the carbon dioxide that the gas bubble stream 12 of 5m is identical.That is,, by restriction 14 is set in gas bubble stream 12, can shorten the length of gas bubble stream 12.The length of this gas bubble stream 12 is designed, so that in the logical situation of carbon dioxide and current, can only spend carbon dioxide solubilized until the time of the desired gas concentration lwevel of carbonate spring generating passes through at gas bubble stream 12.
At this, by the effective diameter d of gas bubble stream 12 12be made as 12mm, the flow H of the water in 12 circulations of gas bubble stream is made as to 8L/ minute, repeatedly change the effective diameter d of restriction 14 14size, calculating gas bubble stream 12 does not have the part of restriction and the pressure differential of restriction 14, obtains relation as shown in Figure 4.Like this, minimum according to the difference of the big or small pressure differential of the effective diameter of restriction 14.Therefore, can think that the carbon dioxide bubble in water carries out grain refined, be not by restriction 14 with there is no the pressure differential of the part of restriction, but caused by speed difference.
The downstream than above-mentioned restriction 14 at gas bubble stream 12, is provided with pressure retaining parts 16.This pressure retaining parts 16 is openings of path or slit-shaped for example, in order to prevent due to the terminal part of gas bubble stream 12 opening significantly, thereby atmosphere enters to inside from the terminal part of gas bubble stream 12, the pressure drop in pipe to atmospheric pressure arranges.Thus, the pressure of the water in gas bubble stream 12 is maintained.
In addition, it is among this restriction 14 that expectation does one's utmost to shorten restriction 14(in the situation that a plurality of restriction 14 is set, be arranged on gas bubble stream 12 downstream, be the restriction 14 of pressure retaining parts 16 sides.Hereinafter referred to as final restriction 14.) and as the distance of shower head 18 of the 1st discharge opening of the carbonate spring that spues.Particularly; even be preferably made as by final restriction 14, by the carbon dioxide bubble of grain refined residue, dissolved in residual situation; from this final restriction 14 to dissolving residual bubble the stream of shower head 18, can partly not be detained yet, but keep the distance that spued from shower head 18 by the state of grain refined.Like this, can preventing from this final restriction 14 to the stream of shower head 18, dissolve residual bubble and be detained formation air pocket, this air pocket is by plug-flow once and by shower head 18, send bubble bubble sound, or mobile such situation that user does not feel soon that gives that gets clogged of water.This is in the situation that the hole of the carbonate spring that spues as shower head 18 is little effective especially.
The openings of sizes of the path in this pressure retaining parts 16, for example, can calculate approx from Bernoulli's theorem.Below an example of the calculation method of the effective diameter of pressure retaining parts 16 is described.Moreover, effective diameter and be man-to-man relation by area, determine either party the opposing party by unique decision, therefore as basic synonym things, describe in this manual.
Fig. 5 be pattern the present embodiment is described the figure of the mode of carbonate spring generating apparatus 10 while being connected with water-supply line.Water pipe 82 is by water main 80 branches.In addition, water pipe 82 is connected via the not shown fire hose is first-class with carbonate spring generating apparatus 10.That is, in the mode of Fig. 5, the hydraulic pressure by water pipe 82 to carbonate spring generating apparatus 10 for feedwater.Moreover, though do not represent in Fig. 5, also can between water pipe 82 and carbonate spring generating apparatus 10, water heater be set, to carbonate spring generating apparatus 10 supplying hot waters.
In such mode, the loss of the stream of water pipe 82 and/or not shown water heater etc. can not be ignored.Therefore, even the situation of the Bernoulli's theorem of the relation of applicable expression throttling and flow also needs to consider that friction loss is viscous drag.Moreover for the restriction 14 of carbonate spring generating apparatus 10, the thickness on the circulating direction of water as thin as a wafer, therefore can be ignored loss.Generally considered the Bernoulli's theorem (expansion Bernoulli's theorem) of friction loss, on certain point, the density of fluid is ρ, and flow velocity is v[m/s], pressure is P[Pa], be highly z[m] time, meet
[several 9]
Figure BDA0000454338580000101
Yet, if usually above-mentioned Reynolds is counted Re it is flowed for laminar flow to hundreds of scopes tens of, more than 1000 be turbulent flow on the contrary.In the carbonate spring generating apparatus 10 of the present embodiment, if this flow is considered pipe arrangement footpath etc., Reynolds is counted Re and is surpassed 10000, so the flowing for turbulent flow of its inside.Friction loss in turbulent flow (for example in the example of Fig. 5, B1, B2), the formula (7) below that can obtain according to experimentally is calculated.
[several 10]
Figure BDA0000454338580000102
At this, λ=0.3164/Re 0.25.
(7) formula of arrangement is
Loss=Bv 1.75
B=f(D, L, ρ, μ)=constant
At this, (8) formula is approximately
Loss ≈ Bv 2
If the source pressure of water main 80 is P 1near [Pa], water pipe 82 and coupling part carbonate spring generating apparatus 10 (near not shown tap; The 40(of water injection pipe portion is with reference to Fig. 1)) pressure be P 2[Pa], from being responsible for 80, near the loss coefficient above-mentioned tap, be B 1, the relation of following formula (9) is set up.
[several 11]
P 1 = 1 2 ρv 2 + P 2 + B 1 v 2 - - - ( 9 )
(9) in formula the right the 1st, be commonly referred to as dynamic pressure item.Fig. 6 represents the figure of the relation of this flowing pressure and flow L for the different water pipe 82 of diameter.As judged from Fig. 6, even if flow is 30L/ minute, for example, be that pipe arrangement footpath (diameter) is the pipe of 12mm, the value of dynamic pressure item mostly is 0.01MPa most.On the other hand, hydrostatic pressure is got for example such value of 0.2MPa, and therefore in (9) formula, dynamic pressure item can be ignored.Moreover, in " Give water device Standard Quasi Meter draws construction method 2.3 Let Meter and makes water consumption Decision fixed (decisions of water supply installation standard plan construction method 2.3 design Water usages) " of MHLW's water supply installation database; the water yield that shower is shown is 8~15L/ minute; above-mentioned flow 30L/ minute corresponding to being far longer than this value; in the situation that having supposed to use shower, far away higher than the situation of supposing the water yield.
According to more than, flow H[m 3/ s] with the pass of loss coefficient and pressure be
P 1≈P 2+B 1v 2 (10)
v 2=(P 1-P 2)/B (11)
Use is by the tube cofficients k of flow velocity v and flow H conversion, and flow H is expressed as
[several 12]
H = P 1 - P 2 b 1 , b 1 = k B 1 - - - ( 12 )
And then be conceived to flowing of water in the carbonate spring generating apparatus 10 of the present embodiment.The loss coefficient that makes the flow rate conversion of carbonate spring generating apparatus 10 is b 2, the hydraulic pressure before the upstream side of next-door neighbour's pressure retaining parts 16 is P 3, the relation of water main 80 and water pipe 82 similarly meets
[several 13]
H = P 2 - P 3 b 2 - - - ( 13 )
Relation.At this, water main 80, water pipe 82, carbonate spring generating apparatus 10 are connected as shown in Figure 5, so the flow H of formula (12) is identical with the flow H of formula (13).
In addition, due to the front and back for pressure retaining parts 16, represent that the left side of the formula (6) of Bernoulli's theorem is equal to each other, therefore meet
[several 14]
1 2 ρ ( 4 H π D 1 2 ) 2 + P 3 = 1 2 ρ ( 4 H πD 2 2 ) 2 - - - ( 14 )
Relation.At this, atmospheric pressure=0 of the rear side of pressure retaining parts 16 (downstream).According to above-mentioned (12) formula, (13) formula and (14) formula, P 2, P 3, H obtains respectively as follows
p 2=P 1-b 1H 2 (15)
p3=P 1-(b 1+b 2)H 2 (16)
[several 15]
H 2 = d 1 4 d 2 4 P 1 ( d 1 4 - d 2 4 ) ω + ( b 1 + b 2 ) d 1 4 d 2 4 - - - ( 17 )
At these ω=8 ρ/π 2.For d2, solve on the contrary, obtain as follows
[several 16]
d 2 4 = d 1 4 H 2 ω H 2 ω + d 1 4 P 1 - H 2 ( b 1 + b 2 ) d 1 4 - - - ( 18 )
The molecule denominator on the right is divided by H 2, for
[several 17]
d 2 4 = d 1 4 ω ω + d 1 4 P 1 H 2 - ( b 1 + b 2 ) d 1 4 - - - ( 19 )
This formula (18) and formula (19), can be used in the effective diameter that is met the such pressure retaining parts of certain flow H 16.
Pressure P at water main 80 1, or the friction loss of the stream of water, be the loss coefficient b of water pipe 82 specifically 1in situation about generally differing widely because of the value in the water channel of family etc., need to, to meet the mode of two important documents below, by (15) formula, (16) formula, (19) formula etc., carry out the effective diameter d of setting pressure maintaining part 16 2.
Important document A: by the hydraulic pressure P of water pipe 82 2more than maintaining authorized pressure.
Important document B: flow H is controlled and becomes specified flow weight range.
At this, the authorized pressure in important document A, refers to and can supply with by the control port of the bubble supply valve 36 to following and bubble supply stop valve 34, switches the minimum hydraulic pressure that this bubble supply valve 36 and bubble are supplied with the switch of stop valve 34.In addition, specified flow weight range in important document B, in view of following carbon dioxide generating unit 20 or the supply capacity of the carbon dioxide bubble in bubble injection unit 30 and/or the length of gas bubble stream 12 etc., by being, realize for example above CO of carbonate spring generating apparatus 10 desired carbonate springs like that of 1000ppm 2(be increased to it above is the CO of carbonate spring to the essential water yield of concentration 2the water yield that concentration ratio required value is low) as the upper limit of flow, and water yield when carbon dioxide is roughly saturated in water is as the lower limit of flow.The reason of lower limit is set in this wise, be because if in carbonate spring carbon dioxide roughly the saturated carbon dioxide bubble thoroughly not dissolving form air pocket and be present in carbonate spring, wasting cause.
In the present embodiment, pressure retaining parts 16 is thin sheet form, as shown in Figure 7, with as the gas bubble of flexible hose, reveal 12 when being connected as the 1st shower head 18 that spues portion, by clamping the pressure retaining parts 16 of this thin sheet form, connect and arrange.Particularly in the example of Fig. 7, when the threaded portion 76 that on the engagement member 70 arranging in the end of gas bubble stream 12, set threaded portion and end at shower head 18 arrange screws togather fixedly, clamping pressure maintaining part 16 and be arranged on the O type ring 72,74 of its both sides between the end of this gas bubble stream 12 and the end of shower head 18.This pressure retaining parts 16 and O type ring 72,74 also can form integrated member.
And, as pressure retaining parts 16, prepare the pressure retaining parts 16 of a plurality of different effective diameters, for example according to user, select an installation arbitrarily.At this, the pressure retaining parts 16 of above-mentioned a plurality of different effective diameters, for example, has the pressure P being set as for assumable water main 80 1, water pipe 82 loss coefficient b 1loss coefficient b with carbonate spring generating apparatus 10 2meet above-mentioned important document A and the effective diameter d of important document B 2.
Inventors of the present invention investigate and test, and determine the water yield (flow H) of supplying with from water-supply line and/or water heater and be 5L/ minute~scope of 30L/ minute.Therefore, the effective diameter of pressure retaining parts 16 (circulation area) is set, and makes in the situation that the water of the flow of this scope, to water injection pipe portion 40 supplies of carbonate spring generating apparatus 10, meets above-mentioned important document A and important document B.Moreover, if flow H, lower than 5L/ minute, generally becomes difficult possibility from shower head 18 water that spues that is shower shape high.
Fig. 8 is in the situation of effective diameter of certain pressure retaining parts of explanation, the figure of the water yield of the water of supplying with to carbonic acid generating apparatus 10 and the relation of the water yield of the carbonate spring of the generation corresponding with it.As shown in Figure 8, with respect to the increase of the water yield of supplying with, the increase of (spuing) carbonate spring amount of generation diminishes.This is at gas bubble stream 12, restriction 14 to be set like that because of above-mentioned, and the result of pressure retaining parts 16 is set, the confined cause of flow of the water circulating at gas bubble stream 12.Therefore, in the carbonate spring generating apparatus 10 of the present embodiment, even supply the situation of feedwater with the scope of above-mentioned flow H to carbonate spring generating apparatus 10, suppose the situation that the water of the upper limit of the scope of above-mentioned flow H is supplied with to carbonate spring generating apparatus 10 and produce carbon dioxide bubble, can reduce and thoroughly not dissolve and become remaining carbon dioxide bubble amount.Say on the contrary it, even the situation that the water more than the water yield of hypothesis is supplied with to carbonate spring generating apparatus 10, it is slow that the decline of the gas concentration lwevel in the carbonate spring of generation also becomes.
In the carbonate spring generating apparatus 10 of the present embodiment, gas bubble stream 12 is set up such as the flexual pipe as flexible pipe etc.Thus, in the situation that spue, the 1st of carbonate spring the spues that shower to be set in portion 18 first-class, the flexible pipe of the stream being connected as portion 18 that the framework and the 1st of accommodating following carbon dioxide generating unit 20 or bubble injection unit 30 etc. is spued can become gas bubble stream 12, therefore the length of pipe of carbonate spring generating apparatus 10 can further shorten, and can make carbonate spring generating apparatus 10 compactnesses.
In addition, the carbonate spring generating apparatus 10 of the present embodiment is provided with water flow generator 56 on gas bubble stream 12.This water flow generator 56, when water is in the situation that gas bubble stream 12 is mobile, generates electricity by turbine of being rotated by this water etc.Water flow generator 56 is electrically connected to LED58, can be luminous in the situation that water flow generator 56 generates electricity.Therefore whether thus, when water, LED58 in the situation that gas bubble stream 12 is mobile is luminous, in the situation that can switch carbonate springs by following generation switching part 46 and generate, generate carbonate spring and can easily confirm by vision.
Carbon dioxide generating unit 20 comprises reative cell 22.The tablet 24 dropping into as raw material in reative cell 22 is configured.In reative cell 22, also can be configured to disposable overlapping a plurality of tablets 24.This tablet 24 comprises the material that for example produces carbon dioxide by solubilizing reaction in water, contains particularly such as sodium acid carbonate, soda ash, malic acid, binding agent etc. and forms.Reative cell 22 is airtight with atmosphere, and the carbon dioxide having produced can not gone in atmosphere.
Water flows into reative cell 22 from the above-mentioned triple valve as selector valve 48, discharges on the other hand from being arranged at the export department 26 of reative cell 22.Now, set the position of export department 26 so that the dipping water level of the tablet 24 in reative cell 22 reaches the value of expectation.That is, by the dipping water level of tablet 24 being made as to the value of expectation, make tablet 24 and water reaction speed, be the formation speed of carbon dioxide, become the value corresponding with the concentration of the carbonate spring of wanting in carbonate spring generating apparatus 10 to generate.
Tablet 24 is impregnated into predetermined water level like this, so water and the speed responsing of tablet 24 to expect, produces carbon dioxide.The carbon dioxide having produced sneaked into the state in water with bubble form under, is discharged from export department 26.
Bubble injection unit 30, the carbon dioxide that the dioxide bottle from being connected with this bubble injection unit 30 38 is supplied with is infused in the interior mobile water of carbonate spring generating apparatus 10 with bubble form.Flow control valve 32, bubble that this bubble injection unit 30 has for controlling the injection rate of carbon dioxide are supplied with stop valve 34, bubble supply valve 36 etc. and are formed.With the carbon dioxide of having supplied with from dioxide bottle 38, Jie is provided with pipe arrangement by flow control valve 32, bubble supply stop valve 34, the mobile mode of bubble supply valve 36, and, at the front end of bubble supply valve 36, the pipe arrangement of water flow connects at the connecting portion 37 of the upstream side of gas bubble stream 12.The connecting portion 37 of the 2nd supply unit 44 is equivalent to the inlet of carbon dioxide bubble, at this connecting portion 37 to injecting carbon dioxide bubble in water.
Wherein, flow control valve 32 is the flow of carbon dioxide and/or valves of pressure of supplying with from dioxide bottle 38 for adjusting, and this pressure is considered to want the length etc. of the concentration of the carbonate spring that obtains and/or the water yield, gas bubble stream 12 to be set according to carbonate spring generating apparatus 10.
Bubble is supplied with stop valve 34, is to have adjusted for controlling by flow control valve 32 the so-called the switch valve whether carbon dioxide of pressure is supplied with.To this bubble, supply with the control port of stop valve 34, supply with the hydraulic pressure of the 1st connecting portion 33 being connected with the 1st supply unit 42.Bubble is supplied with the valve that stop valve 34 be open type, supplies with valve in the situation of authorized pressure close to control port, to the common time valve of the situation of control port supply authorized pressure, does not open on the other hand.That is, in selection portion 48, make current direction the 1st supply unit 42 sides, the 1st supply unit 42 has been supplied with in the situation of hydraulic pressure, bubble is supplied with stop valve 34 and is closed, and does not carry out injecting from the bubble of bubble injection unit 30.On the other hand, in the situation that selection portion 48 makes current direction the 2nd supply unit 44 side, not to the 1st connecting portion 33, be that the control port that bubble is supplied with stop valve 34 applies hydraulic pressure, so bubble is supplied with stop valve 34, open, make to pass through to bubble supply valve 36 from the carbon dioxide of flow control valve 32.Like this, the in the situation that of current direction the 1st supply unit 42, by above-mentioned carbon dioxide generating portion 20, carry out the generation of carbon dioxide, therefore can automatically prevent that the injection of the carbon dioxide bubble that undertaken by bubble injection unit 30 from repeating.
Bubble supply valve 36 is to have passed through bubble and supply with the so-called the switch valve whether carbon dioxide of stop valve 34 is supplied with for controlling.To the control port of this bubble supply valve 36, supply with and to generate the spue hydraulic pressure of mobile water between portion 18 of switching part 46 and the 1st.The valve that bubble supply valve 36 is closed type, in the situation that supplying with authorized pressure to control port, valve is opened, and does not have on the other hand common time valve from the situation of pressure to control port that supply with to close.Particularly, make water lead to the 1st situation that spues portion 18 generating switching part 46, be set as carrying out in the situation of generation of carbonate spring, bubble supply valve 36 is opened, and carries out injecting from the bubble of bubble injection unit 30.On the other hand, make water lead to the 2nd situation that spues portion 50 generating switching part 46, do not carry out in the situation of generation of carbonate spring the hydraulic pressure that hydraulic pressure from the 2nd connecting portion 35 is not supplied with to bubble control valve 36, bubble supply valve 36 cuts out, and carbon dioxide is stopped to the supply of inlet 37.Like this, only made water spue portion's 18 supply from gas bubble stream 12 to the 1st by generation switching part 46 in the situation that, by bubble injection unit 30, carry out the injection of carbon dioxide bubble, therefore can prevent from consuming carbon dioxide in the situation that not needing to carry out carbonate spring generation.Moreover, between bubble supply valve 36 and connecting portion 37, be provided with check (non-return) valve 52, prevent that water from immersing bubble supply valve 36.
In this wise, in the bubble injection unit 30 of the carbonate spring generating apparatus 10 of the present embodiment, above-mentioned bubble is supplied with stop valve 34 setting of being connected with bubble supply valve 36 quilts, therefore can only pass through selection portion 48 to the 2nd supply unit 44 water flowings, and spue in the situation of portion's 18 water flowings, by the bubble injected water of the carbon dioxide of supplying with from dioxide bottle 38 to the 1st by generating switching part 46.That is, make selection portion 48 be communicated with the 1st supply unit 42 sides, and make to generate switching part 46 and be communicated with the 1st and spue in the situation of portion's 18 sides, utilizing the carbonate spring of the carbon dioxide having been generated by carbon dioxide generating unit 20 to generate.Make selection portion 48 be communicated with the 2nd supply unit 44 sides, and making to generate switching part 46 and be communicated with the 1st and spue in the situation of portion's 18 sides, utilizing the carbonate spring of the carbon dioxide of being supplied with from dioxide bottle 38 by bubble injection unit 30 to generate.Even and make selection portion 48 be communicated with the situation of the 2nd supply unit 44 sides, also can be communicated with the 2nd and stop the supply from the carbon dioxide of dioxide bottle 38 spue portion's 50 side in the situation that making to generate switching part 46.
According to the carbonate spring generating apparatus 10 of the present embodiment, the gas bubble stream 12 with the water flow that is mixed with carbon dioxide bubble, by this carbon dioxide bubble, be dissolved in water and generate carbonate spring, gas bubble stream 12 has at least one restriction 14, with pressure retaining parts 16, above-mentioned restriction 14 is cut apart carbon dioxide bubble, above-mentioned pressure retaining parts 16 remains on the hydraulic pressure in gas bubble stream 12 in outlet side one end of gas bubble stream 12, the effective diameter of gas bubble stream 12 is determined, so that the viscous drag R of the bubble under the flow velocity v of the mobile water of gas bubble stream 12, more than the buoyancy F of the carbon dioxide bubble in the situation that to become carbon dioxide bubble be the maximum diameter D of this effective diameter, the length of gas bubble stream 12 is determined, so that in circulating in the water that is mixed with carbon dioxide bubble of gas bubble stream 12, guarantee for making the concentration of carbon dioxide arrive the dissolution time of normal concentration, the effective diameter of restriction 14 is less than gas bubble stream 12, pressure retaining parts 16 have for the hydraulic pressure of carbonate spring generating apparatus 10 inside is maintained the dissolving that can promote carbon dioxide bubble pressure pass through area.Like this, carbon dioxide bubble in water is cut apart by restriction 14 so the contact area of carbon dioxide bubble and water increases, and the effective diameter by gas bubble stream 12 does not flow bubble with being detained, therefore can increase the time of contact of carbon dioxide bubble and water.By pressure retaining parts 16, the hydraulic pressure of carbonate spring generating apparatus 10 inside is maintained at the pressure of the dissolving that can promote carbon dioxide bubble in addition, therefore can by the raising hydraulic pressure such as pump are set, not promote carbon dioxide to the dissolving of water.And by gas bubble stream 12, make to be mixed with the water of carbon dioxide bubble, the concentration of the carbon dioxide that circulates in this gas bubble stream, for more than reaching the dissolution time of normal concentration, therefore can obtain the carbonate spring of normal concentration.Like this, at the water-supply line with general (for example, the minimum flowing pressure that is designed to the local sparge pipe from sparge pipe to feed pipe branch is not less than 150kPa(with reference to 8 sections of 7 of ministerial level decrees determining the technical standard of water facilities)) situation about connecting, need to be for carbon dioxide solubility not be improved to hydraulic pressure in water by pump etc., (for example can guarantee the pressure of the carbonate spring that spues from shower head 18 and the water yield, the water yield 8~15L/ minute, hydraulic pressure 0.07MPa(is with reference to each communal water supply project implementation criteria etc.)).
According to the carbonate spring generating apparatus 10 of the present embodiment, being set by area of pressure retaining parts 16, so that in the situation that the flow of the water of supplying with to carbonate spring generating apparatus 10 is the scope of 5L/ minute~30L/ minute, the hydraulic pressure of carbonate spring generating apparatus 10 inside is maintained to the pressure of the dissolving that can promote carbon dioxide bubble, therefore in the situation that the water yield of generally supplying with by water channel or hot water supply apparatus be the scope of 5L/ minute~30L/ minute for feedwater, can by raising hydraulic pressure such as pumps, not generate carbonate spring.
According to the carbonate spring generating apparatus 10 of the present embodiment, the distance of the portion that spues of above-mentioned restriction and above-mentioned carbonate spring is determined, so that the carbon dioxide bubble of having been cut apart by final restriction 14 can be in conjunction with becoming large so that hindering carbonate spring to flow to the shower head 18 as the portion that spues of carbonate spring, even therefore by final restriction 14 grain refined carbon dioxide bubble dissolve residual situation, the carbonate spring stream from final restriction 14 to shower head 18, dissolve residual bubble also divided and keep the state of grain refined to be spued from the portion of spuing, can prevent from dissolving residual bubble and be detained formation air pocket from final restriction 14 to the stream of the carbonate spring of shower head 18, this air pocket is by plug-flow once and send bubble bubble sound by the portion of spuing, or the flow blockage of water is such gives user the not situation of sensation soon.
According to the carbonate spring generating apparatus 10 of the present embodiment, the length of gas bubble stream 12 is determined, so that in circulating in the water that is mixed with carbon dioxide bubble of gas bubble stream 12, guarantee for making the concentration of carbon dioxide arrive the roughly dissolution time of saturated concentration, the concentration that therefore can be not generate carbon dioxide by raisings hydraulic pressure such as pumps is the carbonate spring of saturated concentration roughly.
According to the carbonate spring generating apparatus 10 of the present embodiment, the passing through area and can change of pressure retaining parts 16, even therefore in the situation that the water yield H of the water of supplying with to carbonate spring generating apparatus 10 is different, also can by change pressure retaining parts 16 by area, set the suitable area that passes through, can by raising hydraulic pressure such as pumps, not generate carbonate spring.
According to the carbonate spring generating apparatus 10 of the present embodiment, pressure retaining parts 16 has the effective diameter d2 less than the effective diameter d1 of gas bubble stream 12, can from the different a plurality of pressure retaining parts of effective diameter, optionally install.Therefore,, even flow into hydraulic pressure P2 and/or the different situation of flow H of the water of carbonate spring generating apparatus 10, also can prevent that the hydraulic pressure P3 in gas bubble stream 12 from dropping to atmospheric pressure.Meanwhile, owing to can guaranteeing for making bubble supply valve 36, bubble supply with the hydraulic pressure of stop valve 34 work, so can supply with the work that stop valve 34 is controlled bubble injection unit 30 well by this bubble supply valve 36, bubble.
According to the carbonate spring generating apparatus 10 of the present embodiment, gas bubble stream 12 is flexual pipe, therefore gas bubble stream 12 can be made as to the flexual pipes such as flexible pipe.Therefore,, than beyond gas bubble stream, the situation of flexible pipe being only set for water distribution, can shorten as a whole the length of pipe arrangement.
According to the carbonate spring generating apparatus 10 of the present embodiment, there is carbon dioxide generating unit 20 and bubble injection unit 30, the raw material that above-mentioned carbon dioxide generating unit 20 makes to produce by reacting with water carbon dioxide is that tablet 24 and water react to produce carbon dioxide, above-mentioned bubble injection unit 30 is by the carbon dioxide in the dioxide bottle 38 having generated in advance with in bubble form injected water, and carbon dioxide bubble is to generate by optionally carrying out the either party of carbon dioxide generating unit 20 and bubble injection unit 30.Like this, the generation source of carbon dioxide bubble can be selected from any of carbon dioxide generating unit 20 and bubble injection unit 30.
According to the carbonate spring generating apparatus 10 of the present embodiment, comprise optionally to carry out and whether to gas bubble stream 12, for the carbonate spring feeding water, generate switching part 46, bubble injection unit 30 has the only bubble supply valve 36 of injecting carbon dioxide generate switching part 46 to the 12 confession feedwater of gas bubble stream by carbonate spring in the situation that, therefore in the situation that not generating carbonate spring, can easily stop the injection from the carbon dioxide of bubble injection unit 30.
According to the carbonate spring generating apparatus 10 of the present embodiment, comprise the 1st supply unit 42 for feedwater to carbon dioxide generating unit 20, the 2nd supply unit 44 to bubble injection unit 30 for feedwater, optionally to the either party of the 1st supply unit 42 and the 2nd supply unit 44, supply the selection portion 48 of feedwater, bubble injection unit 30 has at the bubble that stops the injection of carbon dioxide by selection portion 48 in the situation that the 1st supply unit 42 supplies feedwater supplies with stop valve 34, therefore control as only carrying out becoming easy from the carbon dioxide injection of bubble injection unit 30 being chosen as by selection portion 48 use bubble injection unit 30 in the situation that.
Then, other embodiment of the present invention are described.In the following description, for the part mutual common with embodiment, description thereof is omitted to enclose identical mark.
Embodiment 2
Fig. 9~Figure 11 is the figure of other embodiments of the carbon dioxide generating unit in the carbonate spring generating apparatus 10 of explanation the present embodiment.
The carbon dioxide generating unit 120 of Fig. 9, corresponding to the carbon dioxide generating unit 20 of above-described embodiment 1, difference be its export department 126 compare with the export department 26 of the carbon dioxide generating unit 20 of above-described embodiment be arranged on top.In reative cell 22 middle water levels, rise to higher height like this, therefore more tablet 24 impregnated in water, can increase the generation of carbon dioxide.In addition, as shown in Figure 9, by by tablet 24 overlay configuration in the vertical, can make a plurality of tablets 24 flood simultaneously.
The carbon dioxide generating unit 130 of Figure 10, corresponding to the carbon dioxide generating unit 20 of above-described embodiment 1, is provided with bypass flow path 134 with reative cell 22 and the mobile parallel mode of water.Like this, a part that circulates in the water of the 1st supply unit 42 by the portion of selecting 48 is passed through this bypass flow path 134, therefore by reative cell 22.Therefore, the water yield of the water by reative cell 22 is compared and is not had the situation of bypass flow path 134 to reduce.Tablet 24 diminishes to the pickup of water, can make the generation of carbon dioxide reduce.
The carbon dioxide generating unit 140 of Figure 11, corresponding to the carbon dioxide generating unit 20 of above-described embodiment 1, same with the carbon dioxide generating unit 130 of Figure 10, with reative cell 22 and the mobile parallel mode of water, be provided with on bypass flow path 134 these aspects common.And the carbon dioxide generating unit 140 of Figure 11, in the stream for feedwater to reative cell 22, is provided with for controlling the flow control valve 146 of flow of the water of this stream.By controlling this flow control valve 146, than the example of the carbon dioxide generating unit 130 of Figure 10, can further make to flow into the discharge reduction of reative cell 22, therefore can control so that the amount of carbon dioxide minimizing producing.Moreover in the example of Figure 11, flow control valve 146 is arranged on the downstream with bypass flow path 134 branches, but is not limited to such mode, also can be arranged on the upstream side of bypass flow path 134 branch location.
According to the carbonate spring generating apparatus 10 of the present embodiment, raw material is that tablet 24 is used as the solid matter of regulation shape, carbon dioxide generating unit 20 comprises with respect to atmosphere reative cell 22 airtight, that tablet 24 is reacted with water, can regulate the water yield of supplying with to reative cell 22, and can regulate the dipping water level of the tablet 24 in reative cell 22, can control the reaction time of tablet 24 thus, therefore can control well the growing amount of the carbon dioxide in carbon dioxide generating unit 20.
Above, based on accompanying drawing, embodiments of the invention are had been described in detail, but the present invention is also applicable to other modes.
For example, in the above-described embodiment, be provided with for by the carbon dioxide generating unit 20 of carbon dioxide bubble injected water and bubble injection unit 30 both, but not necessarily must both, as long as possess any one and above-mentioned gas bubble stream 12, can bring into play and can not need to pressurize and carry out the generation of carbonate spring by pump etc., and the effect of the present invention that carbonate spring generating means 10 can miniaturization.
In the above-described embodiment, gas bubble stream 12 is set as flexual pipe, but is not limited to this.It is also harmless that gas bubble stream 12 is made as the effigurate pipe arrangement of tool.In this situation, gas bubble stream 12 also can be arranged in the framework of carbonate spring generating apparatus 10.In addition, flexual pipe important document not necessarily in the situation that gas bubble stream 12 is made as the effigurate pipe arrangement of this tool.And, exemplified with shower head, being arranged on the 1st portion 18 that spues, but being not limited thereto, shower head is important document not necessarily.
In the above-described embodiment, in gas bubble stream 12, be provided with a plurality of restriction 14 but be not limited to this.The effect that at least one restriction 14 can produce the application is set in gas bubble stream 12.
In the above-described embodiment, exemplified with the opening that is shaped as circle, slit-shaped of pressure retaining parts 16, but be not limited to such shape.As long as meet the condition that atmosphere do not enter gas bubble stream 12, just not limit shape.
In addition in the above-described embodiment, from generating switching part 46, to the 1st, spuing the stream of portion 18 and be provided with water flow generator 56, LED58, but these important documents not necessarily, even situation about not arranging also can obtain effect of the present invention.
In addition in the above-described embodiment, export department 26 is arranged on the height of regulation, but is not limited thereto as shown in Fig. 1, Fig. 7 etc.For example, also can adopt the method for any opening among the export department that optionally makes to be arranged on a plurality of height to change its height.
In addition in the above-described embodiment, injection unit 37 is arranged on selection portion 48 and generates on the pipe arrangement between switching part 46, but is not limited to this.Before from the 2nd supply unit 44 to gas bubble stream 12, can produce same effect.
In addition, in the above-described embodiment, pressure retaining parts 16 is clamped and is installed by O type ring 72,74 between the end of gas bubble stream 12 and shower head 18, but is not limited to this, so long as prevent that the parts that leak or flow into from outside air of carbonate spring are just not limited to O type ring.
In addition, in the above-described embodiment, pressure retaining parts 16, by installing from one that selects among the different a plurality of pressure retaining parts 16 of effective diameter, can change it by area, but be not limited to such mode.Particularly for example, as pressure retaining parts, it is that valve that effective diameter can change continuously also can be used as pressure retaining parts and is set up by area.
In addition, in the above-described embodiment, the effective diameter (passing through area) that changes pressure retaining parts 16 on the basis of water yield H that flows into carbonate spring generating apparatus 10 to be to meet above-mentioned important document A and B, but is not limited to such mode.For example, also can replace the effective diameter of pressure retaining parts 16 or outside this, set the amount of the carbon dioxide bubble producing by carbon dioxide generating unit 20 or bubble injection unit 30, to meet above-mentioned important document A and B.Like this, with the above embodiments similarly, with respect to the water of above-mentioned flow, can not reduce as far as possible thoroughly and dissolve and the carbon dioxide bubble of waste, can be met on the other hand the carbonic acid of carbonate spring generating apparatus 10 desired gas concentration lwevels.
Moreover, although do not mention for water temperature in the above embodiments, but the design that the temperature of the water that also can consider the temperature of the carbonate spring that generates or supply with to carbonate spring generating apparatus 10 changes carbonate spring generating apparatus 10, the specifically injection rate of the length of gas bubble stream 12 and/or the carbon dioxide that undertaken by carbon dioxide generating unit 20, bubble injection unit 30 etc.That is, because carbon dioxide bubble is the more high more indissoluble of water temperature solution, therefore can the more high length of gas bubble stream 12 or the amount of carbon dioxide that minimizing is produced by carbon dioxide generating unit 20, bubble injection unit 30 of more increasing of water temperature.Like this, even the high situation of water temperature also can be guaranteed the gas concentration lwevel in carbonate spring, or can not reduce the carbon dioxide that does not thoroughly dissolve and waste.
In the above embodiments, the example of the situation that is 1000ppm for the gas concentration lwevel of carbonate spring generating apparatus 10 desired carbonate springs is illustrated, but is not limited thereto.The carbonate spring concentration that is usually used for bathing use is more high better, therefore also can generate the roughly carbonate spring of saturated concentration of gas concentration lwevel.At this, roughly saturated concentration (roughly saturated concentration), refers to the concentration that can regard the concentration that almost reaches capacity as, for example, be confirmed as 95% degree of saturated concentration above, can be also the concept that comprises saturated concentration.Near saturated concentration, dissolution velocity obviously declines, therefore improve concentration till compare and need the considerable time with this concentration of arrival more than that, on the other hand if can regard the concentration that roughly arrives above-mentioned saturated concentration as, can obtain the effect of the situation based on saturated concentration, be therefore the concentration of considering these settings.In this situation, different according to the meltage of the water temperature carbon dioxide of the water of supplying with to carbonate spring generating apparatus 10 as mentioned above, therefore can consider that this factor carries out the design of carbonate spring generating apparatus 10.
Accompanying drawing explanation
Fig. 1 is the figure of an example of the structure of explanation carbonate spring generating apparatus of the present invention.
Fig. 2 is explanation for making the caliber (effective diameter) of gas bubble stream that the bubble of water do not flow with being detained and the figure of the relation of its flow.
Fig. 3 is the figure that the cross section of the part that comprises restriction in gas bubble stream is described.
Fig. 4 is the figure that explanation is relative with the effective diameter of restriction, gas bubble stream does not have the part of restriction and the pressure differential of restriction.
Fig. 5 is the figure of each variable in explanation pressure retaining parts and the gas bubble stream that is adjacent.
Fig. 6 means the figure of the relation of pressure retaining parts and the pressure differential of gas bubble stream being adjacent and the maximum diameter of pressure retaining parts.
Fig. 7 is the figure of an example of the structure of explanation pressure retaining parts.
Fig. 8 is that explanation is to the figure of the relation of the water yield of carbonate spring generating apparatus supply and the growing amount of carbonate spring.
Fig. 9 is the figure of an example of the structure of the carbon dioxide generating unit of explanation in another embodiment of the present invention.
Figure 10 is the figure of an example of the structure of the carbon dioxide generating unit of explanation in another embodiment of the present invention.
Figure 11 is the figure of an example of the structure of the carbon dioxide generating unit of explanation in another embodiment of the present invention.
Sign flag explanation
10: carbonate spring generating apparatus
12: gas bubble stream
14: restriction
16: pressure retaining parts
20,120,130,140: carbon dioxide generating unit
22: reative cell
24: tablet
26: export department
30: bubble injection unit
34: bubble is supplied with stop valve
36: bubble supply valve
37: inlet
40: water injection pipe portion
42: the 1 supply units
44: the 2 supply units
46: carbonate spring generates switching part
48: selection portion

Claims (11)

1. a carbonate spring generating apparatus, is characterized in that,
This carbonate spring generating apparatus has the gas bubble stream of the water flow that is mixed with carbon dioxide bubble, and by this carbon dioxide bubble, be dissolved in this water and generate carbonate spring,
This gas bubble stream has at least one restriction and pressure retaining parts, described restriction is cut apart described carbon dioxide bubble, described pressure retaining parts is arranged on the downstream by this gas bubble stream than this restriction, keeps the hydraulic pressure in described gas bubble stream
The effective diameter of this gas bubble stream is determined, so that the viscous drag of the bubble under the flow velocity of the described water of this gas bubble flow path, more than the buoyancy of the described carbon dioxide bubble in the situation that to become described carbon dioxide bubble be the maximum diameter of this effective diameter
The length of this gas bubble stream determined so that circulate in this gas bubble stream described in be mixed with in the water of carbon dioxide bubble, guarantee for making the concentration of carbon dioxide arrive the dissolution time of normal concentration,
The effective diameter of described restriction is less than described gas bubble stream,
Described pressure retaining parts, have for the hydraulic pressure of this carbonate spring generating apparatus inside is maintained the dissolving that can promote described carbon dioxide bubble pressure pass through area.
2. carbonate spring generating apparatus according to claim 1, is characterized in that,
Being set by area of described pressure retaining parts, so that in the situation that the flow of the water of supplying with to described carbonate spring generating apparatus is the scope of 5L/ minute~30L/ minute, the hydraulic pressure of this carbonate spring generating apparatus inside is maintained to the pressure of the dissolving that can promote described carbon dioxide bubble.
3. carbonate spring generating apparatus according to claim 1 and 2, is characterized in that,
The distance of the portion that spues of described restriction and described carbonate spring determined, so that the described carbon dioxide bubble of having been cut apart by described restriction can be in conjunction with becoming large so that hindering carbonate spring to flow to the portion that spues of carbonate spring.
4. according to the carbonate spring generating apparatus described in any one of claim 1~3, it is characterized in that,
The length of this gas bubble stream determined so that circulate in this gas bubble stream described in be mixed with in the water of carbon dioxide bubble, guarantee for making the concentration of carbon dioxide arrive the roughly dissolution time of saturated concentration.
5. according to the carbonate spring generating apparatus described in any one of claim 1~4, it is characterized in that the passing through area and can change of described pressure retaining parts.
6. according to the carbonate spring generating apparatus described in any one of claim 1~5, it is characterized in that described pressure retaining parts can optionally be installed from pass through the different a plurality of pressure retaining parts of area.
7. according to the carbonate spring generating apparatus described in any one of claim 1~6, it is characterized in that, described gas bubble stream is flexual pipe.
8. according to the carbonate spring generating apparatus described in any one of claim 1~7, it is characterized in that having:
Carbon dioxide generating unit, it makes the raw material and the water that by reacting with water, produce carbon dioxide react to produce carbon dioxide; With
Bubble injection unit, its by the carbon dioxide having generated in advance with in bubble form injected water,
Described carbon dioxide bubble is to generate by optionally carrying out the either party of this carbon dioxide generating unit and this bubble injection unit.
9. carbonate spring generating apparatus according to claim 8, is characterized in that,
Described raw material is the solid matter of regulation shape,
Described carbon dioxide generating unit comprises with respect to atmosphere reative cell airtight, that make described raw material and water reaction,
By regulating the water yield of supplying with to described reative cell, and the dipping water level of the described raw material in this reative cell can be regulated, the reaction time of described raw material can be controlled thus.
10. carbonate spring generating apparatus according to claim 8 or claim 9, is characterized in that,
Comprise optionally to carry out whether to described gas bubble stream, for the carbonate spring feeding water, generate switching part,
Described bubble injection unit, has and can only by this carbonate spring generation switching part, inject the bubble supply valve of described carbon dioxide in the situation that described gas bubble stream supplies feedwater.
Carbonate spring generating apparatus described in 11. according to Claim 8~10 any one, is characterized in that,
Comprise to described carbon dioxide generating unit supply with described water the 1st supply unit, to described bubble injection unit, supply with the 2nd supply unit of described water and optionally to the either party of the 1st supply unit and the 2nd supply unit, supply with the selection portion of described water,
Described bubble injection unit, has at the bubble that stops the injection of described carbon dioxide by this selection portion in the situation that described the 1st supply unit supplies feedwater and supplies with stop valve.
CN201280033880.1A 2011-12-09 2012-10-19 Carbonate spring generating apparatus Active CN103648627B (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP2011-270557 2011-12-09
JP2011270557A JP6032456B2 (en) 2011-12-09 2011-12-09 Carbonate spring generator
PCT/JP2012/077165 WO2013084603A1 (en) 2011-12-09 2012-10-19 Carbonated spring generating device

Publications (2)

Publication Number Publication Date
CN103648627A true CN103648627A (en) 2014-03-19
CN103648627B CN103648627B (en) 2016-05-25

Family

ID=48573986

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201280033880.1A Active CN103648627B (en) 2011-12-09 2012-10-19 Carbonate spring generating apparatus

Country Status (3)

Country Link
JP (1) JP6032456B2 (en)
CN (1) CN103648627B (en)
WO (1) WO2013084603A1 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111111491A (en) * 2020-01-02 2020-05-08 科勒(中国)投资有限公司 Carbonated water redissolving device and carbonated water generating equipment

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2015008758A (en) * 2013-06-26 2015-01-19 株式会社イマイ Spring unit
KR102011774B1 (en) * 2018-12-11 2019-08-19 (주)휴앤스 Device for manufacturing hydrogen water without water storage tank
JP7350564B2 (en) * 2019-08-19 2023-09-26 敏夫 宮下 Gas-liquid mixing device
JP7352254B2 (en) * 2019-09-27 2023-09-28 敏夫 宮下 Gas-liquid mixing device

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001170463A (en) * 1999-12-14 2001-06-26 Sanyo Electric Co Ltd Carbonated water producing apparatus
JP2008073189A (en) * 2006-09-21 2008-04-03 Act Engineering:Kk Apparatus for producing carbonated spring using circulating bathtub water
CN101349629A (en) * 2001-08-28 2009-01-21 三菱丽阳株式会社 Detection method for gas density applied to dissolving solution, manufacturing apparatus for gas dissolving solution and membrane member

Family Cites Families (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH09290280A (en) * 1996-04-30 1997-11-11 Meidensha Corp Ozone contact tank and control method therefor
JPH10244138A (en) * 1997-02-28 1998-09-14 Idec Izumi Corp Method and device for mixing and dissolving gas and liquid
JPH1119167A (en) * 1997-07-04 1999-01-26 Matsushita Electric Ind Co Ltd Carbonated bathing agent supplier
JP2001137146A (en) * 1999-11-18 2001-05-22 Toto Ltd Water discharge controlling equipment
JP3700513B2 (en) * 2000-01-26 2005-09-28 松下電工株式会社 Bathtub water circulation device
JP4709357B2 (en) * 2000-08-30 2011-06-22 三菱レイヨン株式会社 Portable foot tub
JP2002369762A (en) * 2001-06-14 2002-12-24 Matsushita Electric Works Ltd Foam generator
JP4854942B2 (en) * 2003-08-25 2012-01-18 アクアインテック株式会社 Microbubble generator
JP2006272094A (en) * 2005-03-28 2006-10-12 Matsushita Electric Works Ltd Fine bubble generator
JP2006346638A (en) * 2005-06-20 2006-12-28 Aura Tec:Kk Discharging passage of pressure dissolution apparatus
JP5038600B2 (en) * 2005-06-27 2012-10-03 パナソニック株式会社 Microbubble generator
JP4711227B2 (en) * 2005-11-09 2011-06-29 央 澤栗 Bath gas dissolution production equipment
JP4890143B2 (en) * 2006-08-01 2012-03-07 シャープ株式会社 Mixing and dispersing device
JP2008212495A (en) * 2007-03-06 2008-09-18 Hiroshi Sawakuri Carbonated spring generator
JP2008289990A (en) * 2007-05-23 2008-12-04 Toshio Miyashita Discharge nozzle of microbubble-carbonate spring generator
JP2009172133A (en) * 2008-01-24 2009-08-06 Aisin Seiki Co Ltd Apparatus for fine air bubble bath
JP2010000190A (en) * 2008-06-19 2010-01-07 Sharp Corp Artificial medical treatment spring manufacturing apparatus
JP2010022624A (en) * 2008-07-22 2010-02-04 Sharp Corp Footbath device and footbath water manufacturing method
JP5197762B2 (en) * 2008-12-12 2013-05-15 三菱電機株式会社 Hot water supply method and hot water supply apparatus
JP2010142336A (en) * 2008-12-17 2010-07-01 Toto Ltd Shower device
JP3155884U (en) * 2009-02-17 2009-12-10 篤史 竹田 Micro bubble generator
JP2010201400A (en) * 2009-03-06 2010-09-16 Ebara Corp Gas diffuser and bubble generator
JP6067201B2 (en) * 2009-08-03 2017-01-25 パナソニック株式会社 Fine bubble generating method, fine bubble generating device, etc.
JP2011088050A (en) * 2009-10-21 2011-05-06 Panasonic Electric Works Co Ltd Biologically active water, apparatus for producing biologically active water, and biological activation method
JP2011121002A (en) * 2009-12-10 2011-06-23 Takenaka Komuten Co Ltd Nano bubble generator
JP5672472B2 (en) * 2010-03-30 2015-02-18 国立大学法人三重大学 Fine bubble forming device.
JP5728643B2 (en) * 2010-05-26 2015-06-03 パナソニックIpマネジメント株式会社 Microbubble generator
JP3163836U (en) * 2010-08-23 2010-11-04 中村 正一 Gas mist pressure bath box

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001170463A (en) * 1999-12-14 2001-06-26 Sanyo Electric Co Ltd Carbonated water producing apparatus
CN101349629A (en) * 2001-08-28 2009-01-21 三菱丽阳株式会社 Detection method for gas density applied to dissolving solution, manufacturing apparatus for gas dissolving solution and membrane member
JP2008073189A (en) * 2006-09-21 2008-04-03 Act Engineering:Kk Apparatus for producing carbonated spring using circulating bathtub water

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111111491A (en) * 2020-01-02 2020-05-08 科勒(中国)投资有限公司 Carbonated water redissolving device and carbonated water generating equipment

Also Published As

Publication number Publication date
JP6032456B2 (en) 2016-11-30
JP2013121414A (en) 2013-06-20
CN103648627B (en) 2016-05-25
WO2013084603A1 (en) 2013-06-13

Similar Documents

Publication Publication Date Title
CN103648627A (en) Carbonated spring generating device
JP3984279B2 (en) Method and apparatus for producing hydrogenated water
US8768154B2 (en) Fixed and selectively fixed bypass pumpless instantaneous / storage water heater system
EP3385231A1 (en) Ozone water treatment system using low energy
JP2009243813A (en) Storage water heater
JP2008093515A (en) Fluid mixer and fluid-mixing device
JP4843339B2 (en) Ozone water supply device
JP2012241441A (en) Faucet device
WO2018127986A1 (en) Real-time large-volume hydrogen water generator
WO2008102784A1 (en) Bubble treatment device and water treatment device
JP6067201B2 (en) Fine bubble generating method, fine bubble generating device, etc.
JP5466615B2 (en) Water quality improvement method and apparatus for tidal river
JP6032506B2 (en) Carbonate spring generator
EP2873648B1 (en) Dissolved oxygen removal system, circulating water system with dissolved oxygen removal device, heating device comprising said circulating water circuit system and dissolved oxygen removal method
JP2003053169A (en) Carbonated water manufacturing apparatus and carbonic acid gas dissolving method
CN205740467U (en) Modular hydrogen solution production equipment
JP5361981B2 (en) Hot water storage water heater
JP2007029885A (en) Apparatus for producing carbonated water
CN114832658A (en) Micro-nano bubble liquid generation system and water heater
JP5113552B2 (en) Water purification device
CN110102195A (en) A kind of micro-nano bubble bathtub of high concentration and its control method
JP6584792B2 (en) Hydrogen water production equipment
JP5861028B2 (en) Water heater
KR101579557B1 (en) Apparatus for dissoving oxygen
JP6853980B2 (en) Electrolyzed water generator

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant