CN103635256B - 制备含钴的费-托合成催化剂的方法 - Google Patents

制备含钴的费-托合成催化剂的方法 Download PDF

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Publication number
CN103635256B
CN103635256B CN201280032354.3A CN201280032354A CN103635256B CN 103635256 B CN103635256 B CN 103635256B CN 201280032354 A CN201280032354 A CN 201280032354A CN 103635256 B CN103635256 B CN 103635256B
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catalyst
precursor
subsequently
cobalt
cobalt compound
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CN103635256A (zh
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H·范伦斯博戈
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Sasol Technology Pty Ltd
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Sasol Technology Pty Ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8913Cobalt and noble metals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74Iron group metals
    • B01J23/75Cobalt
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/0201Impregnation
    • B01J37/0205Impregnation in several steps
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/024Multiple impregnation or coating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08Heat treatment
    • B01J37/082Decomposition and pyrolysis
    • B01J37/088Decomposition of a metal salt
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/12Oxidising
    • B01J37/14Oxidising with gases containing free oxygen
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16Reducing
    • B01J37/18Reducing with gases containing free hydrogen
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/04Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
    • C07C1/0425Catalysts; their physical properties
    • C07C1/043Catalysts; their physical properties characterised by the composition
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/12Silica and alumina
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/0201Impregnation
    • B01J37/0213Preparation of the impregnating solution
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/33Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
    • C10G2/331Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
    • C10G2/332Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals of the iron-group

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
CN201280032354.3A 2011-09-21 2012-08-31 制备含钴的费-托合成催化剂的方法 Active CN103635256B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
ZA2011/06909 2011-09-21
ZA201106909 2011-09-21
PCT/IB2012/054493 WO2013041997A1 (en) 2011-09-21 2012-08-31 Process for preparing a cobalt - containing fischer tropsch catalyst

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CN103635256A CN103635256A (zh) 2014-03-12
CN103635256B true CN103635256B (zh) 2016-08-17

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US (1) US9248435B2 (cg-RX-API-DMAC7.html)
EP (1) EP2758170B1 (cg-RX-API-DMAC7.html)
JP (1) JP5961694B2 (cg-RX-API-DMAC7.html)
CN (1) CN103635256B (cg-RX-API-DMAC7.html)
AP (1) AP2013007293A0 (cg-RX-API-DMAC7.html)
AR (1) AR087975A1 (cg-RX-API-DMAC7.html)
AU (1) AU2012311175B2 (cg-RX-API-DMAC7.html)
BR (1) BR112013032165B8 (cg-RX-API-DMAC7.html)
CA (1) CA2838233C (cg-RX-API-DMAC7.html)
MY (1) MY164214A (cg-RX-API-DMAC7.html)
PE (1) PE20140735A1 (cg-RX-API-DMAC7.html)
RU (1) RU2602803C2 (cg-RX-API-DMAC7.html)
WO (1) WO2013041997A1 (cg-RX-API-DMAC7.html)
ZA (1) ZA201309045B (cg-RX-API-DMAC7.html)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5961694B2 (ja) 2011-09-21 2016-08-02 サソル テクノロジー (ピーティーワイ)リミテッド コバルト含有のフィッシャー・トロプシュ触媒を調製する方法
EA036728B1 (ru) * 2014-12-19 2020-12-14 Бп П.Л.К. Способ получения содержащего кобальт катализатора на подложке для синтеза фишера-тропша
CN108430629B (zh) * 2015-12-21 2021-11-12 国际壳牌研究有限公司 氢化催化剂及其制备方法
EP3496856B1 (en) * 2016-08-11 2023-03-01 Sasol South Africa Limited A cobalt-containing catalyst composition

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4413064A (en) * 1981-10-13 1983-11-01 Gulf Research & Development Company Fluid bed catalyst for synthesis gas conversion and utilization thereof for preparation of diesel fuel
US7012104B2 (en) * 2002-10-16 2006-03-14 Conocophillips Company Fischer-Tropsch processes and catalysts made from a material comprising boehmite
CN101052466A (zh) * 2005-01-11 2007-10-10 萨索尔技术(控股)有限公司 费-托合成用的负载型钴催化剂的制造
WO2010097754A2 (en) * 2009-02-26 2010-09-02 Sasol Technology (Proprietary) Limited Catalysts

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3839580C1 (cg-RX-API-DMAC7.html) 1988-11-24 1990-07-05 Condea Chemie Gmbh, 2212 Brunsbuettel, De
DZ2013A1 (fr) 1995-04-07 2002-10-23 Sastech Ltd Catalyseurs.
DE69909112T2 (de) 1998-10-05 2003-12-24 Sasol Technology (Proprietary) Ltd., Johannesburg Tränkungsverfahren für katalysatoren
RU2340394C2 (ru) * 2002-10-16 2008-12-10 Конокофиллипс Кампэни Способ получения носителя для катализатора с повышенной гидротермальной стабильностью (варианты), катализатор для синтеза углеводородов и способ синтеза углеводородов из синтез-газа
RU2311230C2 (ru) * 2003-04-07 2007-11-27 Ниппон Стил Корпорейшн Катализатор для получения углеводорода из синтез-газа и способ получения катализатора
US7524787B2 (en) 2005-01-11 2009-04-28 Sasol Technology (Proprietary Limited) Producing supported cobalt catalysts for the Fisher-Tropsch synthesis
EP1947073A1 (de) 2007-01-22 2008-07-23 Phillip Mertens Zubreitungsform mit verzögerter Freisetzungsrate für wasserlösliche und/oder wasserunlösliche Stoffe
US20100160464A1 (en) * 2008-12-24 2010-06-24 Chevron U.S.A. Inc. Zeolite Supported Cobalt Hybrid Fischer-Tropsch Catalyst
US7943674B1 (en) * 2009-11-20 2011-05-17 Chevron U.S.A. Inc. Zeolite supported cobalt hybrid fischer-tropsch catalyst
JP5961694B2 (ja) 2011-09-21 2016-08-02 サソル テクノロジー (ピーティーワイ)リミテッド コバルト含有のフィッシャー・トロプシュ触媒を調製する方法

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4413064A (en) * 1981-10-13 1983-11-01 Gulf Research & Development Company Fluid bed catalyst for synthesis gas conversion and utilization thereof for preparation of diesel fuel
US7012104B2 (en) * 2002-10-16 2006-03-14 Conocophillips Company Fischer-Tropsch processes and catalysts made from a material comprising boehmite
CN101052466A (zh) * 2005-01-11 2007-10-10 萨索尔技术(控股)有限公司 费-托合成用的负载型钴催化剂的制造
WO2010097754A2 (en) * 2009-02-26 2010-09-02 Sasol Technology (Proprietary) Limited Catalysts

Also Published As

Publication number Publication date
EP2758170B1 (en) 2015-10-07
JP5961694B2 (ja) 2016-08-02
CA2838233A1 (en) 2013-03-28
AU2012311175B2 (en) 2016-09-01
WO2013041997A1 (en) 2013-03-28
CN103635256A (zh) 2014-03-12
PE20140735A1 (es) 2014-06-30
US9248435B2 (en) 2016-02-02
AP2013007293A0 (en) 2013-12-31
US20140155501A1 (en) 2014-06-05
JP2014527908A (ja) 2014-10-23
BR112013032165B8 (pt) 2019-11-05
BR112013032165A2 (pt) 2016-12-13
BR112013032165B1 (pt) 2019-09-03
EP2758170A1 (en) 2014-07-30
MY164214A (en) 2017-11-30
AU2012311175A1 (en) 2014-01-09
RU2013154968A (ru) 2015-10-27
CA2838233C (en) 2019-08-06
ZA201309045B (en) 2014-08-27
NZ618839A (en) 2015-10-30
AR087975A1 (es) 2014-04-30
RU2602803C2 (ru) 2016-11-20

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