CN103614933A - Dyeing method for dyeing cellulose fiber by utilizing walnut green seedcase natural dye - Google Patents
Dyeing method for dyeing cellulose fiber by utilizing walnut green seedcase natural dye Download PDFInfo
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- CN103614933A CN103614933A CN201310671464.0A CN201310671464A CN103614933A CN 103614933 A CN103614933 A CN 103614933A CN 201310671464 A CN201310671464 A CN 201310671464A CN 103614933 A CN103614933 A CN 103614933A
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Abstract
The invention relates to a dyeing method for dyeing a cellulose fiber by utilizing a walnut green seedcase natural dye. The dyeing method comprises the steps of carrying out chitosan pretreatment on a fabric to enhance the moisture-absorbing anti-bacterial property of the fabric; extracting a walnut green seedcase dye liquor by adopting an ultrasonic aqueous solvent method and dyeing the fabric to improve extraction efficiency; then carrying out color fixation finishing on the fabric, and soaping and fixing a color to obtain the fabric which is uniform in dyeing and natural without toxicity and has certain anti-bacterial property. The dyeing process disclosed by the invention has the advantages of being simple, easy to operate, natural without toxicity, low in dyeing cost and wide in market prospect.
Description
Technical field
The present invention relates to a kind of application of natural plant dye, especially a kind of colouring method that dyes cellulose fibre on green peel of walnut natural dye that utilizes.
Background technology
The drawback of synthetic dyestuffs, along with the enhancing of people's health care and environmental consciousness manifests day by day, is dyed the superior parts such as comfortable security of clothing dress and more and more by consumer and dyer author, is re-recognized on the compatibility of natural dye and environment and natural dye.Be subject to the consumption tide impacts such as domestic and international " recovering one's original simplicity " " back to nature " " low-carbon environment-friendly ", utilize natural dye to carry out cellulose base fiber fabric dyeing very valuable and necessary, in addition, many natural dyes also have the multiple efficacies such as medicinal health-care, spices, make the fabric after dress dyeing have certain health-care hospital function to human body, this also makes the fabric dying on natural dye have more wide market prospects.
Walnut is a kind of nut with healthy intelligence function, is subject to liking very much of consumer, and the cultivated area of domestic walnut is very large, so the exocarp raw material sources of walnut are very extensive, and the exocarp of walnut is all used as a kind of refuse and is dropped for a long time, is very waste.Both at home and abroad expert has identified in the main component of green peel of walnut and has contained tannin, juglone, gallic acid and some pigments, therefore the pigment in green peel of walnut is extracted, for dyeing, it is sufficient refuse reclamation, this is to promoting surcharge of Walnut Industry, and build economizing type, friendly environment society also tool be of great significance.
The present invention adopts ultrasonic wave aqueous solvent assisted extraction green peel of walnut natural dye, when object is to improve green peel of walnut natural dye recovery rate, after avoiding extracting with organic solvent, isolate again organic solvent, simplify extraction step, and reach the effect of low-carbon environment-friendly.And the fabric after shitosan pre-treatment, its dye-uptake and degree of fixation all will increase, and this is most important to dying the application of cellulose fibre on natural green peel of walnut dyestuff.
Summary of the invention
The present invention is intended to utilize extraction aboundresources, low-cost natural byproduct green peel of walnut dye liquor to dye to fabric, make fabric after dyeing there is the characteristic of Nantural non-toxic evil, natural antibacterial, a kind of shitosan pre-treatment that utilizes its method of colouring method of dying cellulose fibre on green peel of walnut natural dye to comprise fabric is proposed, adopt ultrasonic wave aqueous solvent carry out green peel of walnut natural dye extraction, fabric on dye and dye after the fixation of soaping.
Fabric is carried out to shitosan pre-treatment, improve hygroscopicity and the antibiotic property of fabric.The shitosan pre-treatment process of fabric is: the pre-treatment aqueous solution of preparation is 5 ~ 15g/L shitosan, first cellulose base fiber fabric being put into the pre-treatment aqueous solution configuring extremely soaks completely, then on padding machine to fabric two enter two roll after, fabric is cured 3 ~ 10 minutes at 80 ~ 120 ℃; With the soda ash of 2g/L in fabric and after, washing, hangs.
Adopt ultrasonic wave aqueous solvent to carry out the extraction of green peel of walnut natural dye, extraction process is: get the green peel of walnut after appropriate pulverizing, take water as solvent, ultrasonic power is 50 ~ 180W, and temperature is 40 ~ 70 ℃, and liquid-solid ratio is (10 ~ 20): 1 ml/g, time is 20 ~ 40 min, pH, 7 ~ 9, extracts 2 ~ 3 times, and recovery rate is 9.2 ~ 13.3%.
On the green peel of walnut natural dye that the present invention extracts, the dyeing of dyeing and weaving thing is: dye strength is 3 ~ 8%, bath raio (6 ~ 30): 1, and room temperature is lowered to dyes, and 1 ~ 2 ℃/min of heating rate is warming up to 60 ℃ ~ 80 ℃, is incubated 60 ~ 100min.Clear water rinses after fabric, adds 3 ~ 7%(to fabric weight) tertiary sodium phosphate, fixation 15 ~ 30min under 80 ~ 100 ℃ of conditions, the fabric after fixation adopts the neutral detergent of 1g/L to wash 10 ~ 30min under 40 ~ 60 ℃ of conditions, then with clear water, cleans and dries.
The specific embodiment
Embodiment mono-
Preparation 5g/L shitosan, puts into fabric the pre-treatment aqueous solution that configures to soaking completely, then on padding machine to fabric two enter two roll after, fabric is cured 10 minutes at 80 ℃.
Adopt ultrasonic wave aqueous solvent to carry out the extraction of green peel of walnut natural dye, extraction process is: get the green peel of walnut after appropriate pulverizing, take water as solvent, ultrasonic power is 50W, temperature is 60 ℃, and liquid-solid ratio is 10:1 ml/g, and the time is 30 min, pH value is 7, extracts 3 times, and recovery rate is 10.2%.
On green peel of walnut natural dye, the dyeing of dyeing and weaving thing is: dye strength is 3%; bath raio 10:1; room temperature is lowered to dyes; 2 ℃/min of heating rate, is warming up to 60 ℃, insulation 60min; add 3%(to fabric weight) sodium chloride; be incubated after 20 ~ 60min, add 3%(to fabric weight) tertiary sodium phosphate, be incubated 30 ~ 60min.Clear water rinses after fabric, adopts the neutral detergent of 2g/L to wash 20min under 50 ℃ of conditions, then with clear water, cleans and dries.
Embodiment bis-
Preparation 10g/L shitosan, puts into fabric the pre-treatment aqueous solution that configures to soaking completely, then on padding machine to fabric two enter two roll after, fabric is cured 8 minutes at 100 ℃.
Adopt ultrasonic wave aqueous solvent to carry out the extraction of green peel of walnut natural dye, extraction process is: get the green peel of walnut after appropriate pulverizing, take water as solvent, ultrasonic power is 50W, temperature is 70 ℃, and liquid-solid ratio is 15:1 ml/g, and the time is 40 min, pH value is 8, extracts 2 times, and recovery rate is 12.5%.
On green peel of walnut natural dye, the dyeing of dyeing and weaving thing is: dye strength is 5%, bath raio 20:1, and room temperature is lowered to dyes, and 1 ℃/min of heating rate is warming up to 70 ℃, insulation 70min.Add 5%(to fabric weight) sodium chloride, be incubated after 20 ~ 60min, add 5%(to fabric weight) tertiary sodium phosphate, be incubated 30 ~ 60min.Clear water rinses after fabric, adopts the neutral detergent of 2g/L to wash 20min under 50 ℃ of conditions, then with clear water, cleans and dries.
Embodiment tri-
Preparation 15g/L shitosan, puts into fabric the pre-treatment aqueous solution that configures to soaking completely, then on padding machine to fabric two enter two roll after, fabric is cured 8 minutes at 100 ℃.
Adopt ultrasonic wave aqueous solvent to carry out the extraction of green peel of walnut natural dye, extraction process is: get the green peel of walnut after appropriate pulverizing, take water as solvent, ultrasonic power is 180W, and temperature is 40 ℃, and liquid-solid ratio is 10:1 ml/g, time is 20 min, pH value is 9, extracts 2 times, and recovery rate is 11.8%.
On green peel of walnut natural dye, the dyeing of dyeing and weaving thing is: dye strength is 8%, bath raio 30:1, and room temperature is lowered to dyes, and 1 ℃/min of heating rate is warming up to 80 ℃, insulation 100min.Add 6%(to fabric weight) sodium chloride, be incubated after 20 ~ 60min, add 6%(to fabric weight) tertiary sodium phosphate, be incubated 30 ~ 60min.Clear water rinses after fabric, adopts the neutral detergent of 2g/L to wash 20min under 50 ℃ of conditions, then with clear water, cleans and dries.
Claims (3)
1. utilize a colouring method that dyes cellulose fibre on green peel of walnut natural dye, it is characterized in that its method comprise fabric shitosan pre-treatment, adopt ultrasonic wave aqueous solvent carry out green peel of walnut natural dye extraction, fabric on dye and dye after the fixation of soaping.
2. a kind of colouring method that dyes cellulose fibre on green peel of walnut natural dye that utilizes as claimed in claim 1, it is characterized in that: the shitosan pre-treatment process of fabric is: the pre-treatment aqueous solution of preparation is 5 ~ 15g/L shitosan, first cellulose base fiber fabric being put into the pre-treatment aqueous solution configuring extremely soaks completely, then on padding machine to fabric two enter two roll after, fabric is cured 3 ~ 10 minutes at 80 ~ 120 ℃; With the soda ash of 2g/L in fabric and after, washing, hangs.
3. a kind of colouring method that dyes cellulose fibre on green peel of walnut natural dye that utilizes as claimed in claim 1, it is characterized in that: adopt ultrasonic wave aqueous solvent to carry out the extraction of green peel of walnut natural dye, extraction process is: get the green peel of walnut after appropriate pulverizing, take water as solvent, ultrasonic power is 50 ~ 180W, temperature is 40 ~ 70 ℃, liquid-solid ratio is (10 ~ 20): 1 ml/g, and the time is 20 ~ 40 min, pH is 7 ~ 9, extract 2 ~ 3 times, recovery rate is 9.2 ~ 13.3%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310671464.0A CN103614933B (en) | 2013-12-12 | 2013-12-12 | It is a kind of to utilize the colouring method that cellulose fibre is contaminated on green peel of walnut natural dye |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310671464.0A CN103614933B (en) | 2013-12-12 | 2013-12-12 | It is a kind of to utilize the colouring method that cellulose fibre is contaminated on green peel of walnut natural dye |
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| CN103614933A true CN103614933A (en) | 2014-03-05 |
| CN103614933B CN103614933B (en) | 2018-05-11 |
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| CN201310671464.0A Expired - Fee Related CN103614933B (en) | 2013-12-12 | 2013-12-12 | It is a kind of to utilize the colouring method that cellulose fibre is contaminated on green peel of walnut natural dye |
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105133380A (en) * | 2015-10-19 | 2015-12-09 | 新疆大学 | Method for extracting pigment from walnut green hulls through subcritical water and using pigment for dyeing |
| CN105401464A (en) * | 2015-12-22 | 2016-03-16 | 广州番禺职业技术学院 | Technology for printing and dyeing artificial leather by using kiwi fruit juice |
| CN105421101A (en) * | 2015-12-22 | 2016-03-23 | 广州番禺职业技术学院 | Process of printing and dyeing artificial leather with pitaya juice |
| CN105420427A (en) * | 2015-12-22 | 2016-03-23 | 广州番禺职业技术学院 | Technology for printing and dyeing animal skin with strawberry juice |
| CN108677559A (en) * | 2018-06-26 | 2018-10-19 | 乡宁县云丘山旅游开发有限责任公司 | A kind of natural plants cloth dyeing technology |
| CN108978260A (en) * | 2018-06-18 | 2018-12-11 | 广东欣薇尔服装有限公司 | A kind of colouring method of natural beet red pigment |
| CN110004739A (en) * | 2019-04-22 | 2019-07-12 | 中原工学院 | A method of it is dyed using leather vegetable tanning confrontation special fiber |
| CN111454587A (en) * | 2020-04-24 | 2020-07-28 | 杭州彩润科技有限公司 | Comprehensive processing and utilizing method for dyeing of pericarpium juglandis |
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| CN1912011A (en) * | 2005-08-11 | 2007-02-14 | 青岛海联植物科技研究所 | Method for extracting matural dye from external skin of walnut |
| CN102644204A (en) * | 2012-04-24 | 2012-08-22 | 大连工业大学 | Method for dyeing modified cellulose fabrics by green walnut epicarp pigment |
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| CN1912011A (en) * | 2005-08-11 | 2007-02-14 | 青岛海联植物科技研究所 | Method for extracting matural dye from external skin of walnut |
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Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105133380A (en) * | 2015-10-19 | 2015-12-09 | 新疆大学 | Method for extracting pigment from walnut green hulls through subcritical water and using pigment for dyeing |
| CN105401464A (en) * | 2015-12-22 | 2016-03-16 | 广州番禺职业技术学院 | Technology for printing and dyeing artificial leather by using kiwi fruit juice |
| CN105421101A (en) * | 2015-12-22 | 2016-03-23 | 广州番禺职业技术学院 | Process of printing and dyeing artificial leather with pitaya juice |
| CN105420427A (en) * | 2015-12-22 | 2016-03-23 | 广州番禺职业技术学院 | Technology for printing and dyeing animal skin with strawberry juice |
| CN105401464B (en) * | 2015-12-22 | 2018-04-13 | 广州番禺职业技术学院 | A kind of technique using unusual fruit juice printing and dyeing artificial leather |
| CN105421101B (en) * | 2015-12-22 | 2018-05-29 | 广州番禺职业技术学院 | A kind of technique using Dragonfruit Juice printing and dyeing artificial leather |
| CN108978260B (en) * | 2018-06-18 | 2021-11-12 | 广东欣薇尔服装有限公司 | Dyeing method of natural beet red pigment |
| CN108978260A (en) * | 2018-06-18 | 2018-12-11 | 广东欣薇尔服装有限公司 | A kind of colouring method of natural beet red pigment |
| CN108677559A (en) * | 2018-06-26 | 2018-10-19 | 乡宁县云丘山旅游开发有限责任公司 | A kind of natural plants cloth dyeing technology |
| CN110004739B (en) * | 2019-04-22 | 2021-08-27 | 中原工学院 | Method for dyeing specific fibers by using leather vegetable tanning material |
| CN110004739A (en) * | 2019-04-22 | 2019-07-12 | 中原工学院 | A method of it is dyed using leather vegetable tanning confrontation special fiber |
| CN111454587A (en) * | 2020-04-24 | 2020-07-28 | 杭州彩润科技有限公司 | Comprehensive processing and utilizing method for dyeing of pericarpium juglandis |
| CN111454587B (en) * | 2020-04-24 | 2021-07-13 | 杭州彩润科技有限公司 | Comprehensive processing and utilizing method for dyeing of pericarpium juglandis |
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| CN103614933B (en) | 2018-05-11 |
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