CN103571421B - A kind of stable form cloud stone glue - Google Patents
A kind of stable form cloud stone glue Download PDFInfo
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- CN103571421B CN103571421B CN201210264392.3A CN201210264392A CN103571421B CN 103571421 B CN103571421 B CN 103571421B CN 201210264392 A CN201210264392 A CN 201210264392A CN 103571421 B CN103571421 B CN 103571421B
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- cloud stone
- stone glue
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- unsaturated polyester
- polyester resin
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Abstract
The invention relates to a kind of stable form cloud stone glue, it is primarily of unsaturated polyester resin, hydrogenated castor oil, filler, thinner and talcum powder composition. Stable form cloud stone glue of the present invention, in storage at normal temperature or transportation, does not occur that resin oozes out, filler deposited phenomenon, thus is more suitable for practicality.
Description
Technical field
The present invention relates in a kind of building stone field the resin used, particularly relate to a kind of stable form cloud stone glue primarily of unsaturated polyester resin composition.
Background technology
Cloud stone glue and unsaturated polyester glue, domestic be also referred to as cloud stone glue. Cloud stone glue is applicable to bonding between all kinds of stone material or repairs crack and the mark of break of stone surface, is usually used in the repairing of each type paving stone engineering and all kinds of stone material, cemented in place and joint filling. It is bonding for the stone material property filled up, and also claims unstructuredness bonding. Unstructuredness is bonding is that a kind of of bonding relative to structure (bearing load bonding) utilizes organic chemistry tackiness agent to the defect of stone material, carries out a kind of technique repaired, fill, strengthen, fix such as crackle, hole, sand holes, product defect, finishing location etc.
At present, also there is many defects in cloud stone glue product in storage and transportation. Cloud stone glue adopts hot-work to produce, production has the process leaving standstill cooling, in this process, the cloud stone glue under liquid state due to the proportion of wherein filler be the proportion much larger than resin, there will be resin and filler local delamination phenomenon, cause the uneven of colloid; In addition, cloud stone glue is long-time storage under the environment of temperature higher than 25 DEG C, also there will be because resin causes surface resin to ooze out with being separated of filler, the phenomenon that bottom glue is hardening owing to amount of resin reduces, not only affect the outward appearance of product, add the difficulty of user's epoxy glue, also cause the unstable of its mechanical property.
It thus is seen that existing cloud stone glue product still has inconvenience and defect, and urgently it is further improved.
Summary of the invention
Based on the defect of existing cloud stone glue product, the main purpose of the present invention is, overcome the defect that existing cloud stone glue exists, and a kind of stable form cloud stone glue is provided, technical problem to be solved be make that cloud stone glue cools in production, in storage at normal temperature and transportation, do not occur that resin oozes out, filler deposited phenomenon, thus be more suitable for practicality, and the utility value having in industry.
Another object of the present invention is to, it is provided that a kind of storage stabilizer for cloud stone glue.
The object of the invention to solve the technical problems realizes by the following technical solutions. A kind of stable form cloud stone glue proposed according to the present invention, it is primarily of unsaturated polyester resin, hydrogenated castor oil, filler, thinner and talcum powder composition.
The object of the invention to solve the technical problems also can be applied to the following technical measures to achieve further.
Aforesaid a kind of stable form cloud stone glue, wherein unsaturated polyester resin is 100 weight parts, and hydrogenated castor oil is 1-2 weight part, and filler is 100-200 weight part, and thinner is 1-5 weight part, and talcum powder is 1-10 weight part.
Aforesaid a kind of stable form cloud stone glue, wherein said unsaturated polyester resin is selected from adjacent benzene-type unsaturated polyester resin, metaphenylene unsaturated polyester resin, Bisphenol a unsaturated polyester resin and/or halogen for unsaturated polyester resin.
Aforesaid a kind of stable form cloud stone glue, the granularity of wherein said filler is micron-sized, be selected from water-ground limestone, Calcium of intensifiens, barium sulfate, silicon-dioxide, anhydrous calciumsulphate, light calcium carbonate, aluminium hydroxide, wilkinite, wollastonite powder and zinc sulfide white one or both; Wherein, zinc sulfide white is also called lithopone, is nontoxic white powder, is insoluble to water, and its thermotolerance is good, can improve weathering resistance, reduces costs and whiteness that it has excellent power of covering.
Aforesaid a kind of stable form cloud stone glue, the granularity of wherein said filler is 300 order-1200 orders.
Aforesaid a kind of stable form cloud stone glue, the granularity of wherein said filler is 300 order-550 orders.
Aforesaid a kind of stable form cloud stone glue, the granularity of wherein said filler is 900 order-1200 orders.
Aforesaid a kind of stable form cloud stone glue, the granularity of wherein said talcum powder is 325 order-1250 orders.
Aforesaid a kind of stable form cloud stone glue, the granularity of wherein said talcum powder is 900 order-1200 orders.
Aforesaid a kind of stable form cloud stone glue, wherein said thinner be selected from vinylbenzene, Vinyl toluene, Phthalic acid, diallyl ester, methyl methacrylate, dimethylbenzene, turps, phenylcarbinol one or both.
Aforesaid talcum powder is white or off-white color, fine, without the powder of sand, hand touches with greasy feeling. It has oilness, anti-stick, help stream, resistivity against fire, resistance to acid, insulativity, fusing point height, chemical torpescence, opacifying power well, the excellent Wuli-Shili-Renli system approach such as softness, good luster, adsorptive power be strong.
By technique scheme, a kind of stable form cloud stone glue of the present invention at least has following advantage:
Stable form cloud stone glue of the present invention has stable storing compared with existing cloud stone glue, does not occur occurring that resin oozes out and the phenomenon of bottom settlings filler because resin is separated with filler. The consumption of the talcum powder played a major role in the present invention is little, does not substantially affect the cost of product.
In sum, a kind of stable form cloud stone glue that the present invention is special, it has above-mentioned many advantages and practical value, and there are no similar disclosure of the invention in like product, no matter it is in design or functionally all has bigger improvement, has large improvement technically, and create handy and practical effect, and more existing cloud stone glue has multinomial effect of enhancement, thus be more suitable for practicality.
Above-mentioned explanation is only the general introduction of technical solution of the present invention, in order to better understand the technique means of the present invention, and can be implemented according to the content of specification sheets, be described in detail as follows with the better embodiment of the present invention below.
Embodiment
Below in conjunction with example, the present invention is further described, but following example does not form the restriction to claim of the present invention.
Embodiment 1:
Stable form cloud stone glue of the present invention, it is made up of unsaturated polyester 100 weight part, hydrogenated castor oil 1.2-2 weight part, calcium carbonate 150 weight part, dimethylbenzene 3 weight part and 325 order talcum powder 10 weight parts.
Embodiment 2:
Stable form cloud stone glue of the present invention, it is made up of unsaturated polyester 100 weight part, hydrogenated castor oil 1.2-2 weight part, calcium carbonate 150 weight part, dimethylbenzene 3 weight part and 800 order talcum powder 5 weight parts.
Embodiment 3:
Stable form cloud stone glue of the present invention, it is made up of unsaturated polyester 100 weight part, hydrogenated castor oil 1.2-2 weight part, calcium carbonate 150 weight part, turps 3 weight part and 800 order talcum powder 3 weight parts.
Embodiment 4:
Stable form cloud stone glue of the present invention, it is made up of unsaturated polyester 100 weight part, hydrogenated castor oil 1.2-2 weight part, calcium carbonate 120 weight part, dimethylbenzene 2 weight part and 1250 order talcum powder 3 weight parts.
Embodiment 5:
Stable form cloud stone glue of the present invention, it is made up of unsaturated polyester 100 weight part, hydrogenated castor oil 1.2-2 weight part, calcium carbonate 100 weight part, dimethylbenzene 3 weight part and 800 order talcum powder 4 weight parts.
The preparation method of stable form cloud stone glue of the present invention is: add hydrogenated castor oil in unsaturated polyester, intensification limit, limit is stirred, whipping process adds thinner, filler and talcum powder, stop when being warming up to 70 DEG C heating, it is stirred to after hydrogenated castor oil dissolves completely, thermal-insulating filling, is cooled to body of paste, is finished product vanning.
Above-described embodiment is made respectively sample, stores in 30 DEG C of baking ovens, observe after 2 months, the phenomenon that resin is separated with filler does not all occur.
The above, it it is only the better embodiment of the present invention, not the present invention is done any restriction in form, although the present invention discloses as above with better embodiment, but and be not used to limit the present invention, any those skilled in the art, do not departing within the scope of technical solution of the present invention, when the method and technology contents that can utilize above-mentioned announcement make a little equivalent embodiment changing or being modified to equivalent variations, in every case it is the content not departing from technical solution of the present invention, the any simple modification above embodiment done according to the technical spirit of the present invention, equivalent variations and modification, all still belong in the scope of technical solution of the present invention.
Claims (8)
1. a cloud stone glue, described cloud stone glue is primarily of unsaturated polyester resin, hydrogenated castor oil, filler, dimethylbenzene and talcum powder composition, wherein unsaturated polyester resin is 100 weight parts, hydrogenated castor oil is 1-2 weight part, filler is 100-200 weight part, dimethylbenzene is 1-5 weight part, and talcum powder is 1-10 weight part.
2. cloud stone glue according to claim 1, wherein said unsaturated polyester resin is selected from adjacent benzene-type unsaturated polyester resin, metaphenylene unsaturated polyester resin, Bisphenol a unsaturated polyester resin and/or halogen for unsaturated polyester resin.
3. cloud stone glue according to claim 1, the granularity of wherein said filler is micron-sized, be selected from water-ground limestone, Calcium of intensifiens, barium sulfate, silicon-dioxide, anhydrous calciumsulphate, light calcium carbonate, aluminium hydroxide, wilkinite, wollastonite powder and zinc sulfide white one or both.
4. cloud stone glue according to claim 3, the granularity of wherein said filler is 300 order-1200 orders.
5. cloud stone glue according to claim 4, the granularity of wherein said filler is 300 order-550 orders.
6. cloud stone glue according to claim 5, the granularity of wherein said filler is 900 order-1200 orders.
7. cloud stone glue according to claim 1, the granularity of wherein said talcum powder is 325 order-1250 orders.
8. cloud stone glue according to claim 7, the granularity of wherein said talcum powder is 900 order-1200 orders.
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CN201210264392.3A CN103571421B (en) | 2012-07-27 | 2012-07-27 | A kind of stable form cloud stone glue |
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CN201210264392.3A CN103571421B (en) | 2012-07-27 | 2012-07-27 | A kind of stable form cloud stone glue |
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CN103571421B true CN103571421B (en) | 2016-06-15 |
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Families Citing this family (5)
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CN104559896A (en) * | 2014-05-20 | 2015-04-29 | 钟翰万 | Binding agent |
CN107674626B (en) * | 2017-09-28 | 2020-08-04 | 武汉市科达云石护理材料有限公司 | High-thixotropic transparent marble adhesive and preparation method thereof |
CN107793985B (en) * | 2017-09-28 | 2020-05-22 | 武汉市科达云石护理材料有限公司 | High-thixotropic colored marble adhesive and preparation method thereof |
CN110818319A (en) * | 2019-12-13 | 2020-02-21 | 西安中科贝昂环保科技有限公司 | Environment-friendly artificial stone for cooking bench and preparation method thereof |
CN112391132B (en) * | 2020-11-05 | 2022-03-15 | 江苏大力士投资有限公司 | Method for prolonging storage period of marble glue |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN101735759A (en) * | 2009-12-10 | 2010-06-16 | 江苏大力士投资有限公司 | High-performance marble glue and preparation method thereof |
CN101805581A (en) * | 2009-03-25 | 2010-08-18 | 武汉市科达云石护理材料有限公司 | Special colored stone material caulking sealant |
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Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN101805581A (en) * | 2009-03-25 | 2010-08-18 | 武汉市科达云石护理材料有限公司 | Special colored stone material caulking sealant |
CN101735759A (en) * | 2009-12-10 | 2010-06-16 | 江苏大力士投资有限公司 | High-performance marble glue and preparation method thereof |
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