CN103571421A - Stable type marble adhesive - Google Patents
Stable type marble adhesive Download PDFInfo
- Publication number
- CN103571421A CN103571421A CN201210264392.3A CN201210264392A CN103571421A CN 103571421 A CN103571421 A CN 103571421A CN 201210264392 A CN201210264392 A CN 201210264392A CN 103571421 A CN103571421 A CN 103571421A
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- stone glue
- cloud stone
- unsaturated polyester
- filler
- polyester resin
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Abstract
The invention relates to a stable type marble adhesive, which is mainly composed of unsaturated polyester resins, hydrogenated castor oil, filling materials, a diluent and powdered steatile. The stable type marble adhesive provided by the invention does not have the phenomenon of resin leakage and filling material precipitation during the storage or transportation process at a normal temperature, so that the marble adhesive is more practicable.
Description
Technical field
The present invention relates to the resin using in a kind of building stone field, particularly relate to a kind of stable form cloud stone glue mainly being formed by unsaturated polyester resin.
Background technology
Cloud stone glue is unsaturated polyester glue, the domestic cloud stone glue that is also referred to as.Cloud stone glue is applicable to crack and the mark of break of the bonding or repairing stone surface between all kinds of stone materials, is usually used in repairing, cemented in place and the joint filling of all types of marble setter journeys and all kinds of stone materials.It is bonding for the stone material property filled up, and also claims unstructuredness bonding.Unstructuredness is bonding is a kind of defect of organic chemistry tackiness agent to stone material of utilizing with respect to structural bonding (carry load is bonding), and as damaged in crackle, hole, sand holes, product, finishing location etc. repair, fill, strengthen, fixing a kind of technique.
At present, also there is many defects in cloud stone glue product in storage and transportation.Cloud stone glue is to adopt hot-work to produce, in production, have standing cooling process, in this process, the cloud stone glue under liquid state is because the proportion of filler is wherein much larger than the proportion of resin, there will be resin and filler local delamination phenomenon, cause the inhomogeneous of colloid; In addition, cloud stone glue stores under higher than the environment of 25 ℃ for a long time in temperature, also there will be and ooze out with the separated surface resin that causes of filler because of resin, bottom glue is the phenomenon of hardening because amount of resin reduces, not only affect the outward appearance of product, increase the difficulty of user's epoxy glue, also caused the unstable of its mechanical property.
As can be seen here, existing cloud stone glue product still has inconvenience and defect, and is urgently further improved.
Summary of the invention
Defect based on existing cloud stone glue product, main purpose of the present invention is, overcome the defect that existing cloud stone glue exists, and provide a kind of stable form cloud stone glue, technical problem to be solved is to make cloud stone glue aborning in cooling, storage at normal temperature and transportation, do not occur that resin oozes out, filler deposited phenomenon, thereby be more suitable for practicality, and there is the utility value in industry.
Another object of the present invention is to, a kind of storage stabilizer for cloud stone glue is provided.
The object of the invention to solve the technical problems realizes by the following technical solutions.A kind of stable form cloud stone glue proposing according to the present invention, it is mainly comprised of unsaturated polyester resin, hydrogenated castor oil, filler, thinner and talcum powder.
The object of the invention to solve the technical problems also can be applied to the following technical measures to achieve further.
Aforesaid a kind of stable form cloud stone glue, wherein unsaturated polyester resin is 100 weight parts, and hydrogenated castor oil is 1-2 weight part, and filler is 100-200 weight part, and thinner is 1-5 weight part, talcum powder is 1-10 weight part.
Aforesaid a kind of stable form cloud stone glue, wherein said unsaturated polyester resin is selected from adjacent benzene type unsaturated polyester resin, metaphenylene unsaturated polyester resin, Bisphenol a unsaturated polyester resin and/or halo unsaturated polyester resin.
Aforesaid a kind of stable form cloud stone glue, the granularity of wherein said filler is micron-sized, is selected from one or both in water-ground limestone, Calcium of intensifiens, barium sulfate, silicon-dioxide, anhydrous calciumsulphate, light calcium carbonate, aluminium hydroxide, wilkinite, wollastonite powder and zinc sulfide white; Wherein, zinc sulfide white is called again lithopone, for nontoxic white powder, water insoluble, and its thermotolerance is good, can improve weathering resistance, reduces costs with and have the whiteness of the excellent power of covering.
Aforesaid a kind of stable form cloud stone glue, the granularity of wherein said filler is 300 order-1200 orders.
Aforesaid a kind of stable form cloud stone glue, the granularity of wherein said filler is 300 order-550 orders.
Aforesaid a kind of stable form cloud stone glue, the granularity of wherein said filler is 900 order-1200 orders.
Aforesaid a kind of stable form cloud stone glue, wherein said talcous granularity is 325 order-1250 orders.
Aforesaid a kind of stable form cloud stone glue, wherein said talcous granularity is 900 order-1200 orders.
Aforesaid a kind of stable form cloud stone glue, wherein said thinner is selected from one or both in vinylbenzene, Vinyl toluene, Phthalic acid, diallyl ester, methyl methacrylate, dimethylbenzene, turps, phenylcarbinol.
Aforesaid talcum powder be white or off-white color, fine, without the powder of grittiness, hand touches with greasy feeling.Good physics, the chemical propertys such as it has oilness, anti-stick, help that stream, resistivity against fire, resistance to acid, insulativity, fusing point are high, chemical torpescence, opacifying power are good, softness, good luster, adsorptive power are strong.
By technique scheme, a kind of stable form cloud stone glue of the present invention at least has following advantages:
Stable form cloud stone glue of the present invention is compared and is had stable storing with existing cloud stone glue, does not occur occurring because resin is separated with filler that resin oozes out the phenomenon with bottom settlings filler.The talcous consumption playing a major role in the present invention seldom, does not affect the cost of product substantially.
In sum, a kind of stable form cloud stone glue that the present invention is special, it has above-mentioned many advantages and practical value, and in like product there are no similar disclosure of the invention, no matter it is in design or all have larger improvement in function, has large improvement technically, and produced handy and practical effect, and more existing cloud stone glue has the multinomial effect of enhancement, thereby be more suitable for practicality.
Above-mentioned explanation is only the general introduction of technical solution of the present invention, in order to better understand technique means of the present invention, and can be implemented according to the content of specification sheets, below with preferred embodiment of the present invention, is described in detail as follows.
Embodiment
Below in conjunction with example, the present invention is further described, but following example does not form the restriction to claim of the present invention.
Embodiment 1:
Stable form cloud stone glue of the present invention, it is comprised of unsaturated polyester 100 weight parts, hydrogenated castor oil 1.2-2 weight part, calcium carbonate 150 weight parts, dimethylbenzene 3 weight parts and 325 order talcum powder 10 weight parts.
Embodiment 2:
Stable form cloud stone glue of the present invention, it is comprised of unsaturated polyester 100 weight parts, hydrogenated castor oil 1.2-2 weight part, calcium carbonate 150 weight parts, dimethylbenzene 3 weight parts and 800 order talcum powder 5 weight parts.
Embodiment 3:
Stable form cloud stone glue of the present invention, it is comprised of unsaturated polyester 100 weight parts, hydrogenated castor oil 1.2-2 weight part, calcium carbonate 150 weight parts, turps 3 weight parts and 800 order talcum powder 3 weight parts.
Embodiment 4:
Stable form cloud stone glue of the present invention, it is comprised of unsaturated polyester 100 weight parts, hydrogenated castor oil 1.2-2 weight part, calcium carbonate 120 weight parts, dimethylbenzene 2 weight parts and 1250 order talcum powder 3 weight parts.
Embodiment 5:
Stable form cloud stone glue of the present invention, it is comprised of unsaturated polyester 100 weight parts, hydrogenated castor oil 1.2-2 weight part, calcium carbonate 100 weight parts, dimethylbenzene 3 weight parts and 800 order talcum powder 4 weight parts.
The preparation method of stable form cloud stone glue of the present invention is: in unsaturated polyester, add hydrogenated castor oil, stir on intensification limit, limit, in whipping process, add thinner, filler and talcum powder, while being warming up to 70 ℃, stop heating, after being stirred to hydrogenated castor oil and dissolving completely, thermal-insulating filling, is cooled to body of paste, is finished product vanning.
Above-described embodiment is made respectively to sample, in 30 ℃ of baking ovens, store, after 2 months, observe, all do not occur the phenomenon that resin is separated with filler.
The above, it is only preferred embodiment of the present invention, not the present invention is done to any pro forma restriction, although the present invention discloses as above with preferred embodiment, yet not in order to limit the present invention, any those skilled in the art, do not departing within the scope of technical solution of the present invention, when can utilizing the method for above-mentioned announcement and technology contents to make a little change or being modified to the equivalent embodiment of equivalent variations, in every case be the content that does not depart from technical solution of the present invention, any simple modification of above embodiment being done according to technical spirit of the present invention, equivalent variations and modification, all still belong in the scope of technical solution of the present invention.
Claims (10)
1. a stable form cloud stone glue, it is mainly comprised of unsaturated polyester resin, hydrogenated castor oil, filler, thinner and talcum powder.
2. cloud stone glue according to claim 1, wherein unsaturated polyester resin is 100 weight parts, and hydrogenated castor oil is 1-2 weight part, and filler is 100-200 weight part, and thinner is 1-5 weight part, talcum powder is 1-10 weight part.
3. cloud stone glue according to claim 1 and 2, wherein said unsaturated polyester resin is selected from adjacent benzene type unsaturated polyester resin, metaphenylene unsaturated polyester resin, Bisphenol a unsaturated polyester resin and/or halo unsaturated polyester resin.
4. cloud stone glue according to claim 1 and 2, the granularity of wherein said filler is micron-sized, is selected from one or both in water-ground limestone, Calcium of intensifiens, barium sulfate, silicon-dioxide, anhydrous calciumsulphate, light calcium carbonate, aluminium hydroxide, wilkinite, wollastonite powder and zinc sulfide white.
5. cloud stone glue according to claim 4, the granularity of wherein said filler is 300 order-1200 orders.
6. cloud stone glue according to claim 5, the granularity of wherein said filler is 300 order-550 orders.
7. cloud stone glue according to claim 6, the granularity of wherein said filler is 900 order-1200 orders.
8. cloud stone glue according to claim 1 and 2, wherein said talcous granularity is 325 order-1250 orders.
9. cloud stone glue according to claim 8, wherein said talcous granularity is 900 order-1200 orders.
10. cloud stone glue according to claim 1 and 2, wherein said thinner is selected from one or both in vinylbenzene, Vinyl toluene, Phthalic acid, diallyl ester, methyl methacrylate, dimethylbenzene, turps, phenylcarbinol.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210264392.3A CN103571421B (en) | 2012-07-27 | 2012-07-27 | A kind of stable form cloud stone glue |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210264392.3A CN103571421B (en) | 2012-07-27 | 2012-07-27 | A kind of stable form cloud stone glue |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103571421A true CN103571421A (en) | 2014-02-12 |
| CN103571421B CN103571421B (en) | 2016-06-15 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210264392.3A Active CN103571421B (en) | 2012-07-27 | 2012-07-27 | A kind of stable form cloud stone glue |
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| CN (1) | CN103571421B (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104559896A (en) * | 2014-05-20 | 2015-04-29 | 钟翰万 | Binding agent |
| CN107674626A (en) * | 2017-09-28 | 2018-02-09 | 武汉市科达云石护理材料有限公司 | A kind of transparent cloud stone glue of high thixotropic and preparation method thereof |
| CN107793985A (en) * | 2017-09-28 | 2018-03-13 | 武汉市科达云石护理材料有限公司 | A kind of coloured cloud stone glue of high thixotropic and preparation method thereof |
| CN110818319A (en) * | 2019-12-13 | 2020-02-21 | 西安中科贝昂环保科技有限公司 | Environment-friendly artificial stone for cooking bench and preparation method thereof |
| CN112391132A (en) * | 2020-11-05 | 2021-02-23 | 江苏大力士投资有限公司 | Method for prolonging storage period of marble glue |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101735759A (en) * | 2009-12-10 | 2010-06-16 | 江苏大力士投资有限公司 | High-performance marble glue and preparation method thereof |
| CN101805581A (en) * | 2009-03-25 | 2010-08-18 | 武汉市科达云石护理材料有限公司 | Special colored stone material caulking sealant |
-
2012
- 2012-07-27 CN CN201210264392.3A patent/CN103571421B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101805581A (en) * | 2009-03-25 | 2010-08-18 | 武汉市科达云石护理材料有限公司 | Special colored stone material caulking sealant |
| CN101735759A (en) * | 2009-12-10 | 2010-06-16 | 江苏大力士投资有限公司 | High-performance marble glue and preparation method thereof |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104559896A (en) * | 2014-05-20 | 2015-04-29 | 钟翰万 | Binding agent |
| CN107674626A (en) * | 2017-09-28 | 2018-02-09 | 武汉市科达云石护理材料有限公司 | A kind of transparent cloud stone glue of high thixotropic and preparation method thereof |
| CN107793985A (en) * | 2017-09-28 | 2018-03-13 | 武汉市科达云石护理材料有限公司 | A kind of coloured cloud stone glue of high thixotropic and preparation method thereof |
| CN107793985B (en) * | 2017-09-28 | 2020-05-22 | 武汉市科达云石护理材料有限公司 | High-thixotropic colored marble adhesive and preparation method thereof |
| CN107674626B (en) * | 2017-09-28 | 2020-08-04 | 武汉市科达云石护理材料有限公司 | High-thixotropic transparent marble adhesive and preparation method thereof |
| CN110818319A (en) * | 2019-12-13 | 2020-02-21 | 西安中科贝昂环保科技有限公司 | Environment-friendly artificial stone for cooking bench and preparation method thereof |
| CN112391132A (en) * | 2020-11-05 | 2021-02-23 | 江苏大力士投资有限公司 | Method for prolonging storage period of marble glue |
| CN112391132B (en) * | 2020-11-05 | 2022-03-15 | 江苏大力士投资有限公司 | Method for prolonging storage period of marble glue |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103571421B (en) | 2016-06-15 |
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