CN101805581A - Special colored stone material caulking sealant - Google Patents
Special colored stone material caulking sealant Download PDFInfo
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- CN101805581A CN101805581A CN 201010147296 CN201010147296A CN101805581A CN 101805581 A CN101805581 A CN 101805581A CN 201010147296 CN201010147296 CN 201010147296 CN 201010147296 A CN201010147296 A CN 201010147296A CN 101805581 A CN101805581 A CN 101805581A
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Abstract
The invention relates to special colored stone material caulking sealant, which at least comprises 100 weight parts of air-dried unsaturated polyester resin, 1 to 5 weight parts of hydrogenated castor oil, 10 to 250 weight parts of filling materials and 1 to 15 parts of antishrinking agents. The invention overcomes the defects of poor air-dried performance, low antishrinking capability, poor permeability and the like when the existing ordinary marble glue is used as the caulking sealant. The stone material caulking sealant of the invention has the advantages of good permeability, hand inadhesion after being cured, strong antishrinking capability, sealant brightness after grinding and the like. The invention enriches the variety of the marble glue, and solves the caulking problem between stone materials.
Description
Technical field
The present invention relates to a kind of special color stone grout, it is mainly used in filling up or filling of slit between the stone material.It also can be used for the jointing that pottery waits other material of construction.
Background technology
Cloud stone glue is a unsaturated polyester glue and since its main be to be used on the marble, the cloud stone glue that is referred to as sanctified by usage in the native land.It is mainly used in the stone material property filled up bonding (general carry load is less), and it is bonding to be called unstructuredness.Structural bonding being meant needs the bonding of carry load.Unstructuredness is bonding to be with respect to structural bonding a kind of defective of utilizing the organic chemistry sizing agent to stone material, as crack, crackle, hole, sand holes finishing location etc. repair, fill, enhancing, a kind of technology of fixed.
The property filled up bonding (unstructuredness is bonding) has tangible difference with structural being bonded on stressed, i.e. the load of the bonding not holding capacity of the property filled up.What is called is filled up, and very large effect is to play the effect that beautifies stone material outward appearance visual sense of beauty and modular product size.And in recent years, continuous development along with adhesive for building, it has also promoted the further growth of whole architectural chemistry product industry, the application of cloud stone glue is also more and more wide, as the decorations of family, the quick location of stone material, repairing, parquets, splice, fill up stone hole and slit etc. and use all very general.
Now there is not special-purpose jointing glue for stone on the market, the common cloud stone glue of general employing replaces, but common cloud stone glue is if being used for jointing exists unreasonable part because common cloud stone glue is mainly used in the bonding of stone material and ground, or more than the ground to below 9 meters with bonding (the state compulsion regulation) of metope.Common cloud stone glue need bear certain less load, therefore for bonding intensity certain requirement is arranged, but requires lower for air-drying property, brightness, contractility, perviousness.And jointing adhesive is mainly used in filling up between the stone material slit, need contact with atmosphere.Therefore low for the bonding strength cloud stone glue that requires to compare, but then higher for contractility, brightness, air-drying property, infiltrative requirement.
Can there be following shortcoming with existing common cloud stone glue as jointing adhesive: 1.. air-drying property is poor, and colloid solidifies the sticking hand in back.2.. polishing back colloid is inconsistent with the brightness of polishing stone material, and aberration is arranged.3.. anti-contractility is poor, and adhesive curing forms depression easily or separates with stone material.4.. poor permeability, joint filling is discontented or exist empty.
Summary of the invention
The objective of the invention is to overcome above-mentioned having now common cloud stone glue is used for the weak point of jointing glue for stone, and a kind of special color stone grout is provided.
The objective of the invention is to reach: special color stone grout by following measure, it is characterized in which comprises at least air-dried unsaturated polyester resin 100 weight parts, hydrogenated castor oil 1-5 weight part, filler 10-250 weight part, antishrinking agent 1-15 weight part.
In technique scheme, which comprises at least air-dried unsaturated polyester resin 100 weight parts, hydrogenated castor oil 1-5 weight part, water-ground limestone 50-200 weight part, talcum powder 2-10 weight part, antishrinking agent 1-15 weight part.
In technique scheme, described filler comprises one or more in lime carbonate, talcum powder, dry powder, silica powder, ground dolomite, the barium sulfate.
In technique scheme, it also comprises reactive thinner 1-5 weight part.
In technique scheme, antishrinking agent comprises one or more in poly-propyl acetate, poly-hexanodioic acid glycerine ester, polyvinyl acetate, polyacrylic ester, polystyrene, polyethylene, polyvinyl chloride, the polymethylmethacrylate.
In technique scheme, described air-dried unsaturated polyester resin is: the modified unsaturated polyester resin that utilizes the synthetic dicyclopentadiene of half esterification process, the glycidyl allyl ether modified unsaturated polyester resin, the air-dried unsaturated polyester resin of trimethylolpropane allyl ether modification adds thinner, promotor and stopper (being furnished with thinner, promotor and stopper in the commercial unsaturated polyester resin product) by constant in the above-mentioned air-dried unsaturated polyester resin.
In technique scheme, described air-dried unsaturated polyester resin is 100 weight parts, and hydrogenated castor oil is the 2-4 weight part, and antishrinking agent is the 5-10 weight part, lime carbonate 75-150 weight part, talcum powder 4-8 weight part.
In technique scheme, it also comprises Rutile type Titanium Dioxide 5-20 weight part.
In technique scheme, it also comprises colored pigment.
In technique scheme, described lime carbonate average out to 300-1000 order.
In technique scheme, described reactive thinner is vinylbenzene, alpha-methyl styrene, glycerine diallyl ether adipic acid ester, Phthalic acid, diallyl ester, chloro styrene, in the t-butyl styrene one or more.
Described air-dried unsaturated polyester resin adds in building-up process: a kind of in naphthenic hydrocarbon dibasic alcohol, neopentyl glycol, Hydrogenated Bisphenol A, the trans pair of dehydration N.F,USP MANNITOL or the m-phthalic acid.
Special color stone grout of the present invention has following advantage: 1.. good penetrability; The colloid exquisiteness easily is in harmonious proportion, and has certain fluidity after being blended into solidifying agent, can be penetrated in the tiny stone material slit; And because the colloid exquisiteness, cemented side seam can be very thin, the increase aesthetic property (jointing adhesive adopts reactive thinner, therefore easily is in harmonious proportion, and good penetrability, and do not influence bonding strength).2.. solidify back tack-free (air-drying property will be got well); After colloid solidifies, at once tack-free.Because if when being used for the renovation of hotel stone floor, require jointing adhesive to use up after, just polishing at once.If colloid glues hand, will make mill material on the sander directly in water throwing or when do throwing, on cemented side seam, form black seam, influence (adopt the good unsaturated polyester resin of air-drying property, so air-drying property being good) attractive in appearance especially.3.. anti-contractility is strong, can not form depression after the adhesive curing or separate (adopt antishrinking agent, the shrinking percentage of jointing glue for stone can be controlled in 1%) with stone material.4.. polishing back glue has brightness, quite (find after deliberation: the brightness of jointing adhesive is relevant with the hardness of unsaturated polyester resin with stone polishing brightness, and the hardness of unsaturated polyester resin is relevant with the softening temperature of polyester, can improve hardness by the softening temperature that improves polyester in building-up process).5.. coloring agent is arranged, and ageing resistance is good, and is not easy to change, particularly white size (adopting Rutile type Titanium Dioxide colloid colour stable) inhibited from yellowing.6.. enrich a kind of cloud stone glue, solved the difficult problem of jointing between the stone material.
Embodiment
Describe performance of the present invention in detail below by embodiment, but they do not constitute limitation of the invention, only do for example.Simultaneously by illustrating that advantage of the present invention will become clear more and understanding easily.
Air-dried unsaturated polyester resin can not be subjected to the interference of oxygen and drying and forming-film in air set, and the surface is non-blocking.This specific character is called dry air again, is called for short air-drying property or empty dryness.
The reaction principle of air-drying property:
During unsaturated polyester resin (being called for short UPR) ambient cure, the product surface stickness is made troubles to application usually.Because the curing mechanism of unsaturated polyester resin is a free radicals copolymerization reaction, the size of the activity of free radical decision polymerization rate and then impact polymer molecular weight.
Surface tack is owing to oxygen participation polyreaction in the air causes during curable polyester.The free radical R that initial stage generates combines with molecular oxygen and generates polymkeric substance peroxy radical RO
2, the specific activity RO of R
2Active big, the transformation period of R is 10
-8S, RO
2Be 10
-2S rests on RO on the surface
2In this stage, just suppressed the growth of polymericular weight.But peroxy radical RO
2Easily with electropositivity carbon on the hydrogen atom that links to each other react, the hydroperoxide of generation polymkeric substance, that is:
ROO·+HR
1→ROOH+R
1·
The polymkeric substance hydroperoxide can produce active strong free radical, and reaction is proceeded, and generate the high-molecular weight compound.
Such as allyl ethers (CH
2=CH-CH
2-O-) and unconjugated double bond (CH=CH-CH
2-CH=CH-) in the system positivity carbon atom is arranged all, all have the ability of automatic oxygen uptake.
The anti-contractile mechanism of antishrinking agent is: during the stone jointing adhesive curing, and antishrinking agent expanded by heating, the volumetric shrinkage when curable polyester has all around been offset in its expansion.Two-phase is cooled off simultaneously subsequently, because antishrinking agent is more much bigger than the shrinking percentage of polyester, therefore forms a lot of little spaces on biphase has a common boundary, and internal stress has been eliminated in its formation, and polyester is no longer shunk.
Better through the following air-dried unsaturated polyester resin air-drying property of a large amount of experiment screenings, air-dried unsaturated polyester resin among the present invention includes but are not limited to following material: the modified unsaturated polyester resin that utilizes the synthetic dicyclopentadiene of half esterification process, the glycidyl allyl ether modified unsaturated polyester resin, the air-dried unsaturated polyester resin of trimethylolpropane allyl ether modification (above material is all commercially available), the shrinking percentage of air-dried unsaturated polyester resin is about 5%-8%.
Behind a large amount of experiment screenings, following reactive thinner also has anti-contraction: Phthalic acid, diallyl ester, chloro styrene, to t-butyl styrene.Reactive thinner glycerine diallyl ether adipic acid ester can also reach the purpose (above material is all commercially available) that gas is done simultaneously.Need to prove: other reactive thinner commonly used also can adopt.
Antishrinking agent comprises polyvinyl acetate, polystyrene, polyethylene, polyvinyl chloride, polyacrylic ester, poly-propyl acetate, poly-hexanodioic acid glycerine ester, polymethylmethacrylate etc.
Existing cloud stone glue performance:
The cloud stone glue technical requirements
(the building material industry standard JC/T989-2006 of the People's Republic of China (PRC))
Embodiment 1 (every part is weight part, down together)
Special color stone grout, it is by air-dried unsaturated polyester resin 100 weight parts, hydrogenated castor oil 5 weight parts, average out to 1000 order water-ground limestones 50 weight parts, talcum powder 2 weight parts, antishrinking agent 1 weight part is formed, and its color is cream-coloured.
Air-dried unsaturated polyester resin is the modified unsaturated polyester resin that utilizes the synthetic dicyclopentadiene of half esterification process, and antishrinking agent is polyacrylic ester 1 weight part.
After testing: its compression shear strength (MPa) is: 16.8, and draw and cut intensity (MPa): 15.9, curved bullet (MPa): 6306.1, impelling strength (KJ/m
2): 2.86, hardness (HSD): 61.7, shrinking percentage (%): 2.41.
During use: need jointing glue for stone of the present invention to be mixed with solidifying agent and stir, the blending ratio of jointing glue for stone and solidifying agent is: 100: 3.
Embodiment 2
Special color stone grout, it is by air-dried unsaturated polyester resin 100 weight parts, hydrogenated castor oil 1 weight part, average out to 300 order lime carbonate 170 weight parts, dry powder 30 weight parts, talcum powder 3 weight parts, antishrinking agent 15 weight parts, reactive thinner 5 weight parts are formed, and its color is cream-coloured.
Air-dried unsaturated polyester resin is the glycidyl allyl ether modified unsaturated polyester resin, antishrinking agent is polyvinyl acetate 7 weight parts, poly-propyl acetate 8 weight parts, and reactive thinner is glycerine diallyl ether adipic acid ester 2 weight parts, Phthalic acid, diallyl ester 3 weight parts.
After testing: its compression shear strength (MPa) is: 13.5, and draw and cut intensity (MPa): 14.8, curved bullet (MPa): 6812.2, impelling strength (KJ/m
2): 2.43, hardness (HSD): 50.2, shrinking percentage (%): 0.12.
Using method is with embodiment 1.
Embodiment 3
Special color stone grout, it is by air-dried unsaturated polyester resin 100 weight parts, hydrogenated castor oil 3 weight parts, average out to 300 order water-ground limestones 130 weight parts, silica powder 20 weight parts, antishrinking agent 8 weight parts are formed, reactive thinner 3 weight parts are formed, and its color is cream-coloured.
Air-dried unsaturated polyester resin is the glycidyl allyl ether modified unsaturated polyester resin, and antishrinking agent is polyacrylic ester 3 weight parts, poly-hexanodioic acid glycerine ester 5 weight parts, and reactive thinner is Phthalic acid, diallyl ester 3 weight parts.
After testing: its compression shear strength (MPa) is: 15.3, and draw and cut intensity (MPa): 16.2, curved bullet (MPa): 6704.5, impelling strength (KJ/m
2): 2.71, hardness (HSD): 54.8, shrinking percentage (%): 0.76.
Using method is with embodiment 1.
Embodiment 4
Special color stone grout, it is by air-dried unsaturated polyester resin 100 weight parts, hydrogenated castor oil 2 weight parts, average out to 600 order water-ground limestones 60 weight parts, talcum powder 10 weight parts, antishrinking agent 5 weight parts are formed, reactive thinner 1 weight part is formed, and its color is cream-coloured.
Air-dried unsaturated polyester resin is the modified unsaturated polyester resin that utilizes the synthetic dicyclopentadiene of half esterification process, and antishrinking agent is polyethylene 3 weight parts, polyacrylic ester 2 weight parts, and reactive thinner is chloro styrene 1 weight part.
After testing: its compression shear strength (MPa) is: 17.2, and draw and cut intensity (MPa): 17.8, curved bullet (MPa): 6418.3, impelling strength (KJ/m
2): 2.80, hardness (HSD): 61.8, shrinking percentage (%): 1.27.
Using method is with embodiment 1.
Embodiment 5
Special color stone grout, it is by air-dried unsaturated polyester resin 100 weight parts, hydrogenated castor oil 4 weight parts, average out to 400 order water-ground limestones 100 weight parts, barium sulfate 30 weight parts, antishrinking agent 10 weight parts, reactive thinner 2 weight parts are formed, and its color is cream-coloured.
Air-dried unsaturated polyester resin is the air-dried unsaturated polyester resin of trimethylolpropane allyl ether modification.Antishrinking agent is polystyrene 5 weight parts, polymethylmethacrylate 5 weight parts, and reactive thinner is to t-butyl styrene 2 weight parts.
After testing: its compression shear strength (MPa) is: 15.7, and draw and cut intensity (MPa): 16.3, curved bullet (MPa): 6634.0, impelling strength (KJ/m
2): 2.78, hardness (HSD): 57.3, shrinking percentage (%): 0.78.
Using method is with embodiment 1.
Embodiment 6
Special color stone grout, it is by air-dried unsaturated polyester resin 100 weight parts, hydrogenated castor oil 2 weight parts, average out to 400 order water-ground limestones 150 weight parts, ground dolomite 3 weight parts, antishrinking agent 12 weight parts, reactive thinner 4 weight parts are formed.Its color is cream-coloured.
Air-dried unsaturated polyester resin is the modified unsaturated polyester resin that utilizes the synthetic dicyclopentadiene of half esterification process, antishrinking agent is polyvinyl acetate 3 weight parts, polyacrylic ester 2 weight parts, polystyrene 5 weight parts, polyethylene 2 weight parts, and reactive thinner is glycerine diallyl ether adipic acid ester 2 weight parts, chloro styrene 2 weight parts.
After testing: its compression shear strength (MPa) is: 15.9, and draw and cut intensity (MPa): 15.8, curved bullet (MPa): 6716.6, impelling strength (KJ/m
2): 2.69, hardness (HSD): 53.6, shrinking percentage (%): 0.15.
Using method is with embodiment 1.
Embodiment 7
Special color stone grout, it is 100 weight parts by air-dried unsaturated polyester resin, hydrogenated castor oil is 3 weight parts, average out to 600 order lime carbonate 75 weight parts, talcum powder 8 weight parts, antishrinking agent are 10 weight parts, reactive thinner 2 weight parts are formed.Its color is cream-coloured.
Air-dried unsaturated polyester resin is the air-dried unsaturated polyester resin of trimethylolpropane allyl ether modification.Antishrinking agent is polystyrene 3 weight parts, polymethylmethacrylate 7 weight parts, and reactive thinner is Phthalic acid, diallyl ester 2 weight parts.
After testing: its compression shear strength (MPa) is: 17.5, and draw and cut intensity (MPa): 18.1, curved bullet (MPa): 6400.3, impelling strength (KJ/m
2): 2.90, hardness (HSD): 60.9, shrinking percentage (%): 0.88.
Using method is with embodiment 1.
Embodiment 8
Special color stone grout, it is 100 weight parts by air-dried unsaturated polyester resin, hydrogenated castor oil is 2 weight parts, average out to 400 order lime carbonate 140 weight parts, talcum powder 4 weight parts, antishrinking agent are 10 weight parts, titanium dioxide 5 weight parts, reactive thinner 3 weight parts are formed.Its color is a white.
Air-dried unsaturated polyester resin is the modified unsaturated polyester resin that utilizes the synthetic dicyclopentadiene of half esterification process, and antishrinking agent is a polyvinyl acetate, and reactive thinner is to t-butyl styrene, and titanium dioxide is a rutile-type.
After testing: its compression shear strength (MPa) is: 15.4, and draw and cut intensity (MPa): 16.2, curved bullet (MPa): 6735.8, impelling strength (KJ/m
2): 2.58, hardness (HSD): 53.2, shrinking percentage (%): 0.08.
Using method is with embodiment 1.
Embodiment 9
Special color stone grout, it is 100 weight parts by air-dried unsaturated polyester resin, hydrogenated castor oil is 3 weight parts, average out to 900 order lime carbonate 70 weight parts, talcum powder 6 weight parts, antishrinking agent are 8 weight parts, titanium dioxide 10 weight parts, reactive thinner 2 weight parts are formed.Its color is a white.
Air-dried unsaturated polyester resin is the air-dried unsaturated polyester resin of trimethylolpropane allyl ether modification, and antishrinking agent is a polyacrylic ester, and reactive thinner is a chloro styrene, and titanium dioxide is a rutile-type.
After testing: its compression shear strength (MPa) is: 16.4, and draw and cut intensity (MPa): 17.3, curved bullet (MPa): 6013.2, impelling strength (KJ/m
2): 2.63, hardness (HSD): 62.0, shrinking percentage (%): 0.17.
Using method is with embodiment 1.
Embodiment 10
Special color stone grout, it is 100 weight parts by air-dried unsaturated polyester resin, hydrogenated castor oil is 2.5 weight parts, average out to 700 order water-ground limestones 110 weight parts, talcum powder 5 weight parts, antishrinking agent are 9 weight parts, reactive thinner 5 weight parts, titanium dioxide 15 weight parts are formed.Its color is a white.
Air-dried unsaturated polyester resin is the air-dried unsaturated polyester resin of trimethylolpropane allyl ether modification.Antishrinking agent is a polymethylmethacrylate, reactive thinner is vinylbenzene 1 weight part, alpha-methyl styrene 1 weight part, glycerine diallyl ether adipic acid ester 1 weight part, Phthalic acid, diallyl ester 1 weight part, chloro styrene 1 weight part, titanium dioxide are rutile-type.
After testing: its compression shear strength (MPa) is: 15.6, and draw and cut intensity (MPa): 16.0, curved bullet (MPa): 6217.8, impelling strength (KJ/m
2): 2.48, hardness (HSD): 56.8, shrinking percentage (%): 0.49.
Using method is with embodiment 1.
Embodiment 11
Special color stone grout, it is 100 weight parts by air-dried unsaturated polyester resin, hydrogenated castor oil is 2 weight parts, average out to 500 order water-ground limestones 150 weight parts, talcum powder 2 weight parts, antishrinking agent are 10 weight parts, reactive thinner 5 weight parts, titanium dioxide 20 weight parts are formed.Its color is a white.
Air-dried unsaturated polyester resin is the glycidyl allyl ether modified unsaturated polyester resin, antishrinking agent is polyvinyl acetate 2 weight parts, polyacrylic ester 2 weight parts, polystyrene 2 weight parts, polyethylene 2 weight parts, polyvinyl chloride 2 weight parts, and reactive thinner is glycerine diallyl ether adipic acid ester 2 weight parts, Phthalic acid, diallyl ester 1 weight part, chloro styrene 1 weight part, to t-butyl styrene 1 weight part.
After testing: its compression shear strength (MPa) is: 15.0, and draw and cut intensity (MPa): 15.7, curved bullet (MPa): 6325.4, impelling strength (KJ/m
2): 2.45, hardness (HSD): 53.7, shrinking percentage (%): 0.32.
Using method is with embodiment 1.
Embodiment 12
Special color stone grout, it is 100 weight parts by air-dried unsaturated polyester resin, hydrogenated castor oil is 2 weight parts, average out to 500 order water-ground limestones 150 weight parts, talcum powder 4 weight parts, antishrinking agent are 10 weight parts, reactive thinner 4 weight parts, red pigment (pigment wherein is the various pigment that colloid needs, and the consumption of pigment is determined according to the depth of required pigment) is formed.Its color is red.
Air-dried unsaturated polyester resin is the modified unsaturated polyester resin that utilizes the synthetic dicyclopentadiene of half esterification process, and antishrinking agent is a polyacrylic ester, and reactive thinner is glycerine diallyl ether adipic acid ester 2 weight parts, Phthalic acid, diallyl ester 2 weight parts.
After testing: its compression shear strength (MPa) is: 15.8, and draw and cut intensity (MPa): 16.1, curved bullet (MPa): 6689.5, impelling strength (KJ/m
2): 2.73, hardness (HSD): 54.0, shrinking percentage (%): 0.06.
Using method is with embodiment 1.
Embodiment 13
Special color stone grout, it is 100 weight parts by air-dried unsaturated polyester resin, hydrogenated castor oil is 2 weight parts, average out to 400 order water-ground limestones 150 weight parts, talcum powder 4 weight parts, antishrinking agent are 10 weight parts, reactive thinner 3 weight parts, yellow ultramarine (pigment wherein is the various pigment that colloid needs, and the consumption of pigment is determined according to the depth of required pigment) is formed.Its color is yellow.
Air-dried unsaturated polyester resin is the glycidyl allyl ether modified unsaturated polyester resin, antishrinking agent is polyvinyl acetate 6 weight parts, polymethylmethacrylate 4 weight parts, reactive thinner are Phthalic acid, diallyl ester 2 weight parts, chloro styrene 1 weight part.
After testing: its compression shear strength (MPa) is: 15.5, and draw and cut intensity (MPa): 16.4, curved bullet (MPa): 6604.9, impelling strength (KJ/m
2): 2.78, hardness (HSD): 54.2, shrinking percentage (%): 0.16.
Using method is with embodiment 1.
Embodiment 14
Special color stone grout, it is 100 weight parts by air-dried unsaturated polyester resin, hydrogenated castor oil is 3 weight parts, average out to 800 order lime carbonate 10 weight parts, antishrinking agent is 10 weight parts, reactive thinner 3 weight parts, yellow ultramarine (pigment wherein is the various pigment that colloid needs, and the consumption of pigment is determined according to the depth of required pigment) is formed.Its color is yellow.
Air-dried unsaturated polyester resin is the glycidyl allyl ether modified unsaturated polyester resin, antishrinking agent is polyvinyl acetate 6 weight parts, polymethylmethacrylate 4 weight parts, reactive thinner are Phthalic acid, diallyl ester 2 weight parts, chloro styrene 1 weight part.
After testing: its compression shear strength (MPa) is: 15.9, and draw and cut intensity (MPa): 14.7, curved bullet (MPa): 6507.3, impelling strength (KJ/m
2): 2.56, hardness (HSD): 63.5, shrinking percentage (%): 0.21.
Using method is with embodiment 1.
Embodiment 15
Special color stone grout, it is 100 weight parts by air-dried unsaturated polyester resin, hydrogenated castor oil is 3 weight parts, average out to 300 order lime carbonate 100 weight parts, barium sulfate 150 weight parts, antishrinking agent are 10 weight parts, reactive thinner 3 weight parts, yellow ultramarine (pigment wherein is the various pigment that colloid needs, and the consumption of pigment is determined according to the depth of required pigment) is formed.Its color is yellow.
Air-dried unsaturated polyester resin is the glycidyl allyl ether modified unsaturated polyester resin, antishrinking agent is polyvinyl acetate 6 weight parts, polymethylmethacrylate 4 weight parts, reactive thinner are Phthalic acid, diallyl ester 2 weight parts, chloro styrene 1 weight part.
After testing: its compression shear strength (MPa) is: 13.1, and draw and cut intensity (MPa): 13.9, curved bullet (MPa): 6613.5, impelling strength (KJ/m
2): 2.37, hardness (HSD): 50.3, shrinking percentage (%): 0.27.
Using method is with embodiment 1.
Satisfy the requirement of jointing between the stone material fully through trial edition invention special color stone grout.
Need to prove: to those of ordinary skill in the art, under the prerequisite that does not change the principle of the invention, can also make suitable improvement and distortion to the present invention, this belongs to protection scope of the present invention equally.As cited materials of the present invention such as antishrinking agent, reactive thinner, air-dried unsaturated polyester resins, comprise but be not limited to above-mentioned substance simultaneously.
Claims (12)
1. special color stone grout is characterized in which comprises at least air-dried unsaturated polyester resin 100 weight parts, hydrogenated castor oil 1-5 weight part, filler 10-250 weight part, antishrinking agent 1-15 weight part.
2. special color stone grout according to claim 1, it is characterized in which comprises at least air-dried unsaturated polyester resin 100 weight parts, hydrogenated castor oil 1-5 weight part, water-ground limestone 50-200 weight part, talcum powder 2-10 weight part, antishrinking agent 1-15 weight part.
3. jointing glue for stone according to claim 1 is characterized in that its described filler comprises one or more in lime carbonate, talcum powder, dry powder, silica powder, ground dolomite, the barium sulfate.
4. jointing glue for stone according to claim 1 and 2 is characterized in that it also comprises reactive thinner 1-5 weight part.
5. special color stone grout according to claim 1 and 2 is characterized in that antishrinking agent comprises one or more in poly-propyl acetate, poly-hexanodioic acid glycerine ester, polyvinyl acetate, polyacrylic ester, polystyrene, polyethylene, polyvinyl chloride, the polymethylmethacrylate.
6. special color stone grout according to claim 1 and 2, it is characterized in that described air-dried unsaturated polyester resin is: the modified unsaturated polyester resin that utilizes the synthetic dicyclopentadiene of half esterification process, the glycidyl allyl ether modified unsaturated polyester resin, the air-dried unsaturated polyester resin of trimethylolpropane allyl ether modification is pressed constant and is added thinner, promotor and stopper in the above-mentioned air-dried unsaturated polyester resin.
7. special color stone grout according to claim 1 and 2, it is characterized in that described air-dried unsaturated polyester resin is 100 weight parts, hydrogenated castor oil is the 2-4 weight part, and antishrinking agent is the 5-10 weight part, lime carbonate 75-150 weight part, talcum powder 4-8 weight part.
8. special color stone grout according to claim 1 and 2 is characterized in that it also comprises Rutile type Titanium Dioxide 5-20 weight part.
9. special color stone grout according to claim 1 and 2 is characterized in that it also comprises colored pigment.
10. special color stone grout according to claim 3 is characterized in that described lime carbonate average out to 300-1000 order.
11. special color stone grout according to claim 4, it is characterized in that described reactive thinner be vinylbenzene, alpha-methyl styrene, glycerine diallyl ether adipic acid ester, Phthalic acid, diallyl ester, chloro styrene, in the t-butyl styrene one or more.
12. special color stone grout according to claim 6 is characterized in that described air-dried unsaturated polyester resin adds in building-up process: a kind of in naphthenic hydrocarbon dibasic alcohol, neopentyl glycol, Hydrogenated Bisphenol A, the trans pair of dehydration N.F,USP MANNITOL or the m-phthalic acid.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201010147296 CN101805581B (en) | 2009-03-25 | 2010-03-22 | Stone material caulking sealant |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200910061335.3 | 2009-03-25 | ||
| CN 200910061335 CN101531875A (en) | 2009-03-25 | 2009-03-25 | Stone pointing adhesive |
| CN 201010147296 CN101805581B (en) | 2009-03-25 | 2010-03-22 | Stone material caulking sealant |
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| Publication Number | Publication Date |
|---|---|
| CN101805581A true CN101805581A (en) | 2010-08-18 |
| CN101805581B CN101805581B (en) | 2013-01-23 |
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|---|---|---|---|
| CN 201010147296 Active CN101805581B (en) | 2009-03-25 | 2010-03-22 | Stone material caulking sealant |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103571421A (en) * | 2012-07-27 | 2014-02-12 | 武汉市石代高新建材有限公司 | Stable type marble adhesive |
| CN106336532A (en) * | 2016-08-17 | 2017-01-18 | 张静 | Preparation method of water-resistant caulking agent |
| CN106634765A (en) * | 2016-12-16 | 2017-05-10 | 深圳市华星光电技术有限公司 | Black sealing compound and LCD (liquid crystal display) special-shaped screen, and manufacturing method thereof |
| CN108913077A (en) * | 2018-07-13 | 2018-11-30 | 深圳中天精装股份有限公司 | A kind of ventilative filleting glue of ceramic tile |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN1178804A (en) * | 1996-10-03 | 1998-04-15 | 中国石化扬子石油化工公司 | Process for preparing dicyclic pentylene modified unsaturated polyester resin |
| CN101531875A (en) * | 2009-03-25 | 2009-09-16 | 武汉市科达云石护理材料有限公司 | Stone pointing adhesive |
-
2010
- 2010-03-22 CN CN 201010147296 patent/CN101805581B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1178804A (en) * | 1996-10-03 | 1998-04-15 | 中国石化扬子石油化工公司 | Process for preparing dicyclic pentylene modified unsaturated polyester resin |
| CN101531875A (en) * | 2009-03-25 | 2009-09-16 | 武汉市科达云石护理材料有限公司 | Stone pointing adhesive |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103571421A (en) * | 2012-07-27 | 2014-02-12 | 武汉市石代高新建材有限公司 | Stable type marble adhesive |
| CN103571421B (en) * | 2012-07-27 | 2016-06-15 | 武汉市石代高新建材有限公司 | A kind of stable form cloud stone glue |
| CN106336532A (en) * | 2016-08-17 | 2017-01-18 | 张静 | Preparation method of water-resistant caulking agent |
| CN106634765A (en) * | 2016-12-16 | 2017-05-10 | 深圳市华星光电技术有限公司 | Black sealing compound and LCD (liquid crystal display) special-shaped screen, and manufacturing method thereof |
| CN108913077A (en) * | 2018-07-13 | 2018-11-30 | 深圳中天精装股份有限公司 | A kind of ventilative filleting glue of ceramic tile |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101805581B (en) | 2013-01-23 |
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Effective date of registration: 20230830 Address after: No. 6 Danjin Road, Industrial Concentration Zone, Baita Town, Jintan District, Changzhou City, Jiangsu Province, 213299 Patentee after: Jiangsu Hercules Marble Care Materials Co.,Ltd. Address before: No. 2 Zhangbai Road, Dongxihu District, Wuhan City, Hubei Province, 430400 Patentee before: WUHAN KEDA MARBLE PROTECTIVE MATERIALS Co.,Ltd. |