CN107021684A - A kind of aging-resistant flame-proof clay for being used to bond stone material and composite - Google Patents

A kind of aging-resistant flame-proof clay for being used to bond stone material and composite Download PDF

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Publication number
CN107021684A
CN107021684A CN201710350117.6A CN201710350117A CN107021684A CN 107021684 A CN107021684 A CN 107021684A CN 201710350117 A CN201710350117 A CN 201710350117A CN 107021684 A CN107021684 A CN 107021684A
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CN
China
Prior art keywords
parts
component
epoxy resin
aging
dry
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710350117.6A
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Chinese (zh)
Inventor
陈海平
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jiangsu Xianglong Stone Industry Co., Ltd.
Original Assignee
Gantry Zhengjiang City Art Of Stone Engraving Engineering Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Gantry Zhengjiang City Art Of Stone Engraving Engineering Co Ltd filed Critical Gantry Zhengjiang City Art Of Stone Engraving Engineering Co Ltd
Priority to CN201710350117.6A priority Critical patent/CN107021684A/en
Publication of CN107021684A publication Critical patent/CN107021684A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00637Uses not provided for elsewhere in C04B2111/00 as glue or binder for uniting building or structural materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • C04B2111/28Fire resistance, i.e. materials resistant to accidental fires or high temperatures

Abstract

The invention provides a kind of aging-resistant flame-proof clay for being used to bond stone material and composite, it is made up of the component of A, B, C tri-, according to the mass fraction, three components composition is as follows respectively:Component A:150 parts of cement, 20 parts of stone flour, 20 parts of iron sand;B component:20~30 parts of epoxy resin, A20 parts of dry-hang glue, diluent;C components:20~25 parts of curing agent, dry-hang glue B20~25 part.This is used for the aging-resistant flame-proof clay for bonding stone material and composite, and with good fire resistance, anti-aging, adhesive effect and good heat-insulation effect, intensity height, good toughness, cost durable in use are low.Raw material is cheap and easily-available, wide using scope, available for the repairing of building and ornament materials compound sticking, joint filling etc..Mechanical each field is can also be used for use.

Description

A kind of aging-resistant flame-proof clay for being used to bond stone material and composite
Technical field
It is more particularly to a kind of to be used to bond stone material and composite the present invention relates to stone material and composite bonding field Aging-resistant flame-proof clay.
Background technology
Marble slabs quality is graceful, and texture is quaint and elegant attractive in appearance, frequently as building inner-outer wall, ground, ceiling, windowsill and The finishing material of desktop, sanitary equipment.With the improvement and the lifting of artistic appreciation of people's living standard, this finishing material is used Quantity is increasing.China rises with stone industries to go to the world with stone material product, the technology that marble is combined with base material In rapid advances.But existing bonding cement slow curing, easy aging, easy firing, impact resistance is poor, and effect of heat insulation is poor, influence Adhesive strength, does not meet environmental requirement, and plasticization effect is difficult to persistently, there is improved necessity really.
The content of the invention
Based on this, it is necessary to provide a kind of aging-resistant flame-proof clay for being used to bond stone material and composite.
A kind of aging-resistant flame-proof clay for being used to bond stone material and composite, is made up of the component of A, B, C tri-, by mass parts Number meter, three components composition is as follows respectively:
Component A:
150 parts of cement, 20 parts of stone flour, 20 parts of iron sand;
B component:
20~30 parts of epoxy resin, A20 parts of dry-hang glue, diluent
C components:
20~25 parts of curing agent, dry-hang glue B20~25 part
Further, application method is:
(1) the husky separately storage of the cement of component A, building stones, iron, without using without diluent.
(2) epoxy resin of B component, dry-hang glue A, diluent are separately deposited, without using without curing agent and dry-hang glue B;
(3) curing agent of C components and dry-hang glue B are separately deposited;
(4) the step of making the aging-resistant flame-proof clay be:The epoxy resin of B component and dry-hang glue A are mixed, then added Enter the dry-hang glue B of C components and stir, then add the curing agent of C components, add component A and stir, be eventually adding dilution Agent, stirs.
Further, the epoxy resin uses unmodified epoxy resin, polyurethane-modified epoxy resin or poly- third One or more in the ester modified epoxy resin of olefin(e) acid.
Further, the diluent is epoxide resin reactive diluent or epoxy resin non-activated thinner, its middle ring Oxygen resin reactive diluents include ethylene glycol diglycidylether, phenyl glycidyl ether, polypropylene glycol diglycidyl ether, benzyl Base glycidol ether, o-tolyl glycidol ether or neopentylglycol diglycidyl ether;Epoxy resin non-activated thinner bag Include dibutyl phthalate or dioctyl phthalate;The diluent uses one or more therein.
Further, the curing agent uses one kind in aliphatic modified amine, alicyclic modified amine or polyamide.
It is above-mentioned to be used to bond the aging-resistant flame-proof clay of stone material and composite, with good fire resistance, anti-aging, Adhesive effect and good heat-insulation effect, intensity height, good toughness, cost durable in use are low.Raw material is cheap and easily-available, wide using scope, can For the repairing of building and ornament materials compound sticking, joint filling etc..Mechanical each field is can also be used for use.
Embodiment
Presently preferred embodiments of the present invention is described in detail below so that advantages and features of the invention can be easier to by It will be appreciated by those skilled in the art that apparent clearly being defined so as to be made to protection scope of the present invention.
The epoxy resin of the present invention uses unmodified epoxy resin, polyurethane-modified epoxy resin or polyacrylate One or more in modified epoxy resin.Diluent is epoxide resin reactive diluent or epoxy resin inactive diluents Agent, wherein epoxide resin reactive diluent include ethylene glycol diglycidylether, phenyl glycidyl ether, polypropylene glycol two and shunk Glycerin ether, benzyl glycidyl ether, o-tolyl glycidol ether or neopentylglycol diglycidyl ether;Epoxy resin is nonactive Diluent includes dibutyl phthalate or dioctyl phthalate;The diluent uses one or more therein. Curing agent uses one kind in aliphatic modified amine, alicyclic modified amine or polyamide.
Cement in the present invention was used no more than 30 days dates of manufacture.
After testing, the epoxide equivalent of epoxy resin is 210-244g/mol, and softening point is 15-23 DEG C, and viscosity is 6-10 DEG C, Easy saponification chlorine≤0.5%, 200≤mg/kg of inorganic chlorine, fugitive constituent≤1.0%, color and luster number 3≤.
Embodiment 1:
A kind of aging-resistant flame-proof clay for being used to bond stone material and composite, is made up of the component of A, B, C tri-, by mass parts Number meter, three components composition is as follows respectively:
Component A:
150 parts of cement, 20 parts of stone flour, 20 parts of iron sand;
B component:
20~30 parts of epoxy resin, A20 parts of dry-hang glue, diluent
C components:
20 parts of curing agent, B20 parts of dry-hang glue
Further, application method is:
(1) the husky separately storage of the cement of component A, building stones, iron, without using without diluent.
(2) epoxy resin of B component, dry-hang glue A, diluent are separately deposited, without using without curing agent and dry-hang glue B;
(3) curing agent of C components and dry-hang glue B are separately deposited;
(4) the step of making the aging-resistant flame-proof clay be:By mass fraction, by the epoxy resin of B component and dry-hang glue A Mixing, is subsequently added into the dry-hang glue B of C components and stirs, and then adds the curing agent of C components, adds component A and stir, most After add diluent, stir.
In the present embodiment, the component of A, B, C tri- carries out cooperation solidification with mass parts, starts solidification after 6~8 hours, 48 is small When after be fully cured.
Embodiment 2:
A kind of aging-resistant flame-proof clay for being used to bond stone material and composite, is made up of the component of A, B, C tri-, by mass parts Number meter, three components composition is as follows respectively:
Component A:
150 parts of cement, 20 parts of stone flour, 20 parts of iron sand;
B component:
20~30 parts of epoxy resin, A20 parts of dry-hang glue, diluent
C components:
22.5 parts of curing agent, B22.5 parts of dry-hang glue
Further, application method is:
(1) the husky separately storage of the cement of component A, building stones, iron, without using without diluent.
(2) epoxy resin of B component, dry-hang glue A, diluent are separately deposited, without using without curing agent and dry-hang glue B;
(3) curing agent of C components and dry-hang glue B are separately deposited;
(4) the step of making the aging-resistant flame-proof clay be:By mass fraction, by the epoxy resin of B component and dry-hang glue A Mixing, is subsequently added into the dry-hang glue B of C components and stirs, and then adds the curing agent of C components, adds component A and stir, most After add diluent, stir.
In the present embodiment, the component of A, B, C tri- carries out cooperation solidification with mass parts, starts solidification after 6~8 hours, 48 is small When after be fully cured.
Embodiment 3:
A kind of aging-resistant flame-proof clay for being used to bond stone material and composite, is made up of the component of A, B, C tri-, by mass parts Number meter, three components composition is as follows respectively:
Component A:
150 parts of cement, 20 parts of stone flour, 20 parts of iron sand;
B component:
20~30 parts of epoxy resin, A20 parts of dry-hang glue, diluent
C components:
25 parts of curing agent, B25 parts of dry-hang glue
Further, application method is:
(1) the husky separately storage of the cement of component A, building stones, iron, without using without diluent.
(2) epoxy resin of B component, dry-hang glue A, diluent are separately deposited, without using without curing agent and dry-hang glue B;
(3) curing agent of C components and dry-hang glue B are separately deposited;
(4) the step of making the aging-resistant flame-proof clay be:By mass fraction, by the epoxy resin of B component and dry-hang glue A Mixing, is subsequently added into the dry-hang glue B of C components and stirs, and then adds the curing agent of C components, adds component A and stir, most After add diluent, stir.
In the present embodiment, the component of A, B, C tri- carries out cooperation solidification with mass parts, starts solidification after 6~8 hours, 48 is small When after be fully cured.
Embodiment described above only expresses the several embodiments of the present invention, and it describes more specific and detailed, but simultaneously Therefore the limitation to the scope of the claims of the present invention can not be interpreted as.It should be pointed out that for one of ordinary skill in the art For, without departing from the inventive concept of the premise, various modifications and improvements can be made, these belong to the guarantor of the present invention Protect scope.Therefore, the protection domain of patent of the present invention should be determined by the appended claims.

Claims (5)

1. a kind of aging-resistant flame-proof clay for being used to bond stone material and composite, it is characterised in that by the component group of A, B, C tri- Into according to the mass fraction, three components composition is as follows respectively:
Component A:
150 parts of cement, 20 parts of stone flour, 20 parts of iron sand;
B component:
20~30 parts of epoxy resin, A20 parts of dry-hang glue, diluent
C components:
20~25 parts of curing agent, dry-hang glue B20~25 part.
2. it is used for the aging-resistant flame-proof clay for bonding stone material and composite according to claim 1, it is characterised in that it makes It is with method:
(1) the husky separately storage of the cement of component A, building stones, iron, without using without diluent.
(2) epoxy resin of B component, dry-hang glue A, diluent are separately deposited, without using without curing agent and dry-hang glue B;
(3) curing agent of C components and dry-hang glue B are separately deposited;
(4) the step of making the aging-resistant flame-proof clay be:The epoxy resin of B component and dry-hang glue A are mixed, C is subsequently added into The dry-hang glue B of component is simultaneously stirred, and is then added the curing agent of C components, is added component A and stir, be eventually adding diluent, stir Mix uniform.
3. it is used for the aging-resistant flame-proof clay for bonding stone material and composite according to claim 1, it is characterised in that described Epoxy resin is used in unmodified epoxy resin, polyurethane-modified epoxy resin or polyacrylate modified epoxy resin One or more.
4. it is used for the aging-resistant flame-proof clay for bonding stone material and composite according to claim 1, it is characterised in that described Diluent is epoxide resin reactive diluent or epoxy resin non-activated thinner, and wherein epoxide resin reactive diluent includes second Hexanediol diglycidyl ether, phenyl glycidyl ether, polypropylene glycol diglycidyl ether, benzyl glycidyl ether, o-tolyl Glycidol ether or neopentylglycol diglycidyl ether;Epoxy resin non-activated thinner includes dibutyl phthalate or neighbour Dioctyl phthalate;The diluent uses one or more therein.
5. it is used for the aging-resistant flame-proof clay for bonding stone material and composite according to claim 1, it is characterised in that described Curing agent uses one kind in aliphatic modified amine, alicyclic modified amine or polyamide.
CN201710350117.6A 2017-05-18 2017-05-18 A kind of aging-resistant flame-proof clay for being used to bond stone material and composite Pending CN107021684A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710350117.6A CN107021684A (en) 2017-05-18 2017-05-18 A kind of aging-resistant flame-proof clay for being used to bond stone material and composite

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710350117.6A CN107021684A (en) 2017-05-18 2017-05-18 A kind of aging-resistant flame-proof clay for being used to bond stone material and composite

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Publication Number Publication Date
CN107021684A true CN107021684A (en) 2017-08-08

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108894074A (en) * 2018-06-10 2018-11-27 重庆诚邦路面材料有限公司 A kind of fine antiskid wearing layer of cement pavement and construction method
CN109551863A (en) * 2018-12-27 2019-04-02 邱世典 The production technology of the inorganic A grades environmental protection enhancing decorative integrated plate directly generated of preventing fires

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Publication number Priority date Publication date Assignee Title
CN1282771A (en) * 2000-06-23 2001-02-07 杭州之江有机硅化工有限公司 Dual-component structural adhesive of epoxy resin for buildings
CN101328053A (en) * 2007-06-22 2008-12-24 上海宝元化学建材有限公司 Epoxy cement-based adhesive and preparation thereof
CN101712857A (en) * 2009-12-22 2010-05-26 江苏大力士投资有限公司 Epoxy dry-hang glue and preparation method thereof
CN102876269A (en) * 2012-09-20 2013-01-16 江苏大力士投资有限公司 High-strength epoxy adhesive and preparation method thereof
CN103131365A (en) * 2011-11-30 2013-06-05 常熟市辛庄镇前进五金厂 Single component room temperature curing epoxy construction glue
CN106431123A (en) * 2015-08-13 2017-02-22 姹ゅ浆 Novel macromolecular cement gum

Patent Citations (6)

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Publication number Priority date Publication date Assignee Title
CN1282771A (en) * 2000-06-23 2001-02-07 杭州之江有机硅化工有限公司 Dual-component structural adhesive of epoxy resin for buildings
CN101328053A (en) * 2007-06-22 2008-12-24 上海宝元化学建材有限公司 Epoxy cement-based adhesive and preparation thereof
CN101712857A (en) * 2009-12-22 2010-05-26 江苏大力士投资有限公司 Epoxy dry-hang glue and preparation method thereof
CN103131365A (en) * 2011-11-30 2013-06-05 常熟市辛庄镇前进五金厂 Single component room temperature curing epoxy construction glue
CN102876269A (en) * 2012-09-20 2013-01-16 江苏大力士投资有限公司 High-strength epoxy adhesive and preparation method thereof
CN106431123A (en) * 2015-08-13 2017-02-22 姹ゅ浆 Novel macromolecular cement gum

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108894074A (en) * 2018-06-10 2018-11-27 重庆诚邦路面材料有限公司 A kind of fine antiskid wearing layer of cement pavement and construction method
CN109551863A (en) * 2018-12-27 2019-04-02 邱世典 The production technology of the inorganic A grades environmental protection enhancing decorative integrated plate directly generated of preventing fires

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PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
TA01 Transfer of patent application right

Effective date of registration: 20190203

Address after: Room F411, Block B, Twin Towers, 468 Ding Mao Zhi Hui Avenue, Zhenjiang New District, Jiangsu Province, 2009

Applicant after: Jiangsu Xianglong Stone Industry Co., Ltd.

Address before: 212000 Stone Processing Zone of Ding Mao Yidu Building Material City, Zhenjiang City, Jiangsu Province

Applicant before: Gantry, Zhengjiang City art of stone engraving Engineering Co., Ltd

TA01 Transfer of patent application right
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20170808

WD01 Invention patent application deemed withdrawn after publication