CN103554807A - 一种纳米改性的无卤耐磨电缆料 - Google Patents
一种纳米改性的无卤耐磨电缆料 Download PDFInfo
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- CN103554807A CN103554807A CN201310473893.7A CN201310473893A CN103554807A CN 103554807 A CN103554807 A CN 103554807A CN 201310473893 A CN201310473893 A CN 201310473893A CN 103554807 A CN103554807 A CN 103554807A
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- butadiene
- wear resistant
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- 239000000463 material Substances 0.000 title claims abstract description 33
- 239000000843 powder Substances 0.000 claims abstract description 23
- -1 acrylate modified butadiene styrene resin Chemical class 0.000 claims abstract description 16
- 239000000945 filler Substances 0.000 claims abstract description 16
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 7
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229920000459 Nitrile rubber Polymers 0.000 claims abstract description 6
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 claims abstract description 6
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 6
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 claims abstract description 6
- 235000013539 calcium stearate Nutrition 0.000 claims abstract description 6
- 239000008116 calcium stearate Substances 0.000 claims abstract description 6
- 239000010436 fluorite Substances 0.000 claims abstract description 6
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims abstract description 6
- 150000003440 styrenes Chemical class 0.000 claims abstract description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 30
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 25
- 230000004048 modification Effects 0.000 claims description 13
- 238000012986 modification Methods 0.000 claims description 12
- 239000005995 Aluminium silicate Substances 0.000 claims description 10
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 10
- 239000004113 Sepiolite Substances 0.000 claims description 10
- 235000012211 aluminium silicate Nutrition 0.000 claims description 10
- 229910052799 carbon Inorganic materials 0.000 claims description 10
- 229920001971 elastomer Polymers 0.000 claims description 10
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 10
- 239000002994 raw material Substances 0.000 claims description 10
- 229910052624 sepiolite Inorganic materials 0.000 claims description 10
- 235000019355 sepiolite Nutrition 0.000 claims description 10
- 238000002360 preparation method Methods 0.000 claims description 8
- 230000032683 aging Effects 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 7
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 claims description 5
- GWZMWHWAWHPNHN-UHFFFAOYSA-N 2-hydroxypropyl prop-2-enoate Chemical compound CC(O)COC(=O)C=C GWZMWHWAWHPNHN-UHFFFAOYSA-N 0.000 claims description 5
- 241000143437 Aciculosporium take Species 0.000 claims description 5
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 claims description 5
- 229910052582 BN Inorganic materials 0.000 claims description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 5
- 235000005747 Carum carvi Nutrition 0.000 claims description 5
- 240000000467 Carum carvi Species 0.000 claims description 5
- VHOQXEIFYTTXJU-UHFFFAOYSA-N Isobutylene-isoprene copolymer Chemical group CC(C)=C.CC(=C)C=C VHOQXEIFYTTXJU-UHFFFAOYSA-N 0.000 claims description 5
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 5
- 229940037003 alum Drugs 0.000 claims description 5
- WHGYBXFWUBPSRW-FOUAGVGXSA-N beta-cyclodextrin Chemical compound OC[C@H]([C@H]([C@@H]([C@H]1O)O)O[C@H]2O[C@@H]([C@@H](O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O3)[C@H](O)[C@H]2O)CO)O[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@@H]3O[C@@H]1CO WHGYBXFWUBPSRW-FOUAGVGXSA-N 0.000 claims description 5
- NTXGQCSETZTARF-UHFFFAOYSA-N buta-1,3-diene;prop-2-enenitrile Chemical compound C=CC=C.C=CC#N NTXGQCSETZTARF-UHFFFAOYSA-N 0.000 claims description 5
- 239000011575 calcium Substances 0.000 claims description 5
- 229910052791 calcium Inorganic materials 0.000 claims description 5
- WUKWITHWXAAZEY-UHFFFAOYSA-L calcium difluoride Chemical compound [F-].[F-].[Ca+2] WUKWITHWXAAZEY-UHFFFAOYSA-L 0.000 claims description 5
- PMHQVHHXPFUNSP-UHFFFAOYSA-M copper(1+);methylsulfanylmethane;bromide Chemical compound Br[Cu].CSC PMHQVHHXPFUNSP-UHFFFAOYSA-M 0.000 claims description 5
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 5
- 239000006185 dispersion Substances 0.000 claims description 5
- 235000013399 edible fruits Nutrition 0.000 claims description 5
- 238000005984 hydrogenation reaction Methods 0.000 claims description 5
- 239000011021 lapis lazuli Substances 0.000 claims description 5
- 239000007788 liquid Substances 0.000 claims description 5
- 239000002105 nanoparticle Substances 0.000 claims description 5
- 230000007935 neutral effect Effects 0.000 claims description 5
- NQPDZGIKBAWPEJ-UHFFFAOYSA-N pentanoic acid group Chemical group C(CCCC)(=O)O NQPDZGIKBAWPEJ-UHFFFAOYSA-N 0.000 claims description 5
- 229920002857 polybutadiene Polymers 0.000 claims description 5
- 239000011591 potassium Substances 0.000 claims description 5
- 229910052700 potassium Inorganic materials 0.000 claims description 5
- 239000004576 sand Substances 0.000 claims description 5
- 239000000377 silicon dioxide Substances 0.000 claims description 5
- 235000010413 sodium alginate Nutrition 0.000 claims description 5
- 239000000661 sodium alginate Substances 0.000 claims description 5
- 229940005550 sodium alginate Drugs 0.000 claims description 5
- 239000000341 volatile oil Substances 0.000 claims description 5
- OMQSJNWFFJOIMO-UHFFFAOYSA-J zirconium tetrafluoride Chemical compound F[Zr](F)(F)F OMQSJNWFFJOIMO-UHFFFAOYSA-J 0.000 claims description 5
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical compound C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 abstract 2
- 229910017083 AlN Inorganic materials 0.000 abstract 1
- PIGFYZPCRLYGLF-UHFFFAOYSA-N Aluminum nitride Chemical compound [Al]#N PIGFYZPCRLYGLF-UHFFFAOYSA-N 0.000 abstract 1
- DLHONNLASJQAHX-UHFFFAOYSA-N aluminum;potassium;oxygen(2-);silicon(4+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Al+3].[Si+4].[Si+4].[Si+4].[K+] DLHONNLASJQAHX-UHFFFAOYSA-N 0.000 abstract 1
- 229920005549 butyl rubber Polymers 0.000 abstract 1
- 229940043348 myristyl alcohol Drugs 0.000 abstract 1
- 239000004810 polytetrafluoroethylene Substances 0.000 abstract 1
- 239000000454 talc Substances 0.000 abstract 1
- 229910052623 talc Inorganic materials 0.000 abstract 1
- 239000003063 flame retardant Substances 0.000 description 4
- 235000019504 cigarettes Nutrition 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 3
- 238000007664 blowing Methods 0.000 description 2
- 238000005453 pelletization Methods 0.000 description 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- 238000012271 agricultural production Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 238000002715 modification method Methods 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310473893.7A CN103554807B (zh) | 2013-10-12 | 2013-10-12 | 一种纳米改性的耐磨电缆料 |
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| CN201310473893.7A CN103554807B (zh) | 2013-10-12 | 2013-10-12 | 一种纳米改性的耐磨电缆料 |
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| Publication Number | Publication Date |
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| CN103554807A true CN103554807A (zh) | 2014-02-05 |
| CN103554807B CN103554807B (zh) | 2016-03-02 |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104177675A (zh) * | 2014-08-26 | 2014-12-03 | 安徽蓝德集团股份有限公司 | 一种抗撕裂阻燃橡胶电缆料 |
| CN105504406A (zh) * | 2015-12-28 | 2016-04-20 | 张桂华 | 一种新型橡胶及其制备方法 |
| CN105859986A (zh) * | 2016-05-31 | 2016-08-17 | 刘雷 | 一种计算机用绝缘阻水电缆材料及其制备方法 |
| CN106317524A (zh) * | 2016-08-17 | 2017-01-11 | 安徽顺驰电缆有限公司 | 电缆用耐油橡胶护套料 |
| CN114479220A (zh) * | 2022-03-01 | 2022-05-13 | 镇江市华银仪表电器有限公司 | 一种基于纳米改性的电动汽车快充电缆的高导热绝缘材料 |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102477205A (zh) * | 2010-11-22 | 2012-05-30 | 深圳至佳美科技有限公司 | 一种纳米改性的无卤耐磨电缆料及其制备方法 |
| CN102757651A (zh) * | 2012-06-12 | 2012-10-31 | 安徽华海特种电缆集团有限公司 | 一种硅橡胶绝缘氟橡胶电缆料及其制备方法 |
| CN103012940A (zh) * | 2012-09-29 | 2013-04-03 | 深圳市沃尔核材股份有限公司 | 一种高温自交联无卤阻燃电缆绝缘料或护套料及制备方法 |
| CN103059456A (zh) * | 2012-12-12 | 2013-04-24 | 安徽海纳川塑业科技有限公司 | 一种含有改性凹凸棒土的pvc管材及其制备方法 |
| CN103183881A (zh) * | 2011-12-29 | 2013-07-03 | 深圳市宏商材料科技股份有限公司 | 一种环保型热收缩应力套管及其制备方法 |
-
2013
- 2013-10-12 CN CN201310473893.7A patent/CN103554807B/zh active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102477205A (zh) * | 2010-11-22 | 2012-05-30 | 深圳至佳美科技有限公司 | 一种纳米改性的无卤耐磨电缆料及其制备方法 |
| CN103183881A (zh) * | 2011-12-29 | 2013-07-03 | 深圳市宏商材料科技股份有限公司 | 一种环保型热收缩应力套管及其制备方法 |
| CN102757651A (zh) * | 2012-06-12 | 2012-10-31 | 安徽华海特种电缆集团有限公司 | 一种硅橡胶绝缘氟橡胶电缆料及其制备方法 |
| CN103012940A (zh) * | 2012-09-29 | 2013-04-03 | 深圳市沃尔核材股份有限公司 | 一种高温自交联无卤阻燃电缆绝缘料或护套料及制备方法 |
| CN103059456A (zh) * | 2012-12-12 | 2013-04-24 | 安徽海纳川塑业科技有限公司 | 一种含有改性凹凸棒土的pvc管材及其制备方法 |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104177675A (zh) * | 2014-08-26 | 2014-12-03 | 安徽蓝德集团股份有限公司 | 一种抗撕裂阻燃橡胶电缆料 |
| CN105504406A (zh) * | 2015-12-28 | 2016-04-20 | 张桂华 | 一种新型橡胶及其制备方法 |
| WO2017114280A1 (zh) * | 2015-12-28 | 2017-07-06 | 张桂华 | 一种新型橡胶及其制备方法 |
| CN105859986A (zh) * | 2016-05-31 | 2016-08-17 | 刘雷 | 一种计算机用绝缘阻水电缆材料及其制备方法 |
| CN106317524A (zh) * | 2016-08-17 | 2017-01-11 | 安徽顺驰电缆有限公司 | 电缆用耐油橡胶护套料 |
| CN114479220A (zh) * | 2022-03-01 | 2022-05-13 | 镇江市华银仪表电器有限公司 | 一种基于纳米改性的电动汽车快充电缆的高导热绝缘材料 |
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| Publication number | Publication date |
|---|---|
| CN103554807B (zh) | 2016-03-02 |
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Date of cancellation: 20230725 Granted publication date: 20160302 Pledgee: Tengzhou Branch of Zaozhuang Bank Co.,Ltd. Pledgor: SHANDONG HUANENG CABLE Ltd. Registration number: Y2022990000489 |
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Denomination of invention: A nano modified wear-resistant cable material Effective date of registration: 20230727 Granted publication date: 20160302 Pledgee: Tengzhou Branch of Zaozhuang Bank Co.,Ltd. Pledgor: SHANDONG HUANENG CABLE Ltd. Registration number: Y2023980050022 |
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