CN103539943B - 一种聚苯胺的制备方法 - Google Patents
一种聚苯胺的制备方法 Download PDFInfo
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- CN103539943B CN103539943B CN201310547288.XA CN201310547288A CN103539943B CN 103539943 B CN103539943 B CN 103539943B CN 201310547288 A CN201310547288 A CN 201310547288A CN 103539943 B CN103539943 B CN 103539943B
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- polyaniline
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- 229920000767 polyaniline Polymers 0.000 title claims abstract description 98
- 238000002360 preparation method Methods 0.000 title claims abstract description 35
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 claims abstract description 96
- 239000000243 solution Substances 0.000 claims abstract description 63
- BYGOPQKDHGXNCD-UHFFFAOYSA-N tripotassium;iron(3+);hexacyanide Chemical compound [K+].[K+].[K+].[Fe+3].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-] BYGOPQKDHGXNCD-UHFFFAOYSA-N 0.000 claims abstract description 25
- 239000003960 organic solvent Substances 0.000 claims abstract description 21
- 238000006243 chemical reaction Methods 0.000 claims abstract description 14
- 239000007864 aqueous solution Substances 0.000 claims abstract description 9
- 150000007522 mineralic acids Chemical class 0.000 claims abstract description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 26
- 238000001291 vacuum drying Methods 0.000 claims description 17
- 239000007795 chemical reaction product Substances 0.000 claims description 14
- 239000000047 product Substances 0.000 claims description 14
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 12
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 12
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 12
- 239000008367 deionised water Substances 0.000 claims description 12
- 229910021641 deionized water Inorganic materials 0.000 claims description 12
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical compound OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 claims description 12
- 235000011114 ammonium hydroxide Nutrition 0.000 claims description 11
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 claims description 10
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 10
- 238000000034 method Methods 0.000 claims description 9
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 claims description 8
- 230000008569 process Effects 0.000 claims description 8
- 239000002253 acid Substances 0.000 claims description 7
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 7
- 239000011707 mineral Substances 0.000 claims description 7
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 6
- 229910017604 nitric acid Inorganic materials 0.000 claims description 6
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 claims description 5
- -1 tetracol phenixin Chemical compound 0.000 claims description 5
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 4
- 239000004327 boric acid Substances 0.000 claims description 4
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 abstract description 52
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 abstract description 48
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 abstract description 26
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract description 23
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 abstract description 14
- 239000002798 polar solvent Substances 0.000 abstract description 11
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 abstract description 10
- 238000012695 Interfacial polymerization Methods 0.000 abstract description 6
- 230000033116 oxidation-reduction process Effects 0.000 abstract description 3
- 239000011259 mixed solution Substances 0.000 description 32
- 239000000178 monomer Substances 0.000 description 30
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 27
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 9
- JEGUKCSWCFPDGT-UHFFFAOYSA-N h2o hydrate Chemical compound O.O JEGUKCSWCFPDGT-UHFFFAOYSA-N 0.000 description 9
- 230000003068 static effect Effects 0.000 description 9
- 238000001035 drying Methods 0.000 description 8
- 239000000706 filtrate Substances 0.000 description 8
- 239000002245 particle Substances 0.000 description 6
- 239000008346 aqueous phase Substances 0.000 description 5
- 235000010755 mineral Nutrition 0.000 description 5
- 239000004160 Ammonium persulphate Substances 0.000 description 4
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 4
- 235000019395 ammonium persulphate Nutrition 0.000 description 4
- 150000005839 radical cations Chemical class 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- 239000007800 oxidant agent Substances 0.000 description 3
- 230000001590 oxidative effect Effects 0.000 description 3
- 238000006116 polymerization reaction Methods 0.000 description 3
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- 239000006227 byproduct Substances 0.000 description 2
- 238000010538 cationic polymerization reaction Methods 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- LCPVQAHEFVXVKT-UHFFFAOYSA-N 2-(2,4-difluorophenoxy)pyridin-3-amine Chemical compound NC1=CC=CN=C1OC1=CC=C(F)C=C1F LCPVQAHEFVXVKT-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 238000005904 alkaline hydrolysis reaction Methods 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000002322 conducting polymer Substances 0.000 description 1
- 229920001940 conductive polymer Polymers 0.000 description 1
- 229910000365 copper sulfate Inorganic materials 0.000 description 1
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 239000011790 ferrous sulphate Substances 0.000 description 1
- 235000003891 ferrous sulphate Nutrition 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 1
- 229910000359 iron(II) sulfate Inorganic materials 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000012046 mixed solvent Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- VKJKEPKFPUWCAS-UHFFFAOYSA-M potassium chlorate Chemical compound [K+].[O-]Cl(=O)=O VKJKEPKFPUWCAS-UHFFFAOYSA-M 0.000 description 1
- KMUONIBRACKNSN-UHFFFAOYSA-N potassium dichromate Chemical compound [K+].[K+].[O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O KMUONIBRACKNSN-UHFFFAOYSA-N 0.000 description 1
- 239000012286 potassium permanganate Substances 0.000 description 1
- 230000002829 reductive effect Effects 0.000 description 1
- 238000012163 sequencing technique Methods 0.000 description 1
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Substances [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Landscapes
- Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
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CN103539943B true CN103539943B (zh) | 2016-01-20 |
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CN105778085A (zh) * | 2016-03-28 | 2016-07-20 | 重庆金固特新材料科技有限公司 | 一种聚苯胺的制备方法 |
CN106633047A (zh) * | 2016-10-21 | 2017-05-10 | 南通绿业中试技术研究院有限公司 | 一种制备聚苯胺的方法 |
CN110183651B (zh) * | 2019-05-29 | 2022-03-18 | 齐鲁工业大学 | 一种聚苯胺/硫复合材料及其制备方法 |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1189510A (zh) * | 1997-01-30 | 1998-08-05 | 中国科学院长春应用化学研究所 | 超低分子量聚苯胺的制备 |
US5959072A (en) * | 1998-01-26 | 1999-09-28 | Conpoly Technology Co., Ltd. | Wastewater-recyclable process for producing a polyaniline resin powder |
CN101016660A (zh) * | 2007-03-07 | 2007-08-15 | 中南大学 | 超级电容器电极材料聚苯胺纳米纤维的制备方法 |
CN101338031A (zh) * | 2008-08-08 | 2009-01-07 | 中国科学院山西煤炭化学研究所 | 一种制备长径比大的聚苯胺纳米线的方法 |
CN102153747A (zh) * | 2011-02-17 | 2011-08-17 | 中国科学院长春应用化学研究所 | 聚苯胺中空微球的制备方法 |
CN103214670A (zh) * | 2013-03-05 | 2013-07-24 | 中国科学院长春应用化学研究所 | 水性聚苯胺中空微球及其制备方法 |
-
2013
- 2013-11-06 CN CN201310547288.XA patent/CN103539943B/zh active Active
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1189510A (zh) * | 1997-01-30 | 1998-08-05 | 中国科学院长春应用化学研究所 | 超低分子量聚苯胺的制备 |
US5959072A (en) * | 1998-01-26 | 1999-09-28 | Conpoly Technology Co., Ltd. | Wastewater-recyclable process for producing a polyaniline resin powder |
CN101016660A (zh) * | 2007-03-07 | 2007-08-15 | 中南大学 | 超级电容器电极材料聚苯胺纳米纤维的制备方法 |
CN101338031A (zh) * | 2008-08-08 | 2009-01-07 | 中国科学院山西煤炭化学研究所 | 一种制备长径比大的聚苯胺纳米线的方法 |
CN102153747A (zh) * | 2011-02-17 | 2011-08-17 | 中国科学院长春应用化学研究所 | 聚苯胺中空微球的制备方法 |
CN103214670A (zh) * | 2013-03-05 | 2013-07-24 | 中国科学院长春应用化学研究所 | 水性聚苯胺中空微球及其制备方法 |
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Address after: 130012 5218 Longhu Road, north new hi-tech, Changchun, Jilin Patentee after: Zhongke Yinghua (Changchun) Technology Co.,Ltd. Address before: 130012 5218 Longhu Road, north new hi-tech, Changchun, Jilin Patentee before: Changchun applied chemical science and Technology General Corporation of Chinese Academy of Sciences |
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Effective date of registration: 20231129 Address after: Inside the Management Committee Building of Longping High tech Park, High tech Industrial Development Zone, Changsha City, Hunan Province, 410000 yuan Patentee after: HUNAN BEN'AN YADA NEW MATERIALS CO.,LTD. Address before: 130012 5218 Longhu Road, north new hi-tech, Changchun, Jilin Patentee before: Zhongke Yinghua (Changchun) Technology Co.,Ltd. |
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