CN103525076A - 一种无卤低烟阻燃tpe电缆料 - Google Patents
一种无卤低烟阻燃tpe电缆料 Download PDFInfo
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- CN103525076A CN103525076A CN201310475726.6A CN201310475726A CN103525076A CN 103525076 A CN103525076 A CN 103525076A CN 201310475726 A CN201310475726 A CN 201310475726A CN 103525076 A CN103525076 A CN 103525076A
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- kaolin
- sodium hydroxide
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- 239000000463 material Substances 0.000 title claims abstract description 35
- 239000003063 flame retardant Substances 0.000 title abstract description 8
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title abstract description 7
- 239000000779 smoke Substances 0.000 title abstract 2
- 239000000843 powder Substances 0.000 claims abstract description 26
- 229920002725 thermoplastic elastomer Polymers 0.000 claims abstract description 14
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 12
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 12
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000002994 raw material Substances 0.000 claims abstract description 11
- 229920001577 copolymer Polymers 0.000 claims abstract description 7
- 229910052580 B4C Inorganic materials 0.000 claims abstract description 6
- 229920000049 Carbon (fiber) Polymers 0.000 claims abstract description 6
- 239000011609 ammonium molybdate Substances 0.000 claims abstract description 6
- 235000018660 ammonium molybdate Nutrition 0.000 claims abstract description 6
- APUPEJJSWDHEBO-UHFFFAOYSA-P ammonium molybdate Chemical compound [NH4+].[NH4+].[O-][Mo]([O-])(=O)=O APUPEJJSWDHEBO-UHFFFAOYSA-P 0.000 claims abstract description 6
- 229940010552 ammonium molybdate Drugs 0.000 claims abstract description 6
- INAHAJYZKVIDIZ-UHFFFAOYSA-N boron carbide Chemical compound B12B3B4C32B41 INAHAJYZKVIDIZ-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 6
- 239000006229 carbon black Substances 0.000 claims abstract description 6
- 239000004917 carbon fiber Substances 0.000 claims abstract description 6
- TVWTZAGVNBPXHU-FOCLMDBBSA-N dioctyl (e)-but-2-enedioate Chemical compound CCCCCCCCOC(=O)\C=C\C(=O)OCCCCCCCC TVWTZAGVNBPXHU-FOCLMDBBSA-N 0.000 claims abstract description 6
- 229920001971 elastomer Polymers 0.000 claims abstract description 6
- 239000000806 elastomer Substances 0.000 claims abstract description 6
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229920002635 polyurethane Polymers 0.000 claims abstract description 6
- 239000004814 polyurethane Substances 0.000 claims abstract description 6
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229910052882 wollastonite Inorganic materials 0.000 claims abstract description 6
- 239000010456 wollastonite Substances 0.000 claims abstract description 6
- 239000011787 zinc oxide Substances 0.000 claims abstract description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 30
- 239000000945 filler Substances 0.000 claims description 17
- 238000002360 preparation method Methods 0.000 claims description 13
- 239000005995 Aluminium silicate Substances 0.000 claims description 10
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 10
- 235000012211 aluminium silicate Nutrition 0.000 claims description 10
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 claims description 10
- 229910052799 carbon Inorganic materials 0.000 claims description 10
- 239000003112 inhibitor Substances 0.000 claims description 10
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 10
- 230000003647 oxidation Effects 0.000 claims description 10
- 238000007254 oxidation reaction Methods 0.000 claims description 10
- 239000004575 stone Substances 0.000 claims description 10
- IMYZYCNQZDBZBQ-SJORKVTESA-N (9S,10R)-epoxyoctadecanoic acid Chemical compound CCCCCCCC[C@H]1O[C@H]1CCCCCCCC(O)=O IMYZYCNQZDBZBQ-SJORKVTESA-N 0.000 claims description 5
- 241000143437 Aciculosporium take Species 0.000 claims description 5
- 239000004925 Acrylic resin Substances 0.000 claims description 5
- 229920000178 Acrylic resin Polymers 0.000 claims description 5
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 claims description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 5
- 244000077995 Coix lacryma jobi Species 0.000 claims description 5
- 229920002367 Polyisobutene Polymers 0.000 claims description 5
- 235000021355 Stearic acid Nutrition 0.000 claims description 5
- WHMDKBIGKVEYHS-IYEMJOQQSA-L Zinc gluconate Chemical compound [Zn+2].OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O.OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O WHMDKBIGKVEYHS-IYEMJOQQSA-L 0.000 claims description 5
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 claims description 5
- 230000032683 aging Effects 0.000 claims description 5
- 150000004645 aluminates Chemical class 0.000 claims description 5
- 229910052782 aluminium Inorganic materials 0.000 claims description 5
- PMHQVHHXPFUNSP-UHFFFAOYSA-M copper(1+);methylsulfanylmethane;bromide Chemical compound Br[Cu].CSC PMHQVHHXPFUNSP-UHFFFAOYSA-M 0.000 claims description 5
- 239000007822 coupling agent Substances 0.000 claims description 5
- 239000006185 dispersion Substances 0.000 claims description 5
- 238000005984 hydrogenation reaction Methods 0.000 claims description 5
- 239000010977 jade Substances 0.000 claims description 5
- 239000007788 liquid Substances 0.000 claims description 5
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 5
- 239000002105 nanoparticle Substances 0.000 claims description 5
- 230000007935 neutral effect Effects 0.000 claims description 5
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 5
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 5
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 5
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical compound CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 claims description 5
- 239000008117 stearic acid Substances 0.000 claims description 5
- 235000015112 vegetable and seed oil Nutrition 0.000 claims description 5
- 239000011670 zinc gluconate Substances 0.000 claims description 5
- 235000011478 zinc gluconate Nutrition 0.000 claims description 5
- 229960000306 zinc gluconate Drugs 0.000 claims description 5
- 230000001105 regulatory effect Effects 0.000 claims description 3
- 239000011347 resin Substances 0.000 abstract description 3
- 229920005989 resin Polymers 0.000 abstract description 3
- HCILJBJJZALOAL-UHFFFAOYSA-N 3-(3,5-ditert-butyl-4-hydroxyphenyl)-n'-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyl]propanehydrazide Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)NNC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 HCILJBJJZALOAL-UHFFFAOYSA-N 0.000 abstract 1
- 239000004593 Epoxy Substances 0.000 abstract 1
- 239000004743 Polypropylene Substances 0.000 abstract 1
- 229910001377 aluminum hypophosphite Inorganic materials 0.000 abstract 1
- 239000003963 antioxidant agent Substances 0.000 abstract 1
- 230000003078 antioxidant effect Effects 0.000 abstract 1
- 239000004020 conductor Substances 0.000 abstract 1
- RLRMXWDXPLINPJ-UHFFFAOYSA-N dioctan-2-yl benzene-1,2-dicarboxylate Chemical compound CCCCCCC(C)OC(=O)C1=CC=CC=C1C(=O)OC(C)CCCCCC RLRMXWDXPLINPJ-UHFFFAOYSA-N 0.000 abstract 1
- WIBFFTLQMKKBLZ-SEYXRHQNSA-N n-butyl oleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCCCC WIBFFTLQMKKBLZ-SEYXRHQNSA-N 0.000 abstract 1
- -1 polypropylene Polymers 0.000 abstract 1
- 229920001155 polypropylene Polymers 0.000 abstract 1
- 230000007613 environmental effect Effects 0.000 description 3
- 238000005453 pelletization Methods 0.000 description 3
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 2
- 229910021502 aluminium hydroxide Inorganic materials 0.000 description 2
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 2
- 239000000347 magnesium hydroxide Substances 0.000 description 2
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000008188 pellet Substances 0.000 description 2
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
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- 238000013461 design Methods 0.000 description 1
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- 230000000694 effects Effects 0.000 description 1
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- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920005672 polyolefin resin Polymers 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000003340 retarding agent Substances 0.000 description 1
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- Compositions Of Macromolecular Compounds (AREA)
- Organic Insulating Materials (AREA)
- Insulated Conductors (AREA)
Abstract
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Cited By (19)
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CN104151612A (zh) * | 2014-07-28 | 2014-11-19 | 淮南文峰航天电缆有限公司 | 一种用于航空电缆护套料的抗冲击填料及其制备方法 |
CN104788832A (zh) * | 2015-04-09 | 2015-07-22 | 安徽省赛华电缆有限公司 | 一种纳米硼纤维增强建筑用低烟无卤阻燃电缆料及其制备方法 |
CN104804315A (zh) * | 2015-04-09 | 2015-07-29 | 安徽省赛华电缆有限公司 | 一种防开裂建筑用低烟无卤阻燃电缆料及其制备方法 |
CN104804314A (zh) * | 2015-04-09 | 2015-07-29 | 安徽省赛华电缆有限公司 | 一种纳米稀土铈改性的建筑用低烟无卤阻燃电缆料及其制备方法 |
CN104804283A (zh) * | 2015-04-09 | 2015-07-29 | 安徽省赛华电缆有限公司 | 一种建筑用聚砜纳米纤维增韧低烟无卤阻燃电缆料及其制备方法 |
CN104804282A (zh) * | 2015-04-09 | 2015-07-29 | 安徽省赛华电缆有限公司 | 一种耐紫外高韧性建筑用低烟无卤阻燃电缆料及其制备方法 |
CN104893060A (zh) * | 2015-05-25 | 2015-09-09 | 力拓电力合金电缆股份有限公司 | 一种耐冲击建筑用低烟无卤阻燃电缆料及其制备方法 |
CN104910482A (zh) * | 2015-05-25 | 2015-09-16 | 力拓电力合金电缆股份有限公司 | 一种建筑用纳米粘土低烟无卤阻燃电缆料及其制备方法 |
CN104910477A (zh) * | 2015-05-25 | 2015-09-16 | 力拓电力合金电缆股份有限公司 | 一种建筑用高强度低烟无卤阻燃电缆料及其制备方法 |
CN104945748A (zh) * | 2015-05-25 | 2015-09-30 | 力拓电力合金电缆股份有限公司 | 一种建筑用高韧性低烟无卤阻燃电缆料及其制备方法 |
CN104945749A (zh) * | 2015-05-25 | 2015-09-30 | 力拓电力合金电缆股份有限公司 | 一种建筑用高绝缘性低烟无卤阻燃电缆料及其制备方法 |
CN105652397A (zh) * | 2016-01-27 | 2016-06-08 | 苏州权素船舶电子有限公司 | 一种耐磨光缆 |
CN105694669A (zh) * | 2016-02-23 | 2016-06-22 | 和县科嘉阀门铸造有限公司 | 一种阀门制造用的内壁保护涂料 |
CN106028485A (zh) * | 2016-06-14 | 2016-10-12 | 中科电力装备(安徽)智能化科技有限公司 | 一种超耐化学品性自限温伴热电缆 |
CN106046751A (zh) * | 2016-07-05 | 2016-10-26 | 安徽吉安特种线缆制造有限公司 | 一种机车用防紫外抗裂型电缆材料 |
CN108841196A (zh) * | 2018-06-12 | 2018-11-20 | 杨杰 | 一种无卤低烟阻燃tpe电缆料及制备方法 |
CN109054157A (zh) * | 2018-08-03 | 2018-12-21 | 国网安徽省电力有限公司六安供电公司 | 一种耐高温纳米电缆材料及其制备方法 |
CN109285620A (zh) * | 2017-07-20 | 2019-01-29 | 四川鸿鑫国泰电缆有限责任公司 | 无卤低烟柔性矿物质绝缘防火电缆 |
CN113881216A (zh) * | 2021-11-24 | 2022-01-04 | 国网河南省电力公司镇平县供电公司 | 耐磨阻燃改性聚氨酯电缆材料及其制备方法 |
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CN102816427A (zh) * | 2012-09-06 | 2012-12-12 | 北京化工大学 | 一种高阻燃高耐热无卤阻燃热塑性聚氨酯弹性体电缆料及其制备方法 |
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EP0275717A1 (en) * | 1986-12-31 | 1988-07-27 | Del Monte Corporation | Acidified pasta salad |
WO2002084675A1 (en) * | 2001-04-16 | 2002-10-24 | Krone, Inc. | Cable with twisting filler and shared sheath |
CN101599314A (zh) * | 2008-06-05 | 2009-12-09 | 上海斯瑞聚合体科技有限公司 | 一种环保阻燃热塑性聚氨酯弹性体电缆料 |
CN101354929A (zh) * | 2008-07-15 | 2009-01-28 | 俞飞 | 电缆、光缆用阻水阻燃带及其制造方法 |
CN101358028A (zh) * | 2008-09-02 | 2009-02-04 | 宁波一舟塑胶有限公司 | 以聚苯醚为基料的无卤阻燃热塑性弹性体电缆料及其制备方法 |
CN102816427A (zh) * | 2012-09-06 | 2012-12-12 | 北京化工大学 | 一种高阻燃高耐热无卤阻燃热塑性聚氨酯弹性体电缆料及其制备方法 |
Cited By (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104151612A (zh) * | 2014-07-28 | 2014-11-19 | 淮南文峰航天电缆有限公司 | 一种用于航空电缆护套料的抗冲击填料及其制备方法 |
CN104788832A (zh) * | 2015-04-09 | 2015-07-22 | 安徽省赛华电缆有限公司 | 一种纳米硼纤维增强建筑用低烟无卤阻燃电缆料及其制备方法 |
CN104804315A (zh) * | 2015-04-09 | 2015-07-29 | 安徽省赛华电缆有限公司 | 一种防开裂建筑用低烟无卤阻燃电缆料及其制备方法 |
CN104804314A (zh) * | 2015-04-09 | 2015-07-29 | 安徽省赛华电缆有限公司 | 一种纳米稀土铈改性的建筑用低烟无卤阻燃电缆料及其制备方法 |
CN104804283A (zh) * | 2015-04-09 | 2015-07-29 | 安徽省赛华电缆有限公司 | 一种建筑用聚砜纳米纤维增韧低烟无卤阻燃电缆料及其制备方法 |
CN104804282A (zh) * | 2015-04-09 | 2015-07-29 | 安徽省赛华电缆有限公司 | 一种耐紫外高韧性建筑用低烟无卤阻燃电缆料及其制备方法 |
CN104945749A (zh) * | 2015-05-25 | 2015-09-30 | 力拓电力合金电缆股份有限公司 | 一种建筑用高绝缘性低烟无卤阻燃电缆料及其制备方法 |
CN104910482A (zh) * | 2015-05-25 | 2015-09-16 | 力拓电力合金电缆股份有限公司 | 一种建筑用纳米粘土低烟无卤阻燃电缆料及其制备方法 |
CN104910477A (zh) * | 2015-05-25 | 2015-09-16 | 力拓电力合金电缆股份有限公司 | 一种建筑用高强度低烟无卤阻燃电缆料及其制备方法 |
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