CN103554630B - 一种电缆料 - Google Patents
一种电缆料 Download PDFInfo
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- CN103554630B CN103554630B CN201310473907.5A CN201310473907A CN103554630B CN 103554630 B CN103554630 B CN 103554630B CN 201310473907 A CN201310473907 A CN 201310473907A CN 103554630 B CN103554630 B CN 103554630B
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- 239000000463 material Substances 0.000 title claims abstract description 36
- 239000000945 filler Substances 0.000 claims abstract description 17
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims abstract description 12
- ZFOZVQLOBQUTQQ-UHFFFAOYSA-N Tributyl citrate Chemical compound CCCCOC(=O)CC(O)(C(=O)OCCCC)CC(=O)OCCCC ZFOZVQLOBQUTQQ-UHFFFAOYSA-N 0.000 claims abstract description 12
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 12
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 claims abstract description 12
- 150000004645 aluminates Chemical class 0.000 claims abstract description 11
- 239000007822 coupling agent Substances 0.000 claims abstract description 11
- 239000002994 raw material Substances 0.000 claims abstract description 11
- 230000032683 aging Effects 0.000 claims abstract description 8
- 239000005038 ethylene vinyl acetate Substances 0.000 claims abstract description 7
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 claims abstract description 7
- FRWYFWZENXDZMU-UHFFFAOYSA-N 2-iodoquinoline Chemical compound C1=CC=CC2=NC(I)=CC=C21 FRWYFWZENXDZMU-UHFFFAOYSA-N 0.000 claims abstract description 6
- SJECZPVISLOESU-UHFFFAOYSA-N 3-trimethoxysilylpropan-1-amine Chemical compound CO[Si](OC)(OC)CCCN SJECZPVISLOESU-UHFFFAOYSA-N 0.000 claims abstract description 6
- 241000276489 Merlangius merlangus Species 0.000 claims abstract description 6
- 239000004113 Sepiolite Substances 0.000 claims abstract description 6
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 claims abstract description 6
- 150000001412 amines Chemical class 0.000 claims abstract description 6
- AGXUVMPSUKZYDT-UHFFFAOYSA-L barium(2+);octadecanoate Chemical compound [Ba+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O AGXUVMPSUKZYDT-UHFFFAOYSA-L 0.000 claims abstract description 6
- LTPBRCUWZOMYOC-UHFFFAOYSA-N beryllium oxide Inorganic materials O=[Be] LTPBRCUWZOMYOC-UHFFFAOYSA-N 0.000 claims abstract description 6
- TVWTZAGVNBPXHU-FOCLMDBBSA-N dioctyl (e)-but-2-enedioate Chemical compound CCCCCCCCOC(=O)\C=C\C(=O)OCCCCCCCC TVWTZAGVNBPXHU-FOCLMDBBSA-N 0.000 claims abstract description 6
- 229920001903 high density polyethylene Polymers 0.000 claims abstract description 6
- 239000004700 high-density polyethylene Substances 0.000 claims abstract description 6
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims abstract description 6
- JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Chemical compound O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 claims abstract description 6
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229960003742 phenol Drugs 0.000 claims abstract description 6
- KCTAWXVAICEBSD-UHFFFAOYSA-N prop-2-enoyloxy prop-2-eneperoxoate Chemical compound C=CC(=O)OOOC(=O)C=C KCTAWXVAICEBSD-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229910052624 sepiolite Inorganic materials 0.000 claims abstract description 6
- 235000019355 sepiolite Nutrition 0.000 claims abstract description 6
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000011787 zinc oxide Substances 0.000 claims abstract description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 30
- 239000000843 powder Substances 0.000 claims description 20
- 239000005995 Aluminium silicate Substances 0.000 claims description 10
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 10
- 235000012211 aluminium silicate Nutrition 0.000 claims description 10
- 229910052799 carbon Inorganic materials 0.000 claims description 10
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 10
- 239000004575 stone Substances 0.000 claims description 10
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 claims description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 5
- 244000077995 Coix lacryma jobi Species 0.000 claims description 5
- 229920002367 Polyisobutene Polymers 0.000 claims description 5
- 235000021355 Stearic acid Nutrition 0.000 claims description 5
- WHMDKBIGKVEYHS-IYEMJOQQSA-L Zinc gluconate Chemical compound [Zn+2].OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O.OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O WHMDKBIGKVEYHS-IYEMJOQQSA-L 0.000 claims description 5
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 claims description 5
- PMHQVHHXPFUNSP-UHFFFAOYSA-M copper(1+);methylsulfanylmethane;bromide Chemical compound Br[Cu].CSC PMHQVHHXPFUNSP-UHFFFAOYSA-M 0.000 claims description 5
- 239000006185 dispersion Substances 0.000 claims description 5
- 239000012467 final product Substances 0.000 claims description 5
- 238000005984 hydrogenation reaction Methods 0.000 claims description 5
- 239000010977 jade Substances 0.000 claims description 5
- 239000007788 liquid Substances 0.000 claims description 5
- 238000000034 method Methods 0.000 claims description 5
- 239000002105 nanoparticle Substances 0.000 claims description 5
- 230000007935 neutral effect Effects 0.000 claims description 5
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 5
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 5
- 239000008117 stearic acid Substances 0.000 claims description 5
- 235000015112 vegetable and seed oil Nutrition 0.000 claims description 5
- 239000011670 zinc gluconate Substances 0.000 claims description 5
- 229960000306 zinc gluconate Drugs 0.000 claims description 5
- 235000011478 zinc gluconate Nutrition 0.000 claims description 5
- 241000143437 Aciculosporium take Species 0.000 claims description 4
- 239000003063 flame retardant Substances 0.000 abstract description 7
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 abstract description 6
- 238000002360 preparation method Methods 0.000 abstract description 6
- 235000019504 cigarettes Nutrition 0.000 abstract description 4
- 229920000915 polyvinyl chloride Polymers 0.000 abstract 1
- 239000004800 polyvinyl chloride Substances 0.000 abstract 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 2
- 229910021502 aluminium hydroxide Inorganic materials 0.000 description 2
- 238000007664 blowing Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 2
- 239000000347 magnesium hydroxide Substances 0.000 description 2
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 2
- 238000005453 pelletization Methods 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
- C08L23/0853—Vinylacetate
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
- H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
- H01B3/441—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from alkenes
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- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
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- C08L2203/00—Applications
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Abstract
本发明提供了一种聚氯乙烯电缆料，由下列重量份的组分原料制备而得：乙烯-醋酸乙烯酯共聚物EVA？50-60、高密度聚乙烯HDPE10-15、环氧丙烯酸酯10-12、ABS树脂5-10、相容剂5-8、3-氨丙基三甲氧基硅烷1-2、铝酸酯偶联剂DL-411？1-2、白云石4-6、海泡石4-6、氧化铍1-2、氧化锌2-3、邻苯二甲酸二丁酯6-8、柠檬酸三丁酯6-8、马来酸二辛酯3-4、油酸酰胺0.1-0.2、重钙10-12、硬脂酸钡1-2、氧化聚乙烯蜡0.1-0.3、硼酸锌10-15、三氧化钼4-6、氧化铁1-2、改性填料10-15。本发明制备方法简单，操作方便，组成原料配方合理，制得的电缆料具有耐候性好、低烟、耐老化，阻燃性能好的特点。
Description
技术领域
本发明涉及电缆料领域，具体涉及一种电缆料及其制备方法。
背景技术
电线电缆具有电力输送和信息输送的作用，在人们生活和生产中发挥着重要的作用。设计和制备低烟、阿低毒，同时又具备优异阻燃性能和绝缘性能的电缆料，成为当今阻燃研究的热点。传统的氢氧化镁与氢氧化铝类阻燃剂，虽然能赋予材料良好的阻燃性能，但是，由于大多数电缆料的基体树脂为非极性的聚烯烃类高分子，与极性的氢氧化镁、氢氧化铝的相容性较差，往往会降低材料的力学性能和加工性能。研究出既具有良好的阻燃性能、同时具有环保性能，良好的机械加工性、较好的绝缘性能的电缆料材料成为电缆料发展的方向，本发明通过添加改性填料，大大提高了材料间的相容性，提高了电缆料的机械加工性能的同时还保证了电缆料的阻燃环保型。
发明内容
本发明提供了一种电缆料及其制备方法。由本发明的电缆料加工成的电缆线具有耐候性好、低烟、耐老化，阻燃性能好。
本发明采用的技术方案为：
一种电缆料,其特征在于,由下列重量份的组分原料制备而得：乙烯-醋酸乙烯酯共聚物EVA50-60、高密度聚乙烯HDPE10-15、环氧丙烯酸酯10-12、ABS树脂5-10、相容剂5-8、3-氨丙基三甲氧基硅烷1-2、铝酸酯偶联剂DL-4111-2、白云石4-6、海泡石4-6、氧化铍1-2、氧化锌2-3、邻苯二甲酸二丁酯6-8、柠檬酸三丁酯6-8、马来酸二辛酯3-4、油酸酰胺0.1-0.2、重钙10-12、硬脂酸钡1-2、氧化聚乙烯蜡0.1-0.3、硼酸锌10-15、三氧化钼4-6、氧化铁1-2、改性填料10-15，
所述改性填料是通过下列方法制备而得：a.取下列重量份的原料：高岭土180-190、麦饭石30-34、纳米碳1-2、抗坏血酸1-2、薏仁油1-2、氮化铝粉1-2、葡萄糖酸锌2-3、玉石粉2-3、聚异丁烯2-3、铝酸酯偶联剂DL-4111-2、硬脂酸2-3、抗氧剂10101-2；
b、将高岭土、麦饭石在450-480℃下煅烧5-6h，冷却至室温，取出后，加入3-4％的氢氧化钠溶液中研磨1-2小时，然后，加入12-15％的盐酸溶液，调节PH值为4-5，陈化10-15小时，再加氢氧化钠溶液调节研磨液pH为中性，过滤，烘干得到填料粉末；
c、将上述所得粉末与其它剩余成分混合，并以8000-10000转/分的高速分散均匀，即得。
所述的电缆料,其特征在于，由下列重量份的组分原料制备而得：乙烯-醋酸乙烯酯共聚物EVA55、高密度聚乙烯HDPE14、环氧丙烯酸酯11、ABS树脂6、相容剂7、3-氨丙基三甲氧基硅烷1、铝酸酯偶联剂DL-4112、白云石5、海泡石4、氧化铍1、氧化锌2、邻苯二甲酸二丁酯7、柠檬酸三丁酯8、马来酸二辛酯4、油酸酰胺0.2、重钙11、硬脂酸钡1、氧化聚乙烯蜡0.2、硼酸锌13、三氧化钼5、氧化铁1、改性填料13，
所述改性填料是通过下列方法制备而得：a.取下列重量份的原料：高岭土184、麦饭石31、纳米碳2、抗坏血酸1、薏仁油2、氮化铝粉1、葡萄糖酸锌3、玉石粉2、聚异丁烯2、铝酸酯偶联剂DL-4112、硬脂酸2、抗氧剂10101；
b、将高岭土、麦饭石在450-480℃下煅烧5-6h，冷却至室温，取出后，加入3-4％的氢氧化钠溶液中研磨1-2小时，然后，加入12-15％的盐酸溶液，调节PH值为4-5，陈化10-15小时，再加氢氧化钠溶液调节研磨液pH为中性，过滤，烘干得到填料粉末；
c、将上述所得粉末与其它剩余成分混合，并以8000-10000转/分的高速分散均匀，即得。
本发明的电缆料的制备方法：
按配方比例称取各组成原料，将组成原料投入高速搅拌机混合3-5miu,放料，将混合好的物料投入到双螺杆挤出机里，挤出造粒，再进入热风干燥机中进行干燥后，即得电缆料，挤出时双螺杆挤出机温度设置为：加料段115℃，熔融段185℃，熔体输送段185～195℃，混炼段195℃，均化段195℃，机头计量段185℃。
有益效果
本发明制备方法简单,操作方便,组成原料配方合理,制得的电缆料具有耐候性好、低烟、耐老化，阻燃性能好的特点。
具体实施方式
一种电缆料，由下列重量(kg)的组分原料制备而得：
乙烯-醋酸乙烯酯共聚物EVA55、高密度聚乙烯HDPE14、环氧丙烯酸酯11、ABS树脂6、相容剂7、3-氨丙基三甲氧基硅烷1、铝酸酯偶联剂DL-4112、白云石5、海泡石4、氧化铍1、氧化锌2、邻苯二甲酸二丁酯7、柠檬酸三丁酯8、马来酸二辛酯4、油酸酰胺0.2、重钙11、硬脂酸钡1、氧化聚乙烯蜡0.2、硼酸锌13、三氧化钼5、氧化铁1、改性填料13，
其中，改性填料是通过下列方法制备而得：
a.取下列重量份的原料：高岭土184、麦饭石31、纳米碳2、抗坏血酸1、薏仁油2、氮化铝粉1、葡萄糖酸锌3、玉石粉2、聚异丁烯2、铝酸酯偶联剂DL-4112、硬脂酸2、抗氧剂10101；
b、将高岭土、麦饭石在450-480℃下煅烧5-6h，冷却至室温，取出后，加入3-4％的氢氧化钠溶液中研磨1-2小时，然后，加入12-15％的盐酸溶液，调节PH值为4-5，陈化10-15小时，再加氢氧化钠溶液调节研磨液pH为中性，过滤，烘干得到填料粉末；
c、将上述所得粉末与其它剩余成分混合，并以8000-10000转/分的高速分散均匀，即得。
电缆料的制备方法：
按配方比例称取各组成原料，将组成原料投入高速搅拌机混合3-5miu,放料，将混合好的物料投入到双螺杆挤出机里，挤出造粒，再进入热风干燥机中进行干燥后，即得电缆料，挤出时双螺杆挤出机温度设置为：加料段115℃，熔融段185℃，熔体输送段185～195℃，混炼段195℃，均化段195℃，机头计量段185℃。
本实施例制得的电缆料的性能测试结果如下表：
Claims (2)
1.一种电缆料，其特征在于,由下列重量份的组分原料制备而得：乙烯-醋酸乙烯酯共聚物EVA50-60、高密度聚乙烯HDPE10-15、环氧丙烯酸酯10-12、ABS树脂5-10、相容剂5-8、3-氨丙基三甲氧基硅烷1-2、铝酸酯偶联剂DL-4111-2、白云石4-6、海泡石4-6、氧化铍1-2、氧化锌2-3、邻苯二甲酸二丁酯6-8、柠檬酸三丁酯6-8、马来酸二辛酯3-4、油酸酰胺0.1-0.2、重钙10-12、硬脂酸钡1-2、氧化聚乙烯蜡0.1-0.3、硼酸锌10-15、三氧化钼4-6、氧化铁1-2、改性填料10-15，所述改性填料是通过下列方法制备而得：a.取下列重量份的原料：高岭土180-190、麦饭石30-34、纳米碳1-2、抗坏血酸1-2、薏仁油1-2、氮化铝粉1-2、葡萄糖酸锌2-3、玉石粉2-3、聚异丁烯2-3、铝酸酯偶联剂DL-4111-2、硬脂酸2-3、抗氧剂10101-2；b、将高岭土、麦饭石在450-480℃下煅烧5-6h，冷却至室温，取出后，加入3-4%的氢氧化钠溶液中研磨1-2小时，然后，加入12-15%的盐酸溶液，调节pH值为4-5，陈化10-15小时，再加氢氧化钠溶液调节研磨液pH为中性，过滤，烘干得到填料粉末；c、将上述所得粉末与其它剩余成分混合，并以8000-10000转/分的高速分散均匀，即得。
2.根据权利要求1所述的电缆料，其特征在于，由下列重量份的组分原料制备而得：乙烯-醋酸乙烯酯共聚物EVA55、高密度聚乙烯HDPE14、环氧丙烯酸酯11、ABS树脂6、相容剂7、3-氨丙基三甲氧基硅烷1、铝酸酯偶联剂DL-4112、白云石5、海泡石4、氧化铍1、氧化锌2、邻苯二甲酸二丁酯7、柠檬酸三丁酯8、马来酸二辛酯4、油酸酰胺0.2、重钙11、硬脂酸钡1、氧化聚乙烯蜡0.2、硼酸锌13、三氧化钼5、氧化铁1、改性填料13，所述改性填料是通过下列方法制备而得：a.取下列重量份的原料：高岭土184、麦饭石31、纳米碳2、抗坏血酸1、薏仁油2、氮化铝粉1、葡萄糖酸锌3、玉石粉2、聚异丁烯2、铝酸酯偶联剂DL-4112、硬脂酸2、抗氧剂10101；b、将高岭土、麦饭石在450-480℃下煅烧5-6h，冷却至室温，取出后，加入3-4%的氢氧化钠溶液中研磨1-2小时，然后，加入12-15%的盐酸溶液，调节pH值为4-5，陈化10-15小时，再加氢氧化钠溶液调节研磨液pH为中性，过滤，烘干得到填料粉末；c、将上述所得粉末与其它剩余成分混合，并以8000-10000转/分的高速分散均匀，即得。
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