CN103478151A - Pesticide composition containing spirotetramat - Google Patents
Pesticide composition containing spirotetramat Download PDFInfo
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- CN103478151A CN103478151A CN201310422203.5A CN201310422203A CN103478151A CN 103478151 A CN103478151 A CN 103478151A CN 201310422203 A CN201310422203 A CN 201310422203A CN 103478151 A CN103478151 A CN 103478151A
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Abstract
The invention discloses a pesticide composite containing spirotetramat and belongs to the technical field of pest chemical prevention. The pesticide composite comprises active ingredients, namely A spirotetramat and B dinotefuran, wherein the weight ratio of A and B is 1:20-20:1. Besides the active ingredients, the pesticide composite further comprises auxiliaries and packing. The active ingredients, namely A and B occupy 15%-50% of the total weight of pesticides, the auxiliaries occupy 20%-30% of the total weight of the pesticides, and the rest is the packing. The pesticide composite can be prepared into wettable powder, suspending agents and the like. The pesticide composition containing the spirotetramat has good prevention effects on rice planthoppers, aphids, vegetable bemisia tabaci and the like. Compared with a conventional agent for preventing the rice planthoppers, the pesticide composite can reduce a dosage, reduce environmental pollution and residues of agricultural products, can delay drug resistance on a single pesticide of the rice planthoppers, and has the advantage of a long lasting period. Compared with the single pesticide, the pesticide composite can reduce cost.
Description
Technical field
The invention belongs to the Chemical Control of Harmful Insects technical field, relate to a kind of insecticides that contains spiral shell worm ethyl ester.
Background technology
Rice fulgorid is one of rice growing season primary pest, and reproduction speed is fast, causing harm property is large, and the lighter causes Rice Heading undesired, thousand kernel weight alleviates, when serious, complete stool is withered, causes the significantly underproduction of paddy rice, but also can cause stripe virus disease, black streak dwarf by transmitted virus.For a long time, the control of rice fulgorid mainly relies on Imidacloprid, Buprofezin, organic phosphor and built agent thereof, wherein high malicious organophosphorous pesticide bans use of, due to long-term single continuous use, brown planthopper, small brown rice planthopper have produced obvious pesticide resistance to Imidacloprid, control efficiency sharply descends, and Buprofezin starts to descend to the preventive effect of rice fulgorid, to paddy rice, produces and brings serious loss.In recent years, control rice fulgorid agricultural chemicals newly developed (as pymetrozine) appearance, continuous, unreasonable use on a large scale in production, certainly will affect the control effect of rice fulgorid, accelerate the drug-fast generation of rice fulgorid, therefore, research and develop the Recompounded pesticide kind of high-efficiency prevention and control brown planthopper, small brown rice planthopper, delay the pesticide resistance of insect.
Spiral shell worm ethyl ester (spirotetramat) is the tetronic acid compounds, and spiral shell worm ethyl ester has unique function Characteristics, is one of modern insecticide had so far two-way interior suction conductive performance.This compound can upwards move down in whole plant corpus, arrives at blade face and bark, thereby control reaches the corticole insect of fruit as on romaine lettuce and Chinese cabbage internal lobe.The interior absorption of this uniqueness can be protected newborn stem, leaf and root, prevents ovum and the larval growth of insect.Its another characteristics are that the lasting period is long, and the effective control that reaches 8 weeks can be provided.
Nitenpyram is a kind of anabasine insecticide, has unique chemistry and biological property.For crops such as paddy rice, vegetables, various aphids, aleyrodid, rice-leaf hopper and thrips have been shown to remarkable activity, there is efficient, low toxicity, interior suction and without the large advantage of cross resistance four, and insecticidal spectrum is wider, the lasting period is longer, use safety.
At present, spiral shell worm ethyl ester, Nitenpyram separately higher for the cost of effectively controlling rice fulgorid, easily develop immunity to drugs, utilize the insecticide of different mechanism to carry out composite, be the main method of administering resistant insect.
Summary of the invention
Technical problem to be solved by this invention is to provide the insecticides that contains spiral shell worm ethyl ester that a kind of control efficiency is prevented and treated rice fulgorid preferably.
The insecticides that contains spiral shell worm ethyl ester of the present invention, its active ingredient: A is that spiral shell worm ethyl ester, B are Nitenpyram, wherein the weight ratio of effective constituents A and B is 1:20-20:1.
The insecticides that contains spiral shell worm ethyl ester of the present invention, except active ingredient, also include auxiliary agent and carrier, and wherein effective constituents A and B account for the 15%-50% of insecticidal total weight, and auxiliary agent accounts for the 10%-30% of insecticidal total weight, and all the other are carrier.
The insecticides that contains spiral shell worm ethyl ester of the present invention can be prepared into the formulations such as wetting powder or suspending agent.
The wetting powder of the insecticides that the present invention contains spiral shell worm ethyl ester, wherein effective constituents A and B account for the 15%-50% of insecticidal total weight, also include auxiliary agent and carrier in its composition; Described auxiliary agent and the weight ratio that respectively accounts for preparation thereof are wetting agent 3-20%, dispersant 3-20%, adsorbent 2-20%; Surplus is carrier.
The wetting powder of the above-mentioned insecticides that contains spiral shell worm ethyl ester, preferred wherein effective constituents A and B account for the 15%-21% of insecticidal total weight, also include auxiliary agent and carrier in its composition; Described auxiliary agent and the weight ratio that respectively accounts for preparation thereof are wetting agent 2%, dispersant 3%, adsorbent 2-10%; Surplus is carrier.
Wetting agent described in above-mentioned wetting powder is one or more in spaonin powder, sodium lignin sulfonate, neopelex;
Described dispersant is sodium metnylene bis-naphthalene sulfonate (being called for short NNO);
Described adsorbent is white carbon;
Described carrier is one or more in kaolin, attapulgite.
The suspending agent of the insecticides that the present invention contains spiral shell worm ethyl ester, wherein effective constituents A and B account for the 15%-50% of insecticidal total weight, also include auxiliary agent and water in its composition; Described auxiliary agent and the weight ratio that respectively accounts for preparation thereof are dispersant 2-30%, thickener 0.5-20%, stabilizing agent 0.01-20%, defoamer 1-5%, bleeding agent 1-5%, antifreezing agent 0.1-15%, appropriate pH adjusting agent, and the surplus water supplies 100%.
The suspending agent of the above-mentioned insecticides that contains spiral shell worm ethyl ester, preferably by weight wherein effective constituents A and B be 15-16%, also include auxiliary agent and water in its composition; Described auxiliary agent and the weight ratio that respectively accounts for preparation thereof are dispersant 10%, thickener 1%, stabilizing agent 2%, defoamer 1%, bleeding agent 1-2%, antifreezing agent 12%, and pH adjusting agent is appropriate, and the surplus water supplies 100%.
Wherein said dispersant is selected from sodium lignin sulfonate, the lignin sodium iodate, lauryl alcohol polyethylene glycol oxide base ether sodium sulfate, Fluhyzon formaldehyde condensation products sodium sulfonate, neopelex, lauryl sodium sulfate, potassium oleate, enuatrol, alkyl polyoxyethylene ether sulfonate, alkylphenol-polyethenoxy base ether formaldehyde condensation products, alkylphenol-polyethenoxy base ether, Nonyl pheno base ether, polyoxyethylene polyoxypropylene base ether block copolymers, pull open powder, poly-second carboxylic esters sodium salt, one or more in alkylpolyoxyethylene phosphate or Fluhyzon first condensate sulfonates.
Wherein said thickener is selected from one or more in xanthans, CMC, hydroxyethylcellulose, methylcellulose or polyvinyl alcohol.
Wherein said stabilizing agent is selected from one or more in catechol, butyl glycidyl ether, phenyl glycidyl ether, cresyl glycidyl ether, polyethylene glycol diglycidyl ether, chloropropylene oxide, sodium sorbate, Sodium Benzoate, epoxidised soybean oil, linseed oil, quinhydrones, anthraquinone, eugenol, citric acid, hydroxy benzoate or nipasol.
Wherein said defoamer is chosen one or more in silicone oil, silicone compound, C10-20 saturated fat acid compounds, C8-10 fat alcohol compound or II-ethylhexanol; Wherein silicone compound as organosilicon etc., as described in C10-20 saturated fat acid compounds as hendecanoic acid, tridecanoic acid, pentadecanoic acid etc., the C8-10 fat alcohol compound is as certain herbaceous plants with big flowers alcohol, ten alkanoic acids etc.
Wherein said antifreezing agent is selected from one or more in ethylene glycol, glycerine, propane diols, polyethylene glycol, sorbierite or urea.
Wherein said pH adjusting agent is selected from hydrogen-oxygen for one or more in sodium, ammoniacal liquor, acetic acid, citric acid or phosphoric acid; The consumption of pH adjusting agent is that to make the pH value of suspending agent be 5～9.
Wherein said bleeding agent is organosilicon, be selected from trisiloxanes, tetrasiloxane, many siloxanes one or more.
A kind of preparation method who contains spiral shell worm ethyl ester insecticides suspending agent for preparing, spiral shell worm ethyl ester, Nitenpyram are mixed in above-mentioned ratio with dispersant, thickener, stabilizing agent, defoamer, antifreezing agent, bleeding agent, pH adjusting agent and water, in ball mill, ball milling is 2～3 hours, makes particle diameter all below the 5 μ m.
Composite insecticide of the present invention is compared with conventional control rice fulgorid medicament, has the following advantages: 1, with single dose, compare said composition rice fulgorid is had to obvious synergistic effect, can significantly improve control efficiency; 2, reduce dosage, reduce the residual of environmental pollution and agricultural product; 3, can delay the pesticide resistance of rice fulgorid to single insecticide, 4, have advantages of that the lasting period is long, with single medicament, compare, can reduce costs.
Embodiment
Following examples are preferred condition, but active component of the present invention and proportioning, auxiliary element etc. are not limited to following examples, and in embodiment, all ratio by weight.
embodiment 1:
Prepare 15% Nitenpyram spiral shell worm ethyl ester wetting powder, each composition weight proportion and the percentage respectively accounted for are:
Nitenpyram (active ingredient) 5g (5%)
Spiral shell worm ethyl ester (active ingredient) 10g (10%)
Neopelex 2g (2%)
Sodium metnylene bis-naphthalene sulfonate (NNO) 3g (3%)
White carbon 5g (5%)
Sodium lignin sulfonate 5g (5%)
Kaolin is supplied 100g
embodiment 2:
Prepare 15% Nitenpyram spiral shell worm ethyl ester suspending agent, each composition weight proportion and the percentage respectively accounted for are:
Nitenpyram (active ingredient) 10g (10%)
Spiral shell worm ethyl ester (active ingredient) 5g (5%)
Sodium lignin sulfonate 10g (10%)
Ethylene glycol 12g (12%)
Xanthans 1g (1%)
Catechol 2 g (2%)
Silicone oil 1g (1%)
Organosilicon 1g (1%)
Water is supplied 100g
embodiment 3:
Prepare 15% Nitenpyram spiral shell worm ethyl ester suspending agent, each composition weight proportion and the percentage respectively accounted for are:
Nitenpyram (active ingredient) 10g (10%)
Spiral shell worm ethyl ester (active ingredient) 5g (5%)
Sodium lignin sulfonate 10g (10%)
Ethylene glycol 12g (12%)
Xanthans 1g (1%)
Catechol 2 g (2%)
Silicone oil 1g (1%)
Organosilicon 2g (2%)
Water is supplied 100g
embodiment 4:
Prepare 16% Nitenpyram spiral shell worm ethyl ester wetting powder, each composition weight proportion and the percentage respectively accounted for are:
Nitenpyram (active ingredient) 8g (8%)
Spiral shell worm ethyl ester (active ingredient) 8g (8%)
Neopelex 2g (2%)
NNO 3g （3%）
White carbon 5g (3%)
Sodium lignin sulfonate 5g (5%)
Kaolin is supplied 100 g
embodiment 5:
Prepare 21% Nitenpyram spiral shell worm ethyl ester wetting powder, each composition weight proportion and the percentage respectively accounted for are:
Nitenpyram (active ingredient) 20g (20%)
Spiral shell worm ethyl ester (active ingredient) 1g (1%)
Neopelex 2g (2%)
NNO 3g （3%）
White carbon 10g (10%)
Sodium lignin sulfonate 10g (5%)
Kaolin is supplied 100 g
embodiment 6:
Prepare 21% Nitenpyram spiral shell worm ethyl ester wetting powder, each composition weight proportion and the percentage respectively accounted for are:
Nitenpyram (active ingredient) 1g (1%)
Spiral shell worm ethyl ester (active ingredient) 20g (20%)
Neopelex 2g (2%)
Sodium metnylene bis-naphthalene sulfonate (NNO) 3g (3%)
White carbon 2g (2%)
Sodium lignin sulfonate 5g (5%)
Kaolin is supplied 100 g
embodiment 7:
Prepare 16% Nitenpyram spiral shell worm ethyl ester suspending agent, each composition weight proportion and the percentage respectively accounted for are:
Nitenpyram (active ingredient) 15g (15%)
Spiral shell worm ethyl ester (active ingredient) 1g (1%)
Sodium lignin sulfonate 10g (10%)
Ethylene glycol 12g (12%)
Xanthans 1g (1%)
Catechol 2 g (2%)
Silicone oil 1g (1%)
Organosilicon 2g (2%)
Water is supplied 100 g
embodiment 8:
Prepare 17% Nitenpyram spiral shell worm ethyl ester suspending agent, each composition weight proportion and the percentage respectively accounted for are:
Nitenpyram (active ingredient) 16g (16%)
Spiral shell worm ethyl ester (active ingredient) 1g (1%)
Sodium lignin sulfonate 10g (10%)
Ethylene glycol 12g (12%)
Xanthans 1g (1%)
Catechol 2 g (2%)
Silicone oil 1g (1%)
Organosilicon 1g (1%)
Water is supplied 100 g
effect experiment one:
Effect to embodiment tri-control white-backed planthoppers is carried out field control effectiveness test (in Table 1), test is processed: 15% Nitenpyram spiral shell worm ethyl ester suspending agent (embodiment tri-) mu consumption 10 grams, 25% Nitenpyram WP mu consumption 4 grams, 20% spiral shell worm ethyl ester wetting powder mu consumption 7 grams, in late July white-backed planthopper nymph peak period dispenser, 50 kilograms of every mu of water consumptions, even spraying, 150 square metres of every processing.Result of the test shows, after medicine 1 day, the control efficiency of 15% Nitenpyram spiral shell worm ethyl ester suspending agent mu consumption 10 grams all extremely significantly is better than the control efficiency of 20% spiral shell worm ethyl ester SC mu consumption 7 grams, with the control efficiency there was no significant difference of 25% Nitenpyram WP mu consumption 4 grams; After medicine 3 days, the control efficiency of 15% Nitenpyram spiral shell worm ethyl ester suspending agent mu consumption 10 grams all extremely significantly is better than, the control efficiency of 25% Nitenpyram WP mu consumption 4 grams and 20% spiral shell worm ethyl ester SC mu consumption 7 grams, after medicine 7 days, the control efficiency of 15% Nitenpyram spiral shell worm ethyl ester suspending agent mu consumption 10 grams reaches 97.15%, extremely significantly is better than, the control efficiency of 25% Nitenpyram WP mu consumption 4 grams, 20% spiral shell worm ethyl ester WG mu consumption 7 grams.
the control efficiency of table 1 15% Nitenpyram spiral shell worm ethyl ester suspending agent Whitebacked Planthopper
effect experiment two:
Effect to embodiment tetra-control brown planthopper adults is carried out field control effectiveness test (in Table 2), supply the reagent kind: 16% Nitenpyram spiral shell worm ethyl ester wetting powder mu consumption 8 grams, 10 grams, 12 grams, 25% Nitenpyram WP mu consumption 4 grams, 24% spiral shell worm ethyl ester SC mu consumption 7 grams, in early September brown planthopper nymph peak period dispenser, 50 kilograms of every mu of water consumptions, even spraying, 20 square metres of every processing, triplicate.The field investigation result shows, after medicine 3 days, the control efficiency of 16% Nitenpyram spiral shell worm ethyl ester wetting powder mu consumption 8 grams, 10 grams, 12 grams is respectively 84.56%, 94.34%, 97.22%, control effect and 16% Nitenpyram spiral shell worm ethyl ester wetting powder mu consumption 8 grams, 10 grams and the 25% Nitenpyram WP mu consumption 4 gram there was no significant differences of 16% Nitenpyram spiral shell worm ethyl ester wetting powder mu consumption 12 grams to brown planthopper wherein, significantly be better than the control efficiency of 24% spiral shell worm ethyl ester SC mu consumption 7 grams; 7-21 days 16% Nitenpyram spiral shell worm ethyl ester wetting powder mu consumption 8 grams after medicine, 10 grams, 12 grams all more than 90%, significantly are better than contrasting medicament 25% Nitenpyram WP mu consumption 4 grams, the 24% spiral shell worm ethyl ester SC control effect to brown planthopper to the control effect of brown planthopper.
the control efficiency of table 2 16 % Nitenpyram spiral shell worm ethyl ester wetting powders to brown planthopper
Claims (9)
1. the insecticides that contains spiral shell worm ethyl ester, is characterized in that its active ingredient: A is that spiral shell worm ethyl ester, B are Nitenpyram, and wherein the weight ratio of effective constituents A and B is 1:20-20:1.
2. the insecticides that contains spiral shell worm ethyl ester according to claim 1, is characterized in that also including auxiliary agent and carrier, and wherein effective constituents A and B account for the 15%-50% of insecticidal total weight, and auxiliary agent accounts for the 10%-30% of insecticidal total weight, and all the other are carrier.
3. the insecticides that contains spiral shell worm ethyl ester according to claim 1, is characterized in that, for wetting powder, wherein effective constituents A and B account for the 15%-50% of insecticidal total weight, also includes auxiliary agent and carrier in its composition; Described auxiliary agent and the weight ratio that respectively accounts for preparation thereof are wetting agent 3-20%, dispersant 3-20%, adsorbent 2-20%; Surplus is carrier.
4. the insecticides that contains spiral shell worm ethyl ester according to claim 3, is characterized in that wherein effective constituents A and B account for the 15%-21% of insecticidal total weight, also include auxiliary agent and carrier in its composition; Described auxiliary agent and the weight ratio that respectively accounts for preparation thereof are wetting agent 2%, dispersant 3%, adsorbent 2-10%; Surplus is carrier.
5. according to the described insecticides that contains spiral shell worm ethyl ester of claim 3 or 4, it is characterized in that the wetting agent of wetting powder wherein is one or more in spaonin powder, sodium lignin sulfonate, neopelex; Described dispersant is sodium metnylene bis-naphthalene sulfonate; Described adsorbent is white carbon; Described carrier is one or more in kaolin, attapulgite.
6. the insecticides that contains spiral shell worm ethyl ester according to claim 1, it is characterized in that suspending agent wherein wherein effective constituents A and B account for the 15%-50% of insecticidal total weight, also include auxiliary agent and water in its composition; Described auxiliary agent and the weight ratio that respectively accounts for preparation thereof are dispersant 2-30%, thickener 0.5-20%, stabilizing agent 0.01-20%, defoamer 1-5%, bleeding agent 1-5%, antifreezing agent 0.1-15%, appropriate pH adjusting agent, and the surplus water supplies 100%.
7. the insecticides that contains spiral shell worm ethyl ester according to claim 6, is characterized in that wherein effective constituents A and B are 15-16%, also includes auxiliary agent and water in its composition; Described auxiliary agent and the weight ratio that respectively accounts for preparation thereof are dispersant 10%, thickener 1%, stabilizing agent 2%, defoamer 1%, bleeding agent 1-2%, antifreezing agent 12%, and pH adjusting agent is appropriate, and the surplus water supplies 100%.
8. according to the described insecticides that contains spiral shell worm ethyl ester of claim 6 or 7, it is characterized in that wherein said dispersant is selected from sodium lignin sulfonate, the lignin sodium iodate, lauryl alcohol polyethylene glycol oxide base ether sodium sulfate, Fluhyzon formaldehyde condensation products sodium sulfonate, neopelex, lauryl sodium sulfate, potassium oleate, enuatrol, alkyl polyoxyethylene ether sulfonate, alkylphenol-polyethenoxy base ether formaldehyde condensation products, alkylphenol-polyethenoxy base ether, Nonyl pheno base ether, polyoxyethylene polyoxypropylene base ether block copolymers, pull open powder, poly-second carboxylic esters sodium salt, one or more in alkylpolyoxyethylene phosphate or Fluhyzon first condensate sulfonates,
Wherein said thickener is selected from one or more in xanthans, CMC, hydroxyethylcellulose, methylcellulose or polyvinyl alcohol;
Wherein said stabilizing agent is selected from one or more in catechol, butyl glycidyl ether, phenyl glycidyl ether, cresyl glycidyl ether, polyethylene glycol diglycidyl ether, chloropropylene oxide, sodium sorbate, Sodium Benzoate, epoxidised soybean oil, linseed oil, quinhydrones, anthraquinone, eugenol, citric acid, hydroxy benzoate or nipasol;
Wherein said defoamer is chosen one or more in silicone oil, silicone compound, C10-20 saturated fat acid compounds, C8-10 fat alcohol compound or II-ethylhexanol; Wherein silicone compound as organosilicon etc., as described in C10-20 saturated fat acid compounds as hendecanoic acid, tridecanoic acid, pentadecanoic acid etc., the C8-10 fat alcohol compound is as certain herbaceous plants with big flowers alcohol, ten alkanoic acids;
Wherein said antifreezing agent is selected from one or more in ethylene glycol, glycerine, propane diols, polyethylene glycol, sorbierite or urea;
Wherein said pH adjusting agent is selected from hydrogen-oxygen for one or more in sodium, ammoniacal liquor, acetic acid, citric acid or phosphoric acid; The consumption of pH adjusting agent is that to make the pH value of suspending agent be 5～9;
Wherein said bleeding agent is organosilicon, be selected from trisiloxanes, tetrasiloxane, many siloxanes one or more.
9. the insecticides that contains spiral shell worm ethyl ester claimed in claim 6, the preparation method who it is characterized in that suspending agent is as follows, spiral shell worm ethyl ester, Nitenpyram are mixed in above-mentioned ratio with dispersant, thickener, stabilizing agent, defoamer, antifreezing agent, bleeding agent, pH adjusting agent and water, in ball mill, ball milling is 2～3 hours, makes particle diameter all below the 5 μ m.
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN106797944A (en) * | 2017-01-17 | 2017-06-06 | 广州京正生物科技有限公司 | Insecticidal composition and preparation thereof |
| CN106818798A (en) * | 2016-12-15 | 2017-06-13 | 天津联合益农科技有限公司 | A kind of compounded pesticides containing anabasine compound |
| CN107736381A (en) * | 2017-11-24 | 2018-02-27 | 江苏省农业科学院 | A kind of microorganism for being used to prevent and treat sucking insect and chemical insecticide compounded combination |
| WO2020208098A1 (en) * | 2019-04-10 | 2020-10-15 | Syngenta Crop Protection Ag | Pesticidal compositions |
| CN114946871A (en) * | 2021-08-10 | 2022-08-30 | 佛山市盈辉作物科学有限公司 | Pesticide composition and application thereof |
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| CN102484995A (en) * | 2010-12-01 | 2012-06-06 | 联保作物科技有限公司 | Insecticidal composition and preparation thereof |
| JP2013133307A (en) * | 2011-12-27 | 2013-07-08 | Sumitomo Chemical Co Ltd | Arthropod pest controlling composition and method for controlling arthropod pest |
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| CN101637159A (en) * | 2009-09-08 | 2010-02-03 | 深圳诺普信农化股份有限公司 | Pesticide composition with synergistic action |
| CN102484995A (en) * | 2010-12-01 | 2012-06-06 | 联保作物科技有限公司 | Insecticidal composition and preparation thereof |
| JP2013133307A (en) * | 2011-12-27 | 2013-07-08 | Sumitomo Chemical Co Ltd | Arthropod pest controlling composition and method for controlling arthropod pest |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN106818798A (en) * | 2016-12-15 | 2017-06-13 | 天津联合益农科技有限公司 | A kind of compounded pesticides containing anabasine compound |
| CN106797944A (en) * | 2017-01-17 | 2017-06-06 | 广州京正生物科技有限公司 | Insecticidal composition and preparation thereof |
| CN107736381A (en) * | 2017-11-24 | 2018-02-27 | 江苏省农业科学院 | A kind of microorganism for being used to prevent and treat sucking insect and chemical insecticide compounded combination |
| WO2020208098A1 (en) * | 2019-04-10 | 2020-10-15 | Syngenta Crop Protection Ag | Pesticidal compositions |
| CN113660861A (en) * | 2019-04-10 | 2021-11-16 | 先正达农作物保护股份公司 | Pesticidal composition |
| CN114946871A (en) * | 2021-08-10 | 2022-08-30 | 佛山市盈辉作物科学有限公司 | Pesticide composition and application thereof |
| CN114946871B (en) * | 2021-08-10 | 2023-09-15 | 佛山市盈辉作物科学有限公司 | Pesticide composition and application thereof |
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Application publication date: 20140101 |