CN102696665A - Insecticide combination containing indoxacarb - Google Patents
Insecticide combination containing indoxacarb Download PDFInfo
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- CN102696665A CN102696665A CN2012101484953A CN201210148495A CN102696665A CN 102696665 A CN102696665 A CN 102696665A CN 2012101484953 A CN2012101484953 A CN 2012101484953A CN 201210148495 A CN201210148495 A CN 201210148495A CN 102696665 A CN102696665 A CN 102696665A
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- agent
- insecticide
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- worm prestige
- indenes worm
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Abstract
The invention discloses an insecticide combination containing indoxacarb and belongs to the technical field of chemical prevention of pests. An active ingredient A of the insecticide combination is indoxacarb, an active ingredient B of the insecticide combination is silafluofen, and the weight ratio between the ingredient A and the ingredient B is (1:20)-(20:1). Besides the active ingredients, the insecticide combination further comprises an additive and fillers, the active ingredient A and B account for 15%-50% of the total weight of the insecticide, the additive accounts for 20%-30% of the total weight of the insecticide, and the balance is the fillers. The insecticide combination can be made into wettable powder, a suspending agent and the like. The insecticide combination has good control effect on rice plant hopper, aphid, vegetable bemisia tabaci, cnaphalocrocis medinalis and stem borer and the like. Compared with a conventional control insecticide, the insecticide combination can be reduced in dosage, reduces environmental pollution and agricultural product residues, can delay insecticide resistance of a single insecticide, has the advantage of being long in lasting time, and can reduce cost in comparison with the single insecticide.
Description
Technical field
The invention belongs to insect chemical control technical field, relate to a kind of insecticides that contains indenes worm prestige.
Background technology
The kind of rice grub is a lot; " two move " insect (rice fulgorid, leaf-roller) is the Rice Production important pests, and rice fulgorid (brown planthopper, small brown rice planthopper, white-backed planthopper) is the rice grub that a kind of migrate very capable (except the small brown rice planthopper), reproduction speed are exceedingly fast, and the paddy rice of causing harm causes rice clump base portion pitchy; It is undesired to ear; Thousand kernel weight alleviates, and complete stool is withered when serious, causes the paddy rice underproduction significantly; But also can cause stripe virus disease, black streak dwarf by transmitted virus, be one of paddy rice primary pest.For a long time; The control of rice fulgorid mainly relies on Imidacloprid, Buprofezin, organic phosphor and composite dose, and wherein high malicious organophosphorous pesticide bans use of, because long-term single continuous use; Brown planthopper, small brown rice planthopper have produced tangible pesticide resistance to Imidacloprid; Control efficiency sharply descends, and Buprofezin begins to descend to the preventive effect of rice fulgorid, produces to paddy rice and brings serious loss.In recent years, the appearance of control rice fulgorid agricultural chemicals newly developed (like pyrrole aphid ketone, Nitenpyram), large-scale continuous, unreasonable use in the production certainly will influence the control effect of rice fulgorid, accelerate the drug-fast generation of rice fulgorid.Leaf-roller is gnawed rice leaf with larva, gently then forms " Bai Ye ", and is heavy then No kernels or seeds are gathered, as in a year of scarcity; The conventional dose preventive effect is undesirable, has formed pesticide resistance, and external pesticide species control cost is higher; The mu cost reaches about 15 yuan, therefore, and the Recompounded pesticide kind of research and development high-efficiency prevention and control rice fulgorid, leaf-roller; Can delay the pesticide resistance of insect, reduce the input of agricultural chemicals.
Indenes worm prestige (indoxacarb) chemical name: 7-chloro-2; 3,4a, 5-tetrahydrochysene-2-[methoxycarbonyl (4-Trifluoromethoxyphen-l) carbamoyl] indeno [1; 2-e] [1; 3,4-] oxadiazines-4a-carboxylate methyl ester is du pont company (E.I.du Pont de Nemours and Company) a kind of insecticide of Development and Production recently.Insecticidal mechanism mainly through the sodium-ion channel in the blocking-up insect nerve cell, makes the nerve cell loss of function.Have and tag and stomach poison function, all effective to each instar larvae.Can be used for preventing and treating beet armyworm, diamond-back moth, cabbage caterpillar, prodenia litura, tomato moth, cotton bollworm, oriental tobacco budworm, leaf rollers, codling moth, leafhopper, spark, the colorado potato beetle on the crops such as wild cabbage, flower coconut palm class, cabbage mustard, tomato, capsicum, cucumber, little cucumber, eggplant, lettuce, apple, pears, peach, apricot, cotton, potato, grape.To mammal, domestic animal low toxicity, as safe as a house to the useful insects such as non-target biology in the environment simultaneously, residual low in crop, can gather in the 2nd day after the medication.
Silafluofene is a kind of novel pyrethroid insecticides, and it belongs to never poison.Have stomach toxicity and action of contace poison; Inhale conduction in not having, activity is high, chemical property is stable, and the speed of knocking down is fast, insecticidal spectrum is wide; Termite there is good repellent action; Insect-proof agent is used as termite control agent, dress material in the family expenses aspect, in agricultural production, can prevent and treat insects such as plant hopper, leafhopper class, stinkbug class, rice leaf roller, locustamigratoria.To mammal and fish low toxicity, can be used safely in crop pest control.
Silafluofene has and tags and stomach poison function as a kind of pyrethroid insecticides of tool knockdown effect, and fast to the insect speed of action, the lasting period is long, and single agent use cost is higher.Indenes worm prestige is controlled effect preferably to the leaf-roller tool, but the speed of effect is slow, and the mu cost is higher; Indenes worm prestige and silafluofene are composite to be to utilize different effects mechanism; Taking into account two kinds of insects, can effectively control rice fulgorid, leaf-roller, is comprehensive regulation resistant insect pesticide species.
Summary of the invention
Technical problem to be solved by this invention provides a kind of insecticides that contains indenes worm prestige of preventing and treating rice grub.
The insecticide that contains indenes worm prestige of the present invention, its active ingredient: A are that indenes worm prestige, B are a kind of of silafluofene or ether chrysanthemum ester, and wherein the weight ratio of effective constituents A and B is 1:20-20:1.
The insecticides that contains indenes worm prestige of the present invention can be prepared into formulations such as wetting powder, suspending agent.
The insecticides that the present invention contains indenes worm prestige is a wetting powder, wherein is made up of the raw material of following parts by weight: effective ingredient A and B 15-21 part,
Wetting agent 3-20 part,
Dispersant 3-20 part,
Adsorbent 2-20 part,
Carrier is supplied 200 parts.
The insecticides that the present invention contains indenes worm prestige is a wetting powder, and the raw material that preferably has following parts by weight is formed:
Effective ingredient A and B 20-21 part,
8 parts of wetting agents,
3 parts of dispersants,
5 parts in adsorbent,
Carrier is supplied 100 parts.
Wherein said wetting agent can be used one or more in spaonin powder, sodium lignin sulfonate, the neopelex;
Wherein said dispersant is sodium metnylene bis-naphthalene sulfonate (being called for short NNO);
Wherein said adsorbent is a white carbon;
Wherein said carrier is one or more in kaolin, the attapulgite.
The insecticides that the present invention contains indenes worm prestige is a suspending agent, wherein is made up of the raw material of following parts by weight:
Effective ingredient A and B account for 15-50 part of insecticidal total weight,
Dispersant 2-40 part,
Thickener 0.5-20 part,
Stabilizing agent 0.01-20 part,
Antifoaming agent 1-10 part,
Bleeding agent 1-10 part,
Antifreezing agent 0.1-5 part,
The pH regulator agent, an amount of, transfer pH usefulness,
Water is supplied 200 parts.
The insecticides that the present invention contains indenes worm prestige is a suspending agent, and the raw material that preferably has following parts by weight is formed:
Effective ingredient A and B account for 15-21 part of insecticidal total weight,
10 parts of dispersants,
1 part of thickener,
2 parts of stabilizing agents,
1 part of antifoaming agent,
2 parts of bleeding agents,
12 parts of antifreezing agents,
The pH regulator agent, an amount of, transfer pH usefulness,
Water is supplied 100 parts.
Wherein said dispersant is selected from sodium lignin sulfonate; The lignin sodium iodate; Lauryl alcohol polyethylene glycol oxide base ether sodium sulfate; Fluhyzon formaldehyde condensation products sodium sulfonate; Neopelex; Lauryl sodium sulfate; Potassium oleate; Enuatrol; Alkyl polyoxyethylene ether sulfonate; Alkylphenol-polyethenoxy base ether formaldehyde condensation products; Alkylphenol-polyethenoxy base ether; Nonyl pheno base ether; Polyoxyethylene polyoxypropylene base ether block copolymers; Draw back powder; Gather second carboxylic esters sodium salt; In dodecyl polyoxyethylene ether phosphate or the Fluhyzon first condensate sulfonates one or more.
Wherein said thickener is selected from one or more in xanthans, CMC, hydroxyethylcellulose, methylcellulose or the polyvinyl alcohol.
Wherein said stabilizing agent is selected from one or more in catechol, butyl glycidyl ether, phenyl glycidyl ether, cresyl glycidyl ether, polyethylene glycol diglycidyl ether, chloropropylene oxide, sodium sorbate, Sodium Benzoate, epoxidised soybean oil, linseed oil, quinhydrones, anthraquinone, eugenol, citric acid, hydroxy benzoate or the nipasol.
Wherein said antifoaming agent is chosen one or more in silicone oil, silicone compound, C10-20 saturated fat acid compounds, C8-10 fat alcohol compound or II-ethylhexanol; Wherein silicone compound such as organosilicon etc., said C10-20 saturated fat acid compounds such as hendecanoic acid, tridecanoic acid, pentadecanoic acid etc., C8-10 fat alcohol compound such as certain herbaceous plants with big flowers alcohol, ten alkanoic acids etc.
Wherein said antifreezing agent is selected from one or more in ethylene glycol, glycerine, propane diols, polyethylene glycol, sorbierite or the urea.
Wherein said pH regulator agent is selected from hydrogen-oxygen in sodium, ammoniacal liquor, acetic acid, citric acid or the phosphoric acid one or more.The consumption of pH regulator agent is that to make the pH value of suspending agent be 5～9.
Wherein said bleeding agent is an organosilicon.
A kind of preparation contains the method for indenes worm prestige composite suspension agent; Indenes worm prestige, silafluofene and dispersant, thickener, stabilizing agent, antifoaming agent, antifreezing agent, bleeding agent, pH regulator agent and water is even by above-mentioned mixed; Ball milling is 2～3 hours in ball mill, makes particle diameter all below the 5 μ m.
Composite insecticide of the present invention is compared with conventional control rice fulgorid medicament, has the following advantages: 1, reduce dosage, reduce the residual of environmental pollution and agricultural product; 2, can delay the pesticide resistance of rice fulgorid to single insecticide, 3, have long advantage of lasting period, compare with single medicament, can reduce cost.
Embodiment
Following examples are preferred condition, but active component of the present invention and proportioning, auxiliary element etc. are not limited to following examples, and ratios all among the embodiment are calculated by weight.
Embodiment one:
Prepare 15% silafluofene indenes worm prestige suspending agent, each composition weight proportion is:
Silafluofene (active ingredient) 10g
Indenes worm prestige (active ingredient) 5g
Sodium lignin sulfonate 10g
Ethylene glycol 12g
Xanthans 1g
Catechol 2g
Silicone oil 1g
Organosilicon 2g
Water is supplied 100g
Embodiment two:
Prepare 15% silafluofene indenes worm prestige suspending agent, each composition weight proportion is:
Silafluofene (active ingredient) 10g
Indenes worm prestige (active ingredient) 5g
Sodium lignin sulfonate 10g
Ethylene glycol 12g
Xanthans 1g
Catechol 2g
Silicone oil 1g
Organosilicon 2g
Water supplies 100
Embodiment three:
Prepare 21% silafluofene indenes worm prestige suspending agent, each composition weight proportion is:
Silafluofene (active ingredient) 1g
Indenes worm prestige (active ingredient) 20g
Sodium lignin sulfonate 10g
Ethylene glycol 12g
Xanthans 1g
Catechol 2g
Silicone oil 1g
Organosilicon 2g
Water supplies 100
Embodiment four
Prepare 21% silafluofene indenes worm prestige wetting powder, each composition weight proportion is:
Silafluofene (active ingredient) 20g
Indenes worm prestige (active ingredient) 1g
Neopelex 3g
NNO 3g
White carbon 5g
Sodium lignin sulfonate 5g
Kaolin is supplied 100 g
Embodiment five
Prepare 20% silafluofene indenes worm prestige wetting powder, each composition weight proportion is:
Silafluofene (active ingredient) 10g
Indenes worm prestige (active ingredient) 10g
Neopelex 3g
NNO 3g
White carbon 5g
Sodium lignin sulfonate 5g
Kaolin is supplied 100 g
Effect experiment one:
Embodiment one, four is prevented and treated the effect field control effectiveness test (seeing table 1) of white-backed planthopper; Test is handled: 15% 80 milliliters of silafluofene indenes worm prestige suspending agent mu consumptions, 100 milliliters of 5% silafluofene missible oil mu consumptions, 21% indenes worm prestige wetting powder mu consumption, 50 grams; In late July white-backed planthopper nymph peak period dispenser; 50 kilograms of every mu of water consumptions, even spraying, 150 square metres of every processing.Result of the test shows; Behind the medicine 3 days; The control efficiency that 15% silafluofene indenes worm prestige suspending agent mu consumption, 10 grams and 21% indenes worm prestige wetting powder mu consumption, 50 grams are handled white-backed planthopper is respectively 86.23%, 89.56%; With the control efficiency there was no significant difference of 100 milliliters of 5% silafluofene missible oil mu consumptions, extremely significantly be better than 10 milliliters of processing of contrast medicament 15% indenes worm prestige; Behind the medicine 7 days; The control efficiency that 15% silafluofene indenes worm prestige suspending agent mu consumption, 10 grams and 21% indenes worm prestige wetting powder mu consumption, 50 grams are handled white-backed planthopper is respectively 93.45%, 95.21%, extremely significantly is better than 100 milliliters of contrast medicament 5% silafluofene missible oil mu consumptions, 10 milliliters of processing of 15% indenes worm prestige; Behind the medicine 14-21 days, behind the trend of test medicine and the medicine 7 days consistent basically.
Table 1 15% silafluofene indenes worm prestige suspending agent is to the control efficiency of white-backed planthopper
Annotate: data are 3 times and repeat mean in the table
Effect experiment two:
Embodiment three, five is carried out field control effectiveness test (seeing table 2), supply the reagent kind: 20% silafluofene indenes worm prestige wetting powder mu consumption, 10 grams, 5 milliliters of 21% silafluofene indenes worm prestige suspending agent mu consumptions; 100 milliliters of 5% silafluofene missible oil mu consumptions, 10 milliliters of 15% indenes worm prestige suspending agent mu consumptions; In early August leaf-roller low age nymph peak period dispenser, 50 kilograms of every mu of water consumptions, even spraying; 20 square metres of every processing, triplicate.Field investigation is the result show; Behind the medicine 3 days; 5 milliliters of 20% silafluofene indenes worm prestige wetting powder mu consumption 10 gram, 21% silafluofene indenes worm prestige suspending agent mu consumptions are respectively 87.96%, 84.52% to the control efficiency of leaf-roller, all extremely significantly are superior to contrasting the control efficiency of medicament; Behind the medicine 7 days, test medicine to behind the control effect of leaf-roller and the medicine 3 days consistent basically.
Composite dose of table 2 silafluofene indenes worm prestige is to the leaf-roller control efficiency
Annotate: data are 3 times and repeat mean in the table.
Claims (9)
1. contain the insecticides of indenes worm prestige, it is characterized in that active ingredient: A is that indenes worm prestige, B are a kind of of silafluofene or ether chrysanthemum ester, and wherein the weight ratio of effective constituents A and B is 1:20-20:1.
2. the insecticides that contains indenes worm prestige according to claim 1 is wetting powder or suspending agent.
3. the insecticides that contains indenes worm prestige according to claim 2 is characterized in that wherein said wetting powder, wherein is made up of the raw material of following parts by weight:
Effective ingredient A and B 15-21 part,
Wetting agent 3-20 part,
Dispersant 3-20 part,
Adsorbent 2-20 part,
Carrier is supplied 200 parts.
4. the insecticides that contains indenes worm prestige according to claim 3 is characterized in that wherein said wetting powder, is made up of the raw material of following parts by weight:
Effective ingredient A and B 20-21 part,
8 parts of wetting agents,
3 parts of dispersants,
5 parts in adsorbent,
Carrier is supplied 100 parts.
5. according to claim 3 or the 4 described insecticides that contain indenes worm prestige, it is characterized in that wherein said wetting agent can use one or more in spaonin powder, sodium lignin sulfonate, the neopelex;
Wherein said dispersant is a sodium metnylene bis-naphthalene sulfonate;
Wherein said adsorbent is a white carbon;
Wherein said carrier is one or more in kaolin, the attapulgite.
6. the insecticides that contains indenes worm prestige according to claim 2 is characterized in that wherein said suspending agent, wherein is made up of the raw material of following parts by weight:
Effective ingredient A and B account for 15-50 part of insecticidal total weight,
Dispersant 2-40 part,
Thickener 0.5-20 part,
Stabilizing agent 0.01-20 part,
Antifoaming agent 1-10 part,
Bleeding agent 1-10 part,
Antifreezing agent 0.1-5 part,
The pH regulator agent, an amount of, transfer pH usefulness,
Water is supplied 200 parts.
7. the insecticides that contains indenes worm prestige according to claim 6 is characterized in that wherein being made up of the raw material of following parts by weight:
Effective ingredient A and B account for 15-21 part of insecticidal total weight,
10 parts of dispersants,
1 part of thickener,
2 parts of stabilizing agents,
1 part of antifoaming agent,
2 parts of bleeding agents,
12 parts of antifreezing agents,
The pH regulator agent, an amount of
Water is supplied 100 parts.
8. according to claim 6 or the 7 described insecticides that contain indenes worm prestige, it is characterized in that wherein said dispersant is selected from sodium lignin sulfonate, lignin sodium iodate, lauryl alcohol polyethylene glycol oxide base ether sodium sulfate, Fluhyzon formaldehyde condensation products sodium sulfonate, neopelex, lauryl sodium sulfate, potassium oleate, enuatrol, alkyl polyoxyethylene ether sulfonate, alkylphenol-polyethenoxy base ether formaldehyde condensation products, alkylphenol-polyethenoxy base ether, Nonyl pheno base ether, polyoxyethylene polyoxypropylene base ether block copolymers, draws back powder, gathers second carboxylic esters sodium salt, in dodecyl polyoxyethylene ether phosphate or the Fluhyzon first condensate sulfonates one or more;
Wherein said thickener is selected from one or more in xanthans, CMC, hydroxyethylcellulose, methylcellulose or the polyvinyl alcohol;
Wherein said stabilizing agent is selected from one or more in catechol, butyl glycidyl ether, phenyl glycidyl ether, cresyl glycidyl ether, polyethylene glycol diglycidyl ether, chloropropylene oxide, sodium sorbate, Sodium Benzoate, epoxidised soybean oil, linseed oil, quinhydrones, anthraquinone, eugenol, citric acid, hydroxy benzoate or the nipasol;
Wherein said antifoaming agent is chosen one or more in silicone oil, silicone compound, C10-20 saturated fat acid compounds, C8-10 fat alcohol compound or II-ethylhexanol; Wherein silicone compound such as organosilicon etc., said C10-20 saturated fat acid compounds such as hendecanoic acid, tridecanoic acid, pentadecanoic acid etc., C8-10 fat alcohol compound such as certain herbaceous plants with big flowers alcohol, ten alkanoic acids;
Wherein said antifreezing agent is selected from one or more in ethylene glycol, glycerine, propane diols, polyethylene glycol, sorbierite or the urea;
Wherein said pH regulator agent is selected from hydrogen-oxygen in sodium, ammoniacal liquor, acetic acid, citric acid or the phosphoric acid one or more; The consumption of pH regulator agent is that to make the pH value of suspending agent be 5～9;
Wherein said bleeding agent is an organosilicon.
9. according to claim 5 or the 6 described preparation methods that contain the insecticides of indenes worm prestige, it is characterized in that
Carry out according to following step: indenes worm prestige, silafluofene and dispersant, thickener, stabilizing agent, antifoaming agent, antifreezing agent, bleeding agent, pH regulator agent and water is even by above-mentioned mixed; Ball milling is 2～3 hours in ball mill, makes particle diameter all below the 5 μ m.
Priority Applications (1)
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| CN2012101484953A CN102696665A (en) | 2012-05-15 | 2012-05-15 | Insecticide combination containing indoxacarb |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012101484953A CN102696665A (en) | 2012-05-15 | 2012-05-15 | Insecticide combination containing indoxacarb |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2016107568A1 (en) * | 2014-12-30 | 2016-07-07 | 江苏龙灯化学有限公司 | Insecticidal composition and uses thereof |
| CN106332883A (en) * | 2016-08-25 | 2017-01-18 | 安徽美兰农业发展股份有限公司 | Ethofenprox and methoxyfenozide compound suspending agent and preparation method thereof |
| CN106359436A (en) * | 2016-08-25 | 2017-02-01 | 安徽美兰农业发展股份有限公司 | Ethofenprox and indoxacarb compound suspension agent and preparation method thereof |
| CN111357754A (en) * | 2020-03-04 | 2020-07-03 | 南通联农佳田作物科技有限公司 | High-chlorine propoxur suspending agent and preparation method and application thereof |
| US11457624B2 (en) | 2016-11-02 | 2022-10-04 | Corbet Scientific, Llc | Adjuvant compositions for plant treatment chemicals |
| US11666048B2 (en) | 2017-02-24 | 2023-06-06 | Corbet Scientific, Llc | Treatment for plants in conjunction with harvesting |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2016107568A1 (en) * | 2014-12-30 | 2016-07-07 | 江苏龙灯化学有限公司 | Insecticidal composition and uses thereof |
| CN106332883A (en) * | 2016-08-25 | 2017-01-18 | 安徽美兰农业发展股份有限公司 | Ethofenprox and methoxyfenozide compound suspending agent and preparation method thereof |
| CN106359436A (en) * | 2016-08-25 | 2017-02-01 | 安徽美兰农业发展股份有限公司 | Ethofenprox and indoxacarb compound suspension agent and preparation method thereof |
| US11457624B2 (en) | 2016-11-02 | 2022-10-04 | Corbet Scientific, Llc | Adjuvant compositions for plant treatment chemicals |
| US11666048B2 (en) | 2017-02-24 | 2023-06-06 | Corbet Scientific, Llc | Treatment for plants in conjunction with harvesting |
| CN111357754A (en) * | 2020-03-04 | 2020-07-03 | 南通联农佳田作物科技有限公司 | High-chlorine propoxur suspending agent and preparation method and application thereof |
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Application publication date: 20121003 |