CN103436072B - A kind of Environment-friendlyhigh-strength high-strength mildew-proof putty powder - Google Patents

A kind of Environment-friendlyhigh-strength high-strength mildew-proof putty powder Download PDF

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Publication number
CN103436072B
CN103436072B CN201310427199.1A CN201310427199A CN103436072B CN 103436072 B CN103436072 B CN 103436072B CN 201310427199 A CN201310427199 A CN 201310427199A CN 103436072 B CN103436072 B CN 103436072B
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strength
putty powder
friendlyhigh
weight percent
environment
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CN103436072A (en
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冯有愉
冯婷
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Shenzhen Mo Dun environmental protection new material Co., Ltd.
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HUBEI PROFESSIONAL NEW BIOLOGICAL MATERIAL Co Ltd
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Abstract

The invention provides a kind of Environment-friendlyhigh-strength high-strength mildew-proof putty powder, comprise the component of following weight percent: water-ground limestone 70-99%, grey calcium 0-30%, starch alkenyl succinate ester 0.5-10%, Vltra tears 0.2-5%, treated starch 0.5-10%, the weight percent sum of above-mentioned each component is 100%; The cohesive strength of this putty powder is strong, and mildew resistance is improved greatly, has not dry linting, non-scale, does not chap, and does not play mould advantage, and easy construction.

Description

A kind of Environment-friendlyhigh-strength high-strength mildew-proof putty powder
Technical field
The present invention relates to a kind of material of construction, particularly relate to a kind of putty powder.
Background technology
Traditional architecture finishing great Bai putty admixture mainly with macromolecule glue water such as polyvinyl alcohol, carboxymethyl cellulose (CMC), carboxymethyl starch, pre-gelatinized starch produces; But polyvinyl alcohol glue is containing formaldehyde, harmful, do not meet environmental requirement, although and carboxymethyl starch and pre-gelatinized starch do not contain hazardous substance, cohesive force is poor with anti-mildew sex change, in putty powder, still there is a lot of drawback during interpolation use:
1. addition great Yi causes putty powder to go mouldy, and causes putty powder to come off unsightly, causes huge waste.
2. putty powder hardness is difficult to the requirement that is up to state standards, and it is bad to cause emulsion paint to be coated with brushing effects.
3. use at China's wet area (Jiangsu and Zhejiang Provinces, Shanghai, Hubei, Guangdong, Fujian, Sichuan, Chongqing, Hunan, Hainan, Guangxi etc.) especially severe that goes mouldy, cause interior wall revision rate high especially, general 1-2 interior wall body of wall will renovate, and cause financial loss huge especially.
Due to carboxymethyl starch and pre-gelatinized starch cheap, China uses the carboxymethyl starch of putty powder industry and pre-gelatinized starch just to need about 100,000 tons every year, there is no particularly preferred substitute material at present, restriction China is in the quality of interior wall great Bai putty and development, therefore need a kind of novel putty material, the present invention proposes based on this.
Summary of the invention
In order to solve the above problem existed in prior art, the invention provides a kind of high bond strength, the putty powder of environmental protection, adopt the metope of this putty powder to have and do not ftracture, not dry linting, hardness is high, the feature of mildew-resistant.
For achieving the above object, the present invention adopts following technical scheme:
A kind of Environment-friendlyhigh-strength high-strength mildew-proof putty powder, comprises the component of following weight percent:
Water-ground limestone: 70-99%;
Ash calcium: 0-30%;
Starch alkenyl succinate ester: 0.5-10%;
Vltra tears: 0.2-5%;
Treated starch: 0.5-10%;
The weight percent sum of above-mentioned each component is 100%.
Described starch alkenyl succinate ester is by maleic anhydride and olefin(e) compound derivative synthesis, wherein alkene can have the chain length of 3-19 carbon atom or two or more mixtures in them, comprise butenylsuccinic anhydride, pentenyl succinyl oxide, hexenyl succinic acid acid anhydride, heptenyl succinic acid acid anhydride, octenyl succinic acid anhydride, nonenyl succinic acid acid anhydride, decenyl succinic acid anhydride and their mixture.
As preferably, the weight percent of water-ground limestone is 80-90%;
As preferably, the weight percent of grey calcium is 5-10%;
As preferably, the weight percent of starch alkenyl succinate ester is 2-5%;
As preferably, the weight percent of Vltra tears is 1-2%;
As preferably, the weight percent of treated starch is 0.5-3%;
Wherein Vltra tears has been thickening, the effect of water conservation, and treated starch plays a part to improve application property.
This putty powder is tackiness agent primarily of starch alkenyl succinate ester, adds mineral filler, and the material such as ether of cellulose is made, have superior cohesive strength and antibacterial and antimildew function, application property is good, does not chap after trowelling, not dry linting, also can support the use with high-grade emulsion paint.Be applicable to southern wet area, and kitchen, toilet, the easy mouldy place such as vault.And this putty powder is not containing organic solvent and harmful composition, so it meets the requirement of environmental type.
Embodiment
Below in conjunction with embodiment, the invention will be further described:
embodiment 1
Formula (weight percent):
Water-ground limestone: 98%;
Starch alkenyl succinate ester: 0.5%;
Vltra tears: 1%;
Treated starch: 0.5%.
embodiment 2
Formula (weight percent):
Water-ground limestone: 70%;
Ash calcium: 28%;
Starch alkenyl succinate ester: 0.5%;
Vltra tears: 1%;
Treated starch: 0.5%.
embodiment 3
Formula (weight percent):
Water-ground limestone: 85%;
Ash calcium: 10%;
Starch alkenyl succinate ester: 3.5%;
Vltra tears: 1%;
Treated starch: 0.5%.
embodiment 4
Formula (weight percent):
Water-ground limestone: 85%;
Ash calcium: 11%;
Vltra tears: 1%;
Treated starch: 3%.
Obtain putty powder to above-mentioned four embodiments to test, test-results is as follows, and wherein embodiment 4 is not containing the control group of starch octenyl succinate anhydride.
Interventions Requested Standard-required Embodiment 1 Embodiment 2 Embodiment 3 Embodiment 4
Condition in container Without caking, evenly Without caking, evenly Without caking, evenly Without caking, evenly Without caking, evenly
Application property Blade coating is accessible Blade coating is accessible Blade coating is accessible Blade coating is accessible Blade coating is accessible
Cohesive strength (14d), MPa >0.5 2.0 2.0 4 0.55
Time of drying (surface drying), h <5 2.5 2.5 2 2.5
Grinability, % 20~80 40 45 60 25
Folding strength (14d), MPa ≥2.5 5.0 6.0 9.5 2.8
Visible, the putty powder containing starch alkenyl succinate ester has superior cohesive strength, grinability and folding strength compared to the control group do not contained, and the formula in embodiment 3 achieves the most excellent technique effect.
It will be recognized by those skilled in the art, under the prerequisite not departing from protection scope of the present invention, various amendment, change and combination can be carried out to above-mentioned embodiment, and think that this amendment, change and combination are within the scope of originality thought.

Claims (7)

1. an Environment-friendlyhigh-strength high-strength mildew-proof putty powder, is characterized in that the component comprising following weight percent:
The weight percent sum of above-mentioned each component is 100%.
2. a kind of Environment-friendlyhigh-strength high-strength mildew-proof putty powder as claimed in claim 1, it is characterized in that, described starch alkenyl succinate ester is by maleic anhydride and olefin(e) compound derivative synthesis, wherein alkene can have the chain length of 3-19 carbon atom or two or more mixtures in them, it is butenylsuccinic anhydride, pentenyl succinyl oxide, hexenyl succinic acid acid anhydride, heptenyl succinic acid acid anhydride, octenyl succinic acid anhydride, nonenyl succinic acid acid anhydride, decenyl succinic acid anhydride and their mixture.
3. a kind of Environment-friendlyhigh-strength high-strength mildew-proof putty powder as claimed in claim 1, is characterized in that the weight percent of water-ground limestone is 80-90%.
4. a kind of Environment-friendlyhigh-strength high-strength mildew-proof putty powder as claimed in claim 1, is characterized in that the weight percent of grey calcium is 5-10%.
5. a kind of Environment-friendlyhigh-strength high-strength mildew-proof putty powder as claimed in claim 1, is characterized in that the weight percent of starch alkenyl succinate ester is 2-5%.
6. a kind of Environment-friendlyhigh-strength high-strength mildew-proof putty powder as claimed in claim 1, is characterized in that the weight percent of Vltra tears is 1-2%.
7. a kind of Environment-friendlyhigh-strength high-strength mildew-proof putty powder as claimed in claim 1, is characterized in that the weight percent of treated starch is 0.5-3%.
CN201310427199.1A 2013-09-18 2013-09-18 A kind of Environment-friendlyhigh-strength high-strength mildew-proof putty powder Active CN103436072B (en)

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Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105017835A (en) * 2015-07-30 2015-11-04 广西梧州龙鱼漆业有限公司 Putty powder for external walls
CN105038363A (en) * 2015-07-30 2015-11-11 广西梧州龙鱼漆业有限公司 Anti-bacteria mouldproof putty powder
CN105348895A (en) * 2015-12-11 2016-02-24 许展 Putty powder
CN106752251A (en) * 2017-02-08 2017-05-31 上海为然环保科技有限公司 A kind of environmentally friendly water-fast antibacterial mastic powder and preparation method thereof
CN110845894A (en) * 2019-11-29 2020-02-28 重庆贝亨源节能建材有限公司 Interior wall putty powder
CN111548666A (en) * 2020-06-06 2020-08-18 范林 Waterproof and bacteriostatic weakly-alkaline negative oxygen ion putty powder for purifying air and preparation method thereof
CN113735511A (en) * 2021-09-06 2021-12-03 中象新材料(大连)有限公司 Application of starch octenyl succinate, building mortar, putty and ceramic tile adhesive

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101121833A (en) * 2006-08-09 2008-02-13 黄春 High-strength environmental protection water putty powder and preparation method thereof
CN102070722A (en) * 2010-02-03 2011-05-25 内蒙古奈伦农业科技股份有限公司 Octenyl succinate distarch phosphate and preparation method and applications thereof
CN102220043A (en) * 2011-06-20 2011-10-19 梁丛丛 Water-resistant putty for interior wall

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101121833A (en) * 2006-08-09 2008-02-13 黄春 High-strength environmental protection water putty powder and preparation method thereof
CN102070722A (en) * 2010-02-03 2011-05-25 内蒙古奈伦农业科技股份有限公司 Octenyl succinate distarch phosphate and preparation method and applications thereof
CN102220043A (en) * 2011-06-20 2011-10-19 梁丛丛 Water-resistant putty for interior wall

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Patentee after: Shenzhen Mo Dun environmental protection new material Co., Ltd.

Address before: No. 168 Airway Road, Liuhe Industrial Park, Xiaogan City, Hubei Province, 432000

Patentee before: Hubei Professional New Biological Material Co., Ltd.

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