CN103430955A - Weeding composition containing halosulfuron-methyl and oxaziclomefone - Google Patents
Weeding composition containing halosulfuron-methyl and oxaziclomefone Download PDFInfo
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Abstract
The invention discloses a weeding composition containing halosulfuron-methyl and oxaziclomefone. The weeding composition containing halosulfuron-methyl and oxaziclomefone is composed of an active component, an additive and a carrier, wherein the active component is composed of halosulfuron-methyl and oxaziclomefone in weight ratio of 0.02-50, and the active component accounts for 1-90% of the total weight of the weeding composition. The weeding composition containing halosulfuron-methyl and oxaziclomefone can be the conventional pesticide dosage forms of wettable powder, water dispersible granules, oil suspension, powder, granules, dry suspending agent, emulsion oil, emulsion in water, microemulsion in water, or suspended emulsion and the like. The weeding composition has a synergistic effect and a broad herbicide controlling spectrum, can prevent and kill various weeds in a grass family and a sedge family and broad leaf weeds, including multiple pernicious weeds such as barnyard grass and difformed galingale herb, can be used before and after seedlings grow and is low in dosage and high in safety to crops.
Description
Technical field
The present invention relates to a kind of weed killer herbicide, be specifically related to a kind of Herbicidal combinations containing halosulfuronmethyl and oxaziclomefone.
Background technology
The chemical name of halosulfuronmethyl (the CAS accession number is 100784-20-1) is: the chloro-5-(4 of 3-, 6-dimethoxypyridin-2-base amino carbonyl amino sulfonyl)-1-methylpyrazole-4-carboxylate methyl ester.Structural formula is as follows:
。
It is a kind of sulfonylurea herbicide, can be used for various crop and the non-crops such as wheat, corn, paddy rice, broad weed-killing spectrum, and using dosage is low, and active high, selectivity is strong.But application technique is required to comparatively harshness, and improper use, easily cause poisoning, and its price is higher.
The chemical name of oxaziclomefone (the CAS accession number is 153197-14-9) is: 3-[1-(3,5-dichlorophenyl)-1-Methylethyl]-2,3-dihydro-6-methyl-5-phenyl-4H-1,3-oxazine-4-ketone.Structural formula is as follows:
。
It is an oxazine ketone weed killer herbicide, and using dosage is 40 gram active ingredients/hectare～50 gram active ingredients/hectare, mainly prevents and kill off important broad leaved weed, sedge weed and Echinochloa weeds.After general seedling, use, therefore, service time is comparatively limited.
Not yet find at present halosulfuronmethyl and the composite relevant report of oxaziclomefone.
Summary of the invention
The object of the invention is to for the deficiencies in the prior art, a kind of Herbicidal combinations containing halosulfuronmethyl and oxaziclomefone is provided.
The technical scheme that realizes the object of the invention is: a kind of Herbicidal combinations containing halosulfuronmethyl and oxaziclomefone is comprised of active component, auxiliary agent and carrier.Described active component is comprised of halosulfuronmethyl and oxaziclomefone, and the weight ratio of halosulfuronmethyl and oxaziclomefone is (1: 50)～(50: 1), preferred (1: 20)～(20: 1), more preferably (1: 6)～(6: 1).The weight of active component is 1%～90% of composition total weight, preferably 12%～75%.
Described auxiliary agent comprises the conventional auxiliary agent of the agricultural chemicals such as wetting agent, dispersant, disintegrant, adhesive, emulsifier, thickener, defoamer.
Described wetting agent is a kind of in sodium sulfate of polyethenoxy ether of fatty alcohol, fatty acid amide N methyl taurine sodium salt, polyox-yethylene-polyoxypropylene block copolymer, alkylnaphthalene sulfonate, fatty alcohol-polyoxyethylene ether, aliphatic alcohol sulfate, alkylbenzenesulfonate, dialkyl succinylsuccinate ester sulphonyl sodium salt, alkylphenol polyoxyethylene, alkylphenol polyoxyethylene formaldehyde condensation products, lignosulfonates, natural wetting agent (as saponin, sulfite cellulose etc.) or two kinds or three kinds; A kind of in preferred fat alcohol polyethenoxy ether sodium sulfate, fatty acid amide N methyl taurine sodium salt, polyox-yethylene-polyoxypropylene block copolymer or two kinds.
Described dispersant is lignosulfonates, the naphthalene sulfonic acid-formaldehyde condensation product sodium salt, alkylbenzenesulfonate, the alkyl polyoxyethylene ether formaldehyde condensation products, aralkyl APEO formaldehyde condensation products, alkyl naphthalene sulfonic acid formaldehyde condensation products sodium salt, aralkyl naphthalene sulfonic acid-formaldehyde condensation product sodium salt, fatty acid amide N methyl taurine sodium salt, polycarboxylate, alkylphenol polyoxyethylene formaldehyde condensation products sulphate, alkylphenol polyoxyethylene, aliphatic amine polyoxyethylene ether, the fatty acid glyceride APEO, a kind of in the vegetable oil ethylene oxide adduct or two kinds or three kinds, preferably a kind of in lignosulfonates, naphthalene sulfonic acid-formaldehyde condensation product sodium salt, alkylbenzenesulfonate or two kinds.
Described disintegrant is a kind of in ammonium sulfate, sodium chloride, urea, starch, starch derivatives or two kinds or three kinds.
Described adhesive is a kind of in polyethylene glycol, Sodium Polyacrylate, polyox-yethylene-polyoxypropylene block copolymer, xanthans, dextrin or two kinds or three kinds.
Described emulsifier is a kind of in castor oil polyoxyethylene ether, alkylphenol polyoxyethylene, Ben-zylphenol Polyoxyethyl Ether, styryl phenol polyethenoxy ether, fatty alcohol-polyoxyethylene ether, polyol fatty acid ester, polyol fatty acid ester ethylene oxide adduct, alkylbenzenesulfonate, organophosphorus ester or two kinds or three kinds.
Described thickener is a kind of in xanthans, gelatin, gum Arabic, melon glue, sodium alginate, sodium carboxymethylcellulose, polyvinyl alcohol, polyacrylamide, gas-phase silica, aluminium-magnesium silicate, sepiolite, diatomite, organobentonite, attapulgite or two kinds or three kinds.
Described defoamer is a kind of in polyglycereol defoamer, fatty acid defoamer, silicone defoaming agent or two kinds or three kinds.
Described carrier is solid carrier or liquid-carrier.
Described solid carrier is a kind of in kaolin, diatomite, attapulgite, bentonite, clay, potter's clay, talcum, float stone, white carbon, precipitated calcium carbonate, flour, bark powder, wood powder, shuck powder, corn ear powder, ammonium sulfate, sodium sulphate or two kinds or three kinds.
Described liquid-carrier is a kind of in water, organic plant oil, vegetable oil derivatives, mineral oil, fatty acid ester, repefral, dibutyl phthalate, dioctyl phthalate or two kinds or three kinds.
The formulation of described composition is the agricultural chemicals regular dosage forms such as wetting powder, water dispersible granules, oil-suspending agent, pulvis, granule, dry suspending agent, missible oil, aqueous emulsion, microemulsion or suspended emulsion, preferably wetting powder, water dispersible granules or oil-suspending agent.
When the formulation of described composition is wetting powder; This wetting powder is comprised of the component of following weight parts: as halosulfuronmethyl 0.5～80 weight portion, oxaziclomefone 0.5～80 weight portion as active component, wetting agent 0.1～10 weight portion as auxiliary agent, dispersant 0.1～10 weight portion as auxiliary agent, solid carrier 5～90 weight portions of active component; Preferably as halosulfuronmethyl 1～60 weight portion, oxaziclomefone 1～60 weight portion as active component, wetting agent 1～8 weight portion as auxiliary agent, dispersant 1～8 weight portion as auxiliary agent, solid carrier 10～90 weight portions of active component.
When the formulation of described composition is water dispersible granules; This water dispersible granules is comprised of the component of following weight parts: as halosulfuronmethyl 0.5～80 weight portion, oxaziclomefone 0.5～80 weight portion as active component, wetting agent 0.1～10 weight portion as auxiliary agent, dispersant 0.1～10 weight portion as auxiliary agent, disintegrant 0.1～5 weight portion as auxiliary agent, adhesive 0～5 weight portion as auxiliary agent, solid carrier 5～80 weight portions of active component; Preferably as halosulfuronmethyl 1～60 weight portion, oxaziclomefone 1～60 weight portion as active component, wetting agent 1～8 weight portion as auxiliary agent, dispersant 1～8 weight portion as auxiliary agent, disintegrant 0.3～3 weight portion as auxiliary agent, adhesive 0～3 weight portion as auxiliary agent, solid carrier 10～80 weight portions of active component.
When the formulation of described composition is oil-suspending agent; This oil-suspending agent is comprised of the component of following weight parts: as halosulfuronmethyl 0.5～50 weight portion, oxaziclomefone 0.5～50 weight portion as active component, wetting agent 0.1～10 weight portion as auxiliary agent, dispersant 0.1～10 weight portion as auxiliary agent, emulsifier 0.1～10 weight portion as auxiliary agent, thickener 0.1～10 weight portion as auxiliary agent, defoamer 0.1～5 weight portion as auxiliary agent, liquid-carrier 10～90 weight portions of active component.
The good effect that the present invention has: (1) Herbicidal combination composition formula of the present invention is reasonable, can be suitable for multiple rice field, and have synergistic effect.(2) Herbicidal combinations broad weed-killing spectrum of the present invention, multiple grass family, broad-leaved class and sedge weed are all had to good preventive effect, comprise multiple malignant weed, as barnyard grass, difformed galingale herb etc., disposable medication can be killed paddy field overwhelming majority weeds, has greatly saved drug cost and labor cost.(3) the Herbicidal combinations optimum period for applying fertilizer of the present invention extends, and after Miao Qianmiao, all can use, and using dosage is low, and crop safety is also improved greatly.(4) Herbicidal combinations of the present invention can be avoided, delays and control paddy field weed and develops immunity to drugs, thereby delays the succession speed of weed community.
Embodiment
(embodiment 1)
The formulation of the Herbicidal combinations of the present embodiment is wetting powder, and this wetting powder is comprised of the component of following weight parts: the lignosulfonates as dispersant of the oxaziclomefone of the halosulfuronmethyl of 8 weight portions, 8 weight portions, the sodium sulfate of polyethenoxy ether of fatty alcohol as wetting agent of 2 weight portions, 1 weight portion, the kaolin as solid carrier of 81 weight portions.
The above-mentioned halosulfuronmethyl as active component and oxaziclomefone all derive from Jiangsu Agricultural Hormone Engineering Technology Research Centre Co., Ltd., and purity all reaches the correlated quality requirement.The above-mentioned sodium sulfate of polyethenoxy ether of fatty alcohol as wetting agent is ethoxylated dodecyl alcohol sodium sulphate, derives from Japanese this grease of bamboo company, and commercial disignation is Pionin A-28.The above-mentioned lignosulfonates as dispersant derive from OMNIChem S.A. company, and commercial disignation is Tensiofix IX.The above-mentioned kaolin as solid carrier is the filler level kaolin TRF1 that China Kaolin Co., Ltd produces.
The preparation method is: according to above-mentioned formula, by the active component oxaziclomefone, with halosulfuronmethyl, coarse crushing becomes the powdered substance of particle diameter≤420 micron stand-by; By two kinds of active components, auxiliary agent and solid carrier mixing and stirring, make the mixed material of particle diameter≤44 micron through the method for air-flow crushing, this mixed material is the wetting powder of Herbicidal combinations.
(embodiment 2)
The formulation of the Herbicidal combinations of the present embodiment is still wetting powder, and this wetting powder is comprised of the component of following weight parts: the lignosulfonates as dispersant of the oxaziclomefone of the halosulfuronmethyl of 8 weight portions, 22 weight portions, the sodium sulfate of polyethenoxy ether of fatty alcohol as wetting agent of 2 weight portions, 2 weight portions, the kaolin as solid carrier of 72 weight portions.
The component source of this embodiment and preparation method are with embodiment 1.
(embodiment 3)
The formulation of the Herbicidal combinations of the present embodiment is still wetting powder, and this wetting powder is comprised of the component of following weight parts: the lignosulfonates as dispersant of the oxaziclomefone of the halosulfuronmethyl of 40 weight portions, 20 weight portions, the sodium sulfate of polyethenoxy ether of fatty alcohol as wetting agent of 4 weight portions, 4 weight portions, the kaolin as solid carrier of 32 weight portions.
The component source of this embodiment and preparation method are with embodiment 1.
(embodiment 4)
The formulation of the Herbicidal combinations of the present embodiment is water dispersible granules, and this water dispersible granules is comprised of the component of following weight parts: the N methyl taurine of the fatty acid amide as the wetting agent sodium salt of the oxaziclomefone of the halosulfuronmethyl of 6 weight portions, 10 weight portions, 3 weight portions, the sodium salt of the naphthalene sulfonic acid-formaldehyde condensation product as dispersant of 2 weight portions, the starch derivatives as disintegrant of 1 weight portion, the kaolin as solid carrier of 78 weight portions.
It is identical that above-mentioned active component derives from embodiment 1.The above-mentioned N methyl taurine of the fatty acid amide as wetting agent sodium salt is N-oleoyl-N-methyltaurine sodium, derives from Rhodia company, and commercial disignation is Geropon T-77.The naphthalene sulfonic acid-formaldehyde condensation product sodium salt of above-mentioned dispersant derives from OMNIChem S.A. company, and commercial disignation is Tensiofix CBZ.The above-mentioned starch derivatives as disintegrant is sodium carboxymethyl starch, derives from the GLYCOLYS Std of Roquette company.
The preparation method is: according to above-mentioned formula; by two kinds of active components, auxiliary agent and solid carrier co-grinding; with after water-wet; by the Squeezinggranulator granulation; carry out again drying, the screening make the granular mixed material that is that particle diameter is 200 microns～5000 microns, this mixed material is the water dispersible granules of Herbicidal combinations.
(embodiment 5)
The formulation of the Herbicidal combinations of the present embodiment is still water dispersible granules, and this water dispersible granules is comprised of the component of following weight parts: the N methyl taurine of the fatty acid amide as the wetting agent sodium salt of the oxaziclomefone of the halosulfuronmethyl of 25 weight portions, 30 weight portions, 4 weight portions, the sodium salt of the naphthalene sulfonic acid-formaldehyde condensation product as dispersant of 3 weight portions, the starch derivatives as disintegrant of 1 weight portion, the kaolin as solid carrier of 37 weight portions.
The component source of this embodiment and preparation method are with embodiment 4.
(embodiment 6)
The formulation of the Herbicidal combinations of the present embodiment is still water dispersible granules, and this water dispersible granules is comprised of the component of following weight parts: the starch derivatives as disintegrant of the N methyl taurine of the fatty acid amide as the wetting agent sodium salt of the oxaziclomefone of the halosulfuronmethyl of 51 weight portions, 24 weight portions, 4 weight portions, the sodium salt of the naphthalene sulfonic acid-formaldehyde condensation product as dispersant of 4 weight portions, 1 weight portion, the xanthans as adhesive of 0.4 weight portion, the diatomite as carrier of 15.6 weight portions.
The above-mentioned xanthans as adhesive is for deriving from Rhodia company, and commercial disignation is RHODOPOL 23; The above-mentioned diatomite as solid carrier derives from the agricultural chemicals filler level product of Mingguang City emerging glad mining industry Co., Ltd.
Other component source of this embodiment and preparation method are with embodiment 4.
(embodiment 7)
The formulation of the Herbicidal combinations of the present embodiment is oil-suspending agent, this oil-suspending agent is comprised of the component of following weight parts: the halosulfuronmethyl of 6 weight portions, the oxaziclomefone of 6 weight portions, the castor oil polyoxyethylene ether as emulsifier of 3 weight portions, 0.8 the polyox-yethylene-polyoxypropylene block copolymer as wetting agent of weight portion, 0.8 the acid metal salt of the benzene sulfonamide as dispersant of weight portion, 0.2 the dimethyl silicone polymer as defoamer of weight portion, 1.5 the organobentonite as thickener of weight portion, 81.7 the epoxidized soybean oil as liquid-carrier of weight portion.
It is identical that above-mentioned active component derives from embodiment 1.The above-mentioned castor oil polyoxyethylene ether as emulsifier derives from BASF AG company, and commercial disignation is EMULAN EL.The above-mentioned polyox-yethylene-polyoxypropylene block copolymer as wetting agent derives from BASF AG, and commercial disignation is Pluronic PE6200.The above-mentioned acid metal salt of the benzene sulfonamide as dispersant is that agriculture breast 500(is calcium dodecyl benzene sulfonate), derive from blue star auxiliary reagent factory, Xingtai.The above-mentioned organobentonite as thickener derives from the organobentonite BT-838F of Anji County, Zhejiang Province sky dragon organobentonite Co., Ltd.The above-mentioned dimethyl silicone polymer as defoamer derives from Dow Corning company, and commercial disignation is DSP.The above-mentioned epoxidized soybean oil as liquid-carrier derives from the first class product of Shanghai Jiu-State Chemical Co., Ltd.
The preparation method is: according to above-mentioned formula, two kinds of active components, wetting agent, dispersant, thickener, defoamer and partial emulsifiers and partially liq carrier are added in the sand milling still, after being ground to certain fineness, by mass transport to mixer for well-distribution, add again remaining emulsifier and liquid-carrier, after mixer for well-distribution mixes, be the oil-suspending agent of Herbicidal combinations.
(embodiment 8)
The formulation of the Herbicidal combinations of the present embodiment is still oil-suspending agent, this oil-suspending agent is comprised of the component of following weight parts: the halosulfuronmethyl of 24 weight portions, the oxaziclomefone of 6 weight portions, 3.8 the castor oil polyoxyethylene ether as emulsifier of weight portion, 0.9 the polyox-yethylene-polyoxypropylene block copolymer as wetting agent of weight portion, benzene sulfonamide as the dispersant acid metal salt of 1 weight portion, 1.5 the organobentonite as thickener of weight portion, 0.3 the dimethyl silicone polymer as defoamer of weight portion, 62.5 the epoxidized soybean oil as liquid-carrier of weight portion.
The component source of this embodiment and preparation method are with embodiment 7.
(embodiment 9)
The formulation of the Herbicidal combinations of the present embodiment is still oil-suspending agent, this oil-suspending agent is comprised of the component of following weight parts: the halosulfuronmethyl of 5 weight portions, the oxaziclomefone of 20 weight portions, 3.8 the castor oil polyoxyethylene ether as emulsifier of weight portion, 0.8 the polyox-yethylene-polyoxypropylene block copolymer as wetting agent of weight portion, 1.2 the acid metal salt of the benzene sulfonamide as dispersant of weight portion, 1.5 the organobentonite as thickener of weight portion, 0.4 the dimethyl silicone polymer as defoamer of weight portion, 67.3 the epoxidized soybean oil as liquid-carrier of weight portion.
The component source of this embodiment and preparation method are with embodiment 7.
(application examples)
Should use-case the field control effectiveness test that is halosulfuronmethyl and the composite product of oxaziclomefone.
The experimental field overview: test is carried out in Institute of agricultural sciences experimental field, Funing, Jiangsu Province.Be experimental field the dry-sowed waterpipe direct sowing rice field, rice varieties is for connecting No. 7, round-grained rice, and June 18 was sowed, seeding quantity 4.5kg/667m
2, dispenser on July 3, during dispenser, paddy rice, weeds 3 leaves are about the phase.Field weed species group is barnyard grass, non-irrigated barnyard grass, without awns barnyard grass, moleplant seed, lady's-grass, difformed galingale herb, cyperus iria, miliary fimbristylis herb, carp intestines, false loosestrife, Procumbent Falsepimpernel, ear leaf water amaranth etc.
Experimental scheme: test arranges 7 processing, repeats community area 20m for 3 times
2, random district group is arranged.
Processing arranges as follows:
600 milliliters/hectare of the oil-suspending agents of A, embodiment 7 (being equivalent to 40 milliliters/every mu).
750 milliliters/hectare of the oil-suspending agents of B, embodiment 7 (being equivalent to 50 milliliters/every mu).
900 milliliters/hectare of the oil-suspending agents of C, embodiment 7 (being equivalent to 60 milliliters/every mu).
1500 milliliters/hectare of the oil-suspending agents of D, embodiment 7 (being equivalent to 100 milliliters/every mu).
60 g/has of E, 75% halosulfuronmethyl water dispersible granules (be equivalent to 4 grams/every mu).
F, 3750 milliliters/hectare of 1% oxaziclomefone suspending agents (being equivalent to 250 milliliters/every mu).
G, clear water contrast.
Spraying time and method: direct-sowing dry paddy field after planting 15 days is paddy rice and weeds 3 leaf dispensers about the phase.During dispenser, field is moisture state, with hand-powered knapsack sprayer blade face even spraying, water consumption 750 kg/ hectares (every community is watered 30kg).Keep the field face moistening 5 days after medicine.
Investigation method: fixed 4 points in every community, every some 0.25m
2, irregularly observe the weeds situation of being poisoned to death after medication,
After medicine, kind, the strain number of 15 days investigation weeds, calculate the strain preventive effect, the results are shown in Table 1; After medicine, kind, strain number and the weeds fresh weight of 30 days investigation weeds, calculate the fresh weight preventive effect, the results are shown in Table 2.
Computing formula: the strain number of strain preventive effect %=(the strain numbers of the strain number of clear water contrast weeds-processing weeds)/clear water contrast weeds * 100.
The fresh weight of fresh weight preventive effect %=(fresh weights of the fresh weight of clear water contrast weeds-processing weeds)/clear water contrast weeds * 100.
Table 1
| Process | The grassy weed preventive effect | The broad leaved weeds preventive effect | The sedge weed preventive effect | Total preventive effect |
| A | 83.46% | 90.24% | 88.36% | 86.08% |
| B | 93.54% | 92.37% | 95.42% | 94.42% |
| C | 97.64% | 96.69% | 96.58% | 97.31% |
| D | 98.84% | 98.64% | 98.67% | 98.74% |
| E | 16.32% | 86.72% | 90.37% | 50.24% |
| F | 83.82% | 67.38% | 86.47% | 78.57% |
Table 2
| Process | Grassy weed strain preventive effect | Grassy weed fresh weight preventive effect | Broad leaved weeds strain preventive effect | Broad leaved weeds fresh weight preventive effect | Sedge weed strain preventive effect | Sedge weed fresh weight preventive effect | Total strain preventive effect | Total fresh weight preventive effect |
| A | 87.16% | 91.34% | 92.15% | 93.25% | 92.58% | 93.25% | 90.34% | 94.34% |
| B | 93.27% | 96.64% | 93.28% | 95.17% | 94.45% | 94.27% | 94.08% | 96.58% |
| C | 95.60% | 98.34% | 96.73% | 96.34% | 96.68% | 97.83% | 96.72% | 97.32% |
| D | 98.22% | 99.08% | 96.80% | 97.05% | 98.37% | 99.07% | 97.96% | 99.12% |
| E | 19.93% | 38.92% | 90.31% | 90.28% | 96.74% | 95.14% | 66.60% | 50.05% |
| F | 90.25% | 87.05% | 66.38% | 76.64% | 89.07% | 90.34% | 86.30% | 82.31% |
Claims (9)
1. the Herbicidal combinations containing halosulfuronmethyl and oxaziclomefone, be comprised of active component, auxiliary agent and carrier; It is characterized in that: described active component is comprised of halosulfuronmethyl and oxaziclomefone, and the weight ratio of halosulfuronmethyl and oxaziclomefone is (1: 50)～(50: 1), and the weight of active component is composition total weight 1%～90%.
2. the Herbicidal combinations containing halosulfuronmethyl and oxaziclomefone according to claim 1, it is characterized in that: the weight ratio of halosulfuronmethyl and oxaziclomefone is (1: 20)～(20: 1), the weight of active component is composition total weight 12%～75%.
3. the Herbicidal combinations containing halosulfuronmethyl and oxaziclomefone according to claim 1 and 2, it is characterized in that: the formulation of described composition is wetting powder, water dispersible granules, oil-suspending agent, pulvis, granule, dry suspending agent, missible oil, aqueous emulsion, microemulsion or suspended emulsion.
4. the Herbicidal combinations containing halosulfuronmethyl and oxaziclomefone according to claim 3, it is characterized in that: the formulation of described composition is wetting powder, water dispersible granules or oil-suspending agent.
5. the Herbicidal combinations containing halosulfuronmethyl and oxaziclomefone according to claim 4, it is characterized in that: the formulation of described composition is wetting powder; This wetting powder is comprised of the component of following weight parts: as halosulfuronmethyl 0.5～80 weight portion, oxaziclomefone 0.5～80 weight portion as active component, wetting agent 0.1～10 weight portion as auxiliary agent, dispersant 0.1～10 weight portion as auxiliary agent, solid carrier 5～90 weight portions of active component.
6. the Herbicidal combinations containing halosulfuronmethyl and oxaziclomefone according to claim 5, it is characterized in that: this wetting powder is comprised of the component of following weight parts: as halosulfuronmethyl 1～60 weight portion, oxaziclomefone 1～60 weight portion as active component, wetting agent 1～8 weight portion as auxiliary agent, dispersant 1～8 weight portion as auxiliary agent, solid carrier 10～90 weight portions of active component.
7. the Herbicidal combinations containing halosulfuronmethyl and oxaziclomefone according to claim 4, it is characterized in that: the formulation of described composition is water dispersible granules; This water dispersible granules is comprised of the component of following weight parts: as halosulfuronmethyl 0.5～80 weight portion, oxaziclomefone 0.5～80 weight portion as active component, wetting agent 0.1～10 weight portion as auxiliary agent, dispersant 0.1～10 weight portion as auxiliary agent, disintegrant 0.1～5 weight portion as auxiliary agent, adhesive 0～5 weight portion as auxiliary agent, solid carrier 5～80 weight portions of active component.
8. the Herbicidal combinations containing halosulfuronmethyl and oxaziclomefone according to claim 7, it is characterized in that: this water dispersible granules is comprised of the component of following weight parts: as halosulfuronmethyl 1～60 weight portion, oxaziclomefone 1～60 weight portion as active component, wetting agent 1～8 weight portion as auxiliary agent, dispersant 1～8 weight portion as auxiliary agent, disintegrant 0.3～3 weight portion as auxiliary agent, adhesive 0～3 weight portion as auxiliary agent, solid carrier 10～80 weight portions of active component.
9. the Herbicidal combinations containing halosulfuronmethyl and oxaziclomefone according to claim 4, it is characterized in that: the formulation of described composition is oil-suspending agent; This oil-suspending agent is comprised of the component of following weight parts: as halosulfuronmethyl 0.5～50 weight portion, oxaziclomefone 0.5～50 weight portion as active component, wetting agent 0.1～10 weight portion as auxiliary agent, dispersant 0.1～10 weight portion as auxiliary agent, emulsifier 0.1～10 weight portion as auxiliary agent, thickener 0.1～10 weight portion as auxiliary agent, defoamer 0.1～5 weight portion as auxiliary agent, liquid-carrier 10～90 weight portions of active component.
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| CN106719760A (en) * | 2017-01-22 | 2017-05-31 | 江苏省苏科农化有限责任公司 | Herbicidal composition for rice field and its application |
| CN107027797A (en) * | 2017-05-22 | 2017-08-11 | 安徽蓝田农业开发有限公司 | A kind of herbicidal composition of Han oxaziclomefones and halosulfuronmethyl |
| CN107047591A (en) * | 2017-01-26 | 2017-08-18 | 安徽蓝田农业开发有限公司 | A kind of herbicidal composition of Han oxaziclomefones and promazine Sulfometuron Methyl |
| CN108235991A (en) * | 2016-12-27 | 2018-07-03 | 江苏龙灯化学有限公司 | A kind of Herbicidal combinations and its application |
| CN112674104A (en) * | 2015-12-23 | 2021-04-20 | 江苏龙灯化学有限公司 | Methods of controlling ALS-tolerant plant growth |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4668277A (en) * | 1984-03-22 | 1987-05-26 | Nissan Chemical Industries, Ltd. | Pyrazolesulfonylurea useful for controlling the growth of undesired vegetation |
| EP0605726A1 (en) * | 1992-01-30 | 1994-07-13 | Mitsubishi Petrochemical Co., Ltd. | 1,3-oxazin-4-one derivative, herbicide containing the same, and novel intermediate for producing the same |
| CN1129893A (en) * | 1993-07-13 | 1996-08-28 | 罗纳-布朗克农业化学公司 | Herbicidal compositions |
| CN1393132A (en) * | 2001-06-29 | 2003-01-29 | 浙江乐吉化工股份有限公司 | Composite herbicide for rice field |
-
2013
- 2013-08-29 CN CN2013103836896A patent/CN103430955A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4668277A (en) * | 1984-03-22 | 1987-05-26 | Nissan Chemical Industries, Ltd. | Pyrazolesulfonylurea useful for controlling the growth of undesired vegetation |
| EP0605726A1 (en) * | 1992-01-30 | 1994-07-13 | Mitsubishi Petrochemical Co., Ltd. | 1,3-oxazin-4-one derivative, herbicide containing the same, and novel intermediate for producing the same |
| EP0605726A4 (en) * | 1992-01-30 | 1994-08-17 | Mitsubishi Petrochemical Co | 1,3-oxazin-4-one derivative, herbicide containing the same, and novel intermediate for producing the same. |
| CN1129893A (en) * | 1993-07-13 | 1996-08-28 | 罗纳-布朗克农业化学公司 | Herbicidal compositions |
| CN1393132A (en) * | 2001-06-29 | 2003-01-29 | 浙江乐吉化工股份有限公司 | Composite herbicide for rice field |
Non-Patent Citations (2)
| Title |
|---|
| 无: ""농약 품목명 표준화 내역"", 《생활과 농약》 * |
| 无: ""농약 품목명 표준화 내역"", 《생활과 농약》, 31 March 2008 (2008-03-31) * |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105052974A (en) * | 2015-08-11 | 2015-11-18 | 广东中迅农科股份有限公司 | Pesticide composition containing pyriminobac-methyl, oxaziclomefone and sulfonylurea herbicide |
| CN112674104A (en) * | 2015-12-23 | 2021-04-20 | 江苏龙灯化学有限公司 | Methods of controlling ALS-tolerant plant growth |
| CN108235991A (en) * | 2016-12-27 | 2018-07-03 | 江苏龙灯化学有限公司 | A kind of Herbicidal combinations and its application |
| CN106719760A (en) * | 2017-01-22 | 2017-05-31 | 江苏省苏科农化有限责任公司 | Herbicidal composition for rice field and its application |
| CN107047591A (en) * | 2017-01-26 | 2017-08-18 | 安徽蓝田农业开发有限公司 | A kind of herbicidal composition of Han oxaziclomefones and promazine Sulfometuron Methyl |
| CN107027797A (en) * | 2017-05-22 | 2017-08-11 | 安徽蓝田农业开发有限公司 | A kind of herbicidal composition of Han oxaziclomefones and halosulfuronmethyl |
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Application publication date: 20131211 |