CN102726410A - Pesticide composition containing chlorantraniliprole and tolfenpyrad and application thereof - Google Patents
Pesticide composition containing chlorantraniliprole and tolfenpyrad and application thereof Download PDFInfo
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- CN102726410A CN102726410A CN2012102394051A CN201210239405A CN102726410A CN 102726410 A CN102726410 A CN 102726410A CN 2012102394051 A CN2012102394051 A CN 2012102394051A CN 201210239405 A CN201210239405 A CN 201210239405A CN 102726410 A CN102726410 A CN 102726410A
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Abstract
The invention discloses a pesticide composition containing chlorantraniliprole and tolfenpyrad and an application thereof, relating to a pesticide composition containing chlorantraniliprole and tolfenpyrad as active components. The invention further relates to the application of combining chlorantraniliprole and tolfenpyrad for preventing or controlling insects, and a method for preventing or controlling the insects. The method comprises applying chlorantraniliprole and tolfenpyrad in a combined manner. The pesticide composition containing chlorantraniliprole and tolfenpyrad is characterized by comprising active components of chlorantraniliprole and tolfenpyrad, wherein the weight ratio of the chlorantraniliprole to the tolfenpyrad is 1:100 to 100:1; and the chlorantraniliprole and tolfenpyrad are totally accounted for 50%-90% of the composition in weight.
Description
Technical field
The present invention relates to a kind of chloride worm benzamide and azoles insect amide composition pesticide; The invention still further relates to Rynaxypyr and azoles insect amide unites and is used to prevent or the purposes of Pest Control; And the method for prevention or Pest Control, said method comprises co-administered Rynaxypyr and azoles insect amide.
Background technology
Chemical control is the important means that agricultural goes up prevention and Pest Control.Yet current, by kind, the existence characteristic of insect etc., reasons such as the weak effect that living environment etc. cause, repellence prosperity can not effectively be prevented and kill off sometimes.Particularly to Lepidoptera (Lepidoptera), coleoptera (Coleoptera), Homoptera (Homoptera), thrips (Thysanoptera) insect utilize conventional dose to carry out prevention and control and just become increasingly difficult.Therefore, for can effectively prevent and kill off can not prevent and kill off or prevent and kill off the difficulty pest and seek a kind of new means and method.
Rynaxypyr (Chlorantraniliprole) is the O-formammidotiazol-benzamide insecticide; Chemical name: 3-bromo-N-[4-chloro-2-methyl-6-[(methyl-carbamoyl) benzene]-1-(3-chloropyridine-2-yl)-1-hydrogen-pyridine-5-formamide; Molecular formula: C18H14N5O2BrCl2; Relative molecular weight is: 481, and structural formula is:
Rynaxypyr is the insecticide of a kind of super-active, high-efficiency broad spectrum, and the target of effect is the ryania acceptor, and Rynaxypyr makes insect ryania receptor channel be in lasting open state; Cause calcium ion and in the sarcoplasmic reticulum chamber, discharge in a large number, destroyed the stable of the interior environment of cytoplasm calcium ion, thereby make the imbalance of insect contraction of muscle; Insect stops to get food rapidly in the effect back; Muscular paralysis occurs, be slow in action, paralysis is until last death.Insect eats paralysis from getting, and stops harm, only needs about 7 minutes time.Learn in the characteristic at the different pharmaceutical that Rynaxypyr produces, these change all is to be different from the binding site mediation of ryania on the ryania acceptor by one, and the effect of this insecticide is highly single-minded to insect ryania acceptor, produces to select toxicity.The Rynaxypyr structure is unique, and the mode of action is novel, and insecticidal spectrum is wide, and is efficient to lepidoptera pest, can control coleoptera Culculionidae, Chrysomelidae, diptera Agromyzidae, insects such as Bemisia tabaci simultaneously.And the Rynaxypyr selectivity is good, to various beneficial insects and natural enemies security, and does not have cross resistance with used insecticide, is suitable for the resistance management and the insect comprehensive regulation.
The azoles insect amide (IUPAC:4-chloro-3-ethyl-1-methyl-N-{ [4-(4-methylphenoxy) phenyl]-methyl }-1H pyrazoles-5-carboxylic acid amides) belong to known commercially available Insecticidal pyrazolines, it is a kind of broad spectrum pesticide.The azoles insect amide shows excellent pesticidal effect through the oxidative phosphorylation of blocking-up insect, demonstrates the broad-spectrum insecticidal activity to various pests (for example Semiptera (Hemiptera), coleoptera (Coleoptera), diptera (Diptera), Lepidoptera (Lepidoptera), thrips (Thysanoptera) and mite class).It is active to the prevention and control of the ovum of purpose insect, larva, pupa and adult that the azoles insect amide mainly provides.Its structural formula is following:
At present, also not relevant for report with Rynaxypyr and azoles insect amide Combination application.
Summary of the invention
The present invention seeks to solving above-mentioned at least one problem or its at least one aspect; In particular for effective Pest Control; Through large number of biological test screening, the unexpected discovery of the inventor can be used for effectively prevention or Pest Control with Rynaxypyr and the combination of azoles insect amide.This effect of Combination is good especially.
Therefore, an object of the present invention is to provide a kind of chloride worm benzamide and azoles insect amide composition pesticide and uses thereof, is a kind of composition pesticide that comprises Rynaxypyr and azoles insect amide as active component.
A kind of chloride worm benzamide and azoles insect amide is characterized in that containing active component Rynaxypyr and azoles insect amide as the composition pesticide of active component, and wherein Rynaxypyr and azoles insect amide composition pesticide are than being 1:100-100:1.
A kind of chloride worm benzamide and azoles insect amide composition pesticide, wherein Rynaxypyr and azoles insect amide composition pesticide are than being 1:50-50:1.
A kind of chloride worm benzamide and azoles insect amide composition pesticide, wherein Rynaxypyr and azoles insect amide composition pesticide are than being 1:20-20:1.
A kind of chloride worm benzamide and azoles insect amide composition pesticide, wherein Rynaxypyr and azoles insect amide composition pesticide are than being 1:10-10:1.
A kind of chloride worm benzamide and azoles insect amide composition pesticide, wherein Rynaxypyr and azoles insect amide account for said composition 5%-90% by weight altogether, preferred 10%-80%, more preferably 20%-55%.
Described a kind of chloride worm benzamide and azoles insect amide composition pesticide also comprise additive, solvent, carrier, surfactant or extender.
Described a kind of chloride worm benzamide and azoles insect amide composition pesticide, formulation are missible oil, suspending agent, the agent of kind clothing, aqueous dispersion particle diameter, wetting powder, suspension emulsion, extrude granule, coated granule, aerosol, aqueous emulsion.
Described a kind of chloride worm benzamide and azoles insect amide composition pesticide, wherein said composition also comprises one or more other active components.
In yet another aspect; The present invention also provides a kind of chloride worm benzamide and azoles insect amide composition pesticide to be used to prevent or the purposes of Pest Control, and wherein said insect is selected from Lepidoptera, coleoptera, diptera, Homoptera, Semiptera, Hymenoptera, thrips.
The present invention also provides a kind of chloride worm benzamide and azoles insect amide composition pesticide; Be used to prevent or the purposes of Pest Control, wherein said insect is selected from striped rice borer (Chilo suppressalis (Walker)), paddy stem borer (Tryporyza incertulas (walker)), rice leaf roller (Cnaphalocrocis medinalis Guenee), rice plant skipper (Rice shell pest), aphid (Homoptera), white-backed planthopper (Sogatella furcifera), aphid (Homoptera), brown plant-hopper (Nilaparvata lugens), diamond-back moth (Plutella xylostella), beet armyworm (Laphygma exigua Hubner), the thin moth of golden mosquito (Lithocolletis ringoniella Mats), peach fruit borer (Carposina niponensis Walsingham), thrips (Haplothrips Chinensis Priesner), striped flea-beetle (Phyllotreta spp), pea leaf dive fly (chromatomyiahorticola), yellow-winged cabbage sawfly (athaliarosaeruficornis) etc.
The present invention also provides the method for a kind of prevention or Pest Control, and a kind of chloride worm benzamide and azoles insect amide composition pesticide composition pesticide are acted on plant or crop or grass class and/or insect and/or its environment and/or plant propagation material.Plant propagation material is seedling, rhizome, garden seedling, cutting or seed.In aspect preferred, said method comprises uses the present composition of Rynaxypyr and azoles insect amide to object.In the method for the invention, Rynaxypyr can separate, use successively or simultaneously with the azoles insect amide.
Another object of the present invention provides and a kind ofly is used to prevent or the kit of Pest Control, and it comprises Rynaxypyr and azoles insect amide.
Embodiment
For describing the present invention better, following exemplary is provided.
The inventor finds: not only can bring the additive property for insecticidal spectrum to improve Rynaxypyr and the combination of azoles insect amide, but also realize amazing synergy.
The term that uses among this paper " synergy " refers to the insecticidal effect of activating agent combination of the present invention or composition greater than each activating agent effect sum, and in other words, its effect is a superadditivity.In addition; Also can be referring to the defined effect of Tammes method " Isoboles, a graphic representation of synergism in pesticides ", Netherlands Journal of Plant Pathology; 70 (1964), pages 73-80.
In one embodiment, the invention provides a kind of composition pesticide that comprises Rynaxypyr and azoles insect amide as active component.
In another embodiment; The invention provides a kind of composition pesticide that comprises Rynaxypyr and azoles insect amide as active component; Wherein the weight ratio of Rynaxypyr and azoles insect amide is 1:100-100:1; Preferred 1:50-50:1, for example 1:20-20:1,1:10-10:1 or 1:5-5:1.
In some more particular embodiments, the weight ratio that can be used for above-mentioned two kinds of compounds of the present invention is 90:1-1:90,80:1-1:80,70:1-1:70,60:1-1:60,50:1-1:50 independently of one another; 40:1-1:40,30:1-1:30,25:1-1:25,20:1-1:20,15:1-1:15; 10:1-1:10,9:1-1:9,8:1-1:8,7:1-1:7,6:1-1:6; 5:1-1:5,4:1-1:4,3:1-1:3,2:1-1:2, perhaps 1:1.
The total amount of active compound component can be selected according to material elements in the present composition, to realize desired effect.Said factor for example formulation, is treated subject, application process etc.In one embodiment, Rynaxypyr and azoles insect amide account for said composition 5%-90% by weight altogether, preferred 10%-80%, 20%-55%, 30%-40%.
Composition of the present invention can randomly comprise acceptable additive on the agronomy, solvent, carrier, surfactant or extender.
According to the present invention, term " carrier " refer to can be with reactive compound combined or associating so that it is easier to use the natural or synthetic organic or inorganic compound to object (for example plant, crop or grass type).Therefore, said carrier is preferably inertia, should be agronomically acceptablely at least.Said carrier can be solid or liquid.
Operable not active media both can be that solid also can be a liquid among the present invention; Can be used as for example having that the solid media material uses: the phyteral powdery type (particle of soybean meal, starch, grain dust, wood powder, bark powder, sawdust, walnut shell powder, wheat bran, cellulose powder, coconut husk, corncob and tobacco stem for example; Extract residue behind the plant essence etc.), paper, sawdust, pulverize synthesized polymer body, clay class (for example kaolin, bentonite, acid china clay etc.), the talcum powder class of synthetic resin etc.Silica class (for example diatomite, silica sand, mica, moisture silicic acid; Calcium silicates), chemical fertilizer, the clay fertilizer of active carbon, natural mineral matter class (float stone, attapulgite and zeolite etc.), the inorganic mineral property powder of firing diatomite, sand, plastics media etc. (for example polyethylene, polypropylene, polyvinylidene chloride etc.), potassium chloride, calcium carbonate, calcium phosphate etc., ammonium sulfate, ammonium phosphate, urea, greening ammonium etc., these materials can use separately or use with more than 2 kinds.
Can be used as can in following material, selecting of liquid media material use; Water for example; Alcohol type (for example methyl alcohol, ethanol, isopropyl alcohol, butanols, ethylene glycol etc.), ketone (for example acetone, methyl ethyl ketone, isobutyrone, cyclohexanone etc.), ethers (for example ether, dioxanes, methylcellulose, oxolane etc.), aliphatic hydrocarbon class (for example kerosene, mineral wet goods), aromatic hydrocarbons class (for example benzene,toluene,xylene, solvent naphtha, Fluhyzon, chlorinated aromatic hydrocarbons, chlorinated aliphatic hydrocarbon, chlorobenzene, etc.), halogenated hydrocarbon class, amide-type, sulfone class, dimethyl sulfoxide (DMSO), mineral and vegetable oil, animal wet goods.
As other adjuvants can select to use according to application target, also can use separately, some occasion more than 2 kinds adjuvant share, or some occasion can not used adjuvant fully.For making the emulsification of active ingredient compound; Disperse; Can dissolve; And/or the wetting surfactant that can use for example can enumerate AEO; Polyoxyethylene alkylaryl ether; The polyoxyethylene high-grade aliphatic ester; The phosphate of polyoxyethylene alcohol or phenol; The fatty acid ester of polyalcohol; The alkane aromatic sulfonic acid; The naphthalene sulfonic acids polymer; Lignosulfonates; A dress copolymer of macromolecule comb shape; Butyl naphthalene sulfonate; Alkylaryl sulfonates; The alkyl sodium sulfosuccinate; Grease; Fatty alcohol and ethylene oxide condensate; Polyacrylates such as alkyltaurate; Protein hydrolysate.Suitable oligosaccharide thing or polymer are for example based on independent vinyl monomer, acrylic acid, EO and/or PO or itself and for example combining of (polynary) alcohol or (polynary) amine.
For making active ingredient compound decentralized stabilization, adhering to and/or combine, for example can use adjuvants such as xanthans, aluminium-magnesium silicate, gelatin, starch, methyl cellulose, polyvinyl alcohol, polyvinyl acetate and natural phospholipid (like cephalin and lecithin) and synthetic phospholipid, bentonite, sodium lignin sulfonate.
The optional spent glycol of antifreezing agent wherein, propane diols, glycerine, sorbierite.Deflocculant as the suspension product can use the for example adjuvant of naphthalene sulfonic acids polymer, polymeric phosphate etc.Can use silicone defoaming agent as antifoaming agent.For the flowability of improvement solid product, can use for example adjuvants such as paraffin, stearate, alkylphosphonate.
Operable colouring agent, inorganic pigment for example is like iron oxide, titanium oxide and Prussian blue; And organic pigment/dyestuff: alizarin dyes, azo dyes and metal phthalocyanine dyestuff; And trace element, for example molysite, manganese salt, boron salt, mantoquita, cobalt salt, molybdenum salt and zinc salt.
Randomly, also can comprise other annexing ingredient, for example protecting colloid, adhesive, thickener, thixotropic agent, bleeding agent, stabilizing agent, screening agent.
The formulation of the composition pesticide of said a kind of Rynaxypyr and azoles insect amide is: missible oil; Aerosol; Suspending agent; The micro-capsule granula; Granula subtilis; Concentrate can flow; Promptly use solution; Pulvis; Aqueous emulsion; Oil emu; Fine granule; The agent of oil content loose powder; The miscible mobile concentrate of oil; The miscible liquid of oil; Foaming agent; Paste; Suspending concentrate; Suspension emulsion; Solubility concentrates thing; Plant the clothing agent; Soluble powder; Granule; Water-soluble granular and/or tablet; Water solube powder; Wetting powder; Natural or synthetic material through the reactive compound dipping; Microcapsules in the polymeric material and water-dispersible granule.In preferred embodiments, said composition pesticide is missible oil, suspending agent, water dispersible granules, wetting powder, the agent of kind clothing, suspension emulsion and/or microcapsule suspending agent.
These compositions not only comprise and can be applicable to pending object immediately like spraying or dusting equipment by suitable device, are applied to the concentrated commercial composition that need dilute before the object but also be included in.
Composition of the present invention can be processed the preparation that is suitable for using with the form of the composition of its active compound component, also can be with the administered of the combination of the commodity preparation of its suitable dosage.
Composition of the present invention can also be co-administered with other active component, and said other active component is fungicide, bactericide, attractant, insecticide, miticide, nematocide, growth regulator, weed killer herbicide, safener, fertilizer or semiochemical etc. for example.
In yet another aspect, the invention provides the method for a kind of prevention or Pest Control, comprise combined administration Rynaxypyr and azoles insect amide.
In some preferred embodiments, said insect is selected from: insects such as Lepidoptera, coleoptera, diptera, Homoptera, Hymenoptera, thrips.
Use a technical term among this paper " insect " mean and can comprise for example insect, fungi, nematode, acarid, microorganism etc. the damnous any organism of the normal condition of plant.
Handle plant or crop or grass class with method of the present invention; Perhaps use the said object of compositions-treated of the present invention, can directly carry out, perhaps through acting on its environment through the normal processing method; Habitat or storage areas and carry out; Said normal processing method is directly carried out, perhaps carry out through acting on its environment, habitat or storage areas, said normal processing method as through pouring (dipping), drip irrigation, spraying, evaporation, atomize, broadcast sowing, modes such as dusting, foaming, coating; Perhaps as being used for solvable pulvis, liquid agent, the slurry that seed or rice shoot are handled; And through dry treatment, slurry processing, liquid handling.Can also use said compound through the ultra low volume method, perhaps said compound or composition itself injected soil.
The present invention provides the method for a kind of prevention or Pest Control, comprises Rynaxypyr and azoles insect amide can be separated, successively or the simultaneous system combined administration.
In a preferred embodiment, method of the present invention comprises the present composition that comprises Rynaxypyr and azoles insect amide is used to object.
The composition pesticide of chloride worm benzamide of the present invention and azoles insect amide, its amount of application, according to cooperation ratio, meteorological condition, the medicament form of active ingredient, use period, application process, use the place, prevent and kill off the difference of target pest etc. and variant:
It is common with favourable that composition of the present invention or surfactant composition are used with following dosage usually:
Handle for leaf portion: 0.1-10000 g/ha, preferred 10-1000 g/ha, more preferably 50-300 g/ha; For dipping or instil use for, said dosage even can also reduce is particularly when using inert base such as asbestos or pearl rock;
Handling (preferred seed processing) for plant propagation material handles: 2-200 g/100kg seed, preferred 3-150 g/100kg seed;
For soil treatment: 0.1-10000 g/ha, preferred 1-5000 g/ha.
Above-mentioned dosage only is general exemplary dose, and those skilled in the art can especially adjust rate of application according to character and the insect pest situation of pending plant or crop according to actual conditions and needs during actual using.
Activating agent of the present invention has good plant compatibility, is suitable for Pest Control, and it preferably acts on the composition of leaf processing, soil treatment and seed, rice shoot processing.
The combination of activating agent of the present invention is usually for responsive all effective with species and whole or single developmental stage with resistance.Said insect for example comprises:
Insects such as Lepidoptera, coleoptera, diptera, Homoptera, Semiptera, Hymenoptera, thrips.
Lepidoptera pest for example comprises: striped rice borer (chilosuppressalis (walker)); Paddy stem borer (Tryporyzaincertulas (walker)); Rice leaf roller (cnaphalocrocismedinalisGuenee); Cabbage heart snout moth's larva (hellullaundalis); Dichocrocis punctiferalis (conogethespunctiferlis); Papilio xuthus Linnaeus (papilioxuthus); Small cabbage white moth (pierisrapaecrucivora); Straight burr rice hesperiidae (parnaraguttata); Tent caterpillar (malacosoma Neustria testacea); Gypsymoth (lymantriadispar); Fall webworm (hyphantriacunea); East poison moth (euproctissubflava); Black line slug moth (scopelodescontracus); Cotton bollworm (helicoverpaarmigera); Pectinophora gossypiella; Cabbage looper (trichoplusiani); Tomato moth (mamestrabrassicae); Beet armyworm (spodopteraexigua); Prodenia litura (spodopteralitura); Tea olethreutid (adoxophyesoranafasciata); Leaf roller (adoxophyeshonmai); Apricot yellow volume moth (archipsfuscocureanus); Tea long paper moth (homonamagnanima); Diamond-back moth (plutellaxylotella); Pink bollworm (pectinophoragossypiella); The gold thin moth of mosquito (Lithocolletis ringoniella Mats); Peach fruit borer (Carposina niponensis Walsingham).
Coleopteran pest for example comprises: rice weevil (sitophilusoryzaelinne), corn weevil (S.zeamails), grain weevil (S.granarius), big daikon leaf beetle (Cabbageleafbeetle), daicon leaf beetle (Daikon leaf beele), flea beetle (fleabeetle), grape flea beetle (Alticachalybea), cabbage flea beetle (phyllotretastriolata), cucumber flea beetle (Epitrixcucumeris), tobacco flea beetle (Ehirtipennis), eggplant flea beetle (E.fuscula), aulacophora femoralis (Aulacophoraindica (Gemlin), striped flea-beetle (Phyllotreta spp).
Diptera pest for example comprises: the rice fly (agromyzaoryzae) of diving; Hydrellia griseola (hydrelliagriseola); Flameray gerbera liriomyza bryoniae (liriomyzatrifolii); The pea leaf fly (chromatomyiahorticola) of diving; Tomato liriomyza bryoniae (liriomyzabryoniae); Delia platura (deliaplatura); Fly (deliaantiqua) Mediterranean fruitfly (ceratitiscapiatawiedgman) is planted on green onion ground; Rhagoletis pomonella (Rhagoletispomonella); Cherry fruit fly (R.cingulata).
The Semiptera insect for example comprises: smelly stinkbug (megacoptapunctatissimum); Cabbage bug (eurydemarugosum); Big thorn white star stinkbug (eysarcorislewisi); White star stinkbug (eysarcorisparvus); Green rice bug (nezaraviridula); Si Shi amber stinkbug (plautiastali); Clerodendron trichotomum stinkbug (halymorphamista); Rice spiny coreid (cletuspunctiger); China's Leptocorisa spp (leptocorisachinensis); Cuckoo lace bug (stephantispyrioides); Red palpus fleahopper (trigonotyluscoelestialium).
Homoptera pest comprises for example rice leafhopper (nephotettixcincticeps), small brown rice planthopper (laodelphaxstriatellus), brown plant-hopper (nilaparvatalugens), white-backed planthopper (sogatellafurcifera), pear sucker (psyllapyrisuga), oranges and tangerines wood louse (diaphorinatabaci), Bemisia tabaci (bemisiatabaci), aphid (homoptera), apple aphid (eriosomalanigerum).
Yellow-winged cabbage sawfly (athaliarosaeruficornis), rose sawfly (argepagana), Black Hills ant (formicajaponica), chestnut cynipid (dryocsmuskuriphilus) etc. are arranged in the Hymenoptera (hymenoptera).
Thrips insect, for example thrips (HaplothripsChinensisPriesner)
Object plant that the present invention is suitable for or crop or grass class do not have special qualification; For example specifiable vegetable oil cereal (rice, barley, wheat, rye, oat, corn etc.), beans (soybean, red bean, broad bean, pea, French beans, peanut etc.), fruit tree kind (apple, citrus, pears, grape, walnut, chestnut, banana, strawberry etc.), leaf vegetables, Cruciferae class (wild cabbage, Chinese cabbage, broccoli), fruit class (cabbage, tomato, spinach, cauliflower, romaine lettuce, onion, green pepper, eggplant, pepper etc.), root vegetables (carrot, potato, sweet potato, taro, radish, garlic etc.), processing are appreciated with crops (lavender, thyme, ginger etc.), flowers class (chrysanthemum, carnation, orchid, rose etc.), flower garden trees, forest (ginkgo, cherry, coral, fir class, dragon spruce class, pine tree class, Thujopsis dolabrata class, Chinese fir etc.), turf with crops (cotton, fiber crops, beet, lupulus, sugarcane, beet, coffee etc.), spices etc.
Composition of the present invention can directly use when prevent and kill off insect pests or water etc. carries out suitable dilution, or when suspended state uses, can predict pest earlier, except its leaves and stems sprays, also can carry out seed is immersed in the medicament, powder clothing seed, covers calper calcium peroxide processing etc., the mixing of soil holostrome, seed furrow and use etc., soil etc. is handled made it absorb use from root.Should be pointed out that in the method for the invention Rynaxypyr can separate, use successively or simultaneously with the azoles insect amide.
The method of seed treatment; For example can enumerate; The medicament of diluent liquid or solid, shaped or need not dilute directly seed is immersed in the method that makes medicament soak into seed in the liquid condition solution, solid chemicals or liquid preparation are mixed with seed carries out the powder clothing and handles the method that makes the surface of the seed adhere to medicament, method such as when planting, near seed, sprays.The seed that carries out this seed treatment is meant the plant corpus at the cultivation initial stage that is used for plant propagation, for example can enumerate, outside the seed, napiform root, stem tuber, potato kind, strain bud, the plant corpus of the usefulness of nourishing and generating of the bulb or the cultivation usefulness of transplanting.
Soil of said plant or cultivation media are meant the supporter that can make crops take root, grow when method for using of the present invention is implemented; For example: soil; Water etc., concrete raw material can use for example sand, float stone, vermiculite, diatomite, agar-agar, gelling material, polymer substance, asbestos, wood chip, bark etc.
In soil, use the method for medicament; For example be diluted in liquid preparation in the water or do not dilute the root that directly is applied to plant corpus or the medium method in rice seedling bed that seedling is used; Method in the rice seedling bed of root or seedling of plant corpus that granule is disseminated to have prior to seeding with pulvis, water dispersible granules etc. be sprayed in the soil and with the whole method of mixing of soil; Before the sowing or before the serike body with being sprayed in implantation hole, the seed furrow behind pulvis, the water-dispersible grain dilution agent, in the method for sowing etc.
In one embodiment, the present invention also provides seed or the seedling that crosses with Rynaxypyr and azoles insect amide combined treatment.In a concrete embodiment, the invention provides the seed or the seedling of handling with agrochemical composition of the present invention.
In another embodiment, the present invention also provides a kind of kit that is used for the prevention and control insect, and it comprises Rynaxypyr and azoles insect amide.
Should be pointed out that on the meaning of the present invention that term " Rynaxypyr and the combination of azoles insect amide " comprises and separates, uses successively or simultaneously Rynaxypyr and azoles insect amide.Preferably, said Rynaxypyr and azoles insect amide are combined as the form of the composition that comprises Rynaxypyr and azoles insect amide.
Any technical characterictic that should be pointed out that any embodiment of the present invention or embodiment can be independently and any other embodiment combination with one another of the present invention.That is to say that one or more technical characterictics of any embodiment of the present invention all can reconfigure with any other technical characterictic.Thus technical characterictic reconfigure and the technical characterictic that forms openly in this article, its special record is the same in this article.
Enforcement through following illustrates the present invention, yet, should be appreciated that the present invention is not limited to given embodiment.
Embodiment
Embodiment 1 2% Rynaxypyr+10% azoles insect amide missible oil
Rynaxypyr 2%
Azoles insect amide 10%
Ethoxylated castor oil 6%
Calcium salt of dodecylbenzene sulfonate 3%
Solvesso 100 complements to 100%
Said components is stirred the solution that obtains clear, promptly obtain 2% Rynaxypyr+10% azoles insect amide missible oil.
Embodiment 2 20% Rynaxypyrs+4% azoles insect amide wetting powder
Rynaxypyr 20%
Azoles insect amide 4%
Lauryl sodium sulfate 2%
Sodium lignin sulfonate 5%
White carbon 10%
Kaolin complements to 100%
Ratio composition in prescription such as active component, various auxiliary agent and filler is mixed, after ultrafine crusher is pulverized, promptly obtain 20% Rynaxypyr+4% azoles insect amide wetting powder.
Embodiment 3 0.2% Rynaxypyrs+20% azoles insect amide aqueous emulsion
Rynaxypyr 0.2%
Azoles insect amide 20%
N-Methyl pyrrolidone 15%
Neopelex 5%
The newborn 600# 5% of farming
Water complements to 100%
Former medicine, solvent, emulsifier are added together, make and be dissolved into even oil phase; With water-soluble component and the mixed water that gets of water; Under high-speed stirred, oil phase is mixed with water, make 0.2% Rynaxypyr+20% azoles insect amide aqueous emulsion
Embodiment 4 3.5% Rynaxypyrs+1.5% azoles insect amide water dispersible granules
Rynaxypyr 3.5%
Azoles insect amide 1.5%
Sodium lignin sulfonate 5%
Lauryl sodium sulfate 2%
Urea 10%
Kaolin complements to 100%
Active component, dispersant, wetting agent, disintegrant and filler is even by the mixed of prescription, become wetting powder through comminution by gas stream, add the granulation of a certain amount of water extrusion again.After dry screened, obtain 5% Rynaxypyr+azoles insect amide water dispersible granules.
Embodiment 5 20% Rynaxypyrs+0.2% azoles insect amide suspending agent
Rynaxypyr 20%
Azoles insect amide 0.2%
Methyl naphthalene sulfonate formaldehyde condensate 15%
Dioctyl sodium sulfosuccinate 5%
Xanthans 0.3%
Propane diols 5%
Antifoaming agent 0.6%
Water complements to 100%
Each component such as active component, dispersant, wetting agent and water is even according to the mixed of prescription, after grinding and/or high speed shear, obtain 20% Rynaxypyr+0.2% azoles insect amide suspending agent.
Embodiment 6 7.5% Rynaxypyrs+2.5% azoles insect amide suspending agent
Rynaxypyr 7.5%
Azoles insect amide 2.5%
Methyl naphthalene sulfonate formaldehyde condensate 10%
Dioctyl sodium sulfosuccinate 4%
Xanthans 0.3%
Propane diols 5%
Antifoaming agent 0.6%
Water complements to 100%
Each component such as active component, dispersant, wetting agent and water is even by the mixed of prescription, after grinding and/or high speed shear, obtain 7.5% Rynaxypyr+2.5% azoles insect amide suspending agent.
Embodiment 7 1% Rynaxypyrs+10% azoles insect amide wetting powder
Rynaxypyr 1%
Azoles insect amide 10%
Lauryl sodium sulfate 10%
Sodium lignin sulfonate 5%
White carbon 10%
Kaolin complements to 100%
Ratio composition in prescription such as active component, various auxiliary agent and filler is mixed, after ultrafine crusher is pulverized, promptly obtains 1% Rynaxypyr+10% azoles insect amide wetting powder.
Embodiment 8 50% Rynaxypyrs+1% azoles insect amide suspending agent
Rynaxypyr 50%
Azoles insect amide 1%
AEO sulfosuccinic acid monoesters disodium 10%
MODIFIED LIGNOSULPHONATE 5%
Xanthans 0.3%
Bentonite 1%
Propane diols 5%
Antifoaming agent 0.6%
Water complements to 100%
Above-mentioned each component is mixed in proportion, and, be prepared into suspending agent through sand milling.
Embodiment 9 30% Rynaxypyrs+20% azoles insect amide aqueous emulsion
Oil phase:
Rynaxypyr 30%
Azoles insect amide 20%
Methyl oleate 40%
Polystyrene 3.7%
Water:
Xanthans 0.07%
The sodium salt 1% of the naphthalene sulfonic acids-formaldehyde condensation products of sulfonation
Bactericide 0.2%
Water complements to 100%
Rynaxypyr and azoles insect amide are dissolved in the methyl oleate, add polystyrene and obtain oil phase; Component according in the prescription mixes and obtains water; Under agitation oil phase is added water and obtain aqueous emulsion.
Embodiment 10 20% Rynaxypyrs+1% azoles insect amide wetting powder
Rynaxypyr 20%
Azoles insect amide 1%
Sodium lignin sulfonate 5%
NaLS 2%
The silicic acid 1% of high degree of dispersion
Kaolin complements to 100%
Combinations thereof is mixed in proportion, and grind, pulverize, be prepared into wetting powder.
Embodiment 11 1% Rynaxypyrs+20% azoles insect amide coated granule
Rynaxypyr 1%
Azoles insect amide 20%
Polyethylene glycol 3%
The silicic acid 1% of high degree of dispersion
Calcium carbonate complements to 100%
In blender, levigate active component evenly is applied to by on the wetting carrier of polyethylene glycol.Can obtain dustless coated granule in this way.
Embodiment 12 60% Rynaxypyrs+30% azoles insect amide wetting powder
Rynaxypyr 60%
Azoles insect amide 30%
Sodium lignin sulfonate 2%
Dodecyl sodium sulfate 1%
Kaolin complements to 100%
Said components is mixed in proportion, and grind, pulverize, be prepared into wetting powder.
Embodiment 13 20% Rynaxypyrs+40% azoles insect amide is extruded granule
Rynaxypyr 50%
Azoles insect amide 5%
Sodium lignin sulfonate 4%
Carboxymethyl cellulose 2%
White carbon 5%
Kaolin complements to 100%
Active component is mixed with auxiliary agent and ground, and the mixture water is moistening.This mixture is extruded, dry in air flow then.
Embodiment 14 1% Rynaxypyrs+50% azoles insect amide suspending agent
Rynaxypyr 1%
Azoles insect amide 50%
AEO sulfosuccinic acid monoesters disodium 10%
EO/PO block copolymer 10%
Xanthans 0.5%
Bentonite 1%
Glycerine 5%
Antifoaming agent 0.6%
Water complements to 100%
Above-mentioned each component is mixed in proportion, and, be prepared into suspending agent through sand milling.
Embodiment 15 10% Rynaxypyrs+20% azoles insect amide suspending agent
Rynaxypyr 10%
Azoles insect amide 20%
AEO sulfosuccinic acid monoesters disodium 10%
Modified lignin resin sodium sulfonate 5%
Xanthans 0.5%
Glycerine 5%
Antifoaming agent 0.6%
Water complements to 100%
Above-mentioned each component is mixed in proportion, and, be prepared into suspending agent through sand milling.
Embodiment 16 5% Rynaxypyrs+15% azoles insect amide suspension emulsion
Rynaxypyr 5%
Azoles insect amide 15%
Solvesso?200 30%
Ethoxylated castor oil 4%
AEO sulfosuccinic acid monoesters disodium 10
MODIFIED LIGNOSULPHONATE 5%
Xanthans 0.5%
Bentonite 1%
Glycerine 5%
Antifoaming agent 0.6%
Water complements to 100%
The azoles insect amide is dissolved among the Solvesso 200, adds ethoxylated castor oil, obtain azoles insect amide missible oil; With Rynaxypyr, AEO sulfosuccinic acid monoesters disodium, MODIFIED LIGNOSULPHONATE, xanthans, bentonite, glycerine, above-mentioned each component such as water mixes in proportion, and through sand milling, is prepared into suspending agent.
The oil phase of azoles insect amide is joined in the suspending agent of chloride worm benzamide, obtain suspended emulsion.
Embodiment 17 10% Rynaxypyrs+10% azoles insect amide suspension seed-coating agent
Rynaxypyr 10%
Azoles insect amide 10%
AEO sulfosuccinic acid monoesters disodium 10%
Modified lignin resin sodium sulfonate 5%
Xanthans 0.5%
Glycerine 5%
Polyvinylpyrrolidone (PVP-K30) 1%
Antifoaming agent 0.6%
Water complements to 100%
Above-mentioned each component is mixed in proportion, and, be prepared into suspension seed-coating agent through sand milling.
Embodiment 18 40% Rynaxypyrs+40% azoles insect amide aerosol
Rynaxypyr 40%
Azoles insect amide 40%
Propane diols 5%
Phosphoric acid ester 3.5%
The castor oil of ethoxylation (EL-40) 2.0%
Solvesso 100 complements to 100%
At first with the antifreezing agent propane diols, thinner SOLVESSO 100 mixes, and stirs to add Rynaxypyr and azoles insect amide down; Surfactant is added wherein, under agitation pulverize through a breaking plant colloid mill, will be through the suspension behind the colloid mill, again through a micronizer.Move in circles till the particle diameter≤2um of solids.
Test Example 1
The rice leaf folder test
On rice crop, handle through spraying with the dilution of the required application concentration of embodiment 1-16, and under the still wetting situation of blade, move into the rice leaf folder larva.After the required time, confirm the killing rate of representing with the % form.100% is meant and has killed all larvas; 0% is meant and does not kill larva.
| Handle | G active component/hectare | Lethality/% (7 days) |
| Embodiment 1 (2% Rynaxypyr+10% azoles insect amide missible oil) | 15 | 93 |
| Embodiment 2 (20% Rynaxypyr+4% azoles insect amide wetting powder) | 15 | 92 |
| Embodiment 3 (0.2% Rynaxypyr+20% azoles insect amide aqueous emulsion) | 15 | 96 |
| Embodiment 4 (3.5% Rynaxypyr+1.5% azoles insect amide water dispersible granules) | 15 | 92 |
| Embodiment 5 (20% Rynaxypyr+0.2% azoles insect amide suspending agent) | 15 | 91 |
| Embodiment 6 (7.5% Rynaxypyr+2.5% azoles insect amide suspending agent) | 15 | 90 |
| Embodiment 7 (1% Rynaxypyr+10% azoles insect amide wetting powder) | 15 | 91 |
| Embodiment 8 (50% Rynaxypyr+1% azoles insect amide suspending agent) | 15 | 93 |
| Embodiment 9 (30% Rynaxypyr+20% azoles insect amide aqueous emulsion) | 15 | 95 |
| Embodiment 10 (20% Rynaxypyr+1% azoles insect amide wetting powder) | 15 | 95 |
| Embodiment 11 (1% Rynaxypyr+20% azoles insect amide coated granule) | 15 | 93 |
| Embodiment 12 (60% Rynaxypyr+30% azoles insect amide wetting powder) | 15 | 92 |
| Embodiment 13 (20% Rynaxypyr+40% azoles insect amide is extruded granule) | 15 | 95 |
| Embodiment 14 (1% Rynaxypyr+50% azoles insect amide suspending agent) | 15 | 91 |
| Embodiment 15 (10% Rynaxypyr+20% azoles insect amide suspending agent) | 15 | 90 |
| Embodiment 16 (5% Rynaxypyr+15% azoles insect amide suspension emulsion) | 15 | 89 |
| 200g/L Rynaxypyr suspending agent | 30 | 80 |
| 15% azoles insect amide missible oil | 120 | 60 |
Can know that by last table the synergistic effect of the composite back of Rynaxypyr and azoles insect amide is obvious, the preventive effect of paddy rice rice leaf roller obviously is better than single agent.And active ingredient obviously reduces, thereby has alleviated environmental pollution.
Test Example 2
The test of paddy rice paddy stem borer
On rice crop, handle through spraying with the dilution of the required application concentration of embodiment 1-16, and under the still wetting situation of blade, move into paddy rice paddy stem borer larva.After the required time, confirm the killing rate of representing with the % form.100% is meant and has killed all larvas; 0% is meant and does not kill larva.
Can know that by last table the synergistic effect of the composite back of Rynaxypyr and azoles insect amide is obvious, the preventive effect of paddy rice paddy stem borer obviously is better than single agent.And the consumption of active ingredient obviously reduces, thereby has alleviated environmental pollution.
Test Example 3
The test of wild cabbage beet armyworm
On the wild cabbage crop, handle through spraying with the dilution of the required application concentration of embodiment 1-16, and under the still wetting situation of blade, move into the larva of beet armyworm.After the required time, confirm the killing rate of representing with the % form.100% is meant and has killed all larvas; 0% is meant and does not kill larva.
Can know that by last table the synergistic effect of the composite back of Rynaxypyr and azoles insect amide is obvious, the preventive effect of beet armyworm obviously is better than single agent.And the consumption of active ingredient obviously reduces, thereby has alleviated environmental pollution.
Test Example 4
The latent fly experiment of pea leaf
On pea, handle through spraying with the dilution of the required application concentration of embodiment 1-16, and under the still wetting situation of blade, move into the latent fly larva of pea leaf.After the required time, confirm the killing rate represented with the % form, 100 are meant and have killed all larvas; 0% is meant and does not kill larva.
Can know that by last table the synergistic effect of the composite back of Rynaxypyr and azoles insect amide is obvious, the dive preventive effect of fly of pea leaf obviously is better than single agent.And the consumption of active ingredient obviously reduces, thereby has alleviated environmental pollution.
Test Example 5
The conventional method F1 of liquid seed dressing
The liquid preparation of aequum is added in the conical flask.Shaking flasks makes liquid distribution arrive the whole bottom of container.The seed that in bottle, adds aequum afterwards immediately.With about 1 minute of the violent shaking flasks of hand so that all seeds are all covered by liquid.Be poured on the drying frame content of flask and at the baking oven inner drying.
The conventional method F2 of dry mixing kind
Give the same number of kind of benevolence of packing in the wide-mouth bottle to each, and a certain amount of solid pharmaceutical preparation of in every bottle, packing into, to obtain 0.3mg active ingredient/kind of the benevolence of aequum.Flask is placed on the roller with 80 rev/mins speed choosing adorns 3 minutes.With hand moving flask, the kind benevolence that is bonded on the flask walls is fallen down, then with flask opposite spin 3 minutes.
Seed dressing is to the effect of the striped flea-beetle larva on the little green vegetables root
With program F1 and the said little green vegetables planting seed of handling of F2 kind.After planting 10 days, put 5 striped flea-beetle larvas in each growing tank bottom in all cases.Invade and harass and assess after 6 days.The number of the instar (larva and pupa) that survives in stem, soil surface and the soil of record plant.
Can know that by last table the synergistic effect of the composite back of Rynaxypyr and azoles insect amide is obvious, the effect preventive effect of the striped flea-beetle larva on the little green vegetables root obviously is better than single agent.
Test Example 6
The conventional method F1 of liquid seed dressing
The liquid preparation of aequum is added in the conical flask.Shaking flasks makes liquid distribution arrive the whole bottom of container.The seed that in bottle, adds aequum afterwards immediately.With about 1 minute of the violent shaking flasks of hand so that all seeds are all covered by liquid.Be poured on the drying frame content of flask and at the baking oven inner drying.
The conventional method F2 of dry mixing kind
Give the same number of kind of benevolence of packing in the wide-mouth bottle to each, and a certain amount of solid pharmaceutical preparation of in every bottle, packing into, to obtain 0.3mg active ingredient/kind of the benevolence of aequum.Flask is placed on the roller with 80 rev/mins speed rotation 3 minutes.With hand moving flask, the kind benevolence that is bonded on the flask walls is fallen down, then with flask opposite spin 3 minutes.
Seed dressing is to the effect of the first-instar young of beet armyworm on the maize leaves
With program F1 and the said corn seed sowing of handling of F2 kind.After planting 26 days, the long part of 5-8cm of getting plant top blade was placed in the glass beaker and with 10 beet armyworm first-instar youngs that just hatched and infects.With the cap covers beaker and remain on 25
OUnder C and the 60% relative atmospheric humidity, illumination every day 16 hours.Assess after infecting 3-5.The larva number of surviving on the plant that record grows up to.
Can know that by last table the synergistic effect of the composite back of Rynaxypyr and azoles insect amide is obvious, the first-instar young of beet armyworm on the maize leaves is had good preventive effect.
Test Example 7
The test of eggplant thrips
On the eggplant crop, handle through spraying with the dilution of the required application concentration of embodiment 1-16, and under the still wetting situation of blade, move into eggplant thrips larva.After the required time, confirm the killing rate represented with the % form, 100 are meant and have killed all larvas; 0% is meant and does not kill larva.
Can know that by last table the synergistic effect of the composite back of Rynaxypyr and azoles insect amide is obvious, the preventive effect of eggplant thrips obviously is better than single agent.And the consumption of active ingredient obviously reduces, thereby has alleviated environmental pollution.
Test Example 8
The test of apple tree peach fruit borer
On apple tree, handle through spraying with the dilution of the required application concentration of embodiment 1-16, and under the still wetting situation of blade, move into the peach fruit borer larva.After the required time, confirm the killing rate represented with the % form, 100 are meant and have killed all larvas; 0% is meant and does not kill larva.
Can know that by last table the synergistic effect of the composite back of Rynaxypyr and azoles insect amide is obvious, the preventive effect of apple tree peach fruit borer obviously is better than single agent.And the consumption of active ingredient obviously reduces, thereby has alleviated environmental pollution.
Embodiment 9 soil treatment
Mixed soil 2: sand 1: saprophage soil 1 preparation experiment soil, the 200g soil of packing in each 300ml plastic container adds the larva of putting 10 striped flea-beetles in mix embodiment 1-16 and 18. each container with the concentration of regulation, and is dark down 25
OAfter C constant temperature left standstill, after the required time, the soil that scatter was confirmed the killing rate of representing with the % form.100% is meant and has killed all larvas; 0% is meant and does not kill larva.
Can know that by last table the synergistic effect of the composite back of Rynaxypyr and azoles insect amide is obvious, when being used for soil treatment, the striped flea-beetle preventive effect obviously is better than single agent.And the consumption of active ingredient obviously reduces, thereby has alleviated environmental pollution.
The experiment of embodiment 10 cotton cotten aphids
At cotton in seedling stage, handle through spraying with the dilution of the required application concentration of embodiment 1-16, and under the still wetting situation of blade, move into.After the required time, confirm the killing rate represented with the % form, 100 are meant and have killed all larvas; 0% is meant and does not kill larva.
Can know that by last table the synergistic effect of the composite back of Rynaxypyr and azoles insect amide is obvious, the preventive effect of cotton cotton aphid obviously is better than single agent.And the consumption of active ingredient obviously reduces, thereby has alleviated environmental pollution.
The experiment of embodiment 11 yellow-winged cabbage sawflies
On the wild cabbage crop, handle through spraying with the dilution of the required application concentration of embodiment 1-16, and under the still wetting situation of blade, move into the larva of yellow-winged cabbage sawfly.After the required time, confirm the killing rate of representing with the % form.100% is meant and has killed all larvas; 0% is meant and does not kill larva.
Can know that by last table the synergistic effect of the composite back of Rynaxypyr and azoles insect amide is obvious, the preventive effect of yellow-winged cabbage sawfly obviously is better than single agent.And the consumption of active ingredient obviously reduces, thereby has alleviated environmental pollution.
Claims (18)
1. the composition pesticide of chloride worm benzamide and azoles insect amide, it is characterized in that: contain active component Rynaxypyr and azoles insect amide, wherein the weight ratio of Rynaxypyr and azoles insect amide is: 1:100-100:1.
2. the composition pesticide of a kind of chloride worm benzamide according to claim 1 and azoles insect amide, it is characterized in that: the weight ratio of said Rynaxypyr and azoles insect amide is 1:50-50:1.
3. the composition pesticide of a kind of chloride worm benzamide according to claim 1 and azoles insect amide, it is characterized in that: the weight ratio of said Rynaxypyr and azoles insect amide is 1:20-20:1.
4. the composition pesticide of a kind of chloride worm benzamide according to claim 1 and azoles insect amide, it is characterized in that: the weight ratio of said Rynaxypyr and azoles insect amide is 1:10-10:1.
5. according to described a kind of chloride worm benzamide of claim 1-4 and azoles insect amide composition pesticide, it is characterized in that: said Rynaxypyr and azoles insect amide account for said composition 5%-90% by weight altogether.
6. a kind of chloride worm benzamide according to claim 5 and azoles insect amide composition pesticide, it is characterized in that: said Rynaxypyr and azoles insect amide account for said composition 10%-80% by weight altogether.
7. according to described a kind of chloride worm benzamide of claim 1-6 and azoles insect amide composition pesticide, it is characterized in that: said Rynaxypyr and azoles insect amide account for said composition 20%-55% by weight altogether.
8. according to each described a kind of chloride worm benzamide and azoles insect amide composition pesticide in the aforementioned claim, it is characterized in that: also comprise additive, solvent, carrier, surfactant or extender.
9. according to each described a kind of Rynaxypyr and azoles insect amide composition pesticide in the aforementioned claim, it is characterized in that: said formulation is missible oil, suspending agent, the agent of kind clothing, aqueous dispersion particle diameter, wetting powder, suspension emulsion, extrudes granule, coated granule, aerosol, aqueous emulsion.
10. chloride worm benzamide and azoles insect amide composition pesticide, it is characterized in that: wherein said composition also comprises one or more other active components.
11. the described composition pesticide of claim 1 is used to prevent or the purposes of Pest Control.
12. the prevention or the method for Pest Control is characterized in that, the composition pesticide of claim 1 is acted on crop and/or insect and/or its environment and/or plant propagation material.
13. method according to claim 12 is characterized in that: said plant propagation material is seedling, rhizome, garden seedling, cutting or seed.
14. the prevention or the method for Pest Control is characterized in that: co-administered Rynaxypyr and azoles insect amide.
15. method according to claim 14 is characterized in that: comprise separately, use successively or simultaneously Rynaxypyr and azoles insect amide.
16. according to claim 11,12 or 14 described methods, it is characterized in that: wherein said insect is selected from Lepidoptera, coleoptera, diptera, Homoptera, Semiptera, Hymenoptera, thrips.
17. according to claim 11,12 or 14 described methods, it is characterized in that: said insect is selected from striped rice borer (Chilo suppressalis (Walker)), paddy stem borer (Tryporyza incertulas (walker)), rice leaf roller (Cnaphalocrocis medinalis Guenee), rice plant skipper (Rice shell pest), aphid (Homoptera), white-backed planthopper (Sogatella furcifera), aphid (Homoptera), brown plant-hopper (Nilaparvata lugens), diamond-back moth (Plutella xylostella), beet armyworm (Laphygma exigua Hubner), the thin moth of golden mosquito (Lithocolletis ringoniella Mats), peach fruit borer (Carposina niponensis Walsingham), thrips (Haplothrips Chinensis Priesner), striped flea-beetle (Phyllotreta spp), the latent fly (chromatomyiahorticola) of pea leaf, yellow-winged cabbage sawfly (athaliarosaeruficornis).
18. one kind is used to prevent or the kit of Pest Control, it comprises Rynaxypyr and azoles insect amide.
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