CN103396689A - LED-UV light source curable coating and preparation method - Google Patents
LED-UV light source curable coating and preparation method Download PDFInfo
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Abstract
The invention discloses an LED-UV light curable coating, comprising the following ingredients by mass: 30-65% of an acrylate oligomer, 20-50% of an active diluent, 2-8% of a photoinitiator, 0-30% of a color filler, 0.2-3% of an auxiliary agent and 2-10% of an assist photosensitizer, wherein the photoinitiator is one or more photoinitiators with characteristic absorption wavelengths of 365 nm and 395 nm. The coating prepared by the invention can effectively utilize an ultraviolet light source of LED-UV, saves energy, is fast in curable speed, and has excellent film-coating performance and environmental protection.
Description
Technical field
The present invention relates to paint field, specifically a kind of LED-UV light source is coating material solidified and preparation method thereof.
Background technology
Over nearly 40 years, be accompanied by the development of UV curing technology, the mesohigh mercury lamp of inflation as ultraviolet source always in occupation of dominant position.In recent years, though the appearance of micro-wave nonpolar lamp, mercury-xenon UV lamp and Excimer uv lamp is arranged, do not shake mesohigh (China is actually middle pressure) mercury lamp dominant position in UV-curing technology.But the UV-light luminous efficiency of this mercury lamp is extremely low, probably at 10-15%, to remaining invalid light wave, is the light source system of a power consumption.
Although it is efficient, energy-conservation that the development of UV brings the most progressive to traditional curing industry, but at present energy-conservation LED technology is solidified field or rudiment at UV, as the most promising ultraviolet-curing paint, LED-UV will bring the Industrial Revolution of new industry.
The LED-UV light-source structure is simple, rapidity, stability, security with its processing, and the quality of product and low cost (equipment cost is not widely applied at present and is not improved, the volume production application can impel decline), for ultraviolet photocureable material has brought new application, reduced to greatest extent electrisity consumption, energy-conserving and environment-protective.Semiconductor LED-UV light source is with its efficient, compact, strong adaptability, and the traditional ultraviolet source of forward has proposed challenge, has eliminated heat effect, electromagnetic interference, process unstable and the danger of traditional mercury lamp.But because the LED-UV light source has constant ultraviolet wavelength, require UV curing system must have good absorption UV-light, and the UV-light photochemical reaction occurs and crosslinked film forming is solidified.So develop its coating that solidifies, also just there isd brighter future, this sunrise industry is promoted more, and development prospect is full of pure hope.
Summary of the invention
The purpose of this invention is to provide a kind of LED-UV light source coating material solidified and preparation method thereof, solve the existing problem that the coating material solidified uv-absorbing efficiency of UV is low, preparation cost is higher.
For addressing the above problem, the present invention by the following technical solutions:
A kind of LED-UV light source is coating material solidified, comprises following component, by mass percentage:
Wherein, described light trigger is one or more of light trigger of 365nm, 395nm characteristic absorption wavelength.
Further, described 395nm characteristic absorption wavelength light trigger is 2,4,6-trimethylbenzoyl diphenyl phosphate oxidation (TPO); Described 365nm characteristic absorption wavelength light trigger is isopropyl thioxanthone (ITX), 2,4-diethyl thioxanthone (DETX) or tetraethyl-michaelis ketone (EMK).
Further, described acrylate quasi-oligomer comprises one or more of epoxy acrylate, urethane acrylate, polyester acrylate, amino acrylates.
Further, described reactive thinner is one or more of acrylic ester monomer, vinyl ethers monomer.
Further, described acrylic ester monomer comprises one or more of Viscoat 295 (TMPTA), ethoxylated neopentylglycol diacrylate (PO-NPGDA), tri (propylene glycol) diacrylate (TPGDA), 1,6 hexanediol diacrylate (HDDA), hydroxyethyl methylacrylate (HEMA) or ethoxylated trimethylolpropane triacrylate (EO-TMPTA); Described vinyl ethers monomer comprises triethylene glycol divinyl ether (DVE-3).
Further, the described photosensitizers that helps is acrylate quasi-oligomer or the monomer that contains active amine, the acrylate quasi-oligomer that wherein contains active amine comprises (amination epoxy acrylate, amination polyester acrylate), and the acrylic ester monomer that contains active amine comprises (amination TMPTA, amination TPGDA).Further, described color stuffing is one or more of pigment, talcum powder, glass powder, aerosil or flatting silica.
Further, described auxiliary agent is one or more of dispersion agent, flow agent, defoamer, stopper.
Beneficial effect of the present invention:
1, the coating material solidified another quantum jump as the application of the inside, ultraviolet light polymerization field of the LED-UV light source for preparing of the present invention, it is to have saved to greatest extent again the energy on the basis that utilizes ultraviolet high efficiency, environmental protection, energy-conservation, high-quality, the energy that utilizes by present UV-LED design, it will save the electric energy of 85% left and right on the basis of mercuryarc lamp, and will bring the non-maintaining maintenance of equipment, the value of bringing for society is apparent.
2, effectively utilize the ultraviolet source of LED-UV: the LED-UV light source has constant ultraviolet wavelength, and coating of the present invention can absorb near the UV-light 365nm, 395nm comprehensively, has saved the energy.
3, curing speed is fast: curing speed can be in less than 0.5s instantaneous solidification complete, according to different equipment, can under 15-60m/min, solidify.
4, film performance excellence: very superior performance is being arranged aspect sticking power, hardness, wear resistance.
5, environmental protection: zero volatile organic compounds (VOC) during due to formulating of recipe, so environment is not had to any pollution.
Embodiment
In order to understand better the present invention, now in conjunction with the embodiments the present invention is described further, but the scope of protection of present invention is not limited in the scope that embodiment represents.The reaction raw materials that the present invention relates to, so long as qualified industrial goods are not limited to producer, is all commercially available conventional products.
A kind of LED-UV light source is coating material solidified, comprises following component, by mass percentage:
Wherein, described light trigger is one or more of light trigger of 365nm, 395nm characteristic absorption wavelength.
Described 395nm characteristic absorption wavelength light trigger is 2,4,6-trimethylbenzoyl diphenyl phosphate oxidation (TPO); Described 365nm characteristic absorption wavelength light trigger is isopropyl thioxanthone (ITX), 2,4-diethyl thioxanthone (DETX) or tetraethyl-michaelis ketone (EMK).
Described acrylate quasi-oligomer comprises one or more of epoxy acrylate, urethane acrylate, polyester acrylate, amino acrylates.Described reactive thinner is one or more of acrylic ester monomer, vinyl ethers monomer.
Described acrylic ester monomer comprises one or more of Viscoat 295 (TMPTA), ethoxylated neopentylglycol diacrylate (PO-NPGDA), tri (propylene glycol) diacrylate (TPGDA), 1,6 hexanediol diacrylate (HDDA), hydroxyethyl methylacrylate (HEMA) or ethoxylated trimethylolpropane triacrylate (EO-TMPTA); Described vinyl ethers monomer comprises triethylene glycol divinyl ether (DVE-3).
The described photosensitizers that helps is acrylate quasi-oligomer or the monomer that contains active amine, the acrylate quasi-oligomer that wherein contains active amine comprises amination epoxy acrylate, amination polyester acrylate, and the acrylic ester monomer that contains active amine comprises amination TMPTA, amination TPGDA.This class contains the photosensitizers that helps of active amino and can make by oneself, the self-control method is: with the acrylate monomer that contains 1.2mol or oligopolymer, add 1mol diethyl alcamines material (diethylethanolamine commonly used), carry out Michael reaction, lower 4 hours of 45 ℃ of temperature controls, net result amine value is 0.1-0.4mmol/g.
Described color stuffing is one or more of pigment, talcum powder, glass powder, aerosil or flatting silica.
Described auxiliary agent is one or more of dispersion agent, flow agent, defoamer, stopper.
Embodiment 1
The LED-UV light source solidifies the sanding primer base and comprises following component, (in Table one) by mass percentage:
Wherein the acrylate quasi-oligomer is epoxy acrylate; Reactive thinner is TMPTA and DVE-3; Light trigger is the TPO that 395nm master absorbs; Color stuffing is aerosil and talcum powder; Auxiliary agent is dispersion agent and defoamer; Helping photosensitizers is amination TMPTA.
Table one LED-UV light source solidifies the mass percent of sanding primer composition
With the painting line rod of 100um, on the 30*60cm oak floor, film, under the LED-UV of 8W lamp with the curing speed film forming of 20m/min.The film performance of test: sticking power----1 grade, hardness---1H, gloss----82 °.
Embodiment 2
The LED-UV light source solidifies white primer coating and comprises following component, (in Table two) by mass percentage:
Wherein the acrylate quasi-oligomer is epoxy acrylate and polyester acrylate; Reactive thinner is TMPTA and PO-NPGDA; Light trigger is that 365nm, 395nm master absorb compound ITX, TPO; Color stuffing is aerosil and white pigment; Auxiliary agent is dispersion agent and defoamer; Helping photosensitizers is the amination epoxy acrylate
Table two LED-UV light source solidifies the mass percent of white primer component
With the painting line rod of 100um, on the 30*60cm oak floor, film, under the LED-UV of 8W lamp with the curing speed film forming of 20m/min.The film performance of test: sticking power----2 grades, hardness---2H, gloss----85 °.
Embodiment 3
The LED-UV light source solidifies high finish coat varnish coating and comprises following component, (in Table three) by mass percentage:
Wherein the acrylate quasi-oligomer is epoxy acrylate and urethane acrylate; Reactive thinner is TMPTA and TPGDA; Light trigger is that 365nm, 395nm master absorb compound DETX, TPO; Color stuffing is zero; Auxiliary agent is dispersion agent, defoamer and flow agent; The amination polyester acrylate
Table three LED-UV light source solidifies the mass percent of high finish coat varnish component
With the painting line rod of 100um, on the 30*60cm oak floor, film, under the LED-UV of 8W lamp with the curing speed film forming of 20m/min.The film performance of test: sticking power----2 grades, hardness---2H, gloss----98 °.
Embodiment 4
The LED-UV light source solidifies dull surface paint coating and comprises following component, (in Table four) by mass percentage:
Wherein the acrylate quasi-oligomer is epoxy acrylate and urethane acrylate; Reactive thinner is TMPTA, TPGDA and HDDA; Light trigger is that 365nm, 395nm master absorb compound ITX, TPO; Color stuffing is aerosil and flatting silica; Auxiliary agent is dispersion agent, defoamer and flow agent; Helping photosensitizers is amination TPGDA.
Table four LED-UV light source solidifies the mass percent of dull surface paint component
With the painting line rod of 100um, on the 30*60cm oak floor, film, under the LED-UV of 8W lamp with the curing speed film forming of 20m/min.The film performance of test: sticking power----2 grades, hardness---2H, gloss----30-40 °.
Embodiment 5
The LED-UV light source solidifies high hard primer base and comprises following component, (in Table five) by mass percentage:
Wherein the acrylate quasi-oligomer is epoxy acrylate and six functional polyurethanes acrylate; Reactive thinner is TMPTA and HEMA; Light trigger is that 365nm, 395nm master absorb compound MEK, TPO; Color stuffing is aerosil and glass powder; Auxiliary agent is dispersion agent and defoamer; Helping photosensitizers is amination TMPTA.
Table five LED-UV light source solidifies the mass percent of high hard primer composition
With the painting line rod of 100um, on the 30*60cm oak floor, film, under the LED-UV of 8W lamp with the curing speed film forming of 20m/min.The film performance of test: sticking power----2 grades, hardness---4H, gloss----72 °.
Embodiment 6
The LED-UV light source solidifies red finish paint coating and comprises following component, (in Table six) by mass percentage:
Wherein the acrylate quasi-oligomer is epoxy acrylate and polyester acrylate; Reactive thinner is EO-TMPTA and DPGDA; Light trigger is that 365nm, 395nm master absorb compound ITX, TPO; Color stuffing is aerosil and red pigment; Auxiliary agent is dispersion agent and defoamer; Helping photosensitizers is amination TMPTA.
Table six LED-UV light source solidifies the mass percent of red finish paint component
With the painting line rod of 100um, on the 30*60cm oak floor, film, under the LED-UV of 8W lamp with the curing speed film forming of 20m/min.The film performance of test: sticking power----2 grades, hardness---2H, gloss----92 °.
Claims (8)
2. LED-UV light source according to claim 1 is coating material solidified, it is characterized in that, described 395nm characteristic absorption wavelength light trigger is 2,4,6-trimethylbenzoyl diphenyl phosphate oxidation; Described 365nm characteristic absorption wavelength light trigger is isopropyl thioxanthone, 2,4-diethyl thioxanthone or tetraethyl-michaelis ketone.
3. LED-UV light source according to claim 1 is coating material solidified, it is characterized in that, described acrylate quasi-oligomer comprises one or more of epoxy acrylate, urethane acrylate, polyester acrylate, amino acrylates.
4. LED-UV light source according to claim 1 is coating material solidified, it is characterized in that, described reactive thinner is one or more of acrylic ester monomer, vinyl ethers monomer.
5. LED-UV light source according to claim 4 is coating material solidified, it is characterized in that, described acrylic ester monomer comprises one or more of Viscoat 295, ethoxylated neopentylglycol diacrylate, tri (propylene glycol) diacrylate, 1,6 hexanediol diacrylate, hydroxyethyl methylacrylate or ethoxylated trimethylolpropane triacrylate; Described vinyl ethers monomer comprises the triethylene glycol divinyl ether.
6. LED-UV light source according to claim 1 is coating material solidified, it is characterized in that, the described photosensitizers that helps is acrylate quasi-oligomer or the monomer that contains active amine, the acrylate quasi-oligomer that wherein contains active amine comprises (amination epoxy acrylate, amination polyester acrylate), and the acrylic ester monomer that contains active amine comprises (amination TMPTA, amination TPGDA).
7. LED-UV light source according to claim 1 is coating material solidified, it is characterized in that, described color stuffing is one or more of pigment, talcum powder, glass powder, aerosil or flatting silica.
8. LED-UV light source according to claim 1 is coating material solidified, it is characterized in that, described auxiliary agent is one or more of dispersion agent, flow agent, defoamer, stopper.
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