CN104151895B - A kind of pottery polyacrylate coating - Google Patents
A kind of pottery polyacrylate coating Download PDFInfo
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- CN104151895B CN104151895B CN201410430865.1A CN201410430865A CN104151895B CN 104151895 B CN104151895 B CN 104151895B CN 201410430865 A CN201410430865 A CN 201410430865A CN 104151895 B CN104151895 B CN 104151895B
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- pottery
- polyacrylate coating
- photosensitizers
- catalyzer
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- 238000000576 coating method Methods 0.000 title claims abstract description 27
- 239000011248 coating agent Substances 0.000 title claims abstract description 26
- 229920000058 polyacrylate Polymers 0.000 title claims abstract description 20
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims abstract description 30
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 24
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 16
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 16
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000002994 raw material Substances 0.000 claims abstract description 14
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims abstract description 8
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 claims abstract description 8
- 239000004372 Polyvinyl alcohol Substances 0.000 claims abstract description 8
- 239000005083 Zinc sulfide Substances 0.000 claims abstract description 8
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 8
- 239000001768 carboxy methyl cellulose Substances 0.000 claims abstract description 8
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229920002451 polyvinyl alcohol Polymers 0.000 claims abstract description 8
- 239000004408 titanium dioxide Substances 0.000 claims abstract description 8
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229910052984 zinc sulfide Inorganic materials 0.000 claims abstract description 8
- DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000003504 photosensitizing agent Substances 0.000 claims abstract description 7
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims description 7
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims description 7
- 150000003863 ammonium salts Chemical class 0.000 claims description 5
- KMNCBSZOIQAUFX-UHFFFAOYSA-N 2-ethoxy-1,2-diphenylethanone Chemical compound C=1C=CC=CC=1C(OCC)C(=O)C1=CC=CC=C1 KMNCBSZOIQAUFX-UHFFFAOYSA-N 0.000 claims description 3
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 claims description 2
- 239000012965 benzophenone Substances 0.000 claims description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 abstract description 10
- 238000005187 foaming Methods 0.000 abstract description 10
- 230000035939 shock Effects 0.000 abstract description 6
- 241000406668 Loxodonta cyclotis Species 0.000 abstract description 5
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical class [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 abstract description 5
- 238000001035 drying Methods 0.000 abstract description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 5
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 abstract 1
- -1 catalyzer Chemical compound 0.000 abstract 1
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 abstract 1
- 238000005524 ceramic coating Methods 0.000 description 7
- 239000000919 ceramic Substances 0.000 description 4
- 239000003973 paint Substances 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 229910052573 porcelain Inorganic materials 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 235000013311 vegetables Nutrition 0.000 description 2
- 239000005995 Aluminium silicate Substances 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 208000037656 Respiratory Sounds Diseases 0.000 description 1
- PZZYQPZGQPZBDN-UHFFFAOYSA-N aluminium silicate Chemical compound O=[Al]O[Si](=O)O[Al]=O PZZYQPZGQPZBDN-UHFFFAOYSA-N 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 229910000323 aluminium silicate Inorganic materials 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 238000001311 chemical methods and process Methods 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 210000003298 dental enamel Anatomy 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 238000005242 forging Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- MJVGBKJNTFCUJM-UHFFFAOYSA-N mexenone Chemical group OC1=CC(OC)=CC=C1C(=O)C1=CC=C(C)C=C1 MJVGBKJNTFCUJM-UHFFFAOYSA-N 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 229910052604 silicate mineral Inorganic materials 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- KJCLYACXIWMFCC-UHFFFAOYSA-M sodium;5-benzoyl-4-hydroxy-2-methoxybenzenesulfonate Chemical group [Na+].C1=C(S([O-])(=O)=O)C(OC)=CC(O)=C1C(=O)C1=CC=CC=C1 KJCLYACXIWMFCC-UHFFFAOYSA-M 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
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- Paints Or Removers (AREA)
Abstract
The present invention discloses a kind of pottery polyacrylate coating, and raw material is: Hydroxyethyl acrylate, titanium dioxide, Resorcinol, wilkinite, toluene, polyvinyl alcohol, photosensitizers, zinc sulfide white, tosic acid, light calcium carbonate, catalyzer, talcum powder, 5% sodium hydroxide, carboxymethyl cellulose and anhydrous magnesium sulfate; Product glossiness 120%-140%, hardness 4-7H, shock strength 5-6MPa; Time of drying, 10-15s, soaked 24-48h without exception in 5% hydrochloric acid soln; Water soaks 5-10d without foaming, obscission, in saturated calcium hydroxide, soak that 3-6d is non-foaming, elephant skin; Product snappiness 4-5mm, resistance to 130-150 DEG C of high temperature.
Description
Technical field
The application belongs to paint field, particularly relates to a kind of pottery polyacrylate coating.
Background technology
Reform and open up to the outside world over 30 years, Chinese pottery industrial boom, nowadays become qualified in the world Production of Ceramics big country, consumption big country. The domestic ceramics output of domestic product accounts for about the 70% of the whole world, and display art ceramic yield is the 65% of the whole world, and architectural pottery output also accounts for Gross World Product half of the country. China industry occupies very important status in world's building material industry. All belong to its scope to the meticulousst fine pottery and porcelain by the most coarse native device. Main raw material for it is the silicate minerals (such as clay, quartz etc.) taking from nature, therefore with industry such as glass, toluene mud, enamel, refractory materialss, belongs to the category of " silicate industry ". Up to now, pottery define like can be described as follows with summarizing: pottery is main raw material with aluminium silicate mineral or some oxide compound etc., the technique rock with a shaping type at high temperature made with certain temperature and atmosphere by specific physical and chemical process according to the intention of people. Surface can glazing or not glazing, some porcelain matter also has translucency in various degree, entire body by one or more crystal or with amorphous cementing matter and pore or form with microtextures such as grog inclusions.
Coating (paint), our usual said paint is one wherein. Refer to coat body surface to form film under certain conditions and play protection, the class I liquid I of decoration or other specific functions (insulation, antirust, mildew-resistant, heat-resisting etc.) or solid material. It is main raw material mainly with vegetables oil greatly because of early stage coating, therefore also known as painting. Instead of vegetables oil at synthetic resins, therefore it is called coating. Founding of New, over 60 years, with the development of national economy every profession and trade, progressively develops into the essential important industry in each field of national economy as its supporting coatings industry from an extremely unobtrusive little industry. Through the struggling hard of several generations, pioneering and keeping forging ahead, China has become second-biggest-in-the-world coating material production state and consumption state, enters into the main flow of world's coating industry development.
Ceramic coating is that one can make organism and inorganics react, thus has had both the novel ceramic coating of both advantages. The hardness of the ceramic coating of a new generation can reach more than 6H. High temperature resistant 400 degree, not sticky effect, color is multiple. And toluene ceramic coating can be made. Ceramic coating weathering resistance and processing characteristics are excellent, resistance to dirty and resistant to damage. Although conventional ceramic coating resistant to damage, but if the parts after application are carried out bending machining, it is easy to produce crackle, and fluorine resin paints and organic coating, it is easy to damaged by sandstone, dust etc. Therefore, the appearance of ceramic coating, receives the favor of ceramic industry, and just to other industry infiltration, prospect is had an optimistic view of. And popularizing along with humanity concept, and the formation of novel harmonious society, the pottery polyacrylate coating designing a kind of Heat stability is good, shock strength height, solvent resistant and snappiness good is very important.
Summary of the invention
The technical problem solved:
The application is for above-mentioned technical problem, it is provided that a kind of pottery polyacrylate coating, solves that existing pottery polyacrylate coating thermostability, hardness are low, not solvent resistant and the technical problem such as snappiness is poor.
Technical scheme:
A kind of pottery polyacrylate coating, the raw materials by weight portion proportioning of described pottery polyacrylate coating is as follows: Hydroxyethyl acrylate 100 parts; Titanium dioxide 25-35 part; Resorcinol 5-15 part; Wilkinite 35-45 part; Toluene 80-100 part; Polyvinyl alcohol 15-25 part; Photosensitizers 1-10 part; Zinc sulfide white 10-30 part; Tosic acid 10-20 part; Light calcium carbonate 25-35 part; Catalyzer 3-5 part; Talcum powder 10-20 part; 5% sodium hydroxide 20-30 part; Carboxymethyl cellulose 2-8 part; Anhydrous magnesium sulfate 1-3 part.
As a preferred technical solution of the present invention: the raw materials by weight portion proportioning of described pottery polyacrylate coating is as follows: Hydroxyethyl acrylate 100 parts; Titanium dioxide 30 parts; Resorcinol 10 parts; Wilkinite 40 parts; Toluene 90 parts; Polyvinyl alcohol 20 parts; Photosensitizers 5 parts; 20 parts, zinc sulfide white; Tosic acid 15 parts; Light calcium carbonate 30 parts; Catalyzer 4 parts; Talcum powder 15 parts; 5% 25 parts, sodium hydroxide; Carboxymethyl cellulose 5 parts; Anhydrous magnesium sulfate 2 parts.
As a preferred technical solution of the present invention: described photosensitizers adopts Benzoin ethyl ether or benzophenone.
As a preferred technical solution of the present invention: described catalyzer adopts quarternary ammonium salt.
Useful effect:
A kind of pottery polyacrylate coating of the present invention adopts above technical scheme compared with prior art, has following technique effect: 1, product glossiness 120%-140%, hardness 4-7H, shock strength 5-6MPa; 2,10-15s time of drying, soaks 24-48h without exception in 5% hydrochloric acid soln; 3, water soak 5-10d without foaming, obscission, in saturated calcium hydroxide, soak that 3-6d is non-foaming, elephant skin; 4, product snappiness 4-5mm, resistance to 130-150 DEG C of high temperature, it is possible to the widespread production not division of history into periods is for current material.
Embodiment
Embodiment 1:
A kind of pottery polyacrylate coating, its raw materials by weight portion proportioning is as follows: Hydroxyethyl acrylate 100 parts; Titanium dioxide 25 parts; Resorcinol 5 parts; Wilkinite 35 parts; Toluene 80 parts; Polyvinyl alcohol 15 parts; Benzoin ethyl ether 1 part; 10 parts, zinc sulfide white; Tosic acid 10 parts; Light calcium carbonate 25 parts;Quarternary ammonium salt 3 parts; Talcum powder 10 parts; 5% 20 parts, sodium hydroxide; Carboxymethyl cellulose 2 parts; Anhydrous magnesium sulfate 1 part.
After above-mentioned raw materials is mixed 2h in a kettle., it is coated on pottery, film uviolizing.
Product glossiness 120%, hardness 4H, shock strength 5MPa; Time of drying, 15s, soaked 24h without exception in 5% hydrochloric acid soln; Water soaks 5d without foaming, obscission, in saturated calcium hydroxide, soak that 3d is non-foaming, elephant skin; Product snappiness 4mm, resistance to 130 DEG C of high temperature.
Embodiment 2:
A kind of pottery polyacrylate coating, its raw materials by weight portion proportioning is as follows: Hydroxyethyl acrylate 100 parts; Titanium dioxide 35 parts; Resorcinol 15 parts; Wilkinite 45 parts; Toluene 100 parts; Polyvinyl alcohol 25 parts; Benzophenone 10 parts; 30 parts, zinc sulfide white; Tosic acid 20 parts; Light calcium carbonate 35 parts; Quarternary ammonium salt 5 parts; Talcum powder 20 parts; 5% 30 parts, sodium hydroxide; Carboxymethyl cellulose 8 parts; Anhydrous magnesium sulfate 3 parts.
After above-mentioned raw materials is mixed 4h in a kettle., it is coated on pottery, film uviolizing.
Product glossiness 130%, hardness 6H, shock strength 5MPa; Time of drying, 12s, soaked 36h without exception in 5% hydrochloric acid soln; Water soaks 8d without foaming, obscission, in saturated calcium hydroxide, soak that 4d is non-foaming, elephant skin; Product snappiness 4mm, resistance to 140 DEG C of high temperature.
Embodiment 3:
A kind of pottery polyacrylate coating, its raw materials by weight portion proportioning is as follows: Hydroxyethyl acrylate 100 parts; Titanium dioxide 30 parts; Resorcinol 10 parts; Wilkinite 40 parts; Toluene 90 parts; Polyvinyl alcohol 20 parts; Benzophenone 5 parts; 20 parts, zinc sulfide white; Tosic acid 15 parts; Light calcium carbonate 30 parts; Quarternary ammonium salt 4 parts; Talcum powder 15 parts; 5% 25 parts, sodium hydroxide; Carboxymethyl cellulose 5 parts; Anhydrous magnesium sulfate 2 parts.
After above-mentioned raw materials is mixed 3h in a kettle., it is coated on pottery, film uviolizing.
Product glossiness 140%, hardness 7H, shock strength 6MPa; Time of drying, 10s, soaked 48h without exception in 5% hydrochloric acid soln; Water soaks 10d without foaming, obscission, in saturated calcium hydroxide, soak that 6d is non-foaming, elephant skin; Product snappiness 5mm, resistance to 150 DEG C of high temperature.
Composition all components in above embodiment all can business be bought.
Above-described embodiment is just for setting forth the content of the present invention, instead of restriction, and the therefore any change in the implication suitable with the claim book of the present invention and scope, all it is believed that be included in the scope of claim book.
Claims (4)
1. a pottery polyacrylate coating, it is characterised in that the raw materials by weight portion proportioning of described pottery polyacrylate coating is as follows: Hydroxyethyl acrylate 100 parts; Titanium dioxide 25-35 part; Resorcinol 5-15 part; Wilkinite 35-45 part; Toluene 80-100 part; Polyvinyl alcohol 15-25 part; Photosensitizers 1-10 part; Zinc sulfide white 10-30 part; Tosic acid 10-20 part; Light calcium carbonate 25-35 part; Catalyzer 3-5 part; Talcum powder 10-20 part; 5% sodium hydroxide 20-30 part; Carboxymethyl cellulose 2-8 part; Anhydrous magnesium sulfate 1-3 part.
2. a kind of pottery polyacrylate coating according to claim 1, it is characterised in that the raw materials by weight portion proportioning of described pottery polyacrylate coating is as follows: Hydroxyethyl acrylate 100 parts;Titanium dioxide 30 parts; Resorcinol 10 parts; Wilkinite 40 parts; Toluene 90 parts; Polyvinyl alcohol 20 parts; Photosensitizers 5 parts; 20 parts, zinc sulfide white; Tosic acid 15 parts; Light calcium carbonate 30 parts; Catalyzer 4 parts; Talcum powder 15 parts; 5% 25 parts, sodium hydroxide; Carboxymethyl cellulose 5 parts; Anhydrous magnesium sulfate 2 parts.
3. a kind of pottery polyacrylate coating according to claim 1, it is characterised in that: described photosensitizers adopts Benzoin ethyl ether or benzophenone.
4. a kind of pottery polyacrylate coating according to claim 1, it is characterised in that: described catalyzer adopts quarternary ammonium salt.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410430865.1A CN104151895B (en) | 2014-08-28 | 2014-08-28 | A kind of pottery polyacrylate coating |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410430865.1A CN104151895B (en) | 2014-08-28 | 2014-08-28 | A kind of pottery polyacrylate coating |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104151895A CN104151895A (en) | 2014-11-19 |
| CN104151895B true CN104151895B (en) | 2016-06-15 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410430865.1A Active CN104151895B (en) | 2014-08-28 | 2014-08-28 | A kind of pottery polyacrylate coating |
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| Country | Link |
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63265980A (en) * | 1987-04-22 | 1988-11-02 | Toyobo Co Ltd | Ultraviolet-curable ink composition |
| CN1486960A (en) * | 2002-08-07 | 2004-04-07 | 珠海东诚化工有限公司 | Ultraviolet light cured ceramic paint |
| CN103305116A (en) * | 2013-06-17 | 2013-09-18 | 武汉绿凯科技有限公司 | Photo-curing transparency-increased film coating solution as well as preparation method and application thereof |
| CN103396689A (en) * | 2013-08-01 | 2013-11-20 | 苏州市明大高分子科技材料有限公司 | LED-UV light source curable coating and preparation method |
| CN103937377A (en) * | 2013-01-21 | 2014-07-23 | 上海参爱贸易有限公司 | Low gloss ultraviolet curing coating |
-
2014
- 2014-08-28 CN CN201410430865.1A patent/CN104151895B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63265980A (en) * | 1987-04-22 | 1988-11-02 | Toyobo Co Ltd | Ultraviolet-curable ink composition |
| CN1486960A (en) * | 2002-08-07 | 2004-04-07 | 珠海东诚化工有限公司 | Ultraviolet light cured ceramic paint |
| CN103937377A (en) * | 2013-01-21 | 2014-07-23 | 上海参爱贸易有限公司 | Low gloss ultraviolet curing coating |
| CN103305116A (en) * | 2013-06-17 | 2013-09-18 | 武汉绿凯科技有限公司 | Photo-curing transparency-increased film coating solution as well as preparation method and application thereof |
| CN103396689A (en) * | 2013-08-01 | 2013-11-20 | 苏州市明大高分子科技材料有限公司 | LED-UV light source curable coating and preparation method |
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| Publication number | Publication date |
|---|---|
| CN104151895A (en) | 2014-11-19 |
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Effective date of registration: 20201222 Address after: 224006 room 109, no.1572, Luming Road, Yanlong street, Yandu District, Yancheng City, Jiangsu Province Patentee after: Yancheng Yanlong water Co., Ltd Address before: Room 4722, Tianlong building, no.378, Zhujiang South Road, Mudu Town, Wuzhong District, Suzhou City, Jiangsu Province Patentee before: SUZHOU LUOTELAN NEW MATERIAL TECHNOLOGY Co.,Ltd. |