CN103390507B - 一种石墨烯/铂纳米粒子复合纤维电极材料及其制备方法 - Google Patents
一种石墨烯/铂纳米粒子复合纤维电极材料及其制备方法 Download PDFInfo
- Publication number
- CN103390507B CN103390507B CN201310278943.6A CN201310278943A CN103390507B CN 103390507 B CN103390507 B CN 103390507B CN 201310278943 A CN201310278943 A CN 201310278943A CN 103390507 B CN103390507 B CN 103390507B
- Authority
- CN
- China
- Prior art keywords
- graphene
- platinum
- composite fibre
- electrode
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 title claims abstract description 74
- 239000000835 fiber Substances 0.000 title claims abstract description 62
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 61
- 229910021389 graphene Inorganic materials 0.000 title claims abstract description 58
- 229910052697 platinum Inorganic materials 0.000 title claims abstract description 37
- 238000002360 preparation method Methods 0.000 title claims abstract description 23
- 239000002105 nanoparticle Substances 0.000 title claims description 18
- 239000007772 electrode material Substances 0.000 title abstract description 11
- 239000002131 composite material Substances 0.000 claims abstract description 24
- 238000000034 method Methods 0.000 claims abstract description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 9
- 239000008367 deionised water Substances 0.000 claims description 8
- 229910021641 deionized water Inorganic materials 0.000 claims description 8
- 239000004567 concrete Substances 0.000 claims description 6
- 238000004070 electrodeposition Methods 0.000 claims description 6
- 239000003792 electrolyte Substances 0.000 claims description 6
- 239000002245 particle Substances 0.000 claims description 6
- 239000007864 aqueous solution Substances 0.000 claims description 4
- ZOMNIUBKTOKEHS-UHFFFAOYSA-L dimercury dichloride Chemical class Cl[Hg][Hg]Cl ZOMNIUBKTOKEHS-UHFFFAOYSA-L 0.000 claims description 3
- 239000011521 glass Substances 0.000 claims description 3
- 238000006243 chemical reaction Methods 0.000 abstract description 7
- 230000005611 electricity Effects 0.000 abstract description 7
- 230000003197 catalytic effect Effects 0.000 abstract description 5
- 206010070834 Sensitisation Diseases 0.000 abstract description 2
- 230000008313 sensitization Effects 0.000 abstract description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 14
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
- 239000004408 titanium dioxide Substances 0.000 description 7
- 239000000084 colloidal system Substances 0.000 description 6
- 238000010586 diagram Methods 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 230000003647 oxidation Effects 0.000 description 5
- 238000007254 oxidation reaction Methods 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 4
- 229920000642 polymer Polymers 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000000975 dye Substances 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 239000010936 titanium Substances 0.000 description 3
- 229910052719 titanium Inorganic materials 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 229920000049 Carbon (fiber) Polymers 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 239000004917 carbon fiber Substances 0.000 description 2
- 239000002041 carbon nanotube Substances 0.000 description 2
- 229910021393 carbon nanotube Inorganic materials 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000002071 nanotube Substances 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 229920005594 polymer fiber Polymers 0.000 description 2
- 230000001172 regenerating effect Effects 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 238000002791 soaking Methods 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 239000006228 supernatant Substances 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- JJWJFWRFHDYQCN-UHFFFAOYSA-J 2-(4-carboxypyridin-2-yl)pyridine-4-carboxylate;ruthenium(2+);tetrabutylazanium;dithiocyanate Chemical compound [Ru+2].[S-]C#N.[S-]C#N.CCCC[N+](CCCC)(CCCC)CCCC.CCCC[N+](CCCC)(CCCC)CCCC.OC(=O)C1=CC=NC(C=2N=CC=C(C=2)C([O-])=O)=C1.OC(=O)C1=CC=NC(C=2N=CC=C(C=2)C([O-])=O)=C1 JJWJFWRFHDYQCN-UHFFFAOYSA-J 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 229920005479 Lucite® Polymers 0.000 description 1
- 206010037544 Purging Diseases 0.000 description 1
- 229910010413 TiO 2 Inorganic materials 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 150000001721 carbon Chemical group 0.000 description 1
- 238000005352 clarification Methods 0.000 description 1
- 230000003749 cleanliness Effects 0.000 description 1
- 230000001112 coagulating effect Effects 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 1
- 229940071870 hydroiodic acid Drugs 0.000 description 1
- 238000001027 hydrothermal synthesis Methods 0.000 description 1
- 239000005457 ice water Substances 0.000 description 1
- 238000002513 implantation Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 239000002114 nanocomposite Substances 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 239000013049 sediment Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 1
- 238000003828 vacuum filtration Methods 0.000 description 1
- 238000012795 verification Methods 0.000 description 1
- 238000002166 wet spinning Methods 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
- Y02E10/542—Dye sensitized solar cells
Landscapes
- Carbon And Carbon Compounds (AREA)
Abstract
Description
Claims (3)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201310278943.6A CN103390507B (zh) | 2013-07-04 | 2013-07-04 | 一种石墨烯/铂纳米粒子复合纤维电极材料及其制备方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201310278943.6A CN103390507B (zh) | 2013-07-04 | 2013-07-04 | 一种石墨烯/铂纳米粒子复合纤维电极材料及其制备方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN103390507A CN103390507A (zh) | 2013-11-13 |
CN103390507B true CN103390507B (zh) | 2016-04-13 |
Family
ID=49534745
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201310278943.6A Expired - Fee Related CN103390507B (zh) | 2013-07-04 | 2013-07-04 | 一种石墨烯/铂纳米粒子复合纤维电极材料及其制备方法 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN103390507B (zh) |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103985546A (zh) * | 2014-05-19 | 2014-08-13 | 东南大学 | 一种石墨烯-CoS纳米片复合对电极及其制备方法 |
CN106486691A (zh) * | 2015-08-26 | 2017-03-08 | 航天金洲(北京)能源科技有限公司 | 一种石墨烯电堆 |
CN106098154B (zh) * | 2016-05-26 | 2017-09-15 | 河南理工大学 | 一种芯鞘型石墨烯纤维复合光电极及其制备方法 |
CN106676878B (zh) * | 2016-12-26 | 2019-08-20 | 浙江大学 | 一种石墨烯-锌复合纤维及其制备方法 |
CN106676876A (zh) * | 2016-12-26 | 2017-05-17 | 浙江大学 | 一种石墨烯‑镁复合纤维及其制备方法 |
CN106676877B (zh) * | 2016-12-26 | 2019-09-03 | 浙江大学 | 一种石墨烯-锰复合纤维及其制备方法 |
CN108598428A (zh) * | 2018-04-26 | 2018-09-28 | 东华大学 | 一种石墨烯/二氧化锡交替层层堆叠复合纤维及其制备方法和应用 |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102061504A (zh) * | 2009-11-13 | 2011-05-18 | 中国科学院兰州化学物理研究所 | 一种含有石墨烯复合薄膜材料的合成方法 |
CN102120186A (zh) * | 2010-11-22 | 2011-07-13 | 南京大学 | 在石墨烯上负载铂纳米颗粒的制备方法 |
CN102254582A (zh) * | 2010-05-18 | 2011-11-23 | 国家纳米科学中心 | 一种石墨烯基导电材料及其制备方法 |
CN102534865A (zh) * | 2012-01-05 | 2012-07-04 | 浙江大学 | 一种离子增强石墨烯纤维及其制备方法 |
CN102751101A (zh) * | 2012-07-11 | 2012-10-24 | 北京大学 | 一种铂/石墨烯纳米复合材料及其制备方法与应用 |
-
2013
- 2013-07-04 CN CN201310278943.6A patent/CN103390507B/zh not_active Expired - Fee Related
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102061504A (zh) * | 2009-11-13 | 2011-05-18 | 中国科学院兰州化学物理研究所 | 一种含有石墨烯复合薄膜材料的合成方法 |
CN102254582A (zh) * | 2010-05-18 | 2011-11-23 | 国家纳米科学中心 | 一种石墨烯基导电材料及其制备方法 |
CN102120186A (zh) * | 2010-11-22 | 2011-07-13 | 南京大学 | 在石墨烯上负载铂纳米颗粒的制备方法 |
CN102534865A (zh) * | 2012-01-05 | 2012-07-04 | 浙江大学 | 一种离子增强石墨烯纤维及其制备方法 |
CN102751101A (zh) * | 2012-07-11 | 2012-10-24 | 北京大学 | 一种铂/石墨烯纳米复合材料及其制备方法与应用 |
Non-Patent Citations (1)
Title |
---|
Highly Electrically Conductive Ag-Doped Graphene Fibers as Stretchable Conductors;Zhen Xu,Zheng Liu,Haiyan Sun,Chao Gao;《ADVANCED MATERIALS》;20130618;第25卷(第23期);全文 * |
Also Published As
Publication number | Publication date |
---|---|
CN103390507A (zh) | 2013-11-13 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN103390507B (zh) | 一种石墨烯/铂纳米粒子复合纤维电极材料及其制备方法 | |
Aboagye et al. | Electrospun carbon nanofibers with surface-attached platinum nanoparticles as cost-effective and efficient counter electrode for dye-sensitized solar cells | |
CN104240967B (zh) | 一种聚苯胺‑二氧化锰‑氮化钛纳米线阵列复合材料及其制备方法和应用 | |
Xiao et al. | High performance of Pt-free dye-sensitized solar cells based on two-step electropolymerized polyaniline counter electrodes | |
CN108103525B (zh) | 氮掺杂碳点修饰三氧化钨复合光电极及其制备方法、和在光电催化分解水中的应用 | |
CN103426648B (zh) | 一种MOS2/TiO2纳米复合材料及其制备方法 | |
Miao et al. | Highly crystalline graphene/carbon black composite counter electrodes with controllable content: Synthesis, characterization and application in dye-sensitized solar cells | |
CN106981377B (zh) | 一种Co3O4@石墨烯纤维超级电容器电极材料的制备方法 | |
CN101901693A (zh) | 石墨烯复合染料敏化太阳能电池的光阳极及其制备方法 | |
CN105140042B (zh) | 一种细菌纤维素/活性碳纤维/碳纳米管膜材料的制备方法及其应用 | |
CN106971860A (zh) | 一种MnO2@石墨烯纤维超级电容器电极材料的制备方法 | |
CN108288547A (zh) | 氮磷硫三元共掺杂有序介孔碳材料的制备方法 | |
CN105070508B (zh) | 一种利用蛋壳膜制备的染料敏化太阳能电池对电极材料及方法 | |
Gao et al. | In situ synthesis of cobalt triphosphate on carbon paper for efficient electrocatalyst in dye-sensitized solar cell | |
CN104310794A (zh) | 三维纳米棒花结构的多孔TiO2纳米晶薄膜、制备方法及应用 | |
CN105778088B (zh) | 一种石墨烯/聚苯胺纳米棒阵列复合材料及其制备方法与应用 | |
CN101853973A (zh) | 一种用于太阳能制氢的纳米结构光电化学电池及制备方法 | |
Wu et al. | Vanadium oxides (V 2 O 5) prepared with different methods for application as counter electrodes in dye-sensitized solar cells (DSCs) | |
CN106098396B (zh) | 一种用于超级电容器的垂直孔碳复合薄膜及其制备方法 | |
CN106024405B (zh) | 一种无模板电沉积法制备硒化钴超级电容器材料的方法 | |
Li et al. | Preparation of carbon nanofibers supported Bi2MoO6 nanosheets as counter electrode materials on Titanium mesh substrate for dye-sensitized solar cells | |
CN107104005B (zh) | 一种NiO@石墨烯纤维超级电容器电极材料的制备方法 | |
CN108987117A (zh) | CoSe2电催化材料的制备方法及其在双面准固态染料敏化太阳能电池中的应用 | |
CN105887130B (zh) | 一种电连接剂制备光催化分解水颗粒膜电极的方法 | |
CN108133827A (zh) | 一种二硫化钼和硫掺杂碳球复合电极的制备方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
ASS | Succession or assignment of patent right |
Owner name: NINGGUO LONGSHENG FLEXIBLE ENERGY MATERIAL TECHNOL Free format text: FORMER OWNER: FUDAN UNIVERSITY Effective date: 20141105 |
|
C41 | Transfer of patent application or patent right or utility model | ||
COR | Change of bibliographic data |
Free format text: CORRECT: ADDRESS; FROM: 200433 YANGPU, SHANGHAI TO: 242300 XUANCHENG, ANHUI PROVINCE |
|
TA01 | Transfer of patent application right |
Effective date of registration: 20141105 Address after: 242300 Ningguo port Ecological Industrial Park in Anhui province by the south side of the road three Applicant after: NINGGUO LONGSHENG FLEXIBLE ENERGY STORAGE MATERIALS TECHNOLOGY Co.,Ltd. Address before: 200433 Handan Road, Shanghai, No. 220, No. Applicant before: Fudan University |
|
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Graphene/ platinum nano particle complex fiber electrode material and preparation method thereof Effective date of registration: 20190726 Granted publication date: 20160413 Pledgee: Anhui Jingdu Investment Development Co.,Ltd. Pledgor: NINGGUO LONGSHENG FLEXIBLE ENERGY STORAGE MATERIALS TECHNOLOGY Co.,Ltd. Registration number: 2019340000419 |
|
CF01 | Termination of patent right due to non-payment of annual fee | ||
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20160413 |