CN103387682B - 可交联耐高电压高储能聚偏氟乙烯塑料薄膜的制备方法 - Google Patents
可交联耐高电压高储能聚偏氟乙烯塑料薄膜的制备方法 Download PDFInfo
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- CN103387682B CN103387682B CN201310132737.4A CN201310132737A CN103387682B CN 103387682 B CN103387682 B CN 103387682B CN 201310132737 A CN201310132737 A CN 201310132737A CN 103387682 B CN103387682 B CN 103387682B
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- 229920002981 polyvinylidene fluoride Polymers 0.000 title claims abstract description 27
- 238000002360 preparation method Methods 0.000 title claims abstract description 11
- 239000002033 PVDF binder Substances 0.000 title abstract 4
- 229920006255 plastic film Polymers 0.000 title abstract 3
- 239000002985 plastic film Substances 0.000 title abstract 3
- 239000002904 solvent Substances 0.000 claims abstract description 55
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims abstract description 42
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims abstract description 35
- 229920000642 polymer Polymers 0.000 claims abstract description 24
- 238000003756 stirring Methods 0.000 claims abstract description 24
- 239000004342 Benzoyl peroxide Substances 0.000 claims abstract description 22
- 235000019400 benzoyl peroxide Nutrition 0.000 claims abstract description 22
- 239000003999 initiator Substances 0.000 claims abstract description 22
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 claims abstract description 20
- 238000012360 testing method Methods 0.000 claims abstract description 20
- 238000006243 chemical reaction Methods 0.000 claims abstract description 17
- 239000000126 substance Substances 0.000 claims description 57
- 238000004146 energy storage Methods 0.000 claims description 36
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 30
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 claims description 27
- 239000005357 flat glass Substances 0.000 claims description 20
- UUAGAQFQZIEFAH-UHFFFAOYSA-N chlorotrifluoroethylene Chemical compound FC(F)=C(F)Cl UUAGAQFQZIEFAH-UHFFFAOYSA-N 0.000 claims description 17
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims description 16
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 claims description 11
- 238000013019 agitation Methods 0.000 claims description 10
- 230000003252 repetitive effect Effects 0.000 claims description 10
- 238000005201 scrubbing Methods 0.000 claims description 10
- 230000001960 triggered effect Effects 0.000 claims description 10
- 238000001291 vacuum drying Methods 0.000 claims description 10
- 239000004033 plastic Substances 0.000 claims description 9
- 229920003023 plastic Polymers 0.000 claims description 9
- 238000011049 filling Methods 0.000 claims description 8
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims description 8
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 claims description 7
- 229920002313 fluoropolymer Polymers 0.000 claims description 5
- 239000004811 fluoropolymer Substances 0.000 claims description 5
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 4
- -1 methyne imines Chemical class 0.000 claims description 3
- 239000002994 raw material Substances 0.000 claims description 3
- IMFACGCPASFAPR-UHFFFAOYSA-N tributylamine Chemical compound CCCCN(CCCC)CCCC IMFACGCPASFAPR-UHFFFAOYSA-N 0.000 claims description 3
- 150000003512 tertiary amines Chemical group 0.000 claims description 2
- 239000010408 film Substances 0.000 abstract description 58
- 238000000034 method Methods 0.000 abstract description 10
- 229920006254 polymer film Polymers 0.000 abstract description 9
- 239000000463 material Substances 0.000 abstract description 7
- 239000010409 thin film Substances 0.000 abstract description 4
- 229920006037 cross link polymer Polymers 0.000 abstract description 3
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 abstract description 2
- 230000015556 catabolic process Effects 0.000 abstract description 2
- 238000004132 cross linking Methods 0.000 abstract description 2
- 229910052731 fluorine Inorganic materials 0.000 abstract description 2
- 239000011737 fluorine Substances 0.000 abstract description 2
- 238000009835 boiling Methods 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 230000002349 favourable effect Effects 0.000 abstract 1
- 239000011521 glass Substances 0.000 abstract 1
- 210000003739 neck Anatomy 0.000 abstract 1
- 230000005311 nuclear magnetism Effects 0.000 description 7
- 230000010287 polarization Effects 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 239000013078 crystal Substances 0.000 description 4
- 230000005684 electric field Effects 0.000 description 4
- 229920002521 macromolecule Polymers 0.000 description 4
- 229920001577 copolymer Polymers 0.000 description 3
- 230000007547 defect Effects 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 238000001228 spectrum Methods 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000012528 membrane Substances 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 238000010791 quenching Methods 0.000 description 2
- 229920001897 terpolymer Polymers 0.000 description 2
- MIZLGWKEZAPEFJ-UHFFFAOYSA-N 1,1,2-trifluoroethene Chemical group FC=C(F)F MIZLGWKEZAPEFJ-UHFFFAOYSA-N 0.000 description 1
- HTHNTJCVPNKCPZ-UHFFFAOYSA-N 2-chloro-1,1-difluoroethene Chemical compound FC(F)=CCl HTHNTJCVPNKCPZ-UHFFFAOYSA-N 0.000 description 1
- 229920005601 base polymer Polymers 0.000 description 1
- 239000003990 capacitor Substances 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 238000007033 dehydrochlorination reaction Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000005621 ferroelectricity Effects 0.000 description 1
- 230000002631 hypothermal effect Effects 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000004377 microelectronic Methods 0.000 description 1
- 229920000131 polyvinylidene Polymers 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000004544 sputter deposition Methods 0.000 description 1
- 239000011232 storage material Substances 0.000 description 1
- 238000001308 synthesis method Methods 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 239000013638 trimer Substances 0.000 description 1
- 229920005609 vinylidenefluoride/hexafluoropropylene copolymer Polymers 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
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CN201310132737.4A CN103387682B (zh) | 2013-04-16 | 2013-04-16 | 可交联耐高电压高储能聚偏氟乙烯塑料薄膜的制备方法 |
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CN103387682A CN103387682A (zh) | 2013-11-13 |
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Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
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CN104987631B (zh) * | 2015-07-21 | 2017-11-03 | 西安交通大学 | 由聚(偏氟乙烯‑三氟氯乙烯)制备荧光聚合物的方法 |
CN105622871B (zh) * | 2015-12-23 | 2018-03-16 | 西安交通大学 | 一种交联型氟聚合物基介电弹性体复合材料及其制备方法 |
FR3069544B1 (fr) * | 2017-07-28 | 2020-05-15 | Arkema France | Procede de preparation d'un film de polymere fluore reticule |
FR3070042B1 (fr) | 2017-08-09 | 2020-08-21 | Arkema France | Transistor organique a effet de champ contenant une couche dielectrique a haute permittivite dielectrique et stable en temperature |
KR20220118463A (ko) * | 2019-12-13 | 2022-08-25 | 아르끄마 프랑스 | 전기 열량 폴리머, 이를 포함하는 필름 및 잉크, 및 이의 용도 |
CN113113671B (zh) * | 2021-04-12 | 2022-11-22 | 清华大学深圳国际研究生院 | 一种聚偏氟乙烯基固态电解质、其制备方法及锂离子电池 |
CN113214424B (zh) * | 2021-06-09 | 2022-06-21 | 上海交通大学 | 改性聚偏氟乙烯基铁电聚合物低电场制冷性能的方法及其应用 |
CN114276576B (zh) * | 2021-12-23 | 2023-03-07 | 中国工程物理研究院化工材料研究所 | 一种γ射线辐照致使含氟共聚物具备光热双重形状记忆性能的方法及应用 |
CN115340623B (zh) * | 2022-08-15 | 2023-12-19 | 万华化学集团股份有限公司 | 一种制备聚偏氟乙烯树脂的方法 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN101058657A (zh) * | 2006-04-20 | 2007-10-24 | 上海道氟化工科技有限公司 | 氟橡胶组合物及其成型制品 |
CN101691412A (zh) * | 2009-09-30 | 2010-04-07 | 西安交通大学 | 一种由聚(偏氟乙烯-三氟氯乙烯)制备聚(偏氟乙烯-三氟氯乙烯-三氟乙烯)或聚(偏氟乙烯-三氟乙烯)的方法 |
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CN102203147A (zh) * | 2008-11-05 | 2011-09-28 | 旭硝子株式会社 | 含氟弹性共聚物、其制造方法及交联橡胶 |
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Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN101058657A (zh) * | 2006-04-20 | 2007-10-24 | 上海道氟化工科技有限公司 | 氟橡胶组合物及其成型制品 |
CN101691412A (zh) * | 2009-09-30 | 2010-04-07 | 西安交通大学 | 一种由聚(偏氟乙烯-三氟氯乙烯)制备聚(偏氟乙烯-三氟氯乙烯-三氟乙烯)或聚(偏氟乙烯-三氟乙烯)的方法 |
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Effective date of registration: 20200116 Address after: 214437 West 3rd Floor, Block B, Chuangzhi Industrial Park, 201 Jinshan Road, Jiangyin City, Wuxi City, Jiangsu Province Patentee after: Wuxi Xinju Electronic Technology Co.,Ltd. Address before: 710049 Xianning Road, Shaanxi, China, No. 28, No. Patentee before: Xi'an Jiaotong University |
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Effective date of registration: 20240423 Address after: Institute of Chemistry, Chinese Academy of Sciences, No. 2 North 1st Street, Zhongguancun, Haidian District, Beijing, 100089 Patentee after: Zhang Zhicheng Country or region after: China Address before: 214437 West, 3rd floor, Cyberport B, Chuangzhi Industrial Park, 201 Jinshan Road, Jiangyin City, Wuxi City, Jiangsu Province Patentee before: Wuxi Xinju Electronic Technology Co.,Ltd. Country or region before: China |
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