CN103380784B - Bactericidal odor removing agent - Google Patents
Bactericidal odor removing agent Download PDFInfo
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- CN103380784B CN103380784B CN201310249838.XA CN201310249838A CN103380784B CN 103380784 B CN103380784 B CN 103380784B CN 201310249838 A CN201310249838 A CN 201310249838A CN 103380784 B CN103380784 B CN 103380784B
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Abstract
The invention discloses a bactericidal odor removing agent in the chemical mixture agent field, and is characterized by comprising the components, in percentage by weight: (A) 0.25 to 5% of an organic silicon quaternary ammonium salt; (B) 0.1 to 2% of an organic silicon coupling agent; (C) 0.2 to 2% of a stabilizing agent; and (D) the balance being deionized water. The bactericidal odor removing agent has antibacterial, mildewproof, odor-removing and deodorant effects, has lastingly bacteriostatic effect and widely bacteriostatic range, simultaneously is safe and reliable for any product, and does not pollute the environment. The organic silicon quaternary ammonium salt has bactericidal and bacteriostatic effects, and non-toxic, gentle, soft and smooth properties of the organic silicon quaternary ammonium salt to human bodies are utilized, so the bactericidal odor removing agent is prepared into a spray medicament form, is used for disinfectant and bactericidal treatment of various traumatic infections and skin infections, can have rapidly bactericidal antipruritic effect for the various skin infections, and can kill bacteria and inhibit bacterial activity.
Description
Technical field
The present invention relates to chemical mixture field, be specifically related to a kind of sterilizing deodoring agent.
Background technology
The article such as individual personal effects, Che Nei and clothing cloth such as indoor various household articles, footwear and socks can gather a large amount of bacterium, fungi, virus and dirt mite and pollute along with the prolongation of service time, easily microbial contamination is produced at the environment of constant humid, not good, the nutritious material that ventilates, thus produce a large amount of peculiar smell, microbial contamination be cause various poisoning, infect, the one of the main reasons of anaphylactia and communicable disease.The most direct method of current process peculiar smell is by the air freshener based on essence, " cover " peculiar smell on the surface, during use and various peculiar smell depositing, the sensation of people to peculiar smell is temporarily releived, in fact do not eliminate peculiar smell, thoroughly cannot solve the pollution problem of foreign odor taste.Need to adopt mildew-resistant and moistureproof product to reduce microbial contamination in addition, but traditional mildew-resistant and moistureproof product are all without sterilizing and deodorizing function simultaneously, cannot by antibacterial and mouldproof from root and the effect of taste removal deodorization.
Close seal ring in the indoor of medical treatment and can there is a large amount of bacterium within the border, tradition adopts infrared radiation mode to carry out killing Jun sterilization, and costly, equipment installs inconvenience, is not easy to extensive popularization in infrared radiation.Meanwhile, can grow the sick Jun such as a large amount of bacterium and true Jun at various trauma infection contamination and skin infection surface, tradition adopts the mode such as to apply ointment to carry out surface treatment, and ointment uses inconvenience, and it is remarkable to kill Jun antipruritic effect, cannot the sick Jun such as kill bacteria and true Jun.
Summary of the invention
The object of the invention is to solve above defect, provide a kind of sterilizing deodoring agent, its scope of application is extensive, is convenient to promote, and can play taste removal deodorization and sterilization in daily and medical field.
The object of the invention is to be realized by following scheme:
A kind of sterilizing deodoring agent, it comprises:
(A) organosilicon quaternary ammonium salt that percentage by weight is 0.25 ~ 5% is accounted for;
(B) organo-silicon coupling agent that percentage by weight is 0.1 ~ 2% is accounted for;
(C) stabilizing agent that percentage by weight is 0.2 ~ 2% is accounted for;
(D) surplus is deionized water;
Sterilizing deodoring agent of the present invention, the preferable range of each component is:
(A) organosilicon quaternary ammonium salt that percentage by weight is 0.5 ~ 2.5% is accounted for;
(B) organo-silicon coupling agent that percentage by weight is 0.5 ~ 1% is accounted for;
(C) stabilizing agent that percentage by weight is 0.5 ~ 1.5% is accounted for;
(D) surplus is deionized water;
Sterilizing deodoring agent of the present invention, the preferable range of each component is:
(A) organosilicon quaternary ammonium salt that percentage by weight is 0.5 ~ 0.75% is accounted for;
(B) organo-silicon coupling agent that percentage by weight is 0.5 ~ 0.75% is accounted for;
(C) stabilizing agent that percentage by weight is 0.5 ~ 1.0% is accounted for;
(D) surplus is deionized water;
As preferably, this sterilizing deodoring agent is also added with mixture of a kind of or its any combination in hydrogen peroxide, lemon extract, alcohol, essence.
As preferably, it is 0.01% ~ 1% that hydrogen peroxide accounts for percentage by weight; It is 0.01% ~ 1% that lemon extract accounts for percentage by weight; It is 1% ~ 30% that alcohol accounts for percentage by weight; It is 0.01% ~ 0.2% that essence accounts for percentage by weight.
As preferably, described stabilizing agent is pentaerythrite.
As preferably, this sterilizing deodoring agent is also added with auxiliary material.
As preferably, described auxiliary material is preservative and for regulating the PH conditioning agent of pH value.
Below each component of the present invention is described in detail:
A. machine silicon quaternary ammonium salt
Organosilicon quaternary ammonium salt is a class Novel Cationic Surfactants, and it has high temperature resistant, water-fastness, lasting effect, and scope of restraining fungi is wide, can effectively suppress gram-positive bacteria, Gram-negative bacteria, saccharomycete and fungi.Its sterilization mechanism is: using organosilicon as medium, the ammonium cation group of the energy that has microbe killing properties is adsorbed in forcefully the surface of bacterium, change the permeability of bacteria cell wall, endobacillary enzyme, coenzyme and metabolic intermediate are overflowed, microorganism is caused to cease breathing function and lethal, thus reach sterilization, antibacterial effect, namely there occurs " contact is dead ".
Quarternary ammonium salt compound can adsorb electronegative bacterium, there is good bactericidal action, common quaternary ammonium salt chemism is lower, substantially exist with free state during application, toxicity is relatively large, and excitant is also strong, it can be used as antibacterial agent to apply is dissolution type on the textile, easy wash-out, and easily in human body surface enrichment gradually, Long-Time Service easily produces pathology.If siloxanes to be introduced obtained organosilicon quaternary ammonium salt in quaternary ammonium salt structure, its performance generation great variety can be made.Therefore, organosilicon quaternary ammonium salt is the comparatively ideal antibacterial raw material of a class combination property, when applying without the need to adding reaction resin, there is not pesticide resistance bacterium produced problem.
B. organo-silicon coupling agent
organo-silicon coupling agentbe a topmost class coupling agent, their general formula is RsiX3, is the trisubstituted silane derivative of facile hydrolysis group one X, therefore also known as silane coupler.The coupling mechanism of silane coupler mainly contains two aspects.Can be there is chemical bonding and cause coupling in the first, such as, functional group in a R group and organic resin forms chemical bond, silanol base and material surface form chemical bond or hydrogen bond through base.It two is that silane coupler viscosity is little, and surface tension power is low, and wellability is good, can launched rapidly by sticky material surface and easily ooze its micropore of people, thus is more conducive to glueing joint.Silane coupler should be made into before use low concentration the aqueous solution and use up within a certain period of time, otherwise can when putting for a long time slow hydrolytic condensation ineffective.As being made into non-aqueous solution, can place more for a long time, but also want hermetically drying to store.
Compared with prior art, the present invention has the following advantages:
(1) daily field: sterilizing deodoring agent of the present invention, mainly be made as the spray form of mixing material, be applied to indoor various household articles, the individual personal effects such as footwear and socks, in car and the article such as clothing cloth, article surface is sprayed directly on to during use, the lasting quaternary ammonium group diaphragm of one deck can be formed at article surface, bacterial cytoplasm and cytoplasma membrane can be destroyed, thus prevent the breeding effect of microorganism, play antibacterial and mouldproof and the effect of taste removal deodorization, article are made to be in pure and fresh dry and comfortable germ-free condition for a long time, there is lasting fungistatic effect, scope of restraining fungi is wide, simultaneously reliable to any product safety, free from environmental pollution.
(2) medical field: because organosilicon quaternary ammonium salt has sterilization, antibacterial effect, and utilize it to human non-toxic, gentleness, soft smooth performance, sterilizing deodoring agent of the present invention, be made into the form of spray formula medicament, for the disinfection process of various trauma infection contamination and skin infection, also can be used for the environment disinfected of medical field simultaneously, it is easy to use, it is high that Jun efficiency is killed in sterilization, antipruritic for various skin infection energy quick sterilization, can kill bacterium and anti-bacteria is movable.
Embodiment
Preparation method
Of the present invention kill Jun eliminating smell agent can by any known or other be effectively applicable to provide the technology preparation of mixing spray, prepare method of the present invention and comprise conventional preparation and hybrid technology, the Jun eliminating smell agent that kills of the present invention is formulated as mixed atomizing formula product, will adopt the dark bottles encapsulation of band shower nozzle after raw material preparation and mixing.
Using method
The Jun eliminating smell agent that kills of the present invention makes shower nozzle spray the mode of liquid to use by extruding jet with routine, mainly be divided into daily and medical, daily field is applied to the article such as the individual personal effects such as indoor various household articles, footwear and socks, Che Nei and clothing cloth, be sprayed directly on to article surface during use, play antibacterial and mouldproof and the effect of taste removal deodorization.Medical field, for the disinfection process of various trauma infection contamination and skin infection, also can be used for the environment disinfected of medical field simultaneously, directly spray at trauma infection contamination and skin infection surface and of the present inventionly kill Jun eliminating smell agent, it is high that Jun efficiency is killed in sterilization, antipruritic for various skin infection energy quick sterilization.
Embodiment
Here is non-limiting example of the present invention, the object provided just to illustrating of these examples, and is not understood to limitation of the invention, because do not depart from the spirit and scope of the present invention basis, can carry out many changes to the present invention.In these embodiments, unless stated otherwise, all concentration is all percentage by weight.
Preparation example I-IV
The method comprising the sterilizing deodoring agent of organosilicon quaternary ammonium salt in suitable preparation example I-IV is as follows:
Appropriate amount of deionized water is added in retort, add organosilicon quaternary ammonium salt and disperse stirring and dissolving at normal temperatures, add organo-silicon coupling agent and pentaerythrite again, and mixing and stirring, add the mixture of a kind of or its any combination in hydrogen peroxide, lemon extract, alcohol, essence again, continue to be stirred to and guarantee to obtain uniform mixture, after adding all components, preservative and PH conditioning agent can be added as required, regulate the PH of product to suitable degree, sterilizing deodoring agent after the present invention's allotment is faintly acid, and its pH value is 4-6.
Example I-V
Example VI-X
Embodiment XI-XV
Efficacy assessments embodiment
Effect the present invention for embodiment adopts chemical test and sensory evaluation method.
Described chemical test is: the quantity of first being tested bacterium in 15 pairs of footwear in same shoe chest by bacterial number test bottle, the product of preparation example I-XV is sprayed directly on in 15 pairs of footwear respectively, tested the quantity of bacterium in each pair of footwear afterwards again by bacterial number test bottle every five minutes, the ratio that bacterium reduces in time in the every two footwear of statistics and analysis respectively after one hour, make chart, finally obtain a result, show through implementation data, at one time in section, when organosilicone quaternary ammonium salt content is 0.5%, and hydrogen peroxide and alcohol content all lower, in its footwear, bacterium minimizing quantity is maximum, reduce fastest, bacterium does not grow again simultaneously, fungistatic effect is the most obvious.
Described sensory evaluation method is: the tester that the product of preparation example I-XV issues 15 foot's fungal infections is respectively carried out clinical testing.Foot's fungal infection degree of tester is similar, according to identical using method and usage amount, various embodiment product is sprayed directly on to foot's fungal infection place, uses four every day, used once every three hours, continuous use one week, tester according to oneself foot produce peculiar smell and itch feel mark, standards of grading ten point system, 1 point the poorest, 10 points best, and the higher effect of mark is better.The result of use of various embodiment the results are shown in table 1.
Table 1 sterilizing deodoring agent result of use is evaluated
Show from the result of use evaluation of upper table, in medical field, remove peculiar smell for antipruritic and kill Jun bacteriostasis, when organosilicone quaternary ammonium salt content is 0.5 ~ 0.75%, effect is comparatively remarkable, antipruritic for various skin infection energy quick sterilization, bacterium and anti-bacteria activity can be killed.
Claims (2)
1. a sterilizing deodoring agent, is characterized in that comprising:
(A) organosilicon quaternary ammonium salt that percentage by weight is 0.25 ~ 5% is accounted for;
(B) organo-silicon coupling agent that percentage by weight is 0.1 ~ 2% is accounted for;
(C) stabilizing agent that percentage by weight is 0.2 ~ 2% is accounted for;
(D) surplus is deionized water;
Also be added with the hydrogen peroxide of 0.01% ~ 0.1%.
2. a kind of sterilizing deodoring agent according to claim 1, is characterized in that comprising:
(A) organosilicon quaternary ammonium salt that percentage by weight is 0.5 ~ 2.5% is accounted for;
(B) organo-silicon coupling agent that percentage by weight is 0.5 ~ 1% is accounted for;
(C) stabilizing agent that percentage by weight is 0.5 ~ 1.5% is accounted for;
(D) surplus is deionized water.
3. a kind of sterilizing deodoring agent according to claim 1, is characterized in that comprising:
(A) organosilicon quaternary ammonium salt that percentage by weight is 0.5 ~ 0.75% is accounted for;
(B) organo-silicon coupling agent that percentage by weight is 0.5 ~ 0.75% is accounted for;
(C) stabilizing agent that percentage by weight is 0.5 ~ 1.0% is accounted for;
(D) surplus is deionized water.
4. a kind of sterilizing deodoring agent according to claims 1 to 3 any one, is characterized in that: described stabilizing agent is pentaerythrite.
5. a kind of sterilizing deodoring agent according to claim 4, is characterized in that: this sterilizing deodoring agent is also added with auxiliary material.
6. a kind of sterilizing deodoring agent according to claim 5, is characterized in that: described auxiliary material is preservative and for regulating the PH conditioning agent of pH value.
7. a kind of sterilizing deodoring agent according to claims 1 to 3 any one, is characterized in that: this sterilizing deodoring agent be also added with 0.01% ~ 1% lemon extract, 0.1% ~ 30% alcohol, 0.01% ~ 0.2% essence in a kind of or its any combination mixture.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310249838.XA CN103380784B (en) | 2013-06-21 | 2013-06-21 | Bactericidal odor removing agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310249838.XA CN103380784B (en) | 2013-06-21 | 2013-06-21 | Bactericidal odor removing agent |
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| CN103380784A CN103380784A (en) | 2013-11-06 |
| CN103380784B true CN103380784B (en) | 2015-04-22 |
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| CN201310249838.XA Expired - Fee Related CN103380784B (en) | 2013-06-21 | 2013-06-21 | Bactericidal odor removing agent |
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Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105696323A (en) * | 2016-03-04 | 2016-06-22 | 湖南利洁生物股份有限公司 | Concentrated continuous antibacterial bedding article care solution and using method thereof |
| CN106188473A (en) * | 2016-08-12 | 2016-12-07 | 湖北安固力聚合物科技有限公司 | Three part polyurethane protection insulation resins |
| CN107318876A (en) * | 2017-07-29 | 2017-11-07 | 安徽扬子生物科技有限公司 | A kind of safety-type strong bactericidal eliminating smell agent |
| CN108579270A (en) * | 2018-01-29 | 2018-09-28 | 复纳新材料科技（上海）有限公司 | A kind of net tobacco powder end of air |
| CN109247348A (en) * | 2018-10-08 | 2019-01-22 | 湖北海联技术咨询有限公司 | A kind of Efficient antibacterial medical disinfecting water and preparation method thereof |
| CN110810434A (en) * | 2019-08-01 | 2020-02-21 | 广州博能能源科技有限公司 | Odor-removing and sterilizing AB agent |
| CN110975553A (en) * | 2019-12-06 | 2020-04-10 | 武汉力祯环保科技有限公司 | Garbage deodorization agent |
| CN111226993B (en) * | 2020-03-25 | 2021-08-10 | 华南理工大学 | Long-acting antibacterial and virucidal sanitary protective product spray and application thereof |
| CN111345295B (en) * | 2020-03-30 | 2021-10-22 | 深圳正海创新材料有限公司 | Traditional Chinese medicine oil modified active silicon antibacterial liquid and preparation method thereof, and preparation method of antibacterial coating |
| CN115043723A (en) * | 2022-06-29 | 2022-09-13 | 北京遇见花瓣科技有限公司 | Application of zinc itaconate and preparation process of zinc itaconate-containing deodorant |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4849219A (en) * | 1985-12-16 | 1989-07-18 | Ciba-Geigy Corporation | Microbicides |
| CN1281885A (en) * | 2000-07-06 | 2001-01-31 | 长春市吉工科教开发技术研究所 | Liquid for counting bank-note |
| CN1793271A (en) * | 2005-11-30 | 2006-06-28 | 山东大学 | Single component mildew-proof flame retarded organic silicon sealing agent for machinery and preparation process thereof |
-
2013
- 2013-06-21 CN CN201310249838.XA patent/CN103380784B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4849219A (en) * | 1985-12-16 | 1989-07-18 | Ciba-Geigy Corporation | Microbicides |
| CN1281885A (en) * | 2000-07-06 | 2001-01-31 | 长春市吉工科教开发技术研究所 | Liquid for counting bank-note |
| CN1793271A (en) * | 2005-11-30 | 2006-06-28 | 山东大学 | Single component mildew-proof flame retarded organic silicon sealing agent for machinery and preparation process thereof |
Non-Patent Citations (3)
| Title |
|---|
| 《以固载氯烷基硅氧烷的硅烷的硅胶中间体为原料制备水不溶性杀菌剂》;李凤艳;《水处理技术》;20020630;第28卷(第3期);全文 * |
| 《以硅胶为载体合成水不溶性季铵盐类杀菌剂》;李凤艳;《应用化学》;20010630;第18卷(第6期);全文 * |
| 《新型水不溶性杀菌剂的研制》;李凤艳;《石油化工科学研究院博士论文》;20011231;全文 * |
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