CN103355295B - Emulsion bird repellent and preparation method and use thereof - Google Patents
Emulsion bird repellent and preparation method and use thereof Download PDFInfo
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- CN103355295B CN103355295B CN201310314974.2A CN201310314974A CN103355295B CN 103355295 B CN103355295 B CN 103355295B CN 201310314974 A CN201310314974 A CN 201310314974A CN 103355295 B CN103355295 B CN 103355295B
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Abstract
The invention provides an emulsion bird repellent and a preparation method and use thereof. The emulsion bird repellent is a composition including 20-40 parts by weight of a bird repellent spice, 10-40 parts by weight of an organic solvent, 10-40 parts by weight of carbomer resin, 40-80 parts by weight of pure water, 0.1-5 parts by weight of a stabilizer, 0.1-5 parts by weight of an antioxidant and 0.1-5 parts by weight of an emulsifier. The emulsion bird repellent combined with the preparation method and the use thereof overcomes the problems of difficult emulsification, short bird repellent time, and high cost.
Description
Technical field
The present invention relates to technological field of biochemistry, particularly a kind of emulsion-type bird repellent and its production and use.
Background technology
In recent years, because people's environmental consciousness strengthens, birds life condition is improved, it is many that the kind of bird becomes.And good greening environment and the abundant physical resources in airport makes birds be gathered in this, " bird is hit " upgraded to category-A aviation disaster by federation of international air service.Knock away aspect preventing and treating of machine bird, generally adopt shotgun, clapnet, drive bird viscose, Colour wind-wheel, coal gas big gun, drive the means such as the physics such as bird special-purpose vehicle or ammoniacal liquor poison mist, agricultural chemicals poisoning.Shoot to death and agricultural chemicals poisoning with shotgun, though there is obvious effect on driving birds, cost is also low, but the environment of having violated " People's Republic of China's wild animal conservation law " and serious pollution.Clapnet to the flock of birds activity that exceedes trammel net height without control efficiency.The sound such as pipe of horrible cry sound when driving bird special-purpose vehicle and voice scarecrow device and adopting simulation birds frightened or the bird of prey drives bird, but birds have adapted to the rear effect on driving birds that just lost.Coal gas big gun is for the birds of the huge noisy environment in long-term custom airport, and its effect on driving birds is also very limited.
At present, on market, there are several bird products that drive, concluded and mainly contain following a few class: (1) with the bird driving composition of chemical raw material preparation, as: tmtd, carbosulfan, anthraquinone, aluminum sulfate are pressed etc.This class mostly has very strong toxicity, so driving bird active constituent content cannot join very high, so just cause effect on driving birds bad, and its formulation is all aqua, emulsifiable concentrate or pulvis, all not can be made into slowly-releasing or controlled release preparation, otherwise cause more residue of pesticide, must drive bird ageing also poor.(2) utilize the bitter taste of plant extracts and the bird driving composition of toxicity preparation, as: kuh-seng, Celastrus angulatus, the tuber of stemona, the root of langdu etc.This class is mainly to utilize bitter taste and toxicity to reach the object of driving bird, if long-term use also can work the mischief to birds.(3) bird driving composition that utilizes the fragrance of plant extracts to prepare, as artificial neroli oil, Moschus, cordate houttuynia essential oil etc.This class be relatively environmental protection drive bird product, less to the injury effect of birds, the harm of environment is also little.But there is an emulsification difficulty in existing product, drives the problem that bird timeliness is short, use cost is high.
And also do not have at present one can not injure birds, can long-actingly drive again bird, the easy to use and nontoxic bird product that drives.
Summary of the invention
The invention provides a kind of emulsion-type bird repellent and its production and use, emulsion-type bird repellent, comprise and drive bird spices, organic solvent, carbomer resin, pure water, stabilizing agent, the composition that antioxidant and emulsifier form, the wherein said parts by weight of bird spices in composition that drive are 20-40 part, the parts by weight of described organic solvent in composition are 10-40 part, the parts by weight of described carbomer resin in composition are 0.1-10 part, the parts by weight of described pure water in composition are 40-80 part, the parts by weight of described stabilizing agent in composition are 0.1-5 part, the parts by weight of described antioxidant in composition are 0.1-5 part, the parts by weight of described emulsifier in composition are 0.1-5 part.And just overcome emulsification difficulty, driven the problem that bird timeliness is short, use cost is high in conjunction with Preparation Method And The Use.
For achieving the above object, technical scheme of the present invention is:
A kind of emulsion-type bird repellent, comprise and drive bird spices, organic solvent, carbomer resin, pure water, stabilizing agent, the composition that antioxidant and emulsifier form, the wherein said parts by weight of bird spices in composition that drive are 20-40 part, the parts by weight of described organic solvent in composition are 10-40 part, the parts by weight of described carbomer resin in composition are 0.1-10 part, the parts by weight of described pure water in composition are 40-80 part, the parts by weight of described stabilizing agent in composition are 0.1-5 part, the parts by weight of described antioxidant in composition are 0.1-5 part, the parts by weight of described emulsifier in composition are 0.1-5 part.
The described bird spices that drives is made up of any one or any two kinds in methyl anthranilate, mesitylenic acid or cinnamic acid.
Described organic solvent is terpene hydrocarbon.
Described terpene hydrocarbon is alkene, dipentene, australene, nopinene or (R)-4-isopropenyl-1-methyl-1-cyclohexene.
Described carbomer resin is made up of any one or any two kinds in carbomer resin series.
Described stabilizing agent is made up of one or both in citric acid or Sodium Benzoate.
Described antioxidant is made up of one or both in butylhydroxy anisole or dibutyl hydroxy toluene.
Described emulsifier is made up of any one or any two kinds in the emulsifier of TX series.
Described emulsion-type bird repellent is by spraying and realize after the dilution of emulsion-type bird repellent in the purposes of driving aspect bird.
The preparation method of described emulsion-type bird repellent, step is as follows:
Step 1: the parts by weight according to described carbomer resin in composition are that the parts by weight in composition are that the pure water of the standard of 40-80 part is poured into and mixed the mixture that forms carbomer resin and pure water in container by carbomer resin with according to described pure water for the standard of 0.1-10 part;
Step 2: be the mark of 20-40 part according to the described parts by weight of bird spices in composition that drive
Brigadier drives in the mixture that bird spices adds described carbomer resin and pure water and mixes and form the mixture that drives bird spices, carbomer resin and pure water;
Step 3: the parts by weight according to described organic solvent in composition are the standard of 10-40 part
In the mixture that drives bird spices, carbomer resin and pure water described in organic solvent is added, mix the mixture that forms organic solvent, drives bird spices, carbomer resin and pure water;
Step 4: the parts by weight according to described emulsifier in composition are that 0.1-5 part is by emulsifier
Add described organic solvent, drive in the mixture of bird spices, carbomer resin and pure water and mix the mixture that forms emulsifier, organic solvent, drives bird spices, carbomer resin and pure water;
Step 5: the parts by weight according to described stabilizing agent in composition are 0.1-5 part and described
The parts by weight of antioxidant in composition are that the standard of 0.1-5 part adds described emulsifier, organic solvent by stabilizing agent and antioxidant respectively, drives the mixture that stirs and form stabilizing agent, antioxidant, emulsifier, organic solvent, drive bird spices, carbomer resin and pure water in the mixture of bird spices, carbomer resin and pure water, obtain the finished product of described emulsion-type bird repellent after stable standing 24h.
The mode of stirring in described step 5 be the pH value scope of mixture that stirs above until described stabilizing agent, antioxidant, emulsifier, the organic solvent of 60min, drive bird spices, carbomer resin and pure water in 6.5-7.5 and specific gravity range between 1.000～1.006.
The preparation method's of described emulsion-type bird repellent operating temperature is normal temperature.
Difference with the prior art of the present invention is that bird repellent emulsion is evenly difficult for layering, has good effect on driving birds, and environment is not polluted, and birds is not injured, to person poultry safety.
Embodiment
Below by specific embodiment, the present invention will be further described:
embodiment 1
Described emulsion-type bird repellent comprises the emulsifier of the TX-7 of butylhydroxy anisole, the 1g of citric acid, the 1g of D-citrene, the 1g of pure water, the 150g of carbomer resin 941, the 577g of methyl anthranilate, the 2g of 250g.
Described emulsion-type bird repellent is by spraying and realize after the dilution of emulsion-type bird repellent in the purposes of driving aspect bird.
The preparation method of described emulsion-type bird repellent, step is as follows:
Step 1: the pure water of the carbomer resin 941 of 2g and 577g is poured in container and mixed by high speed disperser the mixture that forms carbomer resin and pure water;
Step 2: mix and form the mixture that drives bird spices, carbomer resin and pure water in the carbomer resin described in the methyl anthranilate of 250g is added and the mixture of pure water;
Step 3: the D-citrene of 150g is added to described bird spices, carbomer resin and the pure water of driving
Mixture in mix and form organic solvent, drive the mixture of bird spices, carbomer resin and pure water;
Step 4: the TX-7 emulsifier of 1g is added to described organic solvent, drives bird spices, carbomer
In the mixture of resin and pure water, stir and close the mixture that 30min mixes formation emulsifier, organic solvent, drives bird spices, carbomer resin and pure water;
Step 5: respectively the butylhydroxy anisole of the citric acid of 1g and 1g added to described emulsifier, organic solvent, drive the mixture that stirs and form stabilizing agent, antioxidant, emulsifier, organic solvent, drive bird spices, carbomer resin and pure water in the mixture of bird spices, carbomer resin and pure water, obtain the finished product of described emulsion-type bird repellent after stable standing 24h.
The mode of stirring in described step 5 be the pH value scope of mixture that stirs above until described stabilizing agent, antioxidant, emulsifier, the organic solvent of 60min, drive bird spices, carbomer resin and pure water in 6.5-7.5 and specific gravity range between 1.000～1.006.
The preparation method's of described emulsion-type bird repellent operating temperature is normal temperature.
embodiment 2
Described emulsion-type bird repellent comprises the emulsifier of the TX-7 of butylhydroxy anisole, the 1g of citric acid, the 1g of D-citrene, the 1g of pure water, the 150g of carbomer resin 941, the 577g of cinnamic acid, the 5g of methyl anthranilate, the 20g of 230g.
Described emulsion-type bird repellent is by spraying and realize after the dilution of emulsion-type bird repellent in the purposes of driving aspect bird.
The preparation method of described emulsion-type bird repellent, step is as follows:
Step 1: the pure water of the carbomer resin 941 of 2g and 577g is poured in container and mixed by high speed disperser the mixture that forms carbomer resin and pure water;
Step 2: mix and form the mixture that drives bird spices, carbomer resin and pure water in the carbomer resin described in the cinnamic acid of the methyl anthranilate of 230g and 20g is added and the mixture of pure water;
Step 3: the D-citrene of 150g is added to described bird spices, carbomer resin and the pure water of driving
Mixture in mix and form organic solvent, drive the mixture of bird spices, carbomer resin and pure water;
Step 4: the TX-7 emulsifier of 1g is added to described organic solvent, drives bird spices, carbomer
In the mixture of resin and pure water, stir and close the mixture that 30min mixes formation emulsifier, organic solvent, drives bird spices, carbomer resin and pure water;
Step 5: respectively the butylhydroxy anisole of the citric acid of 1g and 1g added to described emulsifier, organic solvent, drive the mixture that stirs and form stabilizing agent, antioxidant, emulsifier, organic solvent, drive bird spices, carbomer resin and pure water in the mixture of bird spices, carbomer resin and pure water, obtain the finished product of described emulsion-type bird repellent after stable standing 24h.
The mode of stirring in described step 5 be the pH value scope of mixture that stirs above until described stabilizing agent, antioxidant, emulsifier, the organic solvent of 60min, drive bird spices, carbomer resin and pure water in 6.5-7.5 and specific gravity range between 1.000～1.006.
The preparation method's of described emulsion-type bird repellent operating temperature is normal temperature.
embodiment 3
Described emulsion-type bird repellent comprises the emulsifier of the TX-9 of butylhydroxy anisole, the 1g of citric acid, the 1g of D-citrene, the 1g of pure water, the 100g of carbomer resin 934, the 587g of mesitylenic acid, the 10g of 300g.
Described emulsion-type bird repellent is by spraying and realize after the dilution of emulsion-type bird repellent in the purposes of driving aspect bird.
The preparation method of described emulsion-type bird repellent, step is as follows:
Step 1: the pure water of the carbomer resin 934 of 10g and 587g is poured in container and mixed by high speed disperser the mixture that forms carbomer resin and pure water;
Step 2: mix and form the mixture that drives bird spices, carbomer resin and pure water in the carbomer resin described in the mesitylenic acid of 300g is added and the mixture of pure water;
Step 3: the D-citrene of 100g is added to described bird spices, carbomer resin and the pure water of driving
Mixture in mix and form organic solvent, drive the mixture of bird spices, carbomer resin and pure water;
Step 4: the TX-9 emulsifier of 1g is added to described organic solvent, drives bird spices, carbomer
In the mixture of resin and pure water, stir and close the mixture that 30min mixes formation emulsifier, organic solvent, drives bird spices, carbomer resin and pure water;
Step 5: respectively the butylhydroxy anisole of the citric acid of 1g and 1g added to described emulsifier, organic solvent, drive the mixture that stirs and form stabilizing agent, antioxidant, emulsifier, organic solvent, drive bird spices, carbomer resin and pure water in the mixture of bird spices, carbomer resin and pure water, obtain the finished product of described emulsion-type bird repellent after stable standing 24h.
The mode of stirring in described step 5 be the pH value scope of mixture that stirs above until described stabilizing agent, antioxidant, emulsifier, the organic solvent of 60min, drive bird spices, carbomer resin and pure water in 6.5-7.5 and specific gravity range between 1.000～1.006.
The preparation method's of described emulsion-type bird repellent operating temperature is normal temperature.
embodiment 4
Described emulsion-type bird repellent comprises the emulsifier of the TX-9 of butylhydroxy anisole, the 1g of citric acid, the 1g of D-citrene, the 1g of pure water, the 100g of carbomer resin 934, the 587g of cinnamic acid, the 10g of mesitylenic acid, the 20g of 280g.
Described emulsion-type bird repellent is by spraying and realize after the dilution of emulsion-type bird repellent in the purposes of driving aspect bird.
The preparation method of described emulsion-type bird repellent, step is as follows:
Step 1: the pure water of the carbomer resin 934 of 10g and 587g is poured in container and mixed by high speed disperser the mixture that forms carbomer resin and pure water;
Step 2: mix and form the mixture that drives bird spices, carbomer resin and pure water in the carbomer resin described in the cinnamic acid of the mesitylenic acid of 280g and 20g is added and the mixture of pure water;
Step 3: the D-citrene of 100g is added to described bird spices, carbomer resin and the pure water of driving
Mixture in mix and form organic solvent, drive the mixture of bird spices, carbomer resin and pure water;
Step 4: the TX-9 emulsifier of 1g is added to described organic solvent, drives bird spices, carbomer
In the mixture of resin and pure water, stir and close the mixture that 30min mixes formation emulsifier, organic solvent, drives bird spices, carbomer resin and pure water;
Step 5: respectively the butylhydroxy anisole of the citric acid of 1g and 1g added to described emulsifier, organic solvent, drive the mixture that stirs and form stabilizing agent, antioxidant, emulsifier, organic solvent, drive bird spices, carbomer resin and pure water in the mixture of bird spices, carbomer resin and pure water, obtain the finished product of described emulsion-type bird repellent after stable standing 24h.
The mode of stirring in described step 5 be the pH value scope of mixture that stirs above until described stabilizing agent, antioxidant, emulsifier, the organic solvent of 60min, drive bird spices, carbomer resin and pure water in 6.5-7.5 and specific gravity range between 1.000～1.006.
The preparation method's of described emulsion-type bird repellent operating temperature is normal temperature.
Then the prepared emulsion-type bird repellent of embodiment 1-embodiment 4 is carried out the effect observation of airport bird scaring, observation ground is western certain airport, the emulsion-type bird repellent time that sprays embodiment 1-embodiment 4 is respectively in March, 2013, in May, 2013, in July, 2013, spraying place is lawns, runway both sides, spraying time is 12 noon, every day tracking observation, the duration is two weeks, the emulsion-type bird repellent experimental result of embodiment 1-embodiment 4 is as shown in table 1:
Can find out from above-mentioned experimental result, use after the emulsion-type bird repellent of embodiment 1-embodiment 4, birds obviously reduce, and repellent effect is good, is to be applicable to the ideal product that airport is used.
Also the prepared emulsion-type bird repellent of embodiment 1-embodiment 4 is carried out to the experiment of the repellent effect to pigeon in addition, experimental subjects is 8 pigeons, test method be by 2 one group of circles of pigeon in wire mesh cage, in several days, making them adapt to corn raises, then processing corn feed with the prepared emulsion-type bird repellent of embodiment 1-embodiment 4 is placed in pigeon cage, wherein one group, the two groups feeds of feeding are undressed, three groups, four groups is to process with embodiment 1-embodiment 4 prepared emulsion-type bird repellents, observes pigeon reaction as shown in table 2:
The above; only the embodiment that the present invention is directed to the inventive method; above-described embodiment not does any restriction to the present invention; every according to the given scope of technical solution of the present invention with to any simple modification made for any of the above embodiments, change and equivalent structure variation, all still belong to the protection domain of technical solution of the present invention.
Claims (3)
1. an emulsion-type bird repellent, it is characterized in that comprising and drive bird spices, organic solvent, carbomer resin, pure water, stabilizing agent, the composition that antioxidant and emulsifier form, the wherein said parts by weight of bird spices in composition that drive are 20-40 part, the parts by weight of described organic solvent in composition are 10-40 part, the parts by weight of described carbomer resin in composition are 0.1-10 part, the parts by weight of described pure water in composition are 40-80 part, the parts by weight of described stabilizing agent in composition are 0.1-5 part, the parts by weight of described antioxidant in composition are 0.1-5 part, the parts by weight of described emulsifier in composition are 0.1-5 part,
The described bird spices that drives is any one or two kinds in methyl anthranilate, mesitylenic acid or cinnamic acid;
Described organic solvent is australene, nopinene or (R)-4-isopropenyl-1-methyl-1-cyclohexene;
Described carbomer resin is any one or two kinds in carbomer resin series;
Described stabilizing agent is one or both in citric acid or Sodium Benzoate;
Described antioxidant is one or both in butylhydroxy anisole or dibutyl hydroxy toluene;
Described emulsifier is any one or two kinds in the emulsifier of TX series.
2. the preparation method of emulsion-type bird repellent claimed in claim 1, is characterized in that, step is as follows:
Step 1: the parts by weight according to described carbomer resin in composition are that the parts by weight in composition are that the pure water of the standard of 40-80 part is poured into and mixed the mixture that forms carbomer resin and pure water in container by carbomer resin with according to described pure water for the standard of 0.1-10 part;
Step 2: be that the standard of 20-40 part mixes and forms the mixture that drives bird spices, carbomer resin and pure water driving bird spices and add in the mixture of described carbomer resin and pure water according to the described parts by weight of bird spices in composition that drive;
Step 3: the parts by weight according to described organic solvent in composition are to mix the mixture that forms organic solvent, drives bird spices, carbomer resin and pure water in the mixture that drives bird spices, carbomer resin and pure water described in the standard of 10-40 part adds organic solvent;
Step 4: to be 0.1-5 part add emulsifier described organic solvent, drive in the mixture of bird spices, carbomer resin and pure water and mix the mixture that forms emulsifier, organic solvent, drives bird spices, carbomer resin and pure water the parts by weight according to described emulsifier in composition;
Step 5: the parts by weight according to described stabilizing agent in composition are that 0.1-5 part and the described antioxidant parts by weight in composition are that the standard of 0.1-5 part adds described emulsifier, organic solvent by stabilizing agent and antioxidant respectively, drives the mixture that stirs and form stabilizing agent, antioxidant, emulsifier, organic solvent, drive bird spices, carbomer resin and pure water in the mixture of bird spices, carbomer resin and pure water, the stable finished product that obtains described emulsion-type bird repellent after 24h that leaves standstill;
The mode of stirring in described step 5 be the pH value scope of mixture that stirs above until described stabilizing agent, antioxidant, emulsifier, the organic solvent of 60min, drive bird spices, carbomer resin and pure water in 6.5-7.5 and specific gravity range between 1.000～1.006.
3. the preparation method of emulsion-type bird repellent according to claim 2, is characterized in that the preparation method's of described emulsion-type bird repellent operating temperature is normal temperature.
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| CN105594753A (en) * | 2015-11-17 | 2016-05-25 | 梅庆波 | Method for preparing spraying agent used in orchards for dispelling birds |
| CN107947014A (en) * | 2017-11-30 | 2018-04-20 | 国网山东省电力公司滨州市滨城区供电公司 | New occupying device |
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| CN101361495A (en) * | 2008-09-25 | 2009-02-11 | 黄山市双宝科技应用有限公司 | Bird driving composition and colloid mixture thereof, suspending agent and preparation method thereof |
| CN101662941A (en) * | 2007-05-28 | 2010-03-03 | 前进生物（株） | Gel-type bird aversion compositions |
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| US20060189690A1 (en) * | 2003-11-14 | 2006-08-24 | Dunham Charles F | Compounds to affect insect behavior and/or bird behavior |
| CN101662941A (en) * | 2007-05-28 | 2010-03-03 | 前进生物（株） | Gel-type bird aversion compositions |
| CN101361495A (en) * | 2008-09-25 | 2009-02-11 | 黄山市双宝科技应用有限公司 | Bird driving composition and colloid mixture thereof, suspending agent and preparation method thereof |
| CN102771518A (en) * | 2012-08-14 | 2012-11-14 | 安徽巨地农业科技有限公司 | Granules and microemulsion for repelling olfactory birds and lepidoptera insets and preparation method of granules and microemulsion |
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