CN102125012B - Method for preventing and controlling plant diseases and insect pests by using trap plant and bionic glue - Google Patents

Method for preventing and controlling plant diseases and insect pests by using trap plant and bionic glue Download PDF

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CN102125012B
CN102125012B CN 201010564239 CN201010564239A CN102125012B CN 102125012 B CN102125012 B CN 102125012B CN 201010564239 CN201010564239 CN 201010564239 CN 201010564239 A CN201010564239 A CN 201010564239A CN 102125012 B CN102125012 B CN 102125012B
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bionic glue
plant
glue
bionic
planting thing
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CN102125012A (en
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陈君
徐常青
余柳英
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Foshan Sanshui Xianghai Adhesive Co Ltd
Institute of Medicinal Plant Development of CAMS and PUMC
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Foshan Sanshui Xianghai Adhesive Co Ltd
Institute of Medicinal Plant Development of CAMS and PUMC
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Abstract

The invention discloses a method for preventing and controlling plant diseases and insect pests by using trap crop and bionic glue. The method comprises the following steps: planting trap crop near target plant; before the adults of the insect pests appear, regularly spraying the bionic glue to the surface of the trap plant so as to adhere the insect pests coming to eat or lay eggs, thereby protecting the target plant from the insect pests. The invention also discloses bionic glue which comprises the following raw materials: 25-50% of soft acrylic monomer, 1-5% of acrylic monomer, 0.1-0.3% of nonionic emulsifier, 0.1-0.8% of anionic emulsifier, 0.2-0.6% of catalyst, 0.1-0.3% of preservative, 0.02-0.05% of antifoaming agent and the balance of deionized water. The method disclosed by the invention has high efficiency in preventing and controlling insect pests by combining the trap crop and bionic glue; the bionic glue is environment friendly and harmless to the plant and environment; and moreover, the method disclosed by the invention is simple and has wide application scope.

Description

Utilization lures the method for massive planting thing and bionic glue control plant pest
Technical field
The invention belongs to the plant insect prevention and control field, be specifically related to utilize the method that lures massive planting thing and bionic glue control plant insect.
Background technology
Adopting period poison bait is the method for traditional pest control, but the used poison bait of period poison bait has pollution to environment, and insect produces resistance to poison bait easily.Lure the massive planting thing to spray insecticide also to be commonly use lure the collection disinsection method, but there is too the pesticide pollution environment that sprays, insect do not like taking food sprayed agricultural chemicals lure the massive planting thing, and insect easily develops immunity to drugs, and lures the shortcomings such as the agricultural chemicals term of validity of massive planting thing surface sprinkling is short.Therefore, need to seek the method for the pest control of the effective and environmental sound of a kind of pest control.
Summary of the invention
The object of the present invention is to provide a kind of utilization to lure the method for massive planting thing and bionic glue control plant pest.The method is efficient, environmental protection, nuisanceless.
For achieving the above object, the present invention has taked following technical scheme:
Utilization of the present invention lures the method for massive planting thing and bionic glue control plant pest; plantation lures the massive planting thing near being included in target plant; and before adult pest occurs; luring massive planting thing surface; especially lure the shoot leaf surface of massive planting thing; the periodically sprinkle bionic glue adhere to the insect that takes food or lay eggs of coming, thereby the protection target plant is avoided pest damage.
The massive planting thing that lures described in the said method refers to having a liking for food plant, vector, survive the winter or getting over the summer host of target pest.
The planting patterns that lures the massive planting thing in the said method for around target plant, middle or adopt the mode such as checkerboard type intersection to plant to lure the massive planting thing.
Lure the massive planting thing to impel by cultivation technique measures such as fertilising, prunings to lure the massive planting thing well to grow described in the said method.
Bionic glue described in the said method, the glue that refers to have stickiness can be sprayed directly on plant surface, makes it have the mythimna separata function, but can not affect the normal growth of plant, environmental friendliness.
Bionic glue described in the said method, its raw material constituent and mass percent thereof are: acrylic acid soft monomer 25~50%, acrylic monomers 1~5%, nonionic emulsifier 0.1~0.3%, anion emulsifier 0.1~0.8%, catalyzer 0.2~0.6%, preservative 0.1~0.3%, defoamer 0.02~0.05%, surplus are deionized water.
Acrylic acid soft monomer described in the above-mentioned bionic glue is a kind of or mixture between them of ethyl acrylate, EMA, butyl acrylate, butyl methacrylate, 2-ethyl hexyl acrylate, Isooctyl acrylate monomer, methyl methacrylate or isobutyl methacrylate etc.
Acrylic monomers described in the above-mentioned bionic glue refers to acrylic or methacrylic acid.
Nonionic emulsifier described in the above-mentioned bionic glue is a kind of or mixture between them of polyoxyethylene nonylphenol ether, fatty alcohol-polyoxyethylene ether mixture, polyether-modified trisiloxanes etc.
Anion emulsifier described in the above-mentioned bionic glue refers to a kind of or mixture between them of sodium sulfate of polyethenoxy ether of fatty alcohol, alkyl ether sulfate, alkyl aryl ether sulfate or sulphosuccinates etc.
Catalyzer described in the above-mentioned bionic glue is inorganic peroxide, and described inorganic peroxide is preferably sodium peroxydisulfate, ammonium persulfate or potassium peroxydisulfate etc.
Preservative described in the above-mentioned bionic glue is the isothiazolinone compounds, or the bronopol compounds etc.Such as U.S.'s ROHM AND HAAS
Figure BSA00000364608900021
LXE bactericide (CMIT+MIT), bromine nitre propyl alcohol (2-bromo-2-nitro-1.3-propane diols, C 3H 6BrNO 4) etc. waterborne-type preservation.
Defoamer described in the above-mentioned bionic glue is the water insoluble defoamers such as polysiloxanes compounds, polyether compound or mineral oil antifoam agent.
Above-mentioned bionic glue can also add following composition: fluorescence class material or insect pheromone etc. are at least a.Wherein said fluorescence class material is 0.1~5% ratio interpolation according to mass percent; Described insect pheromone is 0.01~0.1% ratio interpolation according to mass percent.
Described fluorescence class material is long afterglow luminous powder, such as alkaline earth aluminate base, silicate-base light-accumulating luminous material, zinc sulphide or calcium sulfide series phosphor powder etc., is preferably rare earth aluminic acid alkali or rare earth silicate base luminescent powder.Obtain energy through solar radiation daytime, and these fluorescent materials can send the light of certain wave spectrum in the dark, can strengthen the attracting action that some is had the phototaxis insect, thereby improve control efficiency.
Described insect pheromone is that insect sex pheromone, aggregation pheromone or warning message element etc. are at least a.
The preparation method of above-mentioned bionic glue comprises following concrete steps:
(1) proportionally to reactor 1 interior adding deionized water, anion emulsifier, acrylic acid soft monomer and acrylic monomers, is to stir 15~20min under 40~60rpm condition at rotating speed, gets emulsion; Wherein the additional proportion of deionized water is about 7~25% (mass percents) of deionized water total addition level; The additional proportion of anion emulsifier is about 70~90% (mass percents) of anion emulsifier total addition level;
(2) to reactor 2 interior adding deionized waters, anion emulsifier, catalyzer, then under 70~90 ℃, rotating speed 40~50rpm condition, carry out stirring reaction 10~15min; Reactor 2 stirs with 40~50rpm rotating speed from start to finish; The addition of wherein said deionized water is about 70~88% (mass percents) of deionized water total addition level; The addition of described anion emulsifier is 10~30% (mass percents) of anion emulsifier total addition level; The addition of described catalyzer is 10~20% (mass percents) of catalyzer total addition level;
(3) extracting mass percent from reactor 1 is that 5~30% emulsion injects reactor 2, then stirs 10~15min;
(4) place deionized water to dissolve catalyzer; The emulsion droplet of reactor 1 interior remainder is added in the reactor 2, and time for adding is 3~4hr; Drip simultaneously the catalyzer after dissolving, time for adding is 20~30min; After dropwising, insulation 50~70min; The consumption of wherein said deionized water is 5~23% (mass percents) of its total addition level; The addition of described catalyzer is 80~90% (mass percents) that catalyzer adds total amount, and wherein remaining emulsion is 70~95% (mass percents) of emulsion total amount;
(5) reactor 2 is cooled to 40~50 ℃, proportionally adds preservative, defoamer, nonionic emulsifier in reactor 2, stirs 10~15min, and 80~100 orders filter, and collects filtrate, and gained filtrate is bionic glue.
Above-mentioned bionic glue preparation method can be that 0.01~0.1% ratio is added the insect pheromone material in prepared bionic glue according to mass percent.
Above-mentioned bionic glue preparation method, can be that 0.1~5% ratio is added long-afterglow fluorescent class material according to adding mass percent, wherein said fluorescence class material is long afterglow luminous powder, comprise alkaline earth aluminate base, silicate-base light-accumulating luminous material, zinc sulphide, calcium sulfide series phosphor powder etc., be preferably rare earth aluminic acid alkali or rare earth silicate base luminescent powder etc.
When the inventive method is implemented, utilize atomizer bionic glue to be sprayed onto the surface that lures massive planting thing branches and leaves.
Operation principle of the present invention is: pass through atomizer, with the droplet of bionic glue atomizing for 50~150 microns of particle diameters, intersperse among the plant leaf surface, formation is similar to the sticking droplet shape of being with of insectivorous plants structure, and can not stop up the pore of plant, do not affect the gas exchange of plant, do not affect the photosynthesis of plant, make to lure the massive planting thing still insect to be had strong attraction characteristic.Work as insect, when the insect that has a transference such as wood louse, trialeurodes vaporariorum, thrips, leaf miner etc. endangers in plant community and spreads, lured the collection plants to attract, preferentially be chosen in and lure the enterprising behavior evil of massive planting thing, the result is lured the bionic glue that is sprayed on the massive planting thing to stick and is caused death, thereby alleviates the harm to target plant.Especially occur early stage insect, pest population quantity seldom, be in the starting stage of population quantity accumulation, by to building the compacting of group number of pest, slow down the accumulation of insect, the diffusion of restriction insect makes its time that can not reach or delay to arrive index for control, thereby alleviates the harm to target plant.
Compared with prior art, the advantage of the inventive method: (1) efficient is high, and utilization of the present invention lures the massive planting thing to attract insect, then utilizes to be sprayed on the bionic glue that lures on the massive planting thing and to stick insect and make its death, greatly reduce the population quantity of insect, greatly alleviated the harm to target plant; (2) environmental protection, the used bionic glue of the present invention is to plant and environmentally friendly; (3) applied widely: the inventive method is not subjected to plant and environmental limit, and the whole application in period of growing of early stage and plant can occur insect;
(4) there is not the drug-fast problem that common pesticide control produces in the inventive method; (5) the used bionic glue of the present invention has good water resistance, and precipitation can obviously not affect the trapping effect to insect; (6) the inventive method is simple, is suitable for promoting.
Description of drawings
Fig. 1 plants rose of Sharon schematic diagram around honeysuckle.
Fig. 2 plants the kamuning schematic diagram near the granulated sugar tangerine.
Fig. 3 plants easy susceptible worm matrimony vine kind schematic diagram near matrimony vine.
Embodiment
Below the present invention is further illustrated with embodiment, but protection domain of the present invention is not consisted of any restriction.
The preparation of embodiment 1 bionic glue
Raw material constituent and the ratio thereof of bionic glue are: butyl acrylate 25kg, Isooctyl acrylate monomer 20kg, acrylic acid 1kg, lauryl sodium sulfate 200g, Ammonium Persulfate 98.5 200g, hundred kill clean C25 (isothiazolones) 10g, silicone defoaming agent 20g, polyoxyethylene nonylphenol ether (OP-10) 100g, deionized water 53.47kg; Other adds bluish violet aluminate long afterglow luminescent powder 1Kg.
Be prepared as follows:
(1) to reactor 1 interior adding deionized water 8.5kg, lauryl sodium sulfate 140g, add butyl acrylate 25kg, Isooctyl acrylate monomer 20kg and acrylic acid 1kg, be to stir 15min under the 40rpm at rotating speed, get approximately emulsion 54.64kg;
(2) add deionized water 41.0kg, lauryl sodium sulfate 60g to reactor 2, Ammonium Persulfate 98.5 20g, stirring reaction 15min under 70 ℃, rotating speed 50rpm; Reactor 2 stirs with the 50rpm rotating speed from start to finish in whole polymerization process;
(3) from reactor 1, extract emulsion 5kg and directly inject polymerization reaction kettle 2; Stir 15min;
(4) with deionized water 3.97kg ammonium persulfate 180g is dissolved, get ammonium persulfate solution; Remaining emulsion droplet in the reactor 1 is added reactor 2, and time for adding is 3hr; Be added dropwise to simultaneously Ammonium Persulfate 98.5 solution, time for adding is 30min; Stir with the 50rpm rotating speed from start to finish in the whole dropping process;
(5) dropwise after, the insulation 60min; Be cooled to 50 ℃, add hundred and kill clean C25 (isothiazolones, Quzhou City, Zhejiang Province hundred these specialization Co., Ltds) 10g, silicone defoaming agent 20g, polyoxyethylene nonylphenol ether (OP-10) 100g stirs 10min, filter with 100 mesh filter screens, gained filtrate is bionic glue.
In above-mentioned prepared bionic glue, add bluish violet aluminate long afterglow luminescent powder (such as MH, the MH-W series of products of the bright aura electric material of Zhejiang Lanxi Co., Ltd, or the LMS series of products of the luminous Science and Technology Co., Ltd. of Dalian Road name) 1Kg, stir, filter with 100 mesh filter screens, collect filtrate, namely get the bionic glue that contains fluorescent material, sealing saves backup.
Embodiment 2: near plantation rose of Sharon control honeysuckle aphid comparative trial honeysuckle
Honeysuckle aphid (honeysuckle rounded tail aphid Amphicercidus sinilonicericola Zhang, hyalopterus arundinis Hyalopterus arundinis Fabr., therefore carrot microtubule aphid Semiahis heraclei Takahashi etc.) like taking food and produce hibernating egg at the rose of Sharon (Hibiscus syriacus Linn.) branch, select the rose of Sharon to lure the massive planting thing as target plant honeysuckle (Lonicera japonica Thunb.).
(1) experimental scheme: select 3~5 years living gold and silver gardens, process and contrast area and be respectively 100m 2Process and the daily managements such as contrast is adopted identical fertilising, watered, pruning.
(1) processes: lure massive planting thing+bionic glue to process; Honeysuckle is planted according to the seeding row spacing of 1m * 1m, and every the 10 row honeysuckle strip-types plantation rose of Sharon, 1 row, the rose of Sharon of planting is apart from 1.5~2 meters of honeysuckles (seeing Fig. 1).Used bionic glue is the bionic glue of embodiment 1 preparation.
(2) contrast: be entirely honeysuckle, seeding row spacing is 1m * 1m; 1500 times of liquid sprayings of 10% Imidacloprid.
(2) test method: in autumn, before honeysuckle honeysuckle rounded tail aphid alatae produces, select the fine morning or carry out the field processing at dusk.Process: at the bionic glue of rose of Sharon blade spraying embodiment 1 preparation, consumption is 30kg/667m 2, beginning even spraying apart from 1.5~2 meters of rose of Sharon tree crown, the honeysuckle tree crown is left intact.Contrast: spray with 1500 times of liquid honeysuckles of 10% Imidacloprid tree crown.
Second Year spring, process: prune rose of Sharon branch and make it early send out young leaves, and again spray bionic glue early spring, method and consumption are with processing autumn, adhere to the larva of hibernating egg hatching on the rose of Sharon, and lure near the alatae the collection, thereby avoid alatae to lay eggs at the tender tip of honeysuckle.Contrast: the method that adopts process autumn is processed the honeysuckle tree crown again.
Honeysuckle flowering stage (5~June) is the aphid outbreak period, respectively random searching 50 strains in processing and check plot, every strain respectively in the four corners of the world four orientation get a branch, investigate the aphid number (adult, larva) on each branch, and carry out significance of difference analysis; Pluck Lonicera japonica flowering stage, carry out drying with common method for airing, adopt high efficiency liquid phase (HPLC) to analyze residue of pesticide.
Near plantation rose of Sharon control honeysuckle rounded tail aphid aphid comparative test result table 1 honeysuckle
Test is processed Honeysuckle rounded tail aphid aphid (only/branch) The residual detection of farming
Process 0.245±0.7264 Do not detect
Contrast 4.14±6.3301 0.011mg/kg
Statistic analysis result Significant difference
Result's (seeing Table 1) plants the rose of Sharon near honeysuckle, and the method for spraying bionic glue at rose of Sharon tree crown, on its branch honeysuckle rounded tail aphid aphid quantity significantly be lower than contrast, and do not have residue of pesticide.Illustrate that utilization of the present invention lures massive planting thing and the bionic glue pest control that combines effective, and non agricultural chemical residuum.
Embodiment 3: plantation kamuning, sprinkling bionic glue control oranges and tangerines wood louse comparative trial near the granulated sugar tangerine
Therefore oranges and tangerines wood louse (Diaphorina citri Kuwayama) is had a liking for food kamuning (Murrayapaniculata), selects kamuning to lure the massive planting thing as target plant granulated sugar tangerine (Citrus reticulate) control oranges and tangerines wood louse.
(1) experimental scheme: process (1): select 5~6 years living granulated sugar tangerine orchards, in the orchard, plant kamuning (seeing Fig. 2) every 5~6 granulated sugar tangerine checkerboard type intervals, by fertilising, pruning, make its multiple shoot young leaves, enhancing is to the attracting action of oranges and tangerines wood louse, and sprays the bionic glue of embodiment 1 on the kamuning surface.
(2) contrast: all be granulated sugar tangerine plant.Process with 2500 times of liquid sprayings of 1.8% Avermectin.
(2) test method: the oranges and tangerines wood louse survive the winter adult occur before (11~December), select sunny calm morning or at dusk spraying.Bionic glue is processed: get the bionic glue 4L of embodiment 1 preparation, 150 mesh filter screens filter, and put in the sprayer that cleans up, and apart from 1.5~2 meters sprayings of kamuning tree crown, want up and down even spraying inside and outside the canopy.Contrast: spray at granulated sugar tangerine tree crown with 2500 times of 1.8% Avermectin.Summer shoot budding period in 5~June, autumn growth budding period in 8~September bionic glue are processed and contrast is processed once respectively again.
Wood louse survive the winter (early November) bionic glue treatment region and separately random searching 50 strains of check plot before the adult eclosion, every strain is got a branch in four orientation, the four corners of the world respectively, investigate the quantity of wood louse adult, larva, ovum and pupa on each branch, and carry out significance of difference analysis, fructescence (by the end of November) is plucked granulated sugar tangerine fruit, adopts high efficiency liquid phase (HPLC) to analyze residue of pesticide.
Near the plantation kamuning control oranges and tangerines wood louse comparative test result table 2 granulated sugar tangerine
Test is processed The oranges and tangerines wood louse (only/branch) The residual detection of farming
Process 0.06±0.3286 Do not detect
Contrast 0.93±1.9395 0.013mg/Kg
Statistical analysis Significant difference
Result's (seeing Table 2) plants kamuning in citrus orchard, and at kamuning tree crown sprinkling bionic glue, the quantity of its oranges and tangerines wood louse significantly is lower than contrast, and do not detect residue of pesticide, illustrate that utilization of the present invention lures massive planting thing and bionic glue pest control effective, and do not have the risk of residue of pesticide.
The easy susceptible worm matrimony vine kind control Wolfberry Aphid of plantation, wood louse comparative trial near embodiment 4 matrimony vines
(1) experimental scheme: process (1): strip or checkerboard plantation susceptible insect matrimony vine kind or other lure massive planting thing (seeing Fig. 3) in the matrimony vine garden, utilize the insects such as Wolfberry Aphid, wood louse to like taking food at the tender branch of matrimony vine children the characteristics of harm, wait the farming measure to make it often take out a shoot by pruning fertilising, select calm after each shoot is taken out and sends out or luring massive planting thing tree crown to spray the bionic glue of embodiment 1 preparation at dusk, the insect that trapping is come to take food or laid eggs.
(2) contrast: all be the target plant matrimony vine, process with 3000 times of liquid sprayings of 1.8% Avermectin.
(2) test method: behind the autumn collecting medlar (by the end of September), before the adult eclosion of surviving the winter of the insects such as Paratrioza sinica, aphid, select the morning of calm or gentle breeze or luring massive planting thing surface sprinkling bionic glue at dusk, consumption is 50kg/667m 2, 150 mesh filter screens filter, 70~80 microns of spray particle diameters, and distance lures and collects the spraying of kind tree crown 1.5-2 rice, thorax and peripheral even spraying in the tree crown, the adult that survives the winter that trapping is come to take food or laid eggs, contrast is sprayed with 3000 times of liquid of Avermectin of 1.8%.Before the matrimony vine rudiment in early spring (3~April), during 5~June matrimony vine summer shoot rudiment, lure massive planting thing surface again to spray bionic glue, Avermectin is sprayed in contrast again, and consumption and method are with preventing and treating the worm attitude of surviving the winter autumn.Fructescence (the 7-8 month) is luring separately random searching 50 strains of massive planting thing protection zone and pesticide-treated district, a branch is got in four orientation, every strain minute four corners of the world, investigate wood louse on each branch and the quantity of aphid, carry out significance of difference analysis with statistical software; Gather ripening fruits, adopt usual method (with airing under the sun after the sodium bicarbonate processing) processing system to do, with the residue of pesticide in high performance liquid chromatography (HLPC) the detection dry fruit.
The easy susceptible worm matrimony vine kind control Wolfberry Aphid of plantation, wood louse comparative test result near table 3 matrimony vine
Test is processed Paratrioza sinica (only/branch) Aphid (only/branch) The residual detection of farming
Process 0.41±0.836 0.55±1.778 Do not detect
Contrast 1.50±2.054 3.429±4.275 0.017mg/Kg
Statistic analysis result Significant difference Significant difference
Result's (seeing Table 3) the present invention plants the matrimony vine kind of susceptible insect as luring the massive planting thing in the matrimony vine garden, luring massive planting thing tree crown to spray bionic glue, the quantity of its Paratrioza sinica and aphid significantly is lower than contrast, and do not detect residue of pesticide, illustrate that utilization of the present invention lures massive planting thing and bionic glue pest control effective, and do not have the risk of residue of pesticide.

Claims (9)

1. utilize the method lure massive planting thing and bionic glue control plant pest, it is characterized in that plantation lures the massive planting thing near target plant, and before adult pest occurs, luring massive planting thing surface, the periodically sprinkle bionic glue adheres to the insect that takes food or lay eggs of coming; Raw material constituent and the mass percent thereof of described bionic glue are: acrylic acid soft monomer 25~50%, acrylic monomers 1~5%, nonionic emulsifier 0.1~0.3%, anion emulsifier 0.1~0.8%, catalyzer 0.2~0.6%, preservative 0.1~0.3%, defoamer 0.02~0.05%, surplus is deionized water.
2. in accordance with the method for claim 1, it is characterized in that the described massive planting thing that lures refers to having a liking for food plant, vector, overwintering host or getting over the summer host of target pest.
3. in accordance with the method for claim 1, it is characterized in that the described planting patterns that lures the massive planting thing for around target plant, middle or adopt the plantation of checkerboard type interleaved mode.
4. in accordance with the method for claim 1, it is characterized in that described branch, the leaf surface that lures massive planting thing surface to refer to lure the massive planting thing.
5. in accordance with the method for claim 1, it is characterized in that described bionic glue also contains fluorescence class material, described fluorescence class material is 0.1~5% ratio interpolation according to mass percent.
6. according to claim 1 or 5 described methods, it is characterized in that described bionic glue also contains insect pheromone, described insect pheromone is 0.01~0.1% ratio interpolation according to mass percent.
7. in accordance with the method for claim 1, it is characterized in that described acrylic acid soft monomer is a kind of of ethyl acrylate, EMA, butyl acrylate, butyl methacrylate, 2-ethyl hexyl acrylate, Isooctyl acrylate monomer, methyl methacrylate or isobutyl methacrylate or the mixture between them; Described acrylic monomers refers to acrylic or methacrylic acid, or their mixture.
8. in accordance with the method for claim 1, it is characterized in that described nonionic emulsifier is a kind of or mixture between them of polyoxyethylene nonylphenol ether, fatty alcohol-polyoxyethylene ether mixture, polyether-modified trisiloxanes; Described anion emulsifier refers to a kind of of sodium sulfate of polyethenoxy ether of fatty alcohol, alkyl ether sulfate, alkyl aryl ether sulfate or sulphosuccinates or the mixture between them.
9. in accordance with the method for claim 1, it is characterized in that described catalyzer is sodium peroxydisulfate, ammonium persulfate or potassium peroxydisulfate; Described preservative is the isothiazolinone compounds, or the bronopol compounds; Described defoamer is polysiloxanes compounds, polyether compound or mineral oil antifoam agent.
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