CN102771518A - Granules and microemulsion for repelling olfactory birds and lepidoptera insets and preparation method of granules and microemulsion - Google Patents
Granules and microemulsion for repelling olfactory birds and lepidoptera insets and preparation method of granules and microemulsion Download PDFInfo
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- CN102771518A CN102771518A CN2012102927573A CN201210292757A CN102771518A CN 102771518 A CN102771518 A CN 102771518A CN 2012102927573 A CN2012102927573 A CN 2012102927573A CN 201210292757 A CN201210292757 A CN 201210292757A CN 102771518 A CN102771518 A CN 102771518A
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Abstract
The invention relates to a technology for repelling olfactory birds and lepidoptera insets, and in particular relates to granules and microemulsion for repelling the olfactory birds and the lepidoptera insets and a preparation method of the granules and the microemulsion. A combination of the granules and the microemulsion comprises the following active ingredients in weight percent: 4 to 6 of 10%-50% of methyl anthranilate, 0.2%-0.6% of white mustard seed, 0.1%-0.5% of essential oil of jasmine, 1%-2% of essential oil of houttuynia cordata, 2%-5% of camphor and 0.3%-0.7% of methyl cinnamate, and the balance of water and auxiliaries. The granules and the microemulsion have controlled-release matters with special smells which can stimulate the trigeminal nerve (balance nerve) and nervus centralis of the birds and the lepidoptera insets, so that the birds and the lepidoptera insets are out of balance to cause a fear response, realize the danger and fly away, and thus a repelling effect is realized.
Description
Technical field
The present invention relates to birds homopterous insect repellent technology, relate in particular to repellent granule and microemulsion of a kind of sense of smell type birds homopterous insect and preparation method thereof.
Background technology
Repellant, it is defined as the active chemistry with repel insects effect by plant generation or synthetic.Generally speaking, no insecticidal activity own, the smell repel insects according to volatilizing is fled from insect.
Though the nontoxic effect of murdering worm of these medicaments itself because it has certain special smell, can make insect avoid and keep away, and maybe can disperse insect.Repellant mainly is to cause temporary smell to pollute to the influence of environment, generally can the long-term hazards environment or the destruction ecological balance.
Along with in recent years, owing to the enforcement of conceding the land to forestry policy, the improvement of natural environment, people make the quantity of birds and homopterous insect sharply increase to the enhancing gradually of the protection consciousness of birds and homopterous insect, and orchard and field-crop harm are comparatively serious.At present, the kind of repellant is comparatively various on the market, but main some defectives that exist:
1, unfriendly to environment, be prone to contaminated environment, the residual harmful components that are difficult to degrade.
2, select comparatively expensive raw material for use, production cost is higher.
3, repellent effect is not good, repellent often occurs after a period of time, is prone to produce " immunity " phenomenon, thereby causes birds and (or continuing) generation once more of homopterous insect disaster.
Summary of the invention
To the technical problem that exists in the prior art, the object of the present invention is to provide repellent granule and microemulsion of good, the environment amenable sense of smell type of a kind of repellent effect birds homopterous insect and preparation method thereof.
The technical scheme that the present invention adopted is:
The repellant compositions of sense of smell type birds homopterous insect; It is characterized in that; In total weight percent, active ingredient is 4～6 kinds in methyl anthranilate 10～50%, semen brassicae 0.2～0.6%, Jasmine essential oil 0.1～0.5%, cordate houttuynia essential oil 1～2%, camphor 2～5% and the methyl cinnamate 0.3～0.7%; Surplus is water and auxiliary agent.
Through inventor's long term test, surprised discovery when semen brassicae is applied to the repellent field, produces hot strong pungent effect, and birds and homopterous insect are had repellent effect preferably.Simultaneously, cooperate the Jasmine essential oil, and raw material such as cordate houttuynia essential oil, mix repellant with special odor.
When spraying cereal etc. and use, have the sustained-release materials of special odor, the trigeminal neuralgia (equilibrium nerve) and the nervous centralis of birds and lepidopterous insects stimulated; Let birds and homopterous insect disequilibrium; Produce frightenedly, and recognize danger and flee from, thereby reach repellent effect.
Birds homopterous insect repellant can be made into various formulation of the prior art, for example aqueous emulsion, microemulsion, missible oil, granule or paste etc.
Through lot of experiment validation, when dosage form selection was microemulsion and granule, it is best that its repellent effect reaches.
When processing microemulsion, in total weight percent, auxiliary agent is made up of following component, neopelex 2～3%, glycerine 3～5%, Sodium Benzoate 0.3～0.5%, guar gum 0.2～0.5%, emulsifier 10～12%.
The preparation method of birds homopterous insect repellent microemulsion, step is following:
(1), with active ingredient mix to stir, heating for dissolving, make oil phase;
(2), with water, auxiliary agent mixing and stirring;
(3), (1) is slowly added in (2), stir emulsification pretreatment, sampling, check promptly get.
When processing granule, in total weight percent, auxiliary agent is made up of following component, aminotransferase 0.03～0.09%, active carbon 20～40%, polyvinyl alcohol 0.3～0.5%, Sodium Benzoate 0.3～0.5%, guar gum 0.2～0.5%.
The preparation method of birds homopterous insect repellent granule, step is following:
Each component except that active carbon is mixed, and place mixed solution to soak 48～72h active carbon, pull out, drain, get final product.
According to the repellant of above-mentioned preparation method's preparation,, reach repellent effect not injuring under the healthy prerequisite of birds and homopterous insect.Therefore, the repellant compositions of the present invention research, effectively repellent birds and homopterous insect, environmental sound, genus safe and harmless type repellent product truly.
The product of the present invention's preparation can or spray adaptable across the extension bottle in the agricultural production and spread fertilizer over the fields mellow fruit thing etc., also can be applicable to airport security repellent field.
Embodiment
Below will combine embodiment, the present invention will be carried out comparatively detailed explanation.
Embodiment 1
The repellent microemulsion; Component is methyl anthranilate 10%, semen brassicae 0.6%, Jasmine essential oil 0.3%, cordate houttuynia essential oil 1%, camphor 5% and methyl cinnamate 0.7%, neopelex 2%, glycerine 4.5%, Sodium Benzoate 0.3%, guar gum 0.35%, emulsifier 12%, and surplus is a water.
Preparation method's step is following:
(1), with active ingredient (methyl anthranilate, semen brassicae, Jasmine essential oil, cordate houttuynia essential oil, camphor and methyl cinnamate) mix to stir, heating for dissolving, make oil phase;
(2), with water, whole auxiliary agent mixing and stirring;
(3), (1) is slowly added in (2), stir emulsification pretreatment, sampling, check promptly get.
Embodiment 2
The repellent microemulsion; Component is methyl anthranilate 50%, semen brassicae 0.2%, Jasmine essential oil 0.25%, cordate houttuynia essential oil 2%, camphor 2%, neopelex 3%, glycerine 3.5%, Sodium Benzoate 0.5%, guar gum 0.4%, emulsifier 10%, and surplus is a water.
The preparation method is with embodiment 1.
Embodiment 3
The repellent microemulsion; Component is methyl anthranilate 30%, semen brassicae 0.3%, cordate houttuynia essential oil 1.5%, camphor 2.5%, methyl cinnamate 0.3%, neopelex 2.8%, glycerine 4%, Sodium Benzoate 0.4%, guar gum 0.3%, emulsifier 10.5%, and surplus is a water.
The preparation method is with embodiment 1.
Embodiment 4
The repellent microemulsion; Component is methyl anthranilate 40%, semen brassicae 0.4%, Jasmine essential oil 0.1%, cordate houttuynia essential oil 1.2%, methyl cinnamate 0.4%, neopelex 2.5%, glycerine 5%, Sodium Benzoate 0.45%, guar gum 0.5%, emulsifier 11.5%, and surplus is a water.
The preparation method is with embodiment 1.
Embodiment 5
The repellent microemulsion; Component is methyl anthranilate 25%, semen brassicae 0.5%, Jasmine essential oil 0.5%, camphor 4.5%, methyl cinnamate 0.5%, neopelex 2.2%, glycerine 3%, Sodium Benzoate 0.35%, guar gum 0.2%, emulsifier 11%, and surplus is a water.
The preparation method is with embodiment 1.
Embodiment 6
The repellent granule; Component is methyl anthranilate 10%, semen brassicae 0.6%, Jasmine essential oil 0.3%, cordate houttuynia essential oil 1%, camphor 5% and methyl cinnamate 0.7%, aminotransferase 0.09%, active carbon 40%; Polyvinyl alcohol 0.3%; Sodium Benzoate 0.45%, guar gum 0.5%, surplus is a water.
Preparation method: each component except that active carbon is mixed, and place mixed solution to soak 60h active carbon, pull out, drain, get final product.
Embodiment 7
The repellent granule; Component is methyl anthranilate 50%, semen brassicae 0.2%, Jasmine essential oil 0.25%, cordate houttuynia essential oil 2%, camphor 2%, aminotransferase 0.03%, active carbon 20%, polyvinyl alcohol 0.5%, Sodium Benzoate 0.4%; Guar gum 0.2%, surplus are water.
Preparation method: each component except that active carbon is mixed, and place mixed solution to soak 48h active carbon, pull out, drain, get final product.
Embodiment 8
The repellent granule; Component is methyl anthranilate 30%, semen brassicae 0.3%, cordate houttuynia essential oil 1.5%, camphor 2.5%, methyl cinnamate 0.3%, aminotransferase 0.04%, active carbon 30%, polyvinyl alcohol 0.35%, Sodium Benzoate 0.35%; Guar gum 0.25%, surplus are water.
Preparation method: each component except that active carbon is mixed, and place mixed solution to soak 72h active carbon, pull out, drain, get final product.
Embodiment 9
The repellent granule; Component is methyl anthranilate 40%, semen brassicae 0.4%, Jasmine essential oil 0.1%, cordate houttuynia essential oil 1.2%, methyl cinnamate 0.4%, aminotransferase 0.07%, active carbon 25%; Polyvinyl alcohol 0.45%; Sodium Benzoate 0.5%, guar gum 0.35%, surplus is a water.
Preparation method: each component except that active carbon is mixed, and place mixed solution to soak 55h active carbon, pull out, drain, get final product.
Embodiment 10
The repellent granule; Component is methyl anthranilate 25%, semen brassicae 0.5%, Jasmine essential oil 0.5%, camphor 4.5%, methyl cinnamate 0.5%, aminotransferase 0.065%, active carbon 35%, polyvinyl alcohol 0.4%, Sodium Benzoate 0.3%; Guar gum 0.45%, surplus are water.
Preparation method: each component except that active carbon is mixed, and place mixed solution to soak 68h active carbon, pull out, drain, get final product.
The comparative example 1
Be not add semen brassicae with the difference of embodiment 1, other is identical.
The comparative example 2
Be not add semen brassicae with the difference of embodiment 6, other is identical.
Feed magpie test of embodiment 1～10 and comparative example 1～2:
Processing method:
With the bird mouse repellant of embodiment 1～10 and comparative example's 1～2 preparation, cereal (wheat) is dressed seed.To wait the quantity wheat seed to be seeded in the homalographic soil, the surplus of seed after the observation different number of days.Blank test is that wheat is left intact.
Result of the test, shown in table 1 and table 2:
The table 1 repellent microemulsion magpie result of the test of feeding
Can find out from table 1:
1, combines comparative example 1 and embodiment 1 result of the test, can find out, semen brassicae is applied to birds homopterous insect repellent microemulsion, can significantly improve repellent effect.
2, the result of the test that combines embodiment 1～5, comparative example 1 and blank test; Can find out that sense of smell type birds homopterous insect repellant of the present invention has significant repellent effect to the birds homopterous insect; Effective repellent birds homopterous insect; Simultaneously, environmental sound belongs to safe and harmless type repellent product truly.Because it has the sustained-release materials of special odor, trigeminal neuralgia (equilibrium nerve) and the nervous centralis of birds and lepidopterous insects stimulated, let birds and homopterous insect disequilibrium, the generation fear, and recognize danger and flee from, thereby reach repellent effect.
Yuan's 2 repellent granules magpie result of the test of feeding
Can find out from table 2:
1, combines comparative example 2 and embodiment 6 result of the tests, can find out, semen brassicae is applied to birds homopterous insect repellent granule, can significantly improve repellent effect.
2, the result of the test that combines embodiment 6～10, comparative example 2 and blank test; Can find out that sense of smell type birds homopterous insect repellant of the present invention has significant repellent effect to the birds homopterous insect; Effective repellent birds homopterous insect; Simultaneously, environmental sound belongs to safe and harmless type repellent product truly.
Above content only is giving an example and explanation that the present invention is done; Under the technical staff in present technique field described specific embodiment is made various modifications or replenish or adopt similar mode to substitute; Only otherwise depart from the design of invention or surmount the defined scope of these claims, all should belong to protection scope of the present invention.
Claims (8)
1. the repellant compositions of sense of smell type birds homopterous insect; It is characterized in that; In total weight percent, active ingredient is 4～6 kinds in methyl anthranilate 10～50%, semen brassicae 0.2～0.6%, Jasmine essential oil 0.1～0.5%, cordate houttuynia essential oil 1～2%, camphor 2～5% and the methyl cinnamate 0.3～0.7%; Surplus is water and auxiliary agent.
2. birds homopterous insect repellant, aqueous emulsion, microemulsion, missible oil, granule or the paste processed according to the said composition of claim 1.
3. birds homopterous insect repellant as claimed in claim 2 is characterized in that formulation is a microemulsion.
4. birds homopterous insect repellant as claimed in claim 2 is characterized in that formulation is a granule.
5. birds homopterous insect repellent microemulsion as claimed in claim 3 is characterized in that, in total weight percent; Said auxiliary agent is made up of following component; Neopelex 2～3%, glycerine 3～5%, Sodium Benzoate 0.3～0.5%; Guar gum 0.2～0.5%, emulsifier 10～12%.
6. preparation is characterized in that like the method for the said birds homopterous insect of claim 5 repellent microemulsion step is following:
(1), with active ingredient mix to stir, heating for dissolving, make oil phase;
(2), with water, auxiliary agent mixing and stirring;
(3), (1) is slowly added in (2), stir emulsification pretreatment, sampling, check promptly get.
7. birds homopterous insect repellent granule as claimed in claim 4; It is characterized in that in total weight percent, said auxiliary agent is made up of following component; Aminotransferase 0.03～0.09%, active carbon 20～40%; Polyvinyl alcohol 0.3～0.5%, Sodium Benzoate 0.3～0.5%, guar gum 0.2～0.5%.
8. preparation is characterized in that like the method for the said birds homopterous insect of claim 7 repellent granule step is following: each component except that active carbon is mixed, and place mixed solution to soak 48～72h active carbon, pull out, drain, get final product.
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| CN201210292757.3A CN102771518B (en) | 2012-08-14 | 2012-08-14 | Granules and microemulsion for repelling olfactory birds and lepidoptera insets and preparation method of granules and microemulsion |
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| CN201210292757.3A CN102771518B (en) | 2012-08-14 | 2012-08-14 | Granules and microemulsion for repelling olfactory birds and lepidoptera insets and preparation method of granules and microemulsion |
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| CN102771518A true CN102771518A (en) | 2012-11-14 |
| CN102771518B CN102771518B (en) | 2014-07-23 |
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Cited By (8)
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| CN103147230A (en) * | 2013-03-20 | 2013-06-12 | 武汉纺织大学 | Fully-degradable bird-repelling agricultural non-woven fabric and preparation method for same |
| CN103355295A (en) * | 2013-07-25 | 2013-10-23 | 西安高科理化技术有限责任公司 | Emulsion bird repellent and preparation method and use thereof |
| CN104285990A (en) * | 2014-10-09 | 2015-01-21 | 安徽农业大学 | Compound bird repellent containing carbosulfan, methyl ortho-aminobenzoate and benzyl acetate |
| CN104844110A (en) * | 2015-04-23 | 2015-08-19 | 铜陵祥云消防科技有限责任公司 | Heat insulation and flame retardation material for bird-proof exterior walls |
| CN104861664A (en) * | 2015-04-23 | 2015-08-26 | 铜陵祥云消防科技有限责任公司 | Bird pecking-proofing fireproof jam material and preparation method thereof |
| CN108378015A (en) * | 2018-02-24 | 2018-08-10 | 王鹏飞 | A kind of coating method of particle bird repellent |
| CN109897533A (en) * | 2019-03-16 | 2019-06-18 | 山东申烨电气科技有限公司 | A kind of anti-bird coating of RTV and preparation method thereof |
| CN113662018A (en) * | 2021-09-18 | 2021-11-19 | 西安为开化工科技有限公司 | Repellent for bat and small birds and preparation method thereof |
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Patent Citations (4)
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Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103147230A (en) * | 2013-03-20 | 2013-06-12 | 武汉纺织大学 | Fully-degradable bird-repelling agricultural non-woven fabric and preparation method for same |
| CN103355295A (en) * | 2013-07-25 | 2013-10-23 | 西安高科理化技术有限责任公司 | Emulsion bird repellent and preparation method and use thereof |
| CN103355295B (en) * | 2013-07-25 | 2014-10-15 | 西安高科理化技术有限责任公司 | Emulsion bird repellent and preparation method and use thereof |
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| CN104285990B (en) * | 2014-10-09 | 2016-03-02 | 安徽农业大学 | A kind of composite bird repellent containing carbosulfan, methyl anthranilate and benzyl acetate |
| CN104844110A (en) * | 2015-04-23 | 2015-08-19 | 铜陵祥云消防科技有限责任公司 | Heat insulation and flame retardation material for bird-proof exterior walls |
| CN104861664A (en) * | 2015-04-23 | 2015-08-26 | 铜陵祥云消防科技有限责任公司 | Bird pecking-proofing fireproof jam material and preparation method thereof |
| CN108378015A (en) * | 2018-02-24 | 2018-08-10 | 王鹏飞 | A kind of coating method of particle bird repellent |
| CN109897533A (en) * | 2019-03-16 | 2019-06-18 | 山东申烨电气科技有限公司 | A kind of anti-bird coating of RTV and preparation method thereof |
| CN113662018A (en) * | 2021-09-18 | 2021-11-19 | 西安为开化工科技有限公司 | Repellent for bat and small birds and preparation method thereof |
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| CN102771518B (en) | 2014-07-23 |
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