CN102771518B - Granules and microemulsion for repelling olfactory birds and lepidoptera insets and preparation method of granules and microemulsion - Google Patents
Granules and microemulsion for repelling olfactory birds and lepidoptera insets and preparation method of granules and microemulsion Download PDFInfo
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- CN102771518B CN102771518B CN201210292757.3A CN201210292757A CN102771518B CN 102771518 B CN102771518 B CN 102771518B CN 201210292757 A CN201210292757 A CN 201210292757A CN 102771518 B CN102771518 B CN 102771518B
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Abstract
The invention relates to a technology for repelling olfactory birds and lepidoptera insets, and in particular relates to granules and microemulsion for repelling the olfactory birds and the lepidoptera insets and a preparation method of the granules and the microemulsion. A combination of the granules and the microemulsion comprises the following active ingredients in weight percent: 4 to 6 of 10%-50% of methyl anthranilate, 0.2%-0.6% of white mustard seed, 0.1%-0.5% of essential oil of jasmine, 1%-2% of essential oil of houttuynia cordata, 2%-5% of camphor and 0.3%-0.7% of methyl cinnamate, and the balance of water and auxiliaries. The granules and the microemulsion have controlled-release matters with special smells which can stimulate the trigeminal nerve (balance nerve) and nervus centralis of the birds and the lepidoptera insets, so that the birds and the lepidoptera insets are out of balance to cause a fear response, realize the danger and fly away, and thus a repelling effect is realized.
Description
Technical field
The present invention relates to birds homopterous insect repellent technology, relate in particular to a kind of repellent granule of sense of smell type birds homopterous insect and microemulsion and preparation method thereof.
Background technology
Repellant, it is defined as the active chemistry with repel insects effect that is produced or manually synthesized by plant.Generally, itself according to the smell repel insects volatilizing, flees from insect without insecticidal activity.
Though the effect of the nontoxic kill insects of these medicaments itself, because it has certain special smell, can make insect avoid and keep away, and maybe can disperse insect.Repellant is mainly to cause temporary smell to pollute on the impact of environment, generally can long-term hazards environment or the destruction ecological balance.
Along with in recent years, due to the enforcement of conceding the land to forestry policy, the improvement of natural environment, the enhancing gradually of the protection consciousness of people to birds and homopterous insect, sharply increases the quantity of birds and homopterous insect, and orchard and field-crop harm are comparatively serious.At present, on market, the kind of repellant is comparatively various, but main some defects that exist:
1, unfriendly to environment, easily contaminated environment, the harmful components of residual hard degradation.
2, select comparatively expensive raw material, production cost is higher.
3, repellent effect is not good, often occurs after repellent a period of time, easily produces " immunity " phenomenon, thereby causes birds and (or continuing) generation again of homopterous insect disaster.
Summary of the invention
For the technical problem existing in prior art, the object of the present invention is to provide the repellent granule of good, the environment amenable sense of smell type of a kind of repellent effect birds homopterous insect and microemulsion and preparation method thereof.
The technical solution adopted in the present invention is:
The repellant compositions of sense of smell type birds homopterous insect, it is characterized in that, in total weight percent, active ingredient is 4～6 kinds in methyl anthranilate 10～50%, semen brassicae 0.2～0.6%, Jasmine essential oil 0.1～0.5%, cordate houttuynia essential oil 1～2%, camphor 2～5% and methyl cinnamate 0.3～0.7%; Surplus is water and auxiliary agent.
Through inventor's long term test, surprised discovery, when semen brassicae is applied to repellent field, produces pungent strong pungent effect, and birds and homopterous insect are had to good repellent effect.Meanwhile, coordinate Jasmine essential oil, and the raw material such as cordate houttuynia essential oil, mix the repellant with special odor.
In the time spraying the application such as cereal, there is the sustained-release materials of special odor, trigeminal neuralgia (equilibrium nerve) and nervous centralis to birds and lepidopterous insects stimulate, allow birds and homopterous insect disequilibrium, produce frightenedly, and recognize danger and flee from, thereby reach repellent effect.
Birds homopterous insect repellant, can be made into various formulation of the prior art, such as aqueous emulsion, microemulsion, missible oil, granule or paste etc.
Through lot of experiment validation, in the time that dosage form selection is microemulsion and granule, it is best that its repellent effect reaches.
In the time making microemulsion, in total weight percent, auxiliary agent is made up of following component, neopelex 2～3%, glycerine 3～5%, Sodium Benzoate 0.3～0.5%, guar gum 0.2～0.5%, emulsifier 10～12%.
The preparation method of birds homopterous insect repellent microemulsion, step is as follows:
(1), by active ingredient mix and blend, heating for dissolving, make oil phase;
(2), by water, auxiliary agent mixing and stirring;
(3), (1) is slowly added in (2), stir emulsification pretreatment, sampling, inspection, to obtain final product.
In the time of granulation agent, in total weight percent, auxiliary agent is made up of following component, aminotransferase 0.03～0.09%, active carbon 20～40%, polyvinyl alcohol 0.3～0.5%, Sodium Benzoate 0.3～0.5%, guar gum 0.2～0.5%.
The preparation method of birds homopterous insect repellent granule, step is as follows:
Each component except active carbon is mixed, and active carbon is placed in to mixed solution soaks 48～72h, pull out, drain.
The repellant of preparing according to above-mentioned preparation method, not injuring under the prerequisite of birds and homopterous insect health, reaches repellent effect.Therefore, the repellant compositions of the present invention's research, effectively repellent birds and homopterous insect, environmental sound, belongs to safe and harmless type repellent product truly.
Product prepared by the present invention can be widely used in the extension bottle in agricultural production or spray spreading fertilizer over the fields mellow fruit thing etc., also can be applicable to airport security repellent field.
Embodiment
Below with reference to embodiment, the present invention is described in detail.
Embodiment 1
Repellent microemulsion, component is methyl anthranilate 10%, semen brassicae 0.6%, Jasmine essential oil 0.3%, cordate houttuynia essential oil 1%, camphor 5% and methyl cinnamate 0.7%, neopelex 2%, glycerine 4.5%, Sodium Benzoate 0.3%, guar gum 0.35%, emulsifier 12%, and surplus is water.
Preparation method's step is as follows:
(1), by active ingredient (methyl anthranilate, semen brassicae, Jasmine essential oil, cordate houttuynia essential oil, camphor and methyl cinnamate) mix and blend, heating for dissolving, make oil phase;
(2), by water, whole auxiliary agent mixing and stirring;
(3), (1) is slowly added in (2), stir emulsification pretreatment, sampling, inspection, to obtain final product.
Embodiment 2
Repellent microemulsion, component is methyl anthranilate 50%, semen brassicae 0.2%, Jasmine essential oil 0.25%, cordate houttuynia essential oil 2%, camphor 2%, neopelex 3%, glycerine 3.5%, Sodium Benzoate 0.5%, guar gum 0.4%, emulsifier 10%, and surplus is water.
Preparation method is with embodiment 1.
Embodiment 3
Repellent microemulsion, component is methyl anthranilate 30%, semen brassicae 0.3%, cordate houttuynia essential oil 1.5%, camphor 2.5%, methyl cinnamate 0.3%, neopelex 2.8%, glycerine 4%, Sodium Benzoate 0.4%, guar gum 0.3%, emulsifier 10.5%, and surplus is water.
Preparation method is with embodiment 1.
Embodiment 4
Repellent microemulsion, component is methyl anthranilate 40%, semen brassicae 0.4%, Jasmine essential oil 0.1%, cordate houttuynia essential oil 1.2%, methyl cinnamate 0.4%, neopelex 2.5%, glycerine 5%, Sodium Benzoate 0.45%, guar gum 0.5%, emulsifier 11.5%, and surplus is water.
Preparation method is with embodiment 1.
Embodiment 5
Repellent microemulsion, component is methyl anthranilate 25%, semen brassicae 0.5%, Jasmine essential oil 0.5%, camphor 4.5%, methyl cinnamate 0.5%, neopelex 2.2%, glycerine 3%, Sodium Benzoate 0.35%, guar gum 0.2%, emulsifier 11%, and surplus is water.
Preparation method is with embodiment 1.
Embodiment 6
Repellent granule, component is methyl anthranilate 10%, semen brassicae 0.6%, Jasmine essential oil 0.3%, cordate houttuynia essential oil 1%, camphor 5% and methyl cinnamate 0.7%, aminotransferase 0.09%, active carbon 40%, polyvinyl alcohol 0.3%, Sodium Benzoate 0.45%, guar gum 0.5%, surplus is water.
Preparation method: the each component except active carbon is mixed, and active carbon is placed in to mixed solution soaks 60h, pull out, drain.
Embodiment 7
Repellent granule, component is methyl anthranilate 50%, semen brassicae 0.2%, Jasmine essential oil 0.25%, cordate houttuynia essential oil 2%, camphor 2%, aminotransferase 0.03%, active carbon 20%, polyvinyl alcohol 0.5%, Sodium Benzoate 0.4%, guar gum 0.2%, surplus is water.
Preparation method: the each component except active carbon is mixed, and active carbon is placed in to mixed solution soaks 48h, pull out, drain.
Embodiment 8
Repellent granule, component is methyl anthranilate 30%, semen brassicae 0.3%, cordate houttuynia essential oil 1.5%, camphor 2.5%, methyl cinnamate 0.3%, aminotransferase 0.04%, active carbon 30%, polyvinyl alcohol 0.35%, Sodium Benzoate 0.35%, guar gum 0.25%, surplus is water.
Preparation method: the each component except active carbon is mixed, and active carbon is placed in to mixed solution soaks 72h, pull out, drain.
Embodiment 9
Repellent granule, component is methyl anthranilate 40%, semen brassicae 0.4%, Jasmine essential oil 0.1%, cordate houttuynia essential oil 1.2%, methyl cinnamate 0.4%, aminotransferase 0.07%, active carbon 25%, polyvinyl alcohol 0.45%, Sodium Benzoate 0.5%, guar gum 0.35%, surplus is water.
Preparation method: the each component except active carbon is mixed, and active carbon is placed in to mixed solution soaks 55h, pull out, drain.
Embodiment 10
Repellent granule, component is methyl anthranilate 25%, semen brassicae 0.5%, Jasmine essential oil 0.5%, camphor 4.5%, methyl cinnamate 0.5%, aminotransferase 0.065%, active carbon 35%, polyvinyl alcohol 0.4%, Sodium Benzoate 0.3%, guar gum 0.45%, surplus is water.
Preparation method: the each component except active carbon is mixed, and active carbon is placed in to mixed solution soaks 68h, pull out, drain.
Comparative example 1
Be not add semen brassicae with the difference of embodiment 1, other is identical.
Comparative example 2
Be not add semen brassicae with the difference of embodiment 6, other is identical.
Feed magpie test of embodiment 1～10 and comparative example 1～2:
Processing method:
By the bird mouse repellant of embodiment 1～10 and comparative example's 1～2 preparation, cereal (wheat) is dressed seed.By etc. quantity wheat seed be seeded in homalographic soil, observe the surplus of seed after different number of days.Blank test is that wheat is left intact.
Result of the test, as shown in Table 1 and Table 2:
The table 1 repellent microemulsion magpie result of the test of feeding
As can be seen from Table 1:
1, in conjunction with comparative example 1 and embodiment 1 result of the test, can find out, semen brassicae is applied to birds homopterous insect repellent microemulsion, can significantly improve repellent effect.
2, in conjunction with the embodiments 1～5 the result of the test of comparative example 1 and blank test,, can find out, sense of smell type birds homopterous insect repellant of the present invention, birds homopterous insect is had to significant repellent effect, effectively repellent birds homopterous insect, meanwhile, environmental sound, belongs to safe and harmless type repellent product truly.Because it has the sustained-release materials of special odor, trigeminal neuralgia (equilibrium nerve) and nervous centralis to birds and lepidopterous insects stimulate, and allow birds and homopterous insect disequilibrium, produce frightened, and recognize danger and flee from, thereby reach repellent effect.
Yuan's 2 repellent granules magpie result of the test of feeding
As can be seen from Table 2:
1, in conjunction with comparative example 2 and embodiment 6 result of the tests, can find out, semen brassicae is applied to birds homopterous insect repellent granule, can significantly improve repellent effect.
2, in conjunction with the embodiments 6～10 the result of the test of comparative example 2 and blank test,, can find out, sense of smell type birds homopterous insect repellant of the present invention, birds homopterous insect is had to significant repellent effect, effectively repellent birds homopterous insect, meanwhile, environmental sound, belongs to safe and harmless type repellent product truly.
Above content is only made for the present invention giving an example and explanation; affiliated those skilled in the art make various amendments to described specific embodiment or supplement or adopt similar mode to substitute; only otherwise depart from the design of invention or surmount this scope as defined in the claims, all should belong to protection scope of the present invention.
Claims (8)
1. the repellant compositions of sense of smell type birds homopterous insect, it is characterized in that, in total weight percent, active ingredient is methyl anthranilate 10～50%, semen brassicae 0.2～0.6%, Jasmine essential oil 0.1～0.5%, cordate houttuynia essential oil 1～2%, camphor 2～5% and methyl cinnamate 0.3～0.7%; Surplus is water and auxiliary agent.
2. birds homopterous insect repellant, the aqueous emulsion of making according to composition described in claim 1, microemulsion, missible oil, granule or paste.
3. birds homopterous insect repellant as claimed in claim 2, is characterized in that, formulation is microemulsion.
4. birds homopterous insect repellant as claimed in claim 2, is characterized in that, formulation is granule.
5. birds homopterous insect repellent microemulsion as claimed in claim 3, it is characterized in that, in total weight percent, described auxiliary agent is made up of following component, neopelex 2～3%, glycerine 3～5%, Sodium Benzoate 0.3～0.5%, guar gum 0.2～0.5%, emulsifier 10～12%.
6. prepare the method for birds homopterous insect repellent microemulsion as claimed in claim 5, it is characterized in that, step is as follows:
(1), by active ingredient mix and blend, heating for dissolving, make oil phase;
(2), by water, auxiliary agent mixing and stirring;
(3), (1) is slowly added in (2), stir emulsification pretreatment, sampling, inspection, to obtain final product.
7. birds homopterous insect repellent granule as claimed in claim 4, it is characterized in that, in total weight percent, described auxiliary agent is made up of following component, aminotransferase 0.03～0.09%, active carbon 20～40%, polyvinyl alcohol 0.3～0.5%, Sodium Benzoate 0.3～0.5%, guar gum 0.2～0.5%.
8. prepare the method for birds homopterous insect repellent granule as claimed in claim 7, it is characterized in that, step is as follows: the each component except active carbon is mixed, and active carbon is placed in to mixed solution soaks 48～72h, pull out, drain.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201210292757.3A CN102771518B (en) | 2012-08-14 | 2012-08-14 | Granules and microemulsion for repelling olfactory birds and lepidoptera insets and preparation method of granules and microemulsion |
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| CN201210292757.3A CN102771518B (en) | 2012-08-14 | 2012-08-14 | Granules and microemulsion for repelling olfactory birds and lepidoptera insets and preparation method of granules and microemulsion |
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| CN102771518A CN102771518A (en) | 2012-11-14 |
| CN102771518B true CN102771518B (en) | 2014-07-23 |
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| CN103147230A (en) * | 2013-03-20 | 2013-06-12 | 武汉纺织大学 | Fully-degradable bird-repelling agricultural non-woven fabric and preparation method for same |
| CN103355295B (en) * | 2013-07-25 | 2014-10-15 | 西安高科理化技术有限责任公司 | Emulsion bird repellent and preparation method and use thereof |
| CN104285990B (en) * | 2014-10-09 | 2016-03-02 | 安徽农业大学 | A kind of composite bird repellent containing carbosulfan, methyl anthranilate and benzyl acetate |
| CN104844110A (en) * | 2015-04-23 | 2015-08-19 | 铜陵祥云消防科技有限责任公司 | Heat insulation and flame retardation material for bird-proof exterior walls |
| CN104861664A (en) * | 2015-04-23 | 2015-08-26 | 铜陵祥云消防科技有限责任公司 | Bird pecking-proofing fireproof jam material and preparation method thereof |
| CN108378015A (en) * | 2018-02-24 | 2018-08-10 | 王鹏飞 | A kind of coating method of particle bird repellent |
| CN109897533A (en) * | 2019-03-16 | 2019-06-18 | 山东申烨电气科技有限公司 | A kind of anti-bird coating of RTV and preparation method thereof |
| CN113662018A (en) * | 2021-09-18 | 2021-11-19 | 西安为开化工科技有限公司 | Repellent for bat and small birds and preparation method thereof |
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| CN1220577A (en) * | 1996-05-28 | 1999-06-23 | 拜尔公司 | Siloxane elastomers with insecticidal effect |
| CN101361495A (en) * | 2008-09-25 | 2009-02-11 | 黄山市双宝科技应用有限公司 | Bird driving composition and colloid mixture thereof, suspending agent and preparation method thereof |
| CN101715763A (en) * | 2008-10-09 | 2010-06-02 | 河南农业大学 | Lasioderma serricorne (Fabricius) repellant |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| US20120039973A1 (en) * | 2010-08-11 | 2012-02-16 | Paul Grlica | Composition and method of time releasing essential oils for animal repellency and pesticide use |
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Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1220577A (en) * | 1996-05-28 | 1999-06-23 | 拜尔公司 | Siloxane elastomers with insecticidal effect |
| CN101361495A (en) * | 2008-09-25 | 2009-02-11 | 黄山市双宝科技应用有限公司 | Bird driving composition and colloid mixture thereof, suspending agent and preparation method thereof |
| CN101715763A (en) * | 2008-10-09 | 2010-06-02 | 河南农业大学 | Lasioderma serricorne (Fabricius) repellant |
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