CN104365591B - A kind of pesticide synergistic agent, preparation method and application thereof - Google Patents
A kind of pesticide synergistic agent, preparation method and application thereof Download PDFInfo
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- CN104365591B CN104365591B CN201410568831.9A CN201410568831A CN104365591B CN 104365591 B CN104365591 B CN 104365591B CN 201410568831 A CN201410568831 A CN 201410568831A CN 104365591 B CN104365591 B CN 104365591B
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Abstract
The invention provides a kind of pesticide synergistic agent, preparation method and application, with esterified vegetable oil, emulsifier, extract of soybean, penetrating solvent is the environmental-protecting and high-efficient type pesticide synergistic agent of raw material.Specifically by extract of soybean, high-effective penetrating green solvent, emulsifier and esterified vegetable oil mix according to a certain percentage makes stable preparation.Pesticide synergistic agent of the present invention is applicable to use mixed with the insecticide of various formulation, bactericide, weed killer herbicide and foliage fertilizer bucket, has the characteristic of significant synergy, saving of labor, water saving, province's medicine.Spraying in process of agricultural chemicals, there is good permeability, autgmentability.
Description
Technical field
The present invention relates to preparation method and the application of a kind of pesticide synergistic agent and pesticide synergistic agent, belong to pesticide processing field.
Background technology
Insecticides adjuvant itself does not generally have biologically active in the processing of the formulations of pesticide with in using, but in form formula or dispenser time be indispensable additive.Often kind of insecticides adjuvant has specific function: what have plays the former medicine of dilution; The former medicine that helps had is evenly dispersed in preparation; What have anti-tablet can drip cohesion change greatly; The wettability of the increased particle had, adhesiveness or permeability; The decomposition of the prevented active ingredient had; The safety of the increased dispenser had, etc.In a word, the function of insecticides adjuvant, nothing more than physics or the chemical property of improving agricultural chemicals, plays drug effect to greatest extent or contributes to safe dispenser.Insecticides adjuvant develops with the progress of formulation and pesticide application technology.Early stage inorganic pesticide seldom makes used additives.After organic Agrochemicals, various auxiliary agent also grows up thereupon.Along with the variation of formulation and the raising of performance, auxiliary agent also develops to multi items, seriation, to adapt to the needs of different pesticide species different dosage form processing.
Pesticidal products is jointly made up of former medicine and auxiliary agent, and current China insecticides adjuvant is various in style, about has kind more than 4000, and insecticides adjuvant annual requirement is approximately 400,000-50 ten thousand tons.The 1%-90% that the content of auxiliary agent has accounted for Pesticidal products not etc., is not apparent on impact that is biological and environment.
The success of an agricultural chemicals, half is formulation.By to Pesticide formulation, a small amount of medicament can be evenly distributed in wide farmland, play the effect of agricultural chemicals to greatest extent; Overcome the weak point of agricultural chemicals, improve the safety of user; Reduce the pressure to environment, improve operating characteristics, promote the function of existing medicament.Although conventional adjuvants has certain lifting to agricultural chemicals quality, a large amount of traditional insecticides adjuvant used has contaminated environment at present, technical indicator falls behind, the problem of function singleness.Research and develop a kind of environment-friendly high-efficiency wide spectrum bucket to mix pesticide synergistic agent and become a very important task.
Summary of the invention
The pesticide synergistic agent that the present invention relates to is with esterified vegetable oil, emulsifier, extract of soybean, and high-effective penetrating green solvent is a kind of environmental-protecting and high-efficient type pesticide synergistic agent prepared by raw material.
The object of the invention is to the problem for traditional insecticides adjuvant contaminated environment, technical indicator backwardness, function singleness, provide a kind of with esterified vegetable oil, emulsifier, extract of soybean, high-effective penetrating green solvent is a kind of environmental-protecting and high-efficient type pesticide synergistic agent prepared by raw material.By weight, penetrating solvent 5-15 part, extract of soybean 5-70 part, esterified vegetable oil 5-20 part, emulsifier 5-30 part.
Described penetrating solvent is one or more mixtures in 1-METHYLPYRROLIDONE, N-ethyl pyrrolidone, NOP, N-dodecylpyrrolidone, DMF, DMA.Being preferably penetrating solvent is 1-METHYLPYRROLIDONE and/or N-ethyl pyrrolidone.
Described extract of soybean is soybean lecithin and/or isoflavones.More preferably soybean lecithin.
Described esterified vegetable oil is methylated vegetable oil and/or ethyl esterified vegetable oil.More preferably methylated vegetable oil.
Described emulsifier comprises cationic surfactant, anion surfactant or non-ionic surface active agent, and its cationic surfactant comprises alkylammonium salt or alkyl quaternary ammonium salts; Anion surfactant comprises alkylbenzenesulfonate, alkylnaphthalene sulfonate or aliphatic alcohol sulfate; Non-ionic surface active agent comprise in fatty alcohol-polyoxyethylene ether, alkylphenol polyoxyethylene, phenethyl phenol polyethenoxy ether, Ben-zylphenol Polyoxyethyl Ether, castor oil polyoxyethylene ether one or more.
Being optimized for non-ionic surface active agent is further one or more in agriculture breast 300, agriculture breast 400, agriculture breast 600, agriculture breast 601, agriculture breast 602, agriculture breast 1600, AEO-3, AEO-5, AEO-7, EL-20, EL-40, EL-80.
The present invention also provides a kind of bucket to mix the preparation method of pesticide synergistic agent, and by penetrating solvent, extract of soybean, esterified vegetable oil joins successively in reactor and stirs 1-2h to evenly, then adds emulsifier, is stirred to transparently to obtain pesticide synergistic agent.The formulation of described pesticide synergistic agent is missible oil, oil-suspending agent, aerosol or spray.
Described esterified vegetable oil is now with the current, and the preparation method of esterified vegetable oil is that described lower alcohol is methyl alcohol or ethanol by obtained after crude vegetal and lower alcohol generation alcoholysis reaction.
The present invention also provides a kind of bucket to mix pesticide synergistic agent to prepare the application on insecticide, miticide, bactericide, weed killer herbicide or foliage fertilizer.
The present invention, as pesticide synergistic agent, and has following remarkable advantage after combined use of pesticides:
1. adopt vegetable oil and soybean lecithin as raw material, derive from green plants, have better compatibility with plant, comparatively mineral oil based is higher to plant safety.
2. adopt green Thief zone solvent, plant leaf surface wax coat can be dissolved, strengthen infiltration, penetration enhancement.
3. can improve liquid adhesive capacity, make to be used with agricultural chemicals resistance of rainwater washing against, under extreme climate environment, efficacy stability.
4. raw materials used source and natural green plant, comparatively conventional mineral oil base has easily biological-degradable, without poisoning feature.
5. soybean lecithin contains a large amount of phytosterol, has synergistic effect to plant growth.
6. only needing very little spray amount just can obtain desirable spray effect as a kind of agricultural spray adjuvants, dispenser water can be saved when spraying insecticide.So both can cut the waste, again reduce the pesticide volume be lost in soil and groundwater, and then decrease the residue of pesticide in environment.It has complied with the trend of environmental protection type agricultural chemical development, becomes the first-selected auxiliary agent of environment friendly agricultural.
Embodiment
The present invention is further illustrated for following examples
Embodiment 1
First by 1-METHYLPYRROLIDONE, soybean lecithin, methylated vegetable oil, joins in reactor and stirs under normal temperature, then add AEO-3 and EL-80, is stirred to the transparent pesticide barrel that obtains and mixes synergist.
Described each component proportion is: 1-METHYLPYRROLIDONE 8 parts, soybean lecithin 57 parts, methylated vegetable oil 15 parts, AEO-315 part, EL-805 part.
Embodiment 2
First by N-ethyl pyrrolidone, soybean lecithin, methylated vegetable oil, joins in reactor and stirs under normal temperature, then add AEO-5, is stirred to the transparent pesticide barrel that obtains and mixes synergist.
Described each component proportion is: N-ethyl pyrrolidone 15 parts, soybean lecithin 40 parts, methylated vegetable oil 20 parts, AEO-525 part.
Embodiment 3
First by 1-METHYLPYRROLIDONE, soybean lecithin, ethyl esterified vegetable oil, joins in reactor and stirs under normal temperature, then add AEO-5 and EL-80, is stirred to the transparent pesticide barrel that obtains and mixes synergist.
Described each component proportion is: 1-METHYLPYRROLIDONE 10 parts, soybean lecithin 60 parts, methylated vegetable oil 10 parts, AEO-512 part, EL-808 part.
Embodiment 4
First by NOP, soybean lecithin, methylated vegetable oil, joins in reactor and stirs under normal temperature, then add AEO-7 and EL-20, is stirred to the transparent pesticide barrel that obtains and mixes synergist.
Described each component proportion is: NOP 5 parts, soybean lecithin 55 parts, methylated vegetable oil 14 parts, AEO-710 part, EL-2010 part.
Embodiment 5
First by NOP, isoflavones, ethyl esterified vegetable oil, joins in reactor and stirs under normal temperature, then add lauryl ammonium chloride, is stirred to the transparent pesticide barrel that obtains and mixes synergist.
Described each component proportion is: NOP 8 parts, isoflavones 63 parts, ethyl esterified vegetable oil 16.5 parts, lauryl ammonium chloride 12.5 parts.
Embodiment 6
First by N-dodecylpyrrolidone, isoflavones, ethyl esterified vegetable oil, joins in reactor and stirs under normal temperature, then adds calcium dodecyl benzene sulfonate and agriculture breast 400, is stirred to the transparent pesticide barrel that obtains and mixes synergist.Described each component proportion is: NOP 16 parts, soybean lecithin 53 parts, methylated vegetable oil 16 parts, calcium dodecyl benzene sulfonate 7.5 parts and agriculture breast 4007.5 parts.
Embodiment 7
First by DMA, soybean lecithin, methylated vegetable oil, joins in reactor and stirs under normal temperature, then add ethoxylated alkyl sulfate, is stirred to the transparent pesticide barrel that obtains and mixes synergist.
Described each component proportion is: DMA 12 parts, soybean lecithin 65 parts, methylated vegetable oil 8 parts, ethoxylated alkyl sulfate 15 parts.
Embodiment 8
First by 1-METHYLPYRROLIDONE, isoflavones, methylated vegetable oil, joins in reactor and stirs under normal temperature, then adds methyl naphthalene sulfonic acid sodium, EL-80, is stirred to the transparent pesticide barrel that obtains and mixes synergist.
Described each component proportion is: 1-METHYLPYRROLIDONE 15 parts, isoflavones 8 parts, methylated vegetable oil 20 parts, methyl naphthalene sulfonic acid sodium 12.3, EL-8017.7 part.
Embodiment 9
First by N-ethyl pyrrolidone, isoflavones, ethyl esterified vegetable oil, joins in reactor and stirs under normal temperature, then adds agriculture breast 601, AEO-5 and EL-40, is stirred to the transparent pesticide barrel that obtains and mixes synergist.
Described each component proportion is: N-ethyl pyrrolidone 9 parts, isoflavones 55 parts, ethyl esterified vegetable oil 14 parts, agriculture breast 6016 parts, AEO-58 part, EL-408 part.
Embodiment 10
First by N-ethyl pyrrolidone, NOP, soybean lecithin, isoflavones, methylated vegetable oil, joins in reactor and stirs under normal temperature, then adds agriculture breast 600 and AEO-3, is stirred to the transparent pesticide barrel that obtains and mixes synergist.
Described each component proportion is: N-ethyl pyrrolidone 12 parts, NOP 3 parts, soybean lecithin 23 parts, isoflavones 35 parts, methylated vegetable oil 13 parts, agriculture breast 7 parts, AEO-310 part.
Embodiment 11
First by DMA, 1-METHYLPYRROLIDONE, soybean lecithin, methylated vegetable oil, joins in reactor and stirs under normal temperature, then add AEO-3 and EL-40, is stirred to the transparent pesticide barrel that obtains and mixes synergist.
Described each component proportion is: DMA 9 parts, 1-METHYLPYRROLIDONE 5 parts, soybean lecithin 56 parts, methylated vegetable oil 18 parts, AEO-38 part, EL-404 part.
Embodiment 12
First by DMA, isoflavones, soybean lecithin, methylated vegetable oil, joins in reactor and stirs under normal temperature, then adds agriculture breast 300, AEO-7 and EL-80, is stirred to the transparent pesticide barrel that obtains and mixes synergist.
Described each component proportion is: NOP 13 parts, isoflavones 25 parts, soybean lecithin 35 parts, methylated vegetable oil 15 parts, agriculture breast 3005 parts, AEO-73 part, EL-809 part.
Embodiment 13
First by 1-METHYLPYRROLIDONE, N-ethyl pyrrolidone, soybean lecithin, isoflavones, methylated vegetable oil, joins in reactor and stirs under normal temperature, then add AEO-7 and EL-20, is stirred to the transparent pesticide barrel that obtains and mixes synergist.
Described each component proportion is 1-METHYLPYRROLIDONE 8 parts, N-ethyl pyrrolidone 7 parts, soybean lecithin 22 parts, isoflavones 33 parts, methylated vegetable oil 17 parts, AEO-74 part, EL-809 part.
Embodiment 14
First by DMF, isoflavones, soybean lecithin, methylated vegetable oil, joins in reactor and stirs under normal temperature, then add AEO-3 and EL-20, is stirred to the transparent pesticide barrel that obtains and mixes synergist.
Described each component proportion is: DMF 14 parts, isoflavones 36 parts, soybean lecithin 18 parts, methylated vegetable oil 27 parts, AEO-310 part, EL-205 part.
Embodiment 15
First by N-dodecylpyrrolidone, soybean lecithin, isoflavones, methylated vegetable oil, joins in reactor and stirs under normal temperature, then add AEO-5 and EL-20, is stirred to the transparent pesticide barrel that obtains and mixes synergist.
Described each component proportion is: N-dodecylpyrrolidone 5 parts, soybean lecithin 15 parts, isoflavones 35 parts, methylated vegetable oil 20 parts, AEO-512 part, EL-2013 part.
Embodiment 16
First by DMF, soybean lecithin, esterified vegetable oil, joins in reactor and stirs under normal temperature, then add AEO-3 and EL-80, is stirred to the transparent pesticide barrel that obtains and mixes synergist.
Described each component proportion is: DMF 6 parts, soybean lecithin 70 parts, ethyl esterified vegetable oil 8 parts, AEO-36 part, EL-8010 part.
What finally illustrate is, above embodiment is only in order to illustrate technical scheme of the present invention and unrestricted, although with reference to preferred embodiment to invention has been detailed description, those of ordinary skill in the art is to be understood that, can modify to technical scheme of the present invention or equivalent replacement, and not departing from aim and the scope of technical solution of the present invention, it all should be encompassed in the middle of right of the present invention.
Claims (4)
1. a pesticide synergistic agent, is characterized in that, the raw material of this barrel of mixed pesticide synergistic agent comprises NOP 8 parts, isoflavones 63 parts, ethyl esterified vegetable oil 16.5 parts, lauryl ammonium chloride 12.5 parts.
2. a pesticide synergistic agent, is characterized in that, the raw material of this barrel of mixed pesticide synergistic agent comprises 1-METHYLPYRROLIDONE 15 parts, isoflavones 8 parts, methylated vegetable oil 20 parts, methyl naphthalene sulfonic acid sodium 12.3, EL-8017.7 part.
3. a pesticide synergistic agent, is characterized in that, the raw material of this barrel of mixed pesticide synergistic agent is N-ethyl pyrrolidone 9 parts, isoflavones 55 parts, ethyl esterified vegetable oil 14 parts, agriculture breast 6016 parts, AEO-58 part, EL-408 part.
4. a pesticide synergistic agent, is characterized in that, the raw material of this barrel of mixed pesticide synergistic agent is NOP 13 parts, isoflavones 25 parts, soybean lecithin 35 parts, methylated vegetable oil 15 parts, agriculture breast 3005 parts, AEO-73 part, EL-809 part.
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| CN201410568831.9A CN104365591B (en) | 2014-10-23 | 2014-10-23 | A kind of pesticide synergistic agent, preparation method and application thereof |
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| CN201410568831.9A CN104365591B (en) | 2014-10-23 | 2014-10-23 | A kind of pesticide synergistic agent, preparation method and application thereof |
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| CN104365591B true CN104365591B (en) | 2016-04-06 |
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