CN103332832B - 一种泰乐菌素或罗红霉素生产废水处理系统及方法 - Google Patents
一种泰乐菌素或罗红霉素生产废水处理系统及方法 Download PDFInfo
- Publication number
- CN103332832B CN103332832B CN201310302999.0A CN201310302999A CN103332832B CN 103332832 B CN103332832 B CN 103332832B CN 201310302999 A CN201310302999 A CN 201310302999A CN 103332832 B CN103332832 B CN 103332832B
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- China
- Prior art keywords
- water
- tylosin
- roxithromycin
- communicated
- treatment
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Links
- 229930194936 Tylosin Natural products 0.000 title claims abstract description 30
- 239000004182 Tylosin Substances 0.000 title claims abstract description 30
- WBPYTXDJUQJLPQ-VMXQISHHSA-N tylosin Chemical compound O([C@@H]1[C@@H](C)O[C@H]([C@@H]([C@H]1N(C)C)O)O[C@@H]1[C@@H](C)[C@H](O)CC(=O)O[C@@H]([C@H](/C=C(\C)/C=C/C(=O)[C@H](C)C[C@@H]1CC=O)CO[C@H]1[C@@H]([C@H](OC)[C@H](O)[C@@H](C)O1)OC)CC)[C@H]1C[C@@](C)(O)[C@@H](O)[C@H](C)O1 WBPYTXDJUQJLPQ-VMXQISHHSA-N 0.000 title claims abstract description 30
- 229960004059 tylosin Drugs 0.000 title claims abstract description 30
- 235000019375 tylosin Nutrition 0.000 title claims abstract description 30
- RXZBMPWDPOLZGW-XMRMVWPWSA-N (E)-roxithromycin Chemical compound O([C@@H]1[C@@H](C)C(=O)O[C@@H]([C@@]([C@H](O)[C@@H](C)C(=N/OCOCCOC)/[C@H](C)C[C@@](C)(O)[C@H](O[C@H]2[C@@H]([C@H](C[C@@H](C)O2)N(C)C)O)[C@H]1C)(C)O)CC)[C@H]1C[C@@](C)(OC)[C@@H](O)[C@H](C)O1 RXZBMPWDPOLZGW-XMRMVWPWSA-N 0.000 title claims abstract description 28
- 229960005224 roxithromycin Drugs 0.000 title claims abstract description 28
- 238000004065 wastewater treatment Methods 0.000 title claims abstract description 16
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 15
- 238000000034 method Methods 0.000 title claims description 27
- 239000002351 wastewater Substances 0.000 claims abstract description 47
- 239000010802 sludge Substances 0.000 claims abstract description 35
- 238000003860 storage Methods 0.000 claims abstract description 35
- 230000020477 pH reduction Effects 0.000 claims abstract description 22
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 15
- 230000001105 regulatory effect Effects 0.000 claims abstract description 10
- 239000006228 supernatant Substances 0.000 claims abstract description 9
- 238000002203 pretreatment Methods 0.000 claims abstract description 7
- 230000003647 oxidation Effects 0.000 claims abstract description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 57
- 239000000126 substance Substances 0.000 claims description 22
- 239000002562 thickening agent Substances 0.000 claims description 21
- 239000000945 filler Substances 0.000 claims description 16
- 238000005188 flotation Methods 0.000 claims description 13
- 230000007062 hydrolysis Effects 0.000 claims description 13
- 238000006460 hydrolysis reaction Methods 0.000 claims description 13
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 12
- XKMRRTOUMJRJIA-UHFFFAOYSA-N ammonia nh3 Chemical compound N.N XKMRRTOUMJRJIA-UHFFFAOYSA-N 0.000 claims description 9
- 229940079593 drug Drugs 0.000 claims description 9
- 239000003814 drug Substances 0.000 claims description 9
- 239000007788 liquid Substances 0.000 claims description 9
- 238000012856 packing Methods 0.000 claims description 9
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 8
- 238000000926 separation method Methods 0.000 claims description 8
- 230000000694 effects Effects 0.000 claims description 7
- 229920002401 polyacrylamide Polymers 0.000 claims description 7
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 claims description 7
- 238000010521 absorption reaction Methods 0.000 claims description 5
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 claims description 4
- 229910021529 ammonia Inorganic materials 0.000 claims description 4
- 230000001580 bacterial effect Effects 0.000 claims description 4
- 230000003197 catalytic effect Effects 0.000 claims description 4
- 238000004140 cleaning Methods 0.000 claims description 4
- 238000006477 desulfuration reaction Methods 0.000 claims description 4
- 239000007789 gas Substances 0.000 claims description 4
- 239000008187 granular material Substances 0.000 claims description 4
- 238000010438 heat treatment Methods 0.000 claims description 4
- 229910000037 hydrogen sulfide Inorganic materials 0.000 claims description 4
- 150000003384 small molecules Chemical class 0.000 claims description 4
- 239000002699 waste material Substances 0.000 claims description 4
- 238000013467 fragmentation Methods 0.000 claims 1
- 238000006062 fragmentation reaction Methods 0.000 claims 1
- 238000004062 sedimentation Methods 0.000 abstract description 5
- 230000003301 hydrolyzing effect Effects 0.000 abstract 5
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 5
- 229960001763 zinc sulfate Drugs 0.000 description 5
- 229910000368 zinc sulfate Inorganic materials 0.000 description 5
- 239000003570 air Substances 0.000 description 3
- 230000009189 diving Effects 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 230000003115 biocidal effect Effects 0.000 description 2
- DKPFZGUDAPQIHT-UHFFFAOYSA-N butyl acetate Chemical group CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 2
- 238000010790 dilution Methods 0.000 description 2
- 239000012895 dilution Substances 0.000 description 2
- 239000010815 organic waste Substances 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 230000003385 bacteriostatic effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000013043 chemical agent Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000005008 domestic process Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000002957 persistent organic pollutant Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 231100000167 toxic agent Toxicity 0.000 description 1
- 239000003440 toxic substance Substances 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
Landscapes
- Physical Water Treatments (AREA)
Abstract
Description
Claims (6)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201310302999.0A CN103332832B (zh) | 2013-07-18 | 2013-07-18 | 一种泰乐菌素或罗红霉素生产废水处理系统及方法 |
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CN201310302999.0A CN103332832B (zh) | 2013-07-18 | 2013-07-18 | 一种泰乐菌素或罗红霉素生产废水处理系统及方法 |
Publications (2)
Publication Number | Publication Date |
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CN103332832A CN103332832A (zh) | 2013-10-02 |
CN103332832B true CN103332832B (zh) | 2015-06-17 |
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CN201310302999.0A Active CN103332832B (zh) | 2013-07-18 | 2013-07-18 | 一种泰乐菌素或罗红霉素生产废水处理系统及方法 |
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Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN106746105A (zh) * | 2016-11-18 | 2017-05-31 | 安徽菁硕科技有限公司 | 一种酶解液脱氨的方法 |
CN108751625B (zh) * | 2018-08-20 | 2023-12-29 | 兴源环境科技股份有限公司 | 一种发酵类抗生素废水的处理系统及工艺 |
Family Cites Families (3)
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CN102616992B (zh) * | 2012-03-29 | 2013-12-11 | 南京大学 | 一种去除污水中抗生素抗性基因的方法 |
CN102649592B (zh) * | 2012-05-02 | 2014-09-10 | 平湖美嘉保温容器工业有限公司 | 用于去除饮用水中大环内酯类抗生素的过滤介质及制法 |
CN103011526B (zh) * | 2012-12-23 | 2014-12-31 | 山东新时代药业有限公司 | 一种硫氰酸红霉素废水的处理方法 |
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Address after: 250101, Shandong Province, Ji'nan hi tech Zone, No. 554 Feng Feng Road, environmental science and Technology Park, building 8, Feng Feng building, room 532 Patentee after: SHANDONG PACIFIC ENVIRONMENTAL PROTECTION CO.,LTD. Address before: 250101, 5 floor, environmental science and Technology Park, No. 554 Feng Feng Road, hi tech Zone, Shandong, Ji'nan Patentee before: Shandong Pacific Environmental Protection Co.,Ltd. |
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PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: A wastewater treatment system and method for tylosin or roxithromycin production Effective date of registration: 20230117 Granted publication date: 20150617 Pledgee: Industrial Bank Co.,Ltd. Jinan Branch Pledgor: SHANDONG PACIFIC ENVIRONMENTAL PROTECTION CO.,LTD. Registration number: Y2023980031487 |
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PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
PC01 | Cancellation of the registration of the contract for pledge of patent right |
Granted publication date: 20150617 Pledgee: Industrial Bank Co.,Ltd. Jinan Branch Pledgor: SHANDONG PACIFIC ENVIRONMENTAL PROTECTION CO.,LTD. Registration number: Y2023980031487 |
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PC01 | Cancellation of the registration of the contract for pledge of patent right | ||
PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: A wastewater treatment system and method for the production of Tylosin or Roxithromycin Granted publication date: 20150617 Pledgee: Postal Savings Bank of China Limited Jinan Branch Pledgor: SHANDONG PACIFIC ENVIRONMENTAL PROTECTION CO.,LTD. Registration number: Y2024980011192 |
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PE01 | Entry into force of the registration of the contract for pledge of patent right |